CN205109143U - Modified rice husk ash of handling rural high ammonia -nitrogen concentration water source water membrane device of precoating - Google Patents
Modified rice husk ash of handling rural high ammonia -nitrogen concentration water source water membrane device of precoating Download PDFInfo
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- CN205109143U CN205109143U CN201520907912.7U CN201520907912U CN205109143U CN 205109143 U CN205109143 U CN 205109143U CN 201520907912 U CN201520907912 U CN 201520907912U CN 205109143 U CN205109143 U CN 205109143U
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- CVTZKFWZDBJAHE-UHFFFAOYSA-N [N].N Chemical compound [N].N CVTZKFWZDBJAHE-UHFFFAOYSA-N 0.000 title claims abstract description 38
- 235000007164 Oryza sativa Nutrition 0.000 title claims abstract description 32
- 235000009566 rice Nutrition 0.000 title claims abstract description 32
- 239000012528 membrane Substances 0.000 title abstract description 22
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- 240000007594 Oryza sativa Species 0.000 title 1
- 239000000654 additive Substances 0.000 claims abstract description 50
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- 238000005516 engineering process Methods 0.000 description 10
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- 239000008367 deionised water Substances 0.000 description 6
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- 238000011010 flushing procedure Methods 0.000 description 5
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- NTHWMYGWWRZVTN-UHFFFAOYSA-N Sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 241000282898 Sus scrofa Species 0.000 description 1
- 239000002154 agricultural waste Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
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Abstract
The utility model provides a modified rice husk ash of handling rural high ammonia -nitrogen concentration water source water membrane device of precoating, it relates to a high ammonia -nitrogen concentration water source water treatment facilities. The utility model discloses a membrane filter that precoats that solves present high ammonia -nitrogen concentration water source water treatment facilities obtains precoats that the membrane is inhomogeneous to lead to the fact easily that the filter is inside to produce the bias flow to dynamic membrane because of spreading, causes the increase of filter pressure differential, cycle of operation to shorten, strain the unit and receives the pollution, goes out the problem that water quality of water worsens. A modified rice husk ash of handling rural high ammonia -nitrogen concentration water source water membrane device of precoating includes intake pool, additives bucket, the bucket of precoating, effluent water sump, membrane filter and outlet water pool precoat, the membrane filter that precoats include that filter housing, tubular strain unit, intake pipe valve, blast pipe, exhaust solenoid valve, manometer, delivery port, collecting chamber, inlet tube, flow distribution valve, go up water distribution baffle and water distribution baffle down. The utility model discloses modified rice husk ash of handling rural high ammonia -nitrogen concentration water source water membrane device of precoating mainly used handles rural high ammonia -nitrogen concentration water source water.
Description
Technical field
The utility model relates to a kind of high ammonia nitrogen the water treatment device.
Background technology
The drinking-water facility in China rural area supplies water based on tradition, backward dispersion, there is quite poor other with urban water supply, rural drinking water security is urgently to be resolved hurrily, within 2006, State Council has approved " national economy and social development 11th Five-Year Plan outline ", " national rural drinking water safety projects Eleventh Five-Year Plan " in succession, all using the key project of Expedite the application rural drinking water safety projects as new countryside construction.The Eleventh Five-Year Plan period, colleges and universities and scientific research institutions participate in have studied " research of rural water supply concentration techniques and demonstration " and " samll cities and towns' drinking water treatment technical research and equipment development " science and technology supporting project key project, though have made great progress, rural drinking water safety projects construction task is still heavy; " 12 " period, " country's " 12 " scientific and technological development planning " that the Department of Science and Technology promulgates emphaticallys point out " strengthening the key technology innovation of green cities and towns; promote city and urbanization sustainable development ", solve the safe drinking water problem of 2.98 hundred million urban residents and 11.4 ten thousand rural schools, the central water supply population ratio plan that is benefited in rural area reaches 85%, and comparatively 2012 (68%) will improve 17%; In addition, within 2012, China will realize urban-rural integration, and common implementing " standards for drinking water quality " (GB5749-2006), this proposes higher, tighter requirement to rural drinking water treatment technology and security thereof.
From 2009; Heilongjiang Province is according to national environmental protection portion general plan; give prominence to and solve Rural Environmental Problem; guarantee drinking water safety is considered as emphasis; know from " investigation of Heilongjiang Province's drinking water source area basic environment and assessment general report " (2010): village tap water popularity rate is only 51%; submerged type rural groundwater source is by protogenic geological environment and pollution of area source; change of water quality is larger; livestock and poultry cultivation in the water head site in rural area 80%, farming operation phenomenon are general; ammonia nitrogen exceeds standard, and rural potable water exists potential safety hazard." 12 " period, along with the enforcement of ten million ton of milk strategy engineering, 50,000,000 first-born pig large-scale cultivation strategy engineerings, Heilongjiang Province's productive life water consumption will significantly increase, and drinking-water resource die-offs; Water pollutions load certainly will be increased while the fast-developing economy of " eight economic regions ", " ten major projects " strategy implementation; Current rural environment basis instrument is still seriously delayed, and high ammonia nitrogen source water can not get effective process, makes villages and small towns drinking water quality security problem by severeer for the situation faced.
