CN204873820U - Device for preparing hydrogen by reacting liquid phase alloy with seawater - Google Patents
Device for preparing hydrogen by reacting liquid phase alloy with seawater Download PDFInfo
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- CN204873820U CN204873820U CN201520431780.5U CN201520431780U CN204873820U CN 204873820 U CN204873820 U CN 204873820U CN 201520431780 U CN201520431780 U CN 201520431780U CN 204873820 U CN204873820 U CN 204873820U
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- seawater
- liquid phase
- hydrogen
- phase alloy
- reaction tank
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- 239000001257 hydrogen Substances 0.000 title claims abstract description 66
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 66
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 62
- 239000013535 sea water Substances 0.000 title claims abstract description 54
- RZJQYRCNDBMIAG-UHFFFAOYSA-N [Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Zn].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn] Chemical class [Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Zn].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn] RZJQYRCNDBMIAG-UHFFFAOYSA-N 0.000 title claims abstract description 41
- 239000007791 liquid phase Substances 0.000 title claims abstract description 41
- 238000006243 chemical reaction Methods 0.000 claims abstract description 41
- 239000000446 fuel Substances 0.000 claims abstract description 33
- 238000011084 recovery Methods 0.000 claims abstract description 11
- 229910001338 liquidmetal Inorganic materials 0.000 claims description 15
- 238000005868 electrolysis reaction Methods 0.000 claims description 6
- 150000002431 hydrogen Chemical class 0.000 claims description 4
- 238000000034 method Methods 0.000 abstract description 7
- 238000011161 development Methods 0.000 abstract description 3
- 229910052751 metal Inorganic materials 0.000 description 15
- 239000002184 metal Substances 0.000 description 15
- 238000004519 manufacturing process Methods 0.000 description 10
- 229910045601 alloy Inorganic materials 0.000 description 9
- 239000000956 alloy Substances 0.000 description 9
- 229910052782 aluminium Inorganic materials 0.000 description 8
- 239000004411 aluminium Substances 0.000 description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 7
- MPZNMEBSWMRGFG-UHFFFAOYSA-N bismuth indium Chemical compound [In].[Bi] MPZNMEBSWMRGFG-UHFFFAOYSA-N 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000012535 impurity Substances 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229910000846 In alloy Inorganic materials 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000002203 pretreatment Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 229910001369 Brass Inorganic materials 0.000 description 2
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 238000005275 alloying Methods 0.000 description 2
- XFBXDGLHUSUNMG-UHFFFAOYSA-N alumane;hydrate Chemical compound O.[AlH3] XFBXDGLHUSUNMG-UHFFFAOYSA-N 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000010951 brass Substances 0.000 description 2
- 229910052733 gallium Inorganic materials 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910001128 Sn alloy Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910001297 Zn alloy Inorganic materials 0.000 description 1
- WGCXSIWGFOQDEG-UHFFFAOYSA-N [Zn].[Sn].[In] Chemical compound [Zn].[Sn].[In] WGCXSIWGFOQDEG-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000006263 metalation reaction Methods 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000037361 pathway Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Landscapes
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
The utility model provides a device for preparing hydrogen by reacting liquid phase alloy with seawater. The device comprises: the device comprises a reaction tank, a liquid phase alloy fuel supply tank and a seawater supply tank which are respectively connected with the inlet end of the reaction tank, and a hydrogen gas cavity and a recovery tank which are respectively connected with the outlet end of the reaction tank. The utility model provides a scheme can be used to the ocean navigation and directly acquires the energy and even the supply of the global energy, can greatly promote the development of sea water hydrogen energy utilization technique, has wide application prospect.
Description
Technical field
The utility model belongs to hydrogen preparation field, is specifically related to a kind of liquid phase alloy and seawater reacts the device preparing hydrogen.
Background technology
Hydrogen is the high clean energy of a kind of generating efficiency, is to replace the more promising clean energy of of traditional energy, therefore, widely payes attention to for a long time the acquisition of hydrogen for academia and industry member.In various approach, a kind of typical method obtaining hydrogen is produced by the means water of decomposition such as optical, electrical, but still there is larger challenge in quick, low cost, less energy-consumption.
