CN204879094U - Thermoplasticity pipeline of relevant continuous fibers reinforcing - Google Patents
Thermoplasticity pipeline of relevant continuous fibers reinforcing Download PDFInfo
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- CN204879094U CN204879094U CN201520593483.0U CN201520593483U CN204879094U CN 204879094 U CN204879094 U CN 204879094U CN 201520593483 U CN201520593483 U CN 201520593483U CN 204879094 U CN204879094 U CN 204879094U
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- 239000000835 fiber Substances 0.000 title claims abstract description 21
- 230000003014 reinforcing effect Effects 0.000 title claims description 11
- 239000010410 layer Substances 0.000 claims abstract description 93
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 36
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 36
- 239000012815 thermoplastic material Substances 0.000 claims abstract description 13
- 239000011199 continuous fiber reinforced thermoplastic Substances 0.000 claims abstract description 9
- 239000003365 glass fiber Substances 0.000 claims abstract description 6
- 239000011241 protective layer Substances 0.000 claims abstract description 6
- 230000002787 reinforcement Effects 0.000 claims abstract description 4
- 238000004804 winding Methods 0.000 claims description 9
- 238000001125 extrusion Methods 0.000 claims description 5
- 238000009941 weaving Methods 0.000 claims description 5
- 229920002748 Basalt fiber Polymers 0.000 claims description 3
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 3
- 229920006231 aramid fiber Polymers 0.000 claims description 3
- 239000004917 carbon fiber Substances 0.000 claims description 3
- 238000013461 design Methods 0.000 claims description 3
- 229920001903 high density polyethylene Polymers 0.000 claims description 3
- 239000004700 high-density polyethylene Substances 0.000 claims description 3
- 239000011159 matrix material Substances 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000004800 polyvinyl chloride Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 11
- 238000000034 method Methods 0.000 abstract description 9
- 238000000465 moulding Methods 0.000 abstract description 4
- 238000004904 shortening Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 description 9
- 238000009954 braiding Methods 0.000 description 5
- 238000001816 cooling Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
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- Extrusion Moulding Of Plastics Or The Like (AREA)
- Laminated Bodies (AREA)
Abstract
本实用新型涉及玻璃纤维和管道成型技术领域,具体来说是一种有关连续纤维增强的热塑性管道,该管道由内层及内层上的编织增强结构层以及在内层和增强结构层上的外层热塑性保护层构成,三层结构一次成型,内层采用热塑性膜或片材构成,增强层采用预浸热塑性纤维纱编织、缠绕及纵向配置构成;外层采用热塑性材料在内层和增强层上用挤出机挤出而成,并使三层结构融为一体。管道规格为D1000mm以下,使用压力为1-15MPa。本实用新型保留传统的RTP管三层结构,将传统分步成型方法改变为一次成型,使生产线长度缩短一半,设备投入大大减少,产品质量更稳定,具有非常高的抗压强度和抗冲击能力,可连续生产。
The utility model relates to the technical field of glass fiber and pipe molding, and specifically relates to a continuous fiber-reinforced thermoplastic pipe. The pipe is composed of an inner layer and a braided reinforced structural layer on the inner layer, and a braided reinforced structural layer on the inner layer and the reinforced structural layer. The outer thermoplastic protective layer is composed of a three-layer structure formed at one time. The inner layer is made of thermoplastic film or sheet. The reinforcement layer is made of pre-impregnated thermoplastic fiber yarns that are woven, wound and arranged longitudinally. The outer layer is made of thermoplastic materials in the inner layer and reinforcement layer. It is extruded with an extruder and the three-layer structure is integrated into one. The pipe specification is D1000mm or less, and the operating pressure is 1-15MPa. This utility model retains the traditional three-layer structure of RTP pipes and changes the traditional step-by-step molding method to one-time molding, shortening the length of the production line by half, greatly reducing equipment investment, making the product quality more stable, and having very high compressive strength and impact resistance. , can be produced continuously.