China is paddy first big producing country, and nearly 200,000,000 tons of annual production in recent years, rice husk accounts for 20% of paddy weight." 12 " period, the propelling of country's hundred billion jin of grain production capacity engineerings makes rice husk annual production increase severely, and the rice husk of substantial amounts like this becomes agricultural wastes, causes pollution to environment.Therefore, how to utilize this abundant renewable resource very urgent.For carrying out the important indicative spirit of central authorities' " develop actively modernization multi-form agriculture ", " national modern agricultural development planning (2011-2015) ", " 13 " planning all will " advance agriculture energy-saving and emission-reduction, develop the biomass resource such as stalk, rice husk " and be considered as development priority.Current rice husk all has extensive use in agricultural, chemical industry, food, building materials, but the research that rice husk is used for rural potable water is not yet reported, this invention will realize the pollution treatment new approaches of " treatment of wastes with processes of wastes against one another is gathered materials on the spot ", have important learning value.
To sum up, the present invention will for rural area height ammonia nitrogen source water purification research of technique, avoids finding other water sources and Large Water Works is built, and saves a large sum of expense; Accelerate the target realizing " the centralized drinking water source probability of meeting water quality standard in Heilongjiang Province rural reached 60% in 2015 "; Make urban residents break away from water pollutions puzzlement, ensure that the people's is healthy, improve the quality of life of resident; Improve the investment climate, attract investment, accelerates economic development, the whole Heilongjiang Province of improvement and even other area countryside drinking water qualities is produced to great impact and provides technical support, is conducive to advancing the construction of ecological Longjiang.
Domestic and international drinking water ammonia nitrogen removal method mainly comprises break point chlorination method, chemical method, ammonia aeration aeration, biological denitrificaion method, ion exchange adsorption, membrane filter method.(1) break point chlorination method: need add a large amount of chlorine, will
be converted into N
2, cause DBPs excessive concentration, increase carcinogenic teratogenesis risk, seldom use in recent years.(2) chemical method: dosage is large, though technique is simple, easily cause the generation that other pollute, the shortage phenomenon of current efficient and cheap, free of contamination medicament or flocculation aid limits its extensive use.(3) ammonia aeration aeration: need adjust pH, alkali consumption is large, and power consumption is large, and the easy fouling of tower wall, precipitation be many, cause stripping efficiency to reduce.(4) biological denitrificaion method: mainly for purification of waste water, comprise immobilized cell technology, Anammox technology, membrane bioreactor (MBR) technique, biomembrance process etc., because attachment bacterium aggressiveness on the carrier particles has larger resistance than individual cells bacterium to disinfectant, general cholorination is difficult to kill, and water hygiene security can not ensure.(5) ion exchange adsorption cheap with it, efficient, take up an area the feature such as little and receive publicity gradually, because zeolite pore is generally at about 0.4nm, and
ionic radius is 0.286nm, then
be easy to enter zeolite bug hole inside and carry out ion-exchange.But the exchange capacity of exchanger is limited, exchanger needs the problems such as modification to govern widely using of ion-exchange before using.(6) membrane filter method: there is good Separation of Solid and Liquid performance, removal of bacteria ability and floor space is little, automaticity advantages of higher, but the problems such as the flux decline that membrane module is expensive and fouling membrane causes hinder applying of membrane technology.Dynamic Membrane (Dynamicmembrane, DM) promoted gradually as milipore filter and microfiltration membranes anti-soil technology, under certain pressure differential, the precoating paint that utilization manually prepares or activated sludge form the cake layer with separating property in membrane surface, be mainly used in the fields such as sanitary sewage is separated with wastewater treatment, organic matter, desalination, Dynamic Membrane relies on material to enrich, make the characteristic such as simple, cheap, contamination resistance is strong, permeance property is good, cleaning and regeneration is easy there is good development prospect.But existing precoated dynamic membrane easily causes filter interior to produce bias current because plastic film mulch is uneven, the problems such as filter differential pressure increases, the cycle of operation shortens, filter element is contaminated, effluent quality deterioration are caused to still have to be solved.
Utility model content
The purpose of this utility model is that the precoated dynamic membrane that the pre-filming filter that will solve existing high ammonia nitrogen the water treatment device obtains easily causes filter interior to produce bias current because plastic film mulch is uneven, cause the problem that filter differential pressure increases, the cycle of operation shortens, filter element is contaminated, effluent quality worsens, and a kind of modification rice hull ash pre-coating film device processing rural area height ammonia nitrogen source water is provided.
