CN205209947U - Advance infrared liquid sample cell device of pattern and infrared sample cell in succession - Google Patents
Advance infrared liquid sample cell device of pattern and infrared sample cell in succession Download PDFInfo
- Publication number
- CN205209947U CN205209947U CN201520906118.0U CN201520906118U CN205209947U CN 205209947 U CN205209947 U CN 205209947U CN 201520906118 U CN201520906118 U CN 201520906118U CN 205209947 U CN205209947 U CN 205209947U
- Authority
- CN
- China
- Prior art keywords
- sample
- opening
- cell body
- cell
- infrared
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 77
- 210000004027 cell Anatomy 0.000 claims abstract description 71
- 210000005056 cell body Anatomy 0.000 claims abstract description 63
- 239000000463 material Substances 0.000 claims abstract description 17
- 230000005540 biological transmission Effects 0.000 claims abstract description 10
- 230000002572 peristaltic effect Effects 0.000 claims description 25
- 238000000034 method Methods 0.000 claims description 23
- 238000005070 sampling Methods 0.000 claims description 20
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims description 7
- 229910001634 calcium fluoride Inorganic materials 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- 239000004033 plastic Substances 0.000 claims description 4
- 238000003466 welding Methods 0.000 claims description 4
- 238000009434 installation Methods 0.000 claims description 3
- 238000012360 testing method Methods 0.000 abstract description 2
- 230000010354 integration Effects 0.000 abstract 1
- 238000001514 detection method Methods 0.000 description 12
- 238000007789 sealing Methods 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 9
- 238000010586 diagram Methods 0.000 description 8
- 125000000524 functional group Chemical group 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 238000004566 IR spectroscopy Methods 0.000 description 4
- 238000002329 infrared spectrum Methods 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000004476 mid-IR spectroscopy Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 239000010813 municipal solid waste Substances 0.000 description 1
- 239000012454 non-polar solvent Substances 0.000 description 1
- -1 polytetrafluoroethylene Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 238000004451 qualitative analysis Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Optical Measuring Cells (AREA)
- Investigating Or Analysing Materials By Optical Means (AREA)
Abstract
Description
技术领域 technical field
本实用新型涉及红外光谱检测分析所使用的仪器设备,尤其涉及一种液体样品红外光谱检测分析所使用的样品容置装置。 The utility model relates to instruments and equipment used for infrared spectrum detection and analysis, in particular to a sample holding device used for infrared spectrum detection and analysis of liquid samples.
背景技术 Background technique
红外光谱(InfraredSpectroscopy,IR)的研究始于20世纪初,自1940年红外光谱仪问世,红外光谱在有机化学研究中广泛应用。在有机物分子中,组成化学键或官能团的原子处于不断振动的状态,其振动频率与红外光的振动频率相当。所以,用红外光照射有机物分子时,分子中的化学键或官能团可发生振动吸收,不同的化学键或官能团吸收频率不同,在红外光谱上将处于不同位置,从而可获得分子中含有何种化学键或官能团的信息。 Infrared spectroscopy (Infrared Spectroscopy, IR) research began in the early 20th century, since the advent of infrared spectrometer in 1940, infrared spectroscopy has been widely used in organic chemistry research. In organic molecules, the atoms that make up chemical bonds or functional groups are in a state of constant vibration, and its vibration frequency is comparable to that of infrared light. Therefore, when organic molecules are irradiated with infrared light, the chemical bonds or functional groups in the molecules can undergo vibrational absorption. Different chemical bonds or functional groups have different absorption frequencies and will be in different positions on the infrared spectrum, so that the chemical bonds or functional groups contained in the molecule can be obtained. Information.
所以为了获得有机物分子的化学键或官能团信息,常常需要对其进行红外光谱的测定。而对于液体样品,传统方法是利用液膜法,在实现本实用新型的过程中,发明人发现其存在如下问题,液膜法仅适用于非挥发性的样品,非极性溶剂接触角太小,不易形成液膜,采用上述装置难以制样;并且由于人工操作的不确定性,得到的结果误差比较大,往往只能用于定性分析。 Therefore, in order to obtain the information of chemical bonds or functional groups of organic molecules, it is often necessary to measure them by infrared spectroscopy. For liquid samples, the traditional method is to utilize the liquid film method. In the process of realizing the utility model, the inventor finds that it has the following problems. The liquid film method is only suitable for non-volatile samples, and the contact angle of non-polar solvents is too small , it is not easy to form a liquid film, and it is difficult to prepare samples with the above-mentioned device; and due to the uncertainty of manual operation, the error of the obtained results is relatively large, and it can only be used for qualitative analysis.
近年来出现业内的技术人员陆续发明了固定液体样品池装置等用于红外检测的液体样品池装置,具体可以在如下文献中还可以发现更多与上述技术方案相关的信息: In recent years, technicians in the industry have successively invented liquid sample cell devices for infrared detection such as fixed liquid sample cell devices. Specifically, more information related to the above technical solutions can be found in the following documents:
申请号:201310235997.4,名称为“一种中红外光谱分析液体样品池”的中国专利申请文件; Application number: 201310235997.4, a Chinese patent application document titled "A Liquid Sample Cell for Mid-Infrared Spectroscopy Analysis";
申请号:201420761959.2,名称为“中红外光谱仪”的中国专利申请文件; Application number: 201420761959.2, a Chinese patent application document titled "Mid-infrared Spectrometer";
申请号:200920107183.1,名称为“红外光谱变温双液体样品池装置”的中国专利申请文件; Application number: 200920107183.1, a Chinese patent application document titled "Infrared spectrum variable temperature dual liquid sample cell device";
公开号:CN102706804A,名称为“远红外样品池”的中国专利申请文件; Publication number: CN102706804A, a Chinese patent application document titled "Far Infrared Sample Pool";
公开号:CN104646082A,名称为“恒温红外液体样品池”的中国专利申请文件; Publication number: CN104646082A, a Chinese patent application document titled "Constant Temperature Infrared Liquid Sample Cell";
公开号:CN204027995U,名称为“一种恒温样品池装置”的中国专利申请文件。 Publication number: CN204027995U, a Chinese patent application document titled "a constant temperature sample cell device".