Description
[技术领域][technical field]
本实用新型涉及玻璃纤维和管道成型技术领域,具体来说是一种有关连续纤维增强的热塑性管道。The utility model relates to the technical field of glass fiber and pipe forming, in particular to a continuous fiber reinforced thermoplastic pipe.
[背景技术][Background technique]
近十年来,连续纤维增强热塑性管道(ReinforcedThermoplasticPipes)一直是国际管道领域热门的研究方向,因为它有非常明显的优点,既能发挥纤维的高强度,承受高压,又能保持热塑性塑料良好的柔韧性及耐腐蚀性,在石油输送管、燃气管、给排水管等高压管应用方面有着广阔的市场。In the past ten years, continuous fiber reinforced thermoplastic pipes (Reinforced Thermoplastic Pipes) have been a popular research direction in the international pipeline field, because it has very obvious advantages, which can not only exert the high strength of fibers, withstand high pressure, but also maintain the good flexibility of thermoplastics And corrosion resistance, it has a broad market in the application of high-pressure pipes such as oil pipelines, gas pipes, water supply and drainage pipes.
传统的RTP管分三层结构,即内、外为挤出热塑性塑料层,中间为纤维增强层或钢丝增强层。所采用的方法是先挤出热塑性内层管,再在内层上缠绕增强层,最后挤出外表面保护层。如专利文件CN103878990A中所述,这种方法生产的产品抗压能力高,安全性好,但这种工艺生产线很长,一般需要80M长左右,对于多层增强厚管甚至要100M以上,由于对层与层之间加温熔融技术要求较高,控制不好,容易出现质量问题,目前,成熟的欧洲生产线大约需要2000-3000万人民币,国内的生产线还在研发阶段,预计也需要1000万人民币以上,这种高成本投入,低效率生产阻碍了RTP管的应用。专利文件CN102363363A中所述的方法虽然简单,但目前纤维的在线浸胶技术还远达不到要求,纤维难以浸透,所生产的产品微气泡太多,不能作为抗高压产品使用。如果纤维采用编织型式增强,该方法则根本行不通。The traditional RTP pipe has a three-layer structure, that is, the inner and outer layers are extruded thermoplastic layers, and the middle layer is a fiber-reinforced layer or a steel wire-reinforced layer. The method adopted is to extrude a thermoplastic inner layer tube first, then wind a reinforcement layer on the inner layer, and finally extrude an outer surface protection layer. As described in the patent document CN103878990A, the products produced by this method have high compressive capacity and good safety, but the production line of this process is very long, generally about 80M long, and even more than 100M for multi-layer reinforced thick tubes. The technology of heating and melting between layers is relatively high, the control is not good, and quality problems are prone to occur. At present, the mature European production line needs about 20-30 million RMB. The domestic production line is still in the research and development stage, and it is expected to need 10 million RMB. Above, this kind of high cost investment and low efficiency production hinder the application of RTP pipe. Although the method described in the patent document CN102363363A is simple, the current online fiber dipping technology is far from meeting the requirements, the fiber is difficult to soak, and the product produced has too many microbubbles, so it cannot be used as a high-pressure resistant product. This approach simply does not work if the fibers are reinforced in a braided form.
[发明内容][Content of the invention]
本实用新型的目的是为了克服传统的生产玻璃纤维增强热塑性管道的缺陷,根据热固性拉挤成型的技术原理,结合热塑性挤出方法,采用热塑性膜或片材构成内层,在内层上设有预浸热塑性纤维纱编织、缠绕及纵向配置构成增强层,在内层和增强层上设有外层,外层采用挤出机挤出成型,并使三层结构融为一体一次成型的有关连续纤维增强的热塑性管道。这种产品韧性好,抗压高,质量稳定,且耐腐蚀,使用寿命长,在给排水、燃气管、石油输送管等领域有广阔的应用前景,而且该方法生产设备投入少,占用场地小,具有重要的实用价值。The purpose of this utility model is to overcome the defects of the traditional production of glass fiber reinforced thermoplastic pipes. According to the technical principle of thermosetting pultrusion and combined with thermoplastic extrusion methods, thermoplastic films or sheets are used to form the inner layer. Pre-impregnated thermoplastic fiber yarn is braided, wound and longitudinally arranged to form a reinforced layer, and an outer layer is arranged on the inner layer and the reinforced layer. The outer layer is extruded by an extruder, and the three-layer structure is integrated into a continuous molding process. Fiber reinforced thermoplastic pipes. This product has good toughness, high compression resistance, stable quality, corrosion resistance, and long service life. It has broad application prospects in the fields of water supply and drainage, gas pipes, oil pipelines, etc., and this method requires less investment in production equipment and occupies a small space. , which has important practical value.