As everyone knows, the earth has close to 3/4ths area all by water is covered, wherein seawater accounts for more than 90% of total Water.The seawater of rich reserves provides a large amount of water sources, for the mankind, is inexhaustible, but due to sea water salinity high, cannot directly utilize.Along with the exhaustion day by day of fossil oil, trend is probably obtained hydrogen on a large scale by the final approach that the mankind solve the energy from seawater.Undoubtedly, if can directly utilize seawater to manufacture hydrogen in low cost mode, the problems such as current energy dilemma, environmental pollution and even economic crisis will greatly be alleviated.But owing to being dissolved with various salinity, complex genesis in seawater, dispose comparatively difficulty, this makes directly to obtain hydrogen and faces many technical bottlenecks, and cause the use cost of prior art still to remain high, efficiency is lower, and energy consumption is high.In addition, hydrogen is inflammable and explosive, makes rear needs and is carefully stored, and utilizes the security requirement of link high to transportation, hydrogenation etc.Generally, the links such as current hydrogen producing technology, banking system and transport pathway still seriously limit the utilization of Hydrogen Energy.
In various hydrogen producing technology, the hydrolysis reaction quick obtaining hydrogen of aluminium based metal material is directly utilized to be paid much attention in recent years, this is because, metallic aluminium can to react generation hydrogen with water, therefore can guarantee on-the-spot hydrogen manufacturing and instant hydrogen supply, and aluminium is the metal that on the earth, reserves are maximum, wide material sources, cost is lower, and these factors ensure that the wide application prospect of this hydrogen production process.But existing aluminum-water reaction hydrogen manufacturing exists a natural deficiency, and namely metallic aluminium is easy to oxidized, the fine and close protective membrane of its Surface Creation can cause aluminum-water reaction process can not continue to carry out.A kind of effective way improving this process is alloying, alloy or compound is made by aluminium, like this after adding the aqueous solution, the oxide film that to a certain degree can reduce aluminium surface continues to be formed, thus guarantee the carrying out producing H-H reaction, therefore this alloying hydrogen manufacturing mode steps into the people visual field in recent years, for hydrogen utilization brings new hope.But this method also exists core technology bottleneck, e.g., alloy is made to be needed to pass through high-temperature firing, energy consumption can be increased thus, and the solid alloy made and the catalytic specific surface area of the aqueous solution less, this makes hydrogen generation efficiency on the low side, and thus the method is still not easily practical.
Utility model content
The utility model is intended to overcome defect of the prior art, provides a kind of liquid phase alloy and seawater to react the device preparing hydrogen.
Described device comprises: liquid phase alloy fuel and seawater carry out the reaction tank reacted, the liquid phase alloy fuel replenishing basin be connected with described reaction tank inlet end respectively and seawater replenishing basin, and the hydrogen chamber be connected with described reaction tank exit end respectively and pond for recovering.
The inwall of described reaction tank is uneven surface.Keep the surface of certain roughness can strengthen contact area between liquid phase alloy fuel and seawater, wall, thus improve hydrogen output capacity.
Well heater and agitator is provided with in described reaction tank.Under the condition needed, reaction can be promoted by the mode heated and/or stir, improve the productive rate of hydrogen.
Described liquid phase alloy fuel replenishing basin is connected with reaction tank with the pipeline of valve respectively by being provided with pump with seawater replenishing basin.Described pump and valve are used for liquid phase alloy fuel and seawater to pump into reaction tank.The raw material adopted due to the utility model is liquid, and the energy pumped into by raw material needed for reaction tank is less, and the energy derive of described pump can be battery.
Described seawater replenishing basin is also connected with seawater with the pipeline of valve by being provided with pump.On the described pipeline be connected with seawater, 20nm ~ 20, aperture μm non-corrosibility plastic filter screen can be provided with, be preferably the non-corrosibility plastic filter screen of aperture 500nm.Described filtering net can remove the impurity contained in seawater, thus prevents impurity and liquid phase alloy fuel from reacting, and guarantees that seawater fully contacts with liquid phase alloy fuel, improves the efficiency preparing hydrogen reaction.
Be provided with the separator for separating of liquid metal in described pond for recovering, liquid metal can be separated from the reaction system after collection hydrogen.Described separator can also be connected with liquid phase alloy fuel replenishing basin by recovery channel, the liquid metal after reclaiming is inputted liquid phase alloy fuel replenishing basin, thus realizes the recycling to noble metal.