The modification rice hull ash pre-coating film device processing rural area height ammonia nitrogen source water comprises intake pool, additives bucket, precoating bucket, cesspool, pre-filming filter and a discharge bay,
Described pre-filming filter comprises filter housings, tubular type filter element, air inlet pipe valve, blast pipe, exhaust solenoid valve, Pressure gauge, delivery port, collecting chamber, water inlet pipe, assignment of traffic valve, upper water distribution baffle plate and lower water distribution baffle plate, described collecting chamber is arranged on bottom filter housings, on collecting chamber top, filter housings lower sides is arranged air inlet pipe valve, described Pressure gauge is arranged on filter housing top center, and described blast pipe is arranged on filter housing top, and exhaust solenoid valve installed by blast pipe, above collecting chamber, arrange tubular type filter element in filter housings, above tubular type filter element, arrange water distribution baffle plate, arrange lower water distribution baffle plate below tubular type filter element, described water inlet pipe is through collecting chamber, lower water distribution baffle plate, enclose in upper water distribution baffle plate and tubular type filter element, described lower water distribution baffle plate is spraying head type cavity, and spraying head type cavity is by convex arc upper plate, cavity and concavity arc lower plate composition, and the uniform several apopore of convex arc upper panel surface, described water inlet pipe connects an exit branch in the cavity of lower water distribution baffle plate, described upper water distribution baffle plate is the uniform circular slab arranging several apopore, described water inlet pipe top arranges assignment of traffic valve, in described assignment of traffic valve and filter housings, cavity above upper water distribution baffle plate is communicated with,
During the topping up stage: open entering water electromagnetic valve, feed liquor flow control valve, feed liquor motor-driven valve, compression pump and pre-coating film motor-driven valve, the deionized water of splendid attire in intake pool is flowed through successively entering water electromagnetic valve, feed liquor flow control valve, feed liquor motor-driven valve, compression pump and pre-coating film motor-driven valve, enter in pre-filming filter eventually through water inlet pipe;
When being coated with mem stage: open precoating bucket liquid outlet electromagnetic valve, feed liquor flow control valve, feed liquor motor-driven valve, compression pump, pre-coating film motor-driven valve and precoating bucket liquid inlet electromagnetic valve, the pre-coating solution of splendid attire in precoating bucket is flowed through precoating bucket liquid outlet electromagnetic valve, feed liquor flow control valve, feed liquor motor-driven valve, compression pump and pre-coating film motor-driven valve successively, enter in pre-filming filter eventually through water inlet pipe, then flow back in precoating bucket by the delivery port of pre-filming filter and precoating bucket liquid inlet electromagnetic valve;
During filtration stage: open entering water electromagnetic valve, feed liquor flow control valve, additives flow control valve, additives magnetic valve, feed liquor motor-driven valve, compression pump, pre-coating film motor-driven valve and go out water solenoid valve, the pending rural area height ammonia nitrogen source water of splendid attire in intake pool is flowed through entering water electromagnetic valve successively, feed liquor flow control valve, feed liquor motor-driven valve, compression pump and pre-coating film motor-driven valve, enter in pre-filming filter eventually through water inlet pipe, additives in additives bucket are flowed through additives flow control valve successively simultaneously, additives magnetic valve, feed liquor flow control valve, feed liquor motor-driven valve, compression pump and pre-coating film motor-driven valve, enter in pre-filming filter eventually through water inlet pipe, water after process is assembled at collecting chamber, and pass through delivery port, go out water solenoid valve and rotary flowmeter enters in discharge bay,
During the backwash stage: open backwash motor-driven valve, compression pump, backwash feed liquor motor-driven valve and backwash liquid outlet electromagnetic valve, counter-flushing liquid in discharge bay is flowed through successively backwash motor-driven valve, compression pump and backwash feed liquor motor-driven valve, enter in pre-filming filter eventually through delivery port, in pre-filming filter, liquid is entered in cesspool by water inlet pipe and backwash liquid outlet electromagnetic valve.
The utility model advantage: the utility model adopts assignment of traffic valve and water distribution system to control plastic film mulch flow, and plastic film mulch process stabilization film coverage rate is high, and thickness is even; Adopt the method for supplementing additives, delay filter differential pressure increase tendency, extend filter cycle; Adopt pre-coating film technology, solve fouling membrane and film blockage problem; The utility model principle is simple, is easy to realize; Integrated film-water purification-quick-fried film integration.
Accompanying drawing explanation
Fig. 1 is the structural representation of the modification rice hull ash pre-coating film device of process rural area height ammonia nitrogen source water described in detailed description of the invention one;
Fig. 2 is
concentration-time table curve map, in figure ● in the height ammonia nitrogen source water of pending rural area
concentration-time table curve, after the process that in figure, zero expression step 5 obtains in water
concentration-time table curve.