为了实现上述目的,设计一种有关连续纤维增强的热塑性管道,该管道由热塑性内层及内层上的编织增强结构层,以及在内层和增强结构层上设有外层热塑性保护层组成,所述的三层结构通过拉挤和挤出混合法一次成型,所述的内层采用热塑性膜或片材构成;所述的增强层采用预浸热塑性纤维纱编织、缠绕及纵向配置构成;所述的外层采用热塑性材料在内管和增强层上用挤出机挤出而成,并使三层结构融为一体;所述的管道规格为D1000mm以下,使用压力1-15MPa。In order to achieve the above purpose, a continuous fiber reinforced thermoplastic pipe is designed, which consists of a thermoplastic inner layer and a braided reinforced structural layer on the inner layer, and an outer thermoplastic protective layer on the inner layer and the reinforced structural layer. The three-layer structure is formed by pultrusion and extrusion mixing at one time, the inner layer is made of thermoplastic film or sheet; the reinforcing layer is made of pre-impregnated thermoplastic fiber yarn weaving, winding and longitudinal arrangement; The outer layer is extruded by an extruder on the inner tube and the reinforcing layer of thermoplastic material, and the three-layer structure is integrated; the specification of the pipeline is below D1000mm, and the working pressure is 1-15MPa.
所述的内层由热塑性膜或片材以缠绕或者纵向方式构成,在融熔温度下形成整体内层,厚度约0.2-2mm。The inner layer is made of a thermoplastic film or sheet in a winding or longitudinal manner, and forms an integral inner layer at a melting temperature with a thickness of about 0.2-2mm.
所述的增强层是将预浸有热塑性材料的纤维按设计要求进行编织、缠绕、纵向配置到内层上,其厚度由强度要求决定。The reinforcing layer is made by braiding, winding and longitudinally disposing the fiber pre-impregnated with thermoplastic material on the inner layer according to the design requirements, and its thickness is determined by the strength requirement.
所述的外层是采用热塑性材料在内层和增强层融熔时,用挤出机加压挤出补料,使三层结构融为一体,并在其表面形成厚度为0.5-2mm的热塑性保护层。The outer layer is made of thermoplastic material, when the inner layer and the reinforcing layer are melted, the extruder is used to pressurize and extrude the supplementary material, so that the three-layer structure is integrated, and a thermoplastic layer with a thickness of 0.5-2mm is formed on the surface. The protective layer.
所述的纤维采用为玻璃纤维或玄武岩纤维或碳纤维或芳纶纤维等。The fiber is adopted as glass fiber or basalt fiber or carbon fiber or aramid fiber.
所述的热塑性材料为PVC或PE或HDPE或PP或PA或其他改性热塑性塑料基体。The thermoplastic material is PVC or PE or HDPE or PP or PA or other modified thermoplastic matrix.
本实用新型同现有技术相比,产品结构设计合理,保留现有的RTP管三层结构,但却是一次成型的一个完整的整体,创造性的采用拉挤/挤出混合法生产出一种全新的产品,并使使产品质量得到了一个飞跃,产品质量更稳定,具有非常高的抗压强度及抗冲击能力,产品内、外层厚度可达到0.5mm左右,这是传统RTP管无法实现的,大大降低了产品成本,可连续生产。Compared with the prior art, the utility model has a reasonable product structure design, retains the existing three-layer structure of the RTP pipe, but is a complete whole formed at one time, and creatively adopts the pultrusion/extrusion mixing method to produce a The brand new product has made a leap in product quality. The product quality is more stable, with very high compressive strength and impact resistance. The thickness of the inner and outer layers of the product can reach about 0.5mm, which is impossible for traditional RTP pipes. , which greatly reduces the product cost and can be produced continuously.