从以上文件,可以发现,现有技术中的红外样品池装置基本结构包括:样品池本体,垫片与窗片,其中样品池本体为金属等材质制成,内设有容置垫片与窗片的凹部,窗片包括上窗片与下窗片,窗片通常由氟化钙等透红外线材料制成。上窗片与下窗片之间通过垫片隔开,垫片为O形等中空形状,在上窗片与下窗片之间的空隙用于放置待测的液体样品。在上、下窗片,垫片与样品池本体之间采用垫圈等结构对待测液体进行密封。在放置待测样品时,首先打开样品池本体,放置下窗片与垫片,然后滴入待测液体,盖上上窗片,然后合上样品池本体,通过样品池本体压紧上下窗口,准备好待测的液体样品池装置。 From the above documents, it can be found that the basic structure of the infrared sample cell device in the prior art includes: a sample cell body, a gasket and a window, wherein the sample cell body is made of metal and other materials, and there are accommodating gaskets and windows inside. The concave part of the sheet, the window includes an upper window and a lower window, and the window is usually made of infrared-transmitting materials such as calcium fluoride. The upper window and the lower window are separated by a gasket, which is a hollow shape such as an O shape, and the space between the upper window and the lower window is used to place the liquid sample to be measured. Between the upper and lower windows, the gasket and the sample cell body, gaskets and other structures are used to seal the liquid to be measured. When placing the sample to be tested, first open the sample cell body, place the lower window and gasket, then drop the liquid to be tested, cover the upper window, then close the sample cell body, press the upper and lower windows through the sample cell body, Prepare the liquid sample cell assembly to be tested.
在实现本实用新型的过程中,发明人发现近年来出现的固定液体样品池装置虽然可用于测量易挥发液体,但是整个装置存在装配比较复杂,窗片易损坏,液体膜厚不易控制,不易清洁等缺点,使其使用受到了限制。且人工取样单次操作耗时较长,无法提高采样频率达到实时跟踪监测反应池的目的。 In the process of realizing the utility model, the inventor found that although the fixed liquid sample pool device that appeared in recent years can be used to measure volatile liquids, the assembly of the whole device is relatively complicated, the windows are easily damaged, and the thickness of the liquid film is difficult to control and difficult to clean. and other shortcomings, so that its use has been limited. Moreover, manual sampling takes a long time for a single operation, and the sampling frequency cannot be increased to achieve the purpose of real-time tracking and monitoring of the reaction pool.
实用新型内容 Utility model content
为此,需要提供一种结构简单,方便使用,检测结果准确的红外液体样品池装置与红外样品池。 Therefore, it is necessary to provide an infrared liquid sample cell device and an infrared sample cell with simple structure, convenient use and accurate detection results.
为实现上述目的,发明人提供了一种连续进样式红外液体样品池装置,其特征在于,包括样品池、进样管、出样管与样品池支架; In order to achieve the above object, the inventor provides a continuous feeding infrared liquid sample cell device, which is characterized in that it includes a sample cell, a sample inlet tube, a sample outlet tube and a sample cell bracket;
所述样品池包括由透红外线材料制备的池体,池体顶面、底面、正面、背面与侧面密封,池体内设有容置待测样品之用的样品腔,池体的正面与背面为红外透射面,池体顶面设置有第一开口和第二开口,分别用于连接进样管和出样管,进样管的外壁与第一开口的内壁可插拔配合,出样管的外壁与第二开口的内壁可插拔配合,当进样管插接于第一开口中,以及出样管插接于第二开口中时,插接处液密封配合,所述第一开口和所述第二开口分别与样品腔导通; The sample cell includes a cell body made of infrared-transmitting material. The top, bottom, front, back and sides of the cell body are sealed. The cell body is provided with a sample cavity for accommodating the sample to be tested. Infrared transmission surface, the top surface of the cell body is provided with a first opening and a second opening, which are respectively used to connect the sampling tube and the sampling tube. The outer wall of the sampling tube is pluggable with the inner wall of the first opening. The outer wall is pluggably fitted with the inner wall of the second opening. When the sample inlet tube is plugged into the first opening and the sample outlet tube is plugged into the second opening, the plug joints are in a liquid-tight fit. The first opening and The second openings are respectively connected to the sample cavity;
所述样品池支架包括背板与定位槽,所述定位槽与背板相连接,定位槽的凹槽与样品池池体相适配,样品池池体与定位槽可插拔配合,定位槽的凹槽方向与背板平行,样品池池体插入定位槽后,样品池池体的正面与背面与背板平行,定位槽对应样品池池体正面与背面的位置,开设有第一透光部,背板对应样品池池体背面以及第一透光部的位置,开设有第二透光部。 The sample cell support includes a back plate and a positioning groove, the positioning groove is connected to the back plate, the groove of the positioning groove is compatible with the sample cell body, the sample cell body and the positioning groove can be plugged and matched, and the positioning groove The direction of the groove is parallel to the back plate. After the sample cell body is inserted into the positioning groove, the front and back of the sample cell body are parallel to the back plate. The positioning groove corresponds to the position of the front and back of the sample cell body. The back plate corresponds to the position of the back of the sample cell body and the first light-transmitting part, and a second light-transmitting part is opened.
可选的,所述池体外轮廓为长方体,所述池体为氟化钙材料,定位槽呈U形结构。 Optionally, the outer contour of the pool is a cuboid, the pool body is made of calcium fluoride material, and the positioning groove is in a U-shaped structure.
可选的,所述进样管和出样管分别包括连接头与连接管,所述进样管通过连接头的一端与第一开口可插拔配合,所述出样管通过连接头的一端与第二开口可插拔配合,连接头的另一端与连接管可插拔配合,连接头与连接管的插接处液密封配合。 Optionally, the sample inlet tube and the sample outlet tube respectively include a connector and a connector tube, one end of the inlet tube through the connector is pluggably fitted with the first opening, and the sample outlet tube passes through one end of the connector It is pluggably matched with the second opening, the other end of the connector is pluggably matched with the connecting pipe, and the connector is liquid-tightly matched with the socket of the connecting pipe.