Detailed description of the invention
Detailed description of the invention one: present embodiment is that a kind of modification rice hull ash pre-coating film device processing rural area height ammonia nitrogen source water comprises intake pool 1, additives bucket 2, precoating bucket 3, cesspool 4, pre-filming filter 5 and discharge bay 6,
Described pre-filming filter 5 comprises filter housings 5-1, tubular type filter element 5-2, air inlet pipe valve 5-3, blast pipe 5-4, exhaust solenoid valve 5-5, Pressure gauge 5-6, delivery port 5-7, collecting chamber 5-8, water inlet pipe 5-9, assignment of traffic valve 5-10, upper water distribution baffle plate 5-11 and lower water distribution baffle plate 5-12, described collecting chamber 5-8 is arranged on bottom filter housings 5-1, on collecting chamber 5-8 top, filter housings 5-1 lower sides is arranged air inlet pipe valve 5-3, described Pressure gauge 5-6 is arranged on filter housings 5-1 top center place, described blast pipe 5-4 is arranged on filter housings 5-1 top, and blast pipe 5-4 installs exhaust solenoid valve 5-5, above collecting chamber 5-8, arrange tubular type filter element 5-2 in filter housings 5-1, arrange water distribution baffle plate 5-11 above tubular type filter element 5-2, arrange lower water distribution baffle plate 5-12 below tubular type filter element 5-2, described water inlet pipe 5-9 is through collecting chamber 5-8, lower water distribution baffle plate 5-12, enclose in upper water distribution baffle plate 5-11 and tubular type filter element 5-2, described lower water distribution baffle plate 5-12 is spraying head type cavity, and spraying head type cavity is by convex arc upper plate, cavity and concavity arc lower plate composition, and the uniform several apopore of convex arc upper panel surface, described water inlet pipe 5-9 connects an exit branch in the cavity of lower water distribution baffle plate 5-12, described upper water distribution baffle plate 5-11 is the uniform circular slab arranging several apopore, described water inlet pipe 5-9 top arranges assignment of traffic valve 5-10, in described assignment of traffic valve 5-10 and filter housings 5-1, cavity above upper water distribution baffle plate 5-11 is communicated with,
During the topping up stage: open entering water electromagnetic valve 7, feed liquor flow control valve 8, feed liquor motor-driven valve 12, compression pump 14 and pre-coating film motor-driven valve 17, the deionized water of splendid attire in intake pool 1 is flowed through entering water electromagnetic valve 7, feed liquor flow control valve 8, feed liquor motor-driven valve 12, compression pump 14 and pre-coating film motor-driven valve 17 successively, enters in pre-filming filter 5 eventually through water inlet pipe 5-9;
When being coated with mem stage: open precoating bucket liquid outlet electromagnetic valve 9, feed liquor flow control valve 8, feed liquor motor-driven valve 12, compression pump 14, pre-coating film motor-driven valve 17 and precoating bucket liquid inlet electromagnetic valve 18, the pre-coating solution of splendid attire in precoating bucket 3 is flowed through precoating bucket liquid outlet electromagnetic valve 9, feed liquor flow control valve 8, feed liquor motor-driven valve 12, compression pump 14 and pre-coating film motor-driven valve 17 successively, enter in pre-filming filter 5 eventually through water inlet pipe 5-9, then flow back in precoating bucket 3 by the delivery port 5-7 of pre-filming filter 5 and precoating bucket liquid inlet electromagnetic valve 18;
During filtration stage: open entering water electromagnetic valve 7, feed liquor flow control valve 8, additives flow control valve 10, additives magnetic valve 11, feed liquor motor-driven valve 12, compression pump 14, pre-coating film motor-driven valve 17 and go out water solenoid valve 19, the pending rural area height ammonia nitrogen source water of splendid attire in intake pool 1 is flowed through entering water electromagnetic valve 7 successively, feed liquor flow control valve 8, feed liquor motor-driven valve 12, compression pump 14 and pre-coating film motor-driven valve 17, enter in pre-filming filter 5 eventually through water inlet pipe 5-9, additives in additives bucket 2 are flowed through additives flow control valve 10 successively simultaneously, additives magnetic valve 11, feed liquor flow control valve 8, feed liquor motor-driven valve 12, compression pump 14 and pre-coating film motor-driven valve 17, enter in pre-filming filter 5 eventually through water inlet pipe 5-9, water after process is assembled at collecting chamber 5-8, and by delivery port 5-7, go out water solenoid valve 19 and rotary flowmeter 20 enters in discharge bay 6,
During the backwash stage: open backwash motor-driven valve 13, compression pump 14, backwash feed liquor motor-driven valve 15 and backwash liquid outlet electromagnetic valve 16, counter-flushing liquid in discharge bay 6 is flowed through successively backwash motor-driven valve 13, compression pump 14 and backwash feed liquor motor-driven valve 15, enter in pre-filming filter 5 eventually through delivery port 5-7, in pre-filming filter 5, liquid is entered in cesspool 4 by water inlet pipe 5-9 and backwash liquid outlet electromagnetic valve 16.