[附图说明][Description of drawings]
图1是本实用新型的断面结构示意图;Fig. 1 is the sectional structure schematic diagram of the present utility model;
图2是本实用新型的生产线的结构示意图;Fig. 2 is the structural representation of production line of the present utility model;
图1中:21.外管22.增强层23.内管;In Fig. 1: 21. Outer pipe 22. Reinforcing layer 23. Inner pipe;
图2中:1.内热塑性层2.内编织机3.缠绕机4.外编织机5.芯模6.外模具7.加热圈8.螺杆挤出机9.挤出模头10.内加热棒11.定型套12.真空定型箱13.冷却箱14.牵引机15.切割机;In Figure 2: 1. Inner thermoplastic layer 2. Inner braiding machine 3. Winding machine 4. Outer braiding machine 5. Mandrel 6. Outer mold 7. Heating ring 8. Screw extruder 9. Extrusion die head 10. Inner Heating rod 11. Shaping sleeve 12. Vacuum calibrating box 13. Cooling box 14. Tractor 15. Cutting machine;
指定图1作为本实用新型的摘要附图。Designate Fig. 1 as the abstract accompanying drawing of the utility model.
[具体实施方式][Detailed ways]
下面结合附图对本实用新型作进一步说明,这种装置的结构和原理对本专业的人来说是非常清楚的。应当理解,此处所描述的具体实施例仅仅用以解释本实用新型,并不用于限定本实用新型。Below in conjunction with accompanying drawing, the utility model is further described, and the structure and principle of this device are very clear to those skilled in the art. It should be understood that the specific embodiments described here are only used to explain the utility model, and are not intended to limit the utility model.
如图1所示,本实用新型中的管道由内层及内层上编织增强层结构,在增强层结构上设有外层,三层结构一次成型而成,内层采用热塑性膜或片材构成,增强层采用预浸热塑性纤维纱编织、缠绕及纵向配置构成;外层在内层和增强层的热塑性材料融熔时,用挤出机加压挤出补料,使三层结构融为一体,并在表面形成热塑性保护层。管道规格为D1000mm以下,使用压力为1-15MPa,纤维采用为玻璃纤维、玄武岩纤维、碳纤维、芳纶纤维等。热塑性材料为PVC、PE、HDPE、PP、PA或改性热塑性塑料基体。As shown in Figure 1, the pipeline in the utility model is composed of an inner layer and a reinforced layer structure braided on the inner layer, and an outer layer is arranged on the reinforced layer structure. The three-layer structure is formed at one time, and the inner layer is made of thermoplastic film or sheet Composition, the reinforcing layer is made of pre-impregnated thermoplastic fiber yarn weaving, winding and longitudinal arrangement; when the thermoplastic material of the outer layer and the inner layer and the reinforcing layer are melted, the extruder is used to pressurize and extrude the supplementary material, so that the three-layer structure is fused. One piece, and form a thermoplastic protective layer on the surface. The pipe specification is below D1000mm, the working pressure is 1-15MPa, and the fibers are glass fiber, basalt fiber, carbon fiber, aramid fiber, etc. The thermoplastic material is PVC, PE, HDPE, PP, PA or modified thermoplastic matrix.
本实用新型所设计的生产线如图1,先在前端芯模上包覆内热塑性层,然后是纤维的内编织、缠绕、外编织复合的多层纤维结构,中段是加热的外模与芯模及挤出机、模头、内加热共同构成的核心所在,后段是热塑性塑料生产通用的真空定型箱、冷却箱、牵引机、切割机等。The production line designed by the utility model is shown in Figure 1. First, the inner thermoplastic layer is coated on the front-end mandrel, and then the multi-layer fiber structure is composed of inner weaving, winding and outer weaving of fibers. The middle section is the heated outer mold and mandrel. And extruder, die head, internal heating constitute the core. The latter part is the vacuum calibrating box, cooling box, tractor, cutting machine, etc. commonly used in thermoplastics production.