可选的,所述红外液体样品池装置还包括样品泵与反应器,所述反应器与样品池通过样品管路连接,所述样品管路包括进样管与出样管,所述样品泵设置于样品管路上。 Optionally, the infrared liquid sample pool device also includes a sample pump and a reactor, the reactor and the sample pool are connected through a sample pipeline, the sample pipeline includes a sample inlet tube and a sample outlet tube, and the sample pump Set on the sample line.
可选的,所述样品泵为蠕动泵,所述蠕动泵包括泵头和动力机构,所述背板上设置有安装孔,所述蠕动泵安装于背板上,所述泵头安装于背板设置有样品池的一面,所述动力机构安装于背板的另一面,动力机构的传动轴穿过安装孔与泵头连接。 Optionally, the sample pump is a peristaltic pump, the peristaltic pump includes a pump head and a power mechanism, and mounting holes are arranged on the back plate, the peristaltic pump is installed on the back plate, and the pump head is installed on the back plate One side of the plate is provided with a sample pool, the power mechanism is installed on the other side of the back plate, and the transmission shaft of the power mechanism passes through the installation hole and is connected with the pump head.
可选的,所述背板与定位槽之间的连接方式选自:螺钉连接,卡接,焊接与粘接。 Optionally, the connection method between the back plate and the positioning groove is selected from: screw connection, clamping, welding and bonding.
可选的,所述背板为金属板,所述定位槽为塑料槽,橡胶槽或金属槽。 Optionally, the back plate is a metal plate, and the positioning groove is a plastic groove, a rubber groove or a metal groove.
发明人还提供一种连续进样式红外液体样品池,所述样品池包括由透红外线材料制备的池体,池体顶面、底面、正面、背面与侧面密封,池体的正面与背面为红外透射面,池体顶面设置有第一开口和第二开口,分别用于连接进样管和出样管,进样管的外壁与第一开口的内壁可插拔配合,出样管的外壁与第二开口的内壁可插拔配合,当进样管插接于第一开口中,以及出样管插接于第二开口中时,插接处液密封配合,池体内开设有容置待测样品之用的样品腔,所述第一开口和所述第二开口分别与样品腔导通; The inventor also provides a continuous feed type infrared liquid sample cell, the sample cell includes a cell body made of infrared-transmitting material, the top surface, bottom surface, front, back and sides of the cell body are sealed, and the front and back of the cell body are infrared On the transmission surface, the top surface of the cell body is provided with a first opening and a second opening, which are respectively used to connect the sampling tube and the sampling tube. The outer wall of the sampling tube is pluggable with the inner wall of the first opening, and the outer wall of the It can be plugged and matched with the inner wall of the second opening. When the sample inlet tube is plugged into the first opening and the sample outlet tube is plugged into the second opening, the plug joints are liquid-tightly matched, and there is a storage space in the cell body. A sample cavity for measuring samples, the first opening and the second opening are respectively connected to the sample cavity;
可选的,所述池体外轮廓为长方体,所述池体为氟化钙材料,定位槽呈U形结构。 Optionally, the outer contour of the pool is a cuboid, the pool body is made of calcium fluoride material, and the positioning groove is in a U-shaped structure.
可选的,所述第一开口与第二开口的横截面为圆形。 Optionally, cross-sections of the first opening and the second opening are circular.
发明人还提供一种连续进样式红外液体样品池,样品池包括由透红外线材料制备的池体,池体顶面、底面、正面、背面与侧面密封,池体的正面与背面为红外透射面,池体顶面设置有第一开口和第二开口,分别用于连接进样管和出样管,进样管的外壁与第一开口的内壁可插拔配合,出样管的外壁与第二开口的内壁可插拔配合,当进样管插接于第一开口中,以及出样管插接于第二开口中时,插接处液密封配合,池体内开设有容置待测样品之用的样品腔,所述第一开口和所述第二开口分别与样品腔导通; The inventor also provides a continuous feeding infrared liquid sample cell. The sample cell includes a cell body made of infrared-transmitting material. The top, bottom, front, back and sides of the cell body are sealed, and the front and back of the cell body are infrared transmission surfaces. , the top surface of the cell body is provided with a first opening and a second opening, which are respectively used to connect the sample inlet tube and the sample outlet tube. The inner walls of the two openings can be plugged and matched. When the sample inlet tube is plugged into the first opening and the sample outlet tube is plugged into the second opening, the plugs are liquid-tightly matched, and there is a hole in the cell body to accommodate the sample to be tested. The sample chamber for the purpose, the first opening and the second opening are respectively connected to the sample chamber;
可选的,所述池体外轮廓为长方体,所述池体为氟化钙材料,定位槽呈U形结构。 Optionally, the outer contour of the pool is a cuboid, the pool body is made of calcium fluoride material, and the positioning groove is in a U-shaped structure.
可选的,所述两开口分别为第一开口和第二开口,进样管通过密封连接件与第一开口密封连接,出样管通过密封连接件与第二开口密封连接。 Optionally, the two openings are respectively a first opening and a second opening, the sample inlet tube is sealed and connected to the first opening through a sealing connector, and the sample outlet tube is sealed and connected to the second opening through a sealing connector.
可选的,所述第一开口与第二开口的横截面为圆形。 Optionally, cross-sections of the first opening and the second opening are circular.
区别于现有技术,上述技术方案在使用时,直接通过样品池顶部的样品腔的槽口加入液体样品,由于池体底面、正面、背面与侧面密封,形成了一体化的液体样品池,因此省略了搭建样品池的繁琐流程,且不存在由于搭建过程中的操作失误或器皿的液密封性问题导致的液体样品泄露的问题。并且,由于一体化的液体样品池结构,样品腔的尺寸固定,因此样品腔中的液体样品厚度固定,测量准确度高。在测量时,将注入好样品的样品池插入样品池支架的定位槽中固定,通过样品池支架的背板插入到红外光谱仪的样品位中进行检测,需要更换样品时,将样品池从样品池支架的定位槽中拔出,十分方便。 Different from the prior art, when the above technical solution is in use, the liquid sample is directly added through the notch of the sample chamber on the top of the sample pool. Since the bottom, front, back and side of the pool body are sealed, an integrated liquid sample pool is formed, so The cumbersome process of building the sample pool is omitted, and there is no problem of liquid sample leakage due to operational errors during the building process or liquid tightness of the vessel. Moreover, due to the integrated liquid sample pool structure, the size of the sample cavity is fixed, so the thickness of the liquid sample in the sample cavity is fixed, and the measurement accuracy is high. When measuring, insert the sample cell filled with the sample into the positioning groove of the sample cell bracket and fix it, and insert it into the sample position of the infrared spectrometer through the back plate of the sample cell bracket for detection. When the sample needs to be replaced, remove the sample cell from the sample cell It is very convenient to pull out from the positioning slot of the bracket.