Fig. 1 is the structural representation of the modification rice hull ash pre-coating film device of process rural area height ammonia nitrogen source water described in detailed description of the invention one, in figure, 1 is intake pool, 2 is additives bucket, 3 is precoating bucket, 4 is cesspool, 5 is pre-filming filter, 6 is discharge bay, 5-1 is filter housings, 5-2 is tubular type filter element, 5-3 is air inlet pipe valve, 5-4 is blast pipe, 5-5 is exhaust solenoid valve, 5-6 is Pressure gauge, 5-7 is delivery port, 5-8 is collecting chamber, 5-9 is water inlet pipe, 5-10 assignment of traffic valve, 5-11 is upper water distribution baffle plate, 5-12 is lower water distribution baffle plate, 7 is entering water electromagnetic valve, 8 is feed liquor flow control valve, 9 is precoating bucket liquid outlet electromagnetic valve, 10 is additives flow control valve, 11 is additives magnetic valve, 12 is feed liquor motor-driven valve, 13 is backwash motor-driven valve, 14 is compression pump, 15 is backwash feed liquor motor-driven valve, 16 is backwash liquid outlet electromagnetic valve, 17 is pre-coating film motor-driven valve, 18 is precoating bucket liquid inlet electromagnetic valve, 19 for going out water solenoid valve, 20 is rotary flowmeter.
The modification rice hull ash pre-coating film device of the process rural area height ammonia nitrogen source water described in present embodiment adopts the time relay to control all processes, and control system is switching system.
Detailed description of the invention two: composition graphs 1, the difference of present embodiment and detailed description of the invention one is: described additives bucket 2 is made up of additives staving 2-1 and additives agitator 2-2.Other are identical with detailed description of the invention one.
Detailed description of the invention three: composition graphs 1, one of present embodiment and detailed description of the invention one or two difference is: described precoating bucket 3 is made up of pre-coating solution staving 3-1 and pre-coating solution agitator 3-2.Other are identical with detailed description of the invention one or two.
Detailed description of the invention four: composition graphs 1, one of present embodiment and detailed description of the invention one to three difference is: described tubular type filter element 5-2 is followed successively by filter element stainless steel insert, filtering medium layer and dynamic filter cake layer from the inside to the outside.Other are identical with detailed description of the invention one to three.
The utility model content is not limited only to the content of the respective embodiments described above, and the combination of one of them or several detailed description of the invention equally also can realize the purpose of this utility model.
Adopt following verification experimental verification effect of the present invention
Embodiment 1: composition graphs 1, a kind of modification rice hull ash pre-coating film device processing rural area height ammonia nitrogen source water comprises intake pool 1, additives bucket 2, precoating bucket 3, cesspool 4, pre-filming filter 5 and discharge bay 6,
Described pre-filming filter 5 comprises filter housings 5-1, tubular type filter element 5-2, air inlet pipe valve 5-3, blast pipe 5-4, exhaust solenoid valve 5-5, Pressure gauge 5-6, delivery port 5-7, collecting chamber 5-8, water inlet pipe 5-9, assignment of traffic valve 5-10, upper water distribution baffle plate 5-11 and lower water distribution baffle plate 5-12, described collecting chamber 5-8 is arranged on bottom filter housings 5-1, on collecting chamber 5-8 top, filter housings 5-1 lower sides is arranged air inlet pipe valve 5-3, described Pressure gauge 5-6 is arranged on filter housings 5-1 top center place, described blast pipe 5-4 is arranged on filter housings 5-1 top, and blast pipe 5-4 installs exhaust solenoid valve 5-5, above collecting chamber 5-8, arrange tubular type filter element 5-2 in filter housings 5-1, arrange water distribution baffle plate 5-11 above tubular type filter element 5-2, arrange lower water distribution baffle plate 5-12 below tubular type filter element 5-2, described water inlet pipe 5-9 is through collecting chamber 5-8, lower water distribution baffle plate 5-12, enclose in upper water distribution baffle plate 5-11 and tubular type filter element 5-2, described lower water distribution baffle plate 5-12 is spraying head type cavity, and spraying head type cavity is by convex arc upper plate, cavity and concavity arc lower plate composition, and the uniform several apopore of convex arc upper panel surface, described water inlet pipe 5-9 connects an exit branch in the cavity of lower water distribution baffle plate 5-12, described upper water distribution baffle plate 5-11 is the uniform circular slab arranging several apopore, described water inlet pipe 5-9 top arranges assignment of traffic valve 5-10, in described assignment of traffic valve 5-10 and filter housings 5-1, cavity above upper water distribution baffle plate 5-11 is communicated with,