具体生产方法为:先将热塑性膜或片材均匀包覆在芯模5上,再将有热塑性预浸料的纤维通过内编织机2进行编织,然后缠绕机3进行缠绕环向层,再通过外编织机4编织,构成多层增强结构,在牵引机14作用下,送入加热内模5、外模6的模腔内加热,加热温度根据不同的材料确定,使纤维表面的热塑性材料达到熔融状态,和由螺杆挤出机8挤出的热塑性料在模头9段融合在一起,形成整体。模头加热由外加热圈7和内加热棒10共同完成,出来的管道经过定型套11及真空定型箱12定型,再经过冷却箱13完全冷却,最后通过牵引机14进入切割机15,按要求长度进行切割,成为成品。The specific production method is as follows: First, the thermoplastic film or sheet is evenly coated on the mandrel 5, and then the fibers with thermoplastic prepreg are woven through the inner braiding machine 2, and then the winding machine 3 is used to wrap the circumferential layer, and then through The outer braiding machine 4 weaves to form a multi-layer reinforced structure. Under the action of the tractor 14, it is sent into the cavity of the heated inner mold 5 and outer mold 6 for heating. The heating temperature is determined according to different materials, so that the thermoplastic material on the fiber surface reaches The molten state, and the thermoplastic material extruded by the screw extruder 8 are fused together at the die head 9 sections to form a whole. The heating of the die head is completed by the outer heating ring 7 and the inner heating rod 10. The pipe that comes out is shaped by the calibrating sleeve 11 and the vacuum calibrating box 12, and then completely cooled by the cooling box 13, and finally enters the cutting machine 15 through the tractor 14, and is processed according to the requirements. Cut to length to become a finished product.
Claims (6)
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CN105003753A (en) * | 2015-08-07 | 2015-10-28 | 广东宝通玻璃钢有限公司 | Thermoplastic pipeline related to continuous fiber reinforcement and producing method |
CN110094579A (en) * | 2019-04-02 | 2019-08-06 | 浙江中财管道科技股份有限公司 | A kind of high voltage, haloflex multiple tube of high bending performance and preparation method thereof |
CN115871259A (en) * | 2022-11-15 | 2023-03-31 | 安徽杰蓝特新材料有限公司 | An impact-resistant RTP pressure pipe |
WO2023103110A1 (en) * | 2021-12-10 | 2023-06-15 | 公元股份有限公司 | Processing method for one-step forming of continuous fiber-reinforced composite pipe |
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2015
- 2015-08-07 CN CN201520593483.0U patent/CN204879094U/en active Active
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105003753A (en) * | 2015-08-07 | 2015-10-28 | 广东宝通玻璃钢有限公司 | Thermoplastic pipeline related to continuous fiber reinforcement and producing method |
CN105003753B (en) * | 2015-08-07 | 2017-10-20 | 广东宝通玻璃钢有限公司 | About the thermoplastic pipe and production method of continuous lod |
CN110094579A (en) * | 2019-04-02 | 2019-08-06 | 浙江中财管道科技股份有限公司 | A kind of high voltage, haloflex multiple tube of high bending performance and preparation method thereof |
WO2023103110A1 (en) * | 2021-12-10 | 2023-06-15 | 公元股份有限公司 | Processing method for one-step forming of continuous fiber-reinforced composite pipe |
CN115871259A (en) * | 2022-11-15 | 2023-03-31 | 安徽杰蓝特新材料有限公司 | An impact-resistant RTP pressure pipe |
FR3155051A1 (en) * | 2023-11-08 | 2025-05-09 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Method of manufacturing a sealed tank for containing a gas and/or a fluid |
EP4552817A1 (en) * | 2023-11-08 | 2025-05-14 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Method for manufacturing a sealed tank for containing a gas and/or a fluid |
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