并且,通过进样管和出样管的配合,因此可以在样品腔中连续导入待测液体样品,便于从反应池取样以观测反应物的化合进程,且中间省略了人工取样的操作时间,提高了采样频率,也提高了连续观测的准确性。并且由进样管、出样管以及样品池形成密封结构,提高了检测挥发性或有毒的液体的安全性。 Moreover, through the cooperation of the sample inlet tube and the sample outlet tube, the liquid sample to be tested can be continuously introduced into the sample cavity, which is convenient for sampling from the reaction pool to observe the compounding process of the reactant, and the operation time of manual sampling is omitted in the middle, which improves The sampling frequency is improved, and the accuracy of continuous observation is also improved. And the sealing structure is formed by the sample inlet tube, the sample outlet tube and the sample pool, which improves the safety of detecting volatile or toxic liquids.
附图说明 Description of drawings
图1(a)为具体实施方式所述的连续进样式红外液体样品池装置立体结构示意图; Fig. 1 (a) is the schematic diagram of the three-dimensional structure of the continuous feeding infrared liquid sample pool device described in the specific embodiment;
图1(b)为具体实施方式所述的连续进样式红外液体样品池装置立体结构示意图; Fig. 1 (b) is the schematic diagram of the three-dimensional structure of the continuous feeding infrared liquid sample pool device described in the specific embodiment;
图1(c)为具体实施方式所述的连续进样式红外液体样品池装置使用时的立体状态示意图; Fig. 1 (c) is the schematic diagram of the three-dimensional state when the continuous feeding infrared liquid sample cell device described in the specific embodiment is in use;
图2(a)为具体实施方式所述的连续进样式红外液体样品池立体结构示意图; Fig. 2 (a) is the schematic diagram of the three-dimensional structure of the continuous feeding style infrared liquid sample pool described in the specific embodiment;
图2(b)为具体实施方式所述沿样品池侧面平行的切面所形成的剖面结构示意图; Fig. 2 (b) is a schematic diagram of the cross-sectional structure formed by the cut plane parallel to the side of the sample cell described in the specific embodiment;
图2(c)为具体实施方式所述沿样品池沿俯视视角的结构示意图; Fig. 2 (c) is the structural schematic view along the top view angle along the sample pool described in the specific embodiment;
图2(d)为具体实施方式所述沿样品池沿与背板平行视角的结构示意图; Fig. 2(d) is a structural schematic view along the angle of view parallel to the back plate along the sample cell described in the specific embodiment;
图3为具体实施方式所述背板立体结构示意图; Fig. 3 is a schematic diagram of the three-dimensional structure of the backboard described in the specific embodiment;
图4(a)为具体实施方式所述定位槽立体结构示意图; Fig. 4 (a) is the schematic diagram of the three-dimensional structure of the positioning groove described in the specific embodiment;
图4(b)为具体实施方式所述定位槽立体沿与背板30平行的切面所形成的剖面结构示意图; Fig. 4(b) is a schematic cross-sectional structural view of the positioning grooves in the specific embodiment formed along a cut plane parallel to the back plate 30;
图5为具体实施方式所述定位槽沿与样品池正面平行的切面所形成的剖面结构示意图。 Fig. 5 is a schematic cross-sectional structure diagram of the positioning groove in a specific embodiment formed along a cut plane parallel to the front of the sample cell.
附图标记说明: Explanation of reference signs:
10、池体, 10. Pool body,
101、第一开口, 101. The first opening,
102、第二开口, 102, the second opening,
105、样品腔, 105, sample cavity,
121、池体顶部, 121, the top of the pool body,
122、池体侧面, 122. The side of the pool body,
123、池体底面, 123, the bottom surface of the pool body,
125、池体正面, 125. Pond front,
126、池体背面, 126. The back of the pool body,
20、定位槽, 20. Positioning groove,
210、第一透光部, 210. The first light-transmitting part,
212、定位槽的凹槽, 212, the groove of the positioning groove,
218、螺孔, 218, screw hole,
30、背板, 30. Backplane,
317、第二透光部, 317. The second light-transmitting part,
311、安装孔, 311, mounting holes,
40、进样管, 40. Injection tube,
50、出样管, 50. Sample tube,
60、蠕动泵, 60. Peristaltic pump,
601、泵头; 601. Pump head;
602、电机; 602, motor;
70、直头密封连接件。 70. Straight head sealing connector.
具体实施方式 detailed description
为详细说明技术方案的技术内容、构造特征、所实现目的及效果,以下结合具体实施例并配合附图详予说明。 In order to explain in detail the technical content, structural features, achieved goals and effects of the technical solution, the following will be described in detail in conjunction with specific embodiments and accompanying drawings.
请参阅图1(a)至图5,本实施例提供了一种连续进样式红外液体样品池装置,包括样品池、进样管、出样管和样品池支架;其中样品池为一体化红外液体样品池。 Please refer to Fig. 1 (a) to Fig. 5, the present embodiment provides a kind of continuous feeding pattern infrared liquid sample pool device, comprises sample pool, sample tube, sample tube and sample pool bracket; Wherein sample pool is integrated infrared Liquid sample cell.