During the topping up stage: open entering water electromagnetic valve 7, feed liquor flow control valve 8, feed liquor motor-driven valve 12, compression pump 14 and pre-coating film motor-driven valve 17, the deionized water of splendid attire in intake pool 1 is flowed through entering water electromagnetic valve 7, feed liquor flow control valve 8, feed liquor motor-driven valve 12, compression pump 14 and pre-coating film motor-driven valve 17 successively, enters in pre-filming filter 5 eventually through water inlet pipe 5-9;
When being coated with mem stage: open precoating bucket liquid outlet electromagnetic valve 9, feed liquor flow control valve 8, feed liquor motor-driven valve 12, compression pump 14, pre-coating film motor-driven valve 17 and precoating bucket liquid inlet electromagnetic valve 18, the pre-coating solution of splendid attire in precoating bucket 3 is flowed through precoating bucket liquid outlet electromagnetic valve 9, feed liquor flow control valve 8, feed liquor motor-driven valve 12, compression pump 14 and pre-coating film motor-driven valve 17 successively, enter in pre-filming filter 5 eventually through water inlet pipe 5-9, then flow back in precoating bucket 3 by the delivery port 5-7 of pre-filming filter 5 and precoating bucket liquid inlet electromagnetic valve 18;
During filtration stage: open entering water electromagnetic valve 7, feed liquor flow control valve 8, additives flow control valve 10, additives magnetic valve 11, feed liquor motor-driven valve 12, compression pump 14, pre-coating film motor-driven valve 17 and go out water solenoid valve 19, the pending rural area height ammonia nitrogen source water of splendid attire in intake pool 1 is flowed through entering water electromagnetic valve 7 successively, feed liquor flow control valve 8, feed liquor motor-driven valve 12, compression pump 14 and pre-coating film motor-driven valve 17, enter in pre-filming filter 5 eventually through water inlet pipe 5-9, additives in additives bucket 2 are flowed through additives flow control valve 10 successively simultaneously, additives magnetic valve 11, feed liquor flow control valve 8, feed liquor motor-driven valve 12, compression pump 14 and pre-coating film motor-driven valve 17, enter in pre-filming filter 5 eventually through water inlet pipe 5-9, water after process is assembled at collecting chamber 5-8, and by delivery port 5-7, go out water solenoid valve 19 and rotary flowmeter 20 enters in discharge bay 6,
During the backwash stage: open backwash motor-driven valve 13, compression pump 14, backwash feed liquor motor-driven valve 15 and backwash liquid outlet electromagnetic valve 16, counter-flushing liquid in discharge bay 6 is flowed through successively backwash motor-driven valve 13, compression pump 14 and backwash feed liquor motor-driven valve 15, enter in pre-filming filter 5 eventually through delivery port 5-7, in pre-filming filter 5, liquid is entered in cesspool 4 by water inlet pipe 5-9 and backwash liquid outlet electromagnetic valve 16.
Additives bucket 2 described in the present embodiment is made up of additives staving 2-1 and additives agitator 2-2.
Precoating bucket 3 described in the present embodiment is made up of pre-coating solution staving 3-1 and pre-coating solution agitator 3-2.
Tubular type filter element 5-2 described in the present embodiment is followed successively by filter element stainless steel insert, filtering medium layer and dynamic filter cake layer from the inside to the outside, described filtering medium layer is polypropylene fibre, be wound around polypropylene fibre line at filter element stainless steel insert outer surface and obtain filtering medium layer, described dynamic filter cake layer is 4A molecular sieve, obtains dynamic filter cake layer at filtering medium layer surface attachment 4A molecular sieve.
4A molecular sieve bore diameter described above is 0.4nm, is that raw material is prepared from rice husk.
Take rice husk as the 4A molecular sieve bore diameter prepared of raw material and NH
4 +ionic diameter (NH
4 +diameter be 0.286nm) quite, be in the NH in 4A molecular sieve hole, duct
4 +ion is subject to the dispersion force effect (sphere of action is in 0.3 ~ 0.5) of each side hole wall, produces the superposition of hole wall field, forms the super effect of holes, make it attract NH
4 +ability is strong especially, therefore will replace industrial chemicals synthesis 4A molecular sieve with rice husk.