如图1(a)~图1(b)和图2(a)~图2(d)所示,样品池包括由透红外线材料制备的池体10,池体顶面121、池体底面123、池体正面125、池体背面126与池体侧面122密封,池体的正面与背面为红外透射面,池体内开设有容置待测样品之用的样品腔105,池体顶面设置有两开口,分别为第一开口101和第二开口102,分别用于连接进样管40和出样管50,池体内开设有容置待测样品之用的样品腔105,所述池体顶面的两开口(第一开口101和第二开口102)分别与样品腔105导通。第一开口101和第二开口102分别用于连接进样管和出样管,进样管的外壁与第一开口的内壁可插拔配合,出样管的外壁与第二开口的内壁可插拔配合,当进样管插接于第一开口中,以及出样管插接于第二开口中时,插接处液密封配合,此时进样管与出样管以及样品池内部的样品腔一起形成密闭的腔体。 As shown in Figures 1 (a) to 1 (b) and Figures 2 (a) to 2 (d), the sample cell includes a cell body 10 made of an infrared-transmitting material, a top surface 121 of the cell body, and a bottom surface 123 of the cell body , the pool body front 125, the pool body back 126 and the pool body side 122 are sealed, the front and the back of the pool body are infrared transmission surfaces, the pool body is provided with a sample cavity 105 for accommodating samples to be tested, and the top surface of the pool body is provided with Two openings, respectively the first opening 101 and the second opening 102, are respectively used to connect the sample inlet tube 40 and the sample outlet tube 50, and a sample cavity 105 for accommodating the sample to be tested is provided in the cell body, and the top of the cell body is The two openings on the surface (the first opening 101 and the second opening 102 ) are respectively connected to the sample chamber 105 . The first opening 101 and the second opening 102 are respectively used to connect the sample inlet tube and the sample outlet tube. Pull fit, when the sample tube is plugged into the first opening and the sample tube is plugged into the second opening, the joints are liquid-tightly fitted, at this time the sample tube is connected to the sample tube and the sample inside the sample cell The cavities together form a closed cavity.
在上述实施例中,制备池体的透红外线材料为氟化钙材料。 In the above embodiments, the infrared-transmitting material used to prepare the cell body is calcium fluoride material.
在图2(a)~图2(d)所示实施例中,池体外轮廓为长方体,长方体的池体易于加工、生产,也便于与样品池支架的定位槽插接配合。当然,在其他实施例中,样品池的池体可是扁圆柱形,或者是横截面为三角形、梯形的扁棱柱形等形状,这些实施例中,扁圆柱形或扁棱柱形两端的柱端面构成了池体正面与池体背面。 In the embodiment shown in Fig. 2(a) to Fig. 2(d), the outer contour of the cell is a cuboid, and the cuboid cell body is easy to process and produce, and it is also convenient to insert and fit with the positioning groove of the sample cell bracket. Of course, in other embodiments, the cell body of the sample cell may be in the shape of a flat cylinder, or a shape such as a triangular or trapezoidal flat prism in cross section. The front of the pool body and the back of the pool body.
如图2(a)~图2(d)所示实施例,样品腔105为立体空间,其有两个面与池体正面125以及池体背面126平行,样品腔105与第一开口101和第二开口102导通。 In the embodiment shown in Fig. 2 (a) ~ Fig. 2 (d), the sample chamber 105 is a three-dimensional space, which has two faces parallel to the front 125 of the cell body and the back 126 of the cell body, and the sample chamber 105 is connected to the first opening 101 and the back of the cell body. The second opening 102 conducts.
池体的透视图如图2(c)和图2(d)所示,样品腔105的厚度非常薄,以便于将待检测的液体样品制备为厚度很薄的液体样品膜,待检测液体从开口101导入到样品腔105内。第一开口101和第二开口102的径向尺寸大于样品腔105的厚度。第一开口101和第二开口102一个作为进液口,另一个作为出液口,解决了样品腔105的厚度过小导致不易导入待检测液体的问题;同时也方便了将检测完的液体样品从第一开口101和第二开口102中倾倒出来。两个开口分别进样管40以及出样管50,解决待检测液体样品连续导入池体内的问题。 The perspective view of the cell body is shown in Figure 2(c) and Figure 2(d), the thickness of the sample chamber 105 is very thin, so that the liquid sample to be detected is prepared as a thin liquid sample film, and the liquid to be detected is obtained from The opening 101 leads into a sample chamber 105 . The radial dimensions of the first opening 101 and the second opening 102 are larger than the thickness of the sample cavity 105 . One of the first opening 101 and the second opening 102 is used as a liquid inlet, and the other is used as a liquid outlet, which solves the problem that the thickness of the sample chamber 105 is too small to lead to the difficult introduction of the liquid to be tested; It is poured out from the first opening 101 and the second opening 102 . The two openings are the sample inlet tube 40 and the sample outlet tube 50 respectively, which solve the problem that the liquid sample to be tested is continuously introduced into the cell.
优选的,进样管和出样管分别包括连接头与连接管,连接头优选的为密封连接件;连接头的一端与第一开口的内壁液密封配合,另一端与连接管液密封配合。所述进样管通过连接头的一端与第一开口可插拔配合,所述出样管通过连接头的一端与第二开口可插拔配合,在使用时可以通过插拔连接管,而减少连接头的插拔,可以有效延长第一开口与第二开口的磨损,延长样品池的使用寿命。 Preferably, the sample inlet tube and the sample outlet tube respectively include a connector and a connecting tube, and the connector is preferably a sealed connector; one end of the connector is in fluid-tight fit with the inner wall of the first opening, and the other end is in fluid-tight fit with the connecting tube. One end of the sample inlet tube is pluggably matched with the first opening through the connector, and the one end of the sample outlet tube is pluggably matched with the second opening through the connector. When in use, the connection tube can be plugged and unplugged to reduce the The plugging and unplugging of the connector can effectively prolong the wear of the first opening and the second opening, and prolong the service life of the sample pool.
连接管可以是橡胶管、玻璃管、pvc管等。 The connecting pipe can be rubber pipe, glass pipe, pvc pipe and so on.
优选的,第一开口101和第二开口102圆柱体镂空,其横截面为圆形,以便于通过密封连接件分别连接出样管50和进样管40,密封连接件可以是直头密封连接件,也可以是弯头密封连接件。根据连接件的接头处的大小,第一开口101和第二开口102镂空的径向尺寸也不同,优选的采用图4(a)、图4(b)所示的直头密封连接件70。当然第一开口101与第二开口102以及与之适配的进样管、出样管的横截面也可以是其他形状,例如六边形等多边形。在使用时,与进样、出样的方向相配合,当第一开口用于进样,第二开口用于出样时,第一开口也被称为是进样口,第二开口也被称为是出样口。 Preferably, the first opening 101 and the second opening 102 are hollowed out cylinders, and their cross-sections are circular, so as to connect the sample tube 50 and the sample tube 40 respectively through a sealing connector, and the sealing connector can be a straight head sealing connection parts, or elbow seal connections. According to the size of the joint of the connecting piece, the radial dimensions of the first opening 101 and the second opening 102 are also different, and the straight head sealing connecting piece 70 shown in Fig. 4(a) and Fig. 4(b) is preferably used. Of course, the cross-sections of the first opening 101 and the second opening 102 and the corresponding sample inlet tube and sample outlet tube can also be other shapes, such as polygons such as hexagon. When in use, it matches the direction of sample introduction and sample discharge. When the first opening is used for sample introduction and the second opening is used for sample discharge, the first opening is also called a sample inlet, and the second opening is also called a sample inlet. called the sample outlet.
反应池(或反应器)中的液体混合物为待测样品的来源。 The liquid mixture in the reaction pool (or reactor) is the source of the sample to be tested.
红外液体样品池装置还包括样品泵与反应器,所述反应器与样品池通过样品管路连接,所述样品管路包括进样管与出样管,所述样品泵设置于样品管路上,用于将反应器中的待测样品输送至样品池中。另一方面通过样品泵的作用,将样品池中的样品输出(例如输送到反应器或垃圾桶中)。 The infrared liquid sample pool device also includes a sample pump and a reactor, the reactor and the sample pool are connected through a sample pipeline, the sample pipeline includes a sample inlet tube and a sample outlet tube, and the sample pump is arranged on the sample pipeline, It is used to transfer the sample to be tested in the reactor to the sample pool. On the other hand, the sample in the sample pool is output (for example, sent to a reactor or a trash can) through the function of the sample pump.
所述样品泵可以选用蠕动泵,所述蠕动泵包括泵头和动力机构,所述背板上设置有安装孔,所述蠕动泵安装于背板上,所述泵头安装于背板设置有样品池的一面,所述动力机构安装于背板的另一面,动力机构的传动轴穿过安装孔与泵头连接。 The sample pump can be a peristaltic pump, the peristaltic pump includes a pump head and a power mechanism, the back plate is provided with mounting holes, the peristaltic pump is installed on the back plate, the pump head is installed on the back plate and is provided with One side of the sample pool, the power mechanism is installed on the other side of the back plate, and the transmission shaft of the power mechanism is connected with the pump head through the installation hole.
如图1(a)和图1(b)所示,将进样管50连接蠕动泵的出口软管,蠕动泵的入口软管连接反应池。在另一些实施例中,也可以是蠕动泵的入口软管接出样管(如图中箭头C和箭头D标识待检测液体的流动方向)。在检测过程中,通过蠕动泵将反应池中的反应混合物连续导入样品池中,进行连续的检测,以监控反应池中化合程度。通过蠕动泵还可以控制待检测样品的流速。 As shown in FIG. 1(a) and FIG. 1(b), the sampling tube 50 is connected to the outlet hose of the peristaltic pump, and the inlet hose of the peristaltic pump is connected to the reaction pool. In some other embodiments, the inlet hose of the peristaltic pump can also be connected to the sample tube (as shown in the figure, arrows C and D indicate the flow direction of the liquid to be tested). During the detection process, the reaction mixture in the reaction cell is continuously introduced into the sample cell by a peristaltic pump for continuous detection to monitor the degree of compounding in the reaction cell. The flow rate of the sample to be tested can also be controlled by the peristaltic pump.
如图1(a)、图1(b)和图3所示,蠕动泵60固定在背板30上,背板与蠕动泵之间的连接方式可以为螺钉连接,卡接,焊接或粘接。具体的,如图3所示实施例,在背板30上开设有安装孔321,在蠕动泵60上开设有对应的安装孔,蠕动泵的泵头601穿过背板上的安装孔321,与样品池位于同一侧,蠕动泵的动力机构,如图1(b)中的电机602)位于背板的另一侧。螺接于蠕动泵对应的螺孔。 As shown in Figure 1(a), Figure 1(b) and Figure 3, the peristaltic pump 60 is fixed on the back plate 30, and the connection between the back plate and the peristaltic pump can be screw connection, clamping, welding or bonding . Specifically, in the embodiment shown in FIG. 3 , a mounting hole 321 is opened on the back plate 30, and a corresponding mounting hole is opened on the peristaltic pump 60. The pump head 601 of the peristaltic pump passes through the mounting hole 321 on the back plate, Located on the same side as the sample cell, the power mechanism of the peristaltic pump, such as the motor 602 in FIG. 1( b ), is located on the other side of the back plate. Screwed to the corresponding screw hole of the peristaltic pump.
如图1(a)、图1(b)、图3、图4(a)和图4(b)所示,所述样品池支架包括背板30与定位槽20,所述定位槽20与背板30相连接,定位槽的凹槽212与样品池池体10相适配,样品池池体10与定位槽可插拔配合,定位槽的凹槽方向背板平行,这样使得池体10插入定位槽后,池体正面125与池体背面126与背板30平行,定位槽对应池体正面125与池体背面126的位置,开设有第一透光部210,这样定位槽20整体呈U字形结构。 As shown in Fig. 1 (a), Fig. 1 (b), Fig. 3, Fig. 4 (a) and Fig. 4 (b), the sample cell support includes a back plate 30 and a positioning groove 20, and the positioning groove 20 and The back plate 30 is connected, the groove 212 of the positioning groove is adapted to the cell body 10 of the sample cell, the cell body 10 of the sample cell is pluggably matched with the positioning groove, and the direction of the groove of the positioning groove is parallel to the back plate, so that the cell body 10 After being inserted into the positioning slot, the front 125 of the pool body and the back 126 of the pool body are parallel to the back plate 30, and the positioning slot corresponds to the position of the front 125 of the pool body and the back 126 of the pool body, and a first light-transmitting portion 210 is provided, so that the positioning slot 20 as a whole has a shape of U-shaped structure.
背板对应样品池背面以及第一透光部的位置,开设有第二透光部317。在检测时,红外光通过第一透光部210与第二透光317部穿过样品池池体10,实现对样品的检测。 The back plate corresponds to the position of the back of the sample cell and the first light-transmitting part, and a second light-transmitting part 317 is opened. During detection, the infrared light passes through the first light-transmitting part 210 and the second light-transmitting part 317 and passes through the sample cell body 10 to realize the detection of the sample.