Embodiment 2: the method utilizing the modification rice hull ash pre-coating film device process rural area height ammonia nitrogen source water of the process rural area height ammonia nitrogen source water described in embodiment 1, specifically completes according to the following steps:
One, 4A molecular sieve is prepared:
Rice husk through removal of impurities, washing after through 1mol/LHCl acidifying 2h under 100 DEG C of conditions, then put under Muffle furnace completely cuts off air 800 DEG C of conditions and calcine carbonization 3h, obtain carbonization rice husk, by NaOH solution heating reflux reaction 2h under 100 DEG C of conditions of carbonization rice husk and 0.2mol/L, then centrifugal filtration, obtain sodium silicate solution, according to SiO
2with Al
2o
3mol ratio be 1.5:1, Na
2o and SiO
2mol ratio be 2.0:1 and H
2o and Na
2the mol ratio of O is that 60:1 adds NaOH, NaAlO
2and H
2o, then crystallization 8h at temperature is 90 DEG C, then put into Constant Temp. Oven dry, namely obtain 4A molecular sieve;
Two, the topping up stage: tubular type filter element step 2 prepared is as the tubular type filter element 5-2 of the modification rice hull ash pre-coating film device of process rural area height ammonia nitrogen source water, then in intake pool 1, deionized water is filled, open entering water electromagnetic valve 7, feed liquor flow control valve 8, feed liquor motor-driven valve 12, compression pump 14 and pre-coating film motor-driven valve 17, all the other valves are all closed, the deionized water of splendid attire in intake pool 1 is flowed through entering water electromagnetic valve 7 successively, feed liquor flow control valve 8, feed liquor motor-driven valve 12, compression pump 14 and pre-coating film motor-driven valve 17, enter in pre-filming filter 5 eventually through water inlet pipe 5-9, deionized water is filled to pre-filming filter 5,
Three, be coated with mem stage: described precoating bucket 3 is made up of pre-coating solution staving 3-1 and pre-coating solution agitator 3-2, start pre-coating solution agitator 3-2, be in precoating bucket 3, fill pre-coating solution under the condition of 1000r/min at rotating speed, described pre-coating solution is the mixed serum of 4A molecular sieve and water, wherein said 4A molecular sieve is 80 order 4A molecular sieves and 250 order 4A molecular sieves, and the concentration of 80 order 4A molecular sieves is 1g/L in described pre-coating solution, in described pre-coating solution, the concentration of 250 order 4A molecular sieves is 1g/L, then precoating bucket liquid outlet electromagnetic valve 9 is opened, feed liquor flow control valve 8, feed liquor motor-driven valve 12, compression pump 14, pre-coating film motor-driven valve 17 and precoating bucket liquid inlet electromagnetic valve 18, under the rotating speed of pre-coating solution agitator 3-2 is the condition of 1000r/min, the pre-coating solution of splendid attire in precoating bucket 3 is flowed through precoating bucket liquid outlet electromagnetic valve 9 successively, feed liquor flow control valve 8, feed liquor motor-driven valve 12, compression pump 14 and pre-coating film motor-driven valve 17, enter in pre-filming filter 5 eventually through water inlet pipe 5-9, flow back in precoating bucket 3 by the delivery port 5-7 of pre-filming filter 5 and precoating bucket liquid inlet electromagnetic valve 18 again, circular treatment 30min,
Four, filtration stage: described additives bucket 2 is made up of additives staving 2-1 and additives agitator 2-2, start additives agitator 2-2, be in additives bucket 2, fill additives under the condition of 1000r/min at rotating speed, described additives are mixed serums of 4A molecular sieve and water, wherein said 4A molecular sieve is 80 order 4A molecular sieves and 250 order 4A molecular sieves, and the concentration of 80 order 4A molecular sieves is 0.1g/L in described pre-coating solution, in described pre-coating solution, the concentration of 250 order 4A molecular sieves is 0.11g/L, in intake pool 1, fill pending rural area height ammonia nitrogen source water simultaneously, then entering water electromagnetic valve 7 is opened, feed liquor flow control valve 8, additives flow control valve 10, additives magnetic valve 11, feed liquor motor-driven valve 12, compression pump 14, pre-coating film motor-driven valve 17 and go out water solenoid valve 19, in intake pool 1, the pending rural area height ammonia nitrogen source water of splendid attire take flow as 0.50m
3/ h flows through entering water electromagnetic valve 7, feed liquor flow control valve 8, feed liquor motor-driven valve 12, compression pump 14 and pre-coating film motor-driven valve 17 successively, enter in pre-filming filter 5 eventually through water inlet pipe 5-9, be 0.04m with flow simultaneously under the rotating speed of additives agitator 2-2 is the condition of 1000r/min
3additives in additives bucket 2 are flowed through additives flow control valve 10, additives magnetic valve 11, feed liquor flow control valve 8, feed liquor motor-driven valve 12, compression pump 14 and pre-coating film motor-driven valve 17 by/h successively, enter in pre-filming filter 5 eventually through water inlet pipe 5-9, water after process is assembled at collecting chamber 5-8, and is 0.54m with flow
3/ h by delivery port 5-7, go out water solenoid valve 19 and rotary flowmeter 20 enters in discharge bay 6,
Five, the backwash stage: stop filtering when the pressure that filtration phase lasts moves to Pressure gauge 5-6 display is 0.20MPa, open backwash motor-driven valve 13, compression pump 14, backwash feed liquor motor-driven valve 15 and backwash liquid outlet electromagnetic valve 16, counter-flushing liquid in discharge bay 6 is flowed through backwash motor-driven valve 13 successively, compression pump 14 and backwash feed liquor motor-driven valve 15, enter in pre-filming filter 5 eventually through delivery port 5-7, in pre-filming filter 5, liquid enters in cesspool 4 by water inlet pipe 5-9 and backwash liquid outlet electromagnetic valve 16, described counter-flushing liquid is water after the process that obtains of step 4.