背板与定位槽之间的连接方式可以为螺钉连接,卡接,焊接或粘接。具体的,如图3、图4(a)和图4(b)所示实施例,在背板30上开设有通孔317,在定位槽20上开设有螺孔218,通过穿过通孔317,并螺接于螺孔218的螺钉,将背板30与定位槽20相固定。 The connection mode between the back plate and the positioning groove can be screw connection, card connection, welding or bonding. Specifically, in the embodiment shown in Figure 3, Figure 4(a) and Figure 4(b), a through hole 317 is provided on the back plate 30, and a screw hole 218 is provided on the positioning groove 20, and through the through hole 317, and screwed to the screw hole 218, the back plate 30 and the positioning groove 20 are fixed.
实施例中,背板30可以选用金属板,例如不锈钢板、铝合金板、铜合金板等,当然也可以使用塑料板。 In an embodiment, the back plate 30 can be a metal plate, such as a stainless steel plate, an aluminum alloy plate, a copper alloy plate, etc. Of course, a plastic plate can also be used.
所述定位槽为塑料槽,橡胶槽或金属槽,具体例如聚四氟乙烯材料等。 The positioning groove is a plastic groove, a rubber groove or a metal groove, such as polytetrafluoroethylene material.
在使用时,如图1(c)所示将样品池侧放,使得进样口位于出样口下方,便于液体样品充满整个腔体,也有利于样品均匀流动,使检测结果更加准确。可以理解的蠕动泵相对于样品池的位置是可选的,在不同的实施例中,蠕动泵可以位于相对样品池的任意位置。如图1(c)所示的一个实施例中,样品管上的箭头标识了液体流动的方向,蠕动泵60将待检测的液体样品送入样品池10中,待检测液体样品从下方的进样口(进样口与进样管40连接)进入样品池,从上方的出样口(出样口与出样管50连接)离开样品池10,这样样品池中不会出现气泡,并且液体样品充满样品池的整个腔体。 When in use, place the sample cell on its side as shown in Figure 1(c), so that the sample inlet is located below the sample outlet, which facilitates the liquid sample to fill the entire cavity, and is also conducive to the uniform flow of the sample, making the detection result more accurate. It can be understood that the position of the peristaltic pump relative to the sample pool is optional, and in different embodiments, the peristaltic pump can be located at any position relative to the sample pool. In an embodiment shown in Figure 1 (c), the arrow on the sample tube indicates the direction of liquid flow, and the peristaltic pump 60 sends the liquid sample to be detected into the sample pool 10, and the liquid sample to be detected enters from the bottom. The sample port (the sample inlet is connected with the sample tube 40) enters the sample cell, and leaves the sample cell 10 from the sample outlet (the sample port is connected with the sample tube 50) above, so that bubbles will not appear in the sample cell like this, and the liquid The sample fills the entire cavity of the sample cell.
上述实施例在使用时,直接通过样品池顶部的样品腔的第一开口或第二开口加入液体样品,由于池体顶面、底面、正面、背面与侧面密封,形成了一体化的液体样品池,因此省略了搭建样品池的繁琐流程,且不存在由于搭建过程中的操作失误或器皿的液密封性问题导致的液体样品泄露的问题。并且,由于一体化的液体样品池结构,样品腔的尺寸固定,因此样品腔中的液体样品厚度固定,测量准确度高。在测量时,将注入好样品的样品池插入样品池支架的定位槽中固定,通过样品池支架的背板插入到红外光谱仪的样品位中进行检测,需要更换不同厚度的样品池时,将样品池从样品池支架的定位槽中拔出,十分方便。 When the above-mentioned embodiment is in use, the liquid sample is directly added through the first opening or the second opening of the sample cavity on the top of the sample pool, and an integrated liquid sample pool is formed due to the sealing of the top, bottom, front, back and side of the pool body , so the cumbersome process of building the sample pool is omitted, and there is no problem of liquid sample leakage due to operational errors during the building process or liquid tightness of the vessel. Moreover, due to the integrated liquid sample pool structure, the size of the sample cavity is fixed, so the thickness of the liquid sample in the sample cavity is fixed, and the measurement accuracy is high. When measuring, insert the sample cell filled with the sample into the positioning groove of the sample cell bracket and fix it, and insert it into the sample position of the infrared spectrometer through the back plate of the sample cell bracket for detection. The cell is pulled out from the positioning groove of the sample cell holder, which is very convenient.
并且,通过进样管和出样管的配合,因此可以在样品腔中连续导入待测液体样品,便于从反应池取样以观测反应物的化合进程,且中间省略了人工取样的操作时间,提高了采样频率,也提高了连续观测的准确性。并且由进样管、出样管以及样品池形成密封结构,提高了检测挥发性或有毒的液体的安全性。 Moreover, through the cooperation of the sample inlet tube and the sample outlet tube, the liquid sample to be tested can be continuously introduced into the sample cavity, which is convenient for sampling from the reaction pool to observe the compounding process of the reactant, and the operation time of manual sampling is omitted in the middle, which improves The sampling frequency is improved, and the accuracy of continuous observation is also improved. And the sealing structure is formed by the sample inlet tube, the sample outlet tube and the sample pool, which improves the safety of detecting volatile or toxic liquids.
可以理解的是,通过连续导入待测液体样品,还有利于连续测试和采集待检测液体的动力学信息,以利于探测样品实时发生的化学反应。同时,在清洗时,清洗液体的运动方向按照正向,再反向,如此反复循环数次,清洗液体的运动方向通过蠕动泵控制,解决从下往上冲洗可能会清洗不到位的问题。 It can be understood that by continuously introducing the liquid sample to be tested, it is also beneficial to continuously test and collect kinetic information of the liquid to be tested, so as to facilitate the detection of the chemical reaction occurring in the sample in real time. At the same time, when cleaning, the moving direction of the cleaning liquid is in the forward direction, and then reversed, so that the cycle is repeated several times. The moving direction of the cleaning liquid is controlled by the peristaltic pump, which solves the problem that the washing from the bottom to the top may not be in place.
需要说明的是,在本文中,诸如第一和第二等之类的关系术语仅仅用来将一个实体或者操作与另一个实体或操作区分开来,而不一定要求或者暗示这些实体或操作之间存在任何这种实际的关系或者顺序。而且,术语“包括”、“包含”或者其任何其他变体意在涵盖非排他性的包含,从而使得包括一系列要素的过程、方法、物品或者终端设备不仅包括那些要素,而且还包括没有明确列出的其他要素,或者是还包括为这种过程、方法、物品或者终端设备所固有的要素。在没有更多限制的情况下,由语句“包括……”或“包含……”限定的要素,并不排除在包括所述要素的过程、方法、物品或者终端设备中还存在另外的要素。此外,在本文中,“大于”、“小于”、“超过”等理解为不包括本数;“以上”、“以下”、“以内”等理解为包括本数。 It should be noted that in this article, relational terms such as first and second are only used to distinguish one entity or operation from another entity or operation, and do not necessarily require or imply that there is a relationship between these entities or operations. There is no such actual relationship or order between them. Furthermore, the term "comprises", "comprises" or any other variation thereof is intended to cover a non-exclusive inclusion such that a process, method, article, or terminal equipment comprising a set of elements includes not only those elements, but also includes elements not expressly listed. other elements identified, or also include elements inherent in such a process, method, article, or end-equipment. Without further limitations, an element defined by the words "comprising..." or "comprising..." does not exclude the presence of additional elements in the process, method, article or terminal device comprising said element. In addition, in this article, "greater than", "less than", "exceeding" and so on are understood as not including the original number; "above", "below", "within" and so on are understood as including the original number.
尽管已经对上述各实施例进行了描述,但本领域内的技术人员一旦得知了基本创造性概念,则可对这些实施例做出另外的变更和修改,所以以上所述仅为本实用新型的实施例,并非因此限制本实用新型的专利保护范围,凡是利用本实用新型说明书及附图内容所作的等效结构或等效流程变换,或直接或间接运用在其他相关的技术领域,均同理包括在本实用新型的专利保护范围之内。 Although the above-mentioned embodiments have been described, those skilled in the art can make additional changes and modifications to these embodiments once they know the basic creative concepts, so the above is only a summary of the present utility model. The embodiment does not limit the scope of patent protection of the present utility model, and any equivalent structure or equivalent process conversion made by using the specification of the utility model and the contents of the accompanying drawings, or directly or indirectly used in other related technical fields, is the same. Included within the scope of patent protection of the utility model.
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201520906118.0U CN205209947U (en) | 2015-11-13 | 2015-11-13 | Advance infrared liquid sample cell device of pattern and infrared sample cell in succession |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201520906118.0U CN205209947U (en) | 2015-11-13 | 2015-11-13 | Advance infrared liquid sample cell device of pattern and infrared sample cell in succession |
Publications (1)
Publication Number | Publication Date |
---|---|
CN205209947U true CN205209947U (en) | 2016-05-04 |
Family
ID=55847656
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201520906118.0U Expired - Fee Related CN205209947U (en) | 2015-11-13 | 2015-11-13 | Advance infrared liquid sample cell device of pattern and infrared sample cell in succession |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN205209947U (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105352892A (en) * | 2015-11-13 | 2016-02-24 | 福建师范大学 | A continuous-injection type infrared liquid sample chamber device and an infrared sample chamber |
CN109358020A (en) * | 2018-09-06 | 2019-02-19 | 中国原子能科学研究院 | An infrared spectrometer liquid pool sampling device |
-
2015
- 2015-11-13 CN CN201520906118.0U patent/CN205209947U/en not_active Expired - Fee Related
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105352892A (en) * | 2015-11-13 | 2016-02-24 | 福建师范大学 | A continuous-injection type infrared liquid sample chamber device and an infrared sample chamber |
CN109358020A (en) * | 2018-09-06 | 2019-02-19 | 中国原子能科学研究院 | An infrared spectrometer liquid pool sampling device |
CN109358020B (en) * | 2018-09-06 | 2024-01-16 | 中国原子能科学研究院 | Liquid pool sample injection device of infrared spectrometer |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN104931373B (en) | A kind of Corrosion Fatigue Crack Propagation experimental rig | |
JPS60218059A (en) | Device and method of determining analyte in liquid | |
CN105547989B (en) | A kind of electro-chemical test experimental provision of metal Dynamic Corrosion | |
CN205209947U (en) | Advance infrared liquid sample cell device of pattern and infrared sample cell in succession | |
CN110186900B (en) | A test cell for testing metal corrosion by coupled Raman spectroscopy and its design method | |
CN105300886B (en) | Integrated infrared liquid sample cell device and infrared sample cell | |
CN2804853Y (en) | Circulation type testing pond | |
CN110132905B (en) | Dynamic measuring system | |
CN105352892B (en) | Continuous sample introduction type infrared liquid sample pool device | |
CN108051350A (en) | A kind of porous material testing permeability device and test method | |
CN205049439U (en) | Multi -functionally dismantle portable viscosimeter | |
CN205209948U (en) | Infrared liquid sample cell device of integration and infrared sample cell | |
CN219224711U (en) | Titration head for universal adjustable titration instruments | |
CN107831328B (en) | Time-sharing injection system and water quality on-line monitoring instrument | |
CN214845201U (en) | Online quality control instrument for water quality | |
CN201203589Y (en) | Thermal conductivity low temperature measuring device with locking mechanism | |
CN101525575B (en) | Contamination polyphase metabolism germiculture and product collection interface device used for analyzer | |
CN209280546U (en) | Flow cell | |
CN204346882U (en) | Metal erosion electrochemical experimental device in Flow Corrosion medium | |
CN216484806U (en) | Qualitative and quantitative gas chromatography rapid determination equipment for alachlor poisoning in serum | |
CN2826410Y (en) | Circulation type near-infrared optical fiber detection cell | |
CN207850918U (en) | The temperature controlled sample pond measured near infrared spectral transmission fibre-optical probe | |
CN222561400U (en) | Sample stage capable of cleaning stainless steel sample by chemical reagent | |
CN220040232U (en) | High-precision refractometer | |
CN219319981U (en) | Stainless steel pipe hydrostatic test device |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160504 Termination date: 20181113 |
|
CF01 | Termination of patent right due to non-payment of annual fee |