As shown in Figure 2, Fig. 2 is
concentration-time table curve map, in figure ● in the height ammonia nitrogen source water of pending rural area
concentration-time table curve, after the process that in figure, zero expression step 4 obtains in water
concentration-time table curve.In pending rural area height ammonia nitrogen source water described in embodiment 2 step 4
value is 0.25mg/L ~ 1.1mg/L, after the process that step 5 obtains in water
value all-the-time stable, all lower than 0.15mg/L, meets " standards for drinking water quality " (GB5749-2006).
Under film optimal conditions, utilize the modification rice hull ash pre-coating film device of process rural area height ammonia nitrogen source water to process rural area height ammonia nitrogen source water continuously and run 30d, each run 120min, Na is carried out to the 4A molecular sieve of discharging with backwash liquid
2cO
3solution physical clean and reuse, continues to recycle as precoating paint.
Claims (4)
1. one kind processes the modification rice hull ash pre-coating film device of rural area height ammonia nitrogen source water, it is characterized in that a kind of modification rice hull ash pre-coating film device processing rural area height ammonia nitrogen source water comprises intake pool (1), additives bucket (2), precoating bucket (3), cesspool (4), pre-filming filter (5) and discharge bay (6)
Described pre-filming filter (5) comprises filter housings (5-1), tubular type filter element (5-2), air inlet pipe valve (5-3), blast pipe (5-4), exhaust solenoid valve (5-5), Pressure gauge (5-6), delivery port (5-7), collecting chamber (5-8), water inlet pipe (5-9), assignment of traffic valve (5-10), upper water distribution baffle plate (5-11) and lower water distribution baffle plate (5-12), described collecting chamber (5-8) is arranged on filter housings (5-1) bottom, in collecting chamber (5-8) top, filter housings (5-1) lower sides is arranged air inlet pipe valve (5-3), described Pressure gauge (5-6) is arranged on filter housings (5-1) top center place, described blast pipe (5-4) is arranged on filter housings (5-1) top, blast pipe (5-4) is installed exhaust solenoid valve (5-5), in collecting chamber (5-8) top, tubular type filter element (5-2) is set in filter housings (5-1), in tubular type filter element (5-2) top, upper water distribution baffle plate (5-11) is set, in tubular type filter element (5-2) below, lower water distribution baffle plate (5-12) is set, described water inlet pipe (5-9) is through collecting chamber (5-8), lower water distribution baffle plate (5-12), enclose in upper water distribution baffle plate (5-11) and tubular type filter element (5-2), described lower water distribution baffle plate (5-12) is spraying head type cavity, spraying head type cavity is by convex arc upper plate, cavity and concavity arc lower plate composition, and the uniform several apopore of convex arc upper panel surface, described water inlet pipe (5-9) connects an exit branch in the cavity of lower water distribution baffle plate (5-12), described upper water distribution baffle plate (5-11) is the uniform circular slab arranging several apopore, described water inlet pipe (5-9) top arranges assignment of traffic valve (5-10), described assignment of traffic valve (5-10) is with in filter housings (5-1), the cavity of upper water distribution baffle plate (5-11) top is communicated with.
2. a kind of modification rice hull ash pre-coating film device processing rural area height ammonia nitrogen source water according to claim 1, is characterized in that described additives bucket (2) is made up of additives staving (2-1) and additives agitator (2-2).
3. a kind of modification rice hull ash pre-coating film device processing rural area height ammonia nitrogen source water according to claim 1, is characterized in that described precoating bucket (3) is made up of pre-coating solution staving (3-1) and pre-coating solution agitator (3-2).
4. a kind of modification rice hull ash pre-coating film device processing rural area height ammonia nitrogen source water according to claim 1, is characterized in that described tubular type filter element (5-2) is followed successively by filter element stainless steel insert, filtering medium layer and dynamic filter cake layer from the inside to the outside.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201520907912.7U CN205109143U (en) | 2015-11-13 | 2015-11-13 | Modified rice husk ash of handling rural high ammonia -nitrogen concentration water source water membrane device of precoating |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201520907912.7U CN205109143U (en) | 2015-11-13 | 2015-11-13 | Modified rice husk ash of handling rural high ammonia -nitrogen concentration water source water membrane device of precoating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN205109143U true CN205109143U (en) | 2016-03-30 |
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ID=55564792
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|---|---|---|---|
| CN201520907912.7U Active CN205109143U (en) | 2015-11-13 | 2015-11-13 | Modified rice husk ash of handling rural high ammonia -nitrogen concentration water source water membrane device of precoating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN205109143U (en) |
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2015
- 2015-11-13 CN CN201520907912.7U patent/CN205109143U/en active Active
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