The electrolysis electrode obtaining producing hydrogen metal for electrolytic reduction is also provided with in described pond for recovering.Described electrolysis electrode is used for being become by waste liquid electrolytic reduction fine aluminium etc. to produce hydrogen metal.Described electrolysis electrode is preferably the one in platinum, carbon, graphite, gold, stainless steel.
Utilize the device that the utility model provides, the liquid phase alloy fuel containing liquid metal and hydrogen manufacturing metal can be pumped into reaction tank, in reaction tank, pump into seawater, alloy fuel and seawater fully react and can produce hydrogen simultaneously; As required, suitably can add mild stirring, to control whole hydrogen production process; Be reduced to pure hydrogen manufacturing metal and liquid metal once again after reaction residue is separated again, again make liquid phase alloy fuel, producing hydrogen for reacting with seawater once again, realizing circulation hydrogen production process thus.
In the device that the utility model provides, only need stop the supply of alloy fuel, then hydrogen weakens or interrupts, and controls corresponding hydrogen thus and exports.
The device that theres is provided of the utility model is provided, liquid phase alloy and seawater can be realized according to the method comprised the following steps and react and prepare hydrogen:
(1) liquid metal and product hydrogen metal are mixed with mass ratio 80 ~ 99:1 ~ 20, obtain liquid phase alloy fuel;
Described liquid metal is selected from gallium, gallium-indium alloy, gallium-indium-tin alloy, gallium indium tin zinc alloy, bismuth indium alloy, bismuth indium stannum alloy, bismuth indium red brass, bismuth-base alloy as bismuth indium alloy, bismuth indium stannum alloy, bismuth indium red brass; Described product hydrogen metal is selected from aluminium, zinc, magnesium;
(2) described liquid phase alloy fuel is mixed with volume ratio 1 ~ 10:50 ~ 90 with seawater, 15 ~ 90 DEG C, with the speed agitation condition of 1 ~ 100r/min under fully react, collect hydrogen.
Liquid metal described in the utility model is the metal or alloy be in a liquid state under room temperature.
Before described seawater mixes with liquid phase alloy fuel, can through pre-treatment, described pre-treatment can remove the impurity contained in seawater, thus guarantees that seawater fully contacts with liquid phase alloy fuel, prevent impurity and liquid phase alloy fuel from reacting, improve the efficiency preparing hydrogen reaction.Described pre-treatment comprises the following steps: be that a 20nm ~ 20 μm filter screen filters seawater with aperture, and described aperture is preferably 500nm.
As required, temperature can also be adjusted and stir in reaction process, to control whole hydrogen production process, liquid phase alloy fuel and seawater fully being reacted, improving the output of hydrogen.
In order to realize making full use of of resource, described method can also comprise the following steps: the reaction system after collecting hydrogen carried out being separated, reducing, and obtains liquid metal and produces hydrogen metal, and preparation liquid phase alloy fuel, realizes recycle.
The scheme that the utility model provides can obtain following beneficial effect: the liquid phase alloy seawater device for producing hydrogen that the utility model provides can realize easy, quick, efficiently prepare hydrogen, and this device can on-demand hydrogen generation, thus substantially increases security and the handiness of use.The development of this technology, by greatly promoting the development of seawater hydrogen utilization technology, has broad application prospects.This technology can be used for supply ocean navigation directly obtaining the energy and even global energy.
Accompanying drawing explanation
Fig. 1 reacts the structural representation preparing hydrogen device for liquid phase alloy described in embodiment 1 and seawater; In figure, 1-liquid phase alloy fuel replenishing basin; 2-reaction tank; 4-seawater replenishing basin; 6-well heater; 7-agitator; 8-hydrogen chamber; 9-pond for recovering; 91-separator; 92-electrolysis electrode; 11-liquid phase alloy fuel replenishing basin pipeline; The external pump of 12-liquid phase alloy fuel replenishing basin and valve; 31-reaction tank external pipe; The external pump of 32-reaction tank and valve; 41-seawater replenishing basin external pipe; The external pump of 42-seawater replenishing basin and valve; 93-liquid metal recovery channel; 94-liquid metal recovery pump and valve; 95-produces hydrogen metal recovery pump and valve; 96-produces hydrogen metal recovery pipeline.
Embodiment
Following examples for illustration of the utility model, but are not used for limiting scope of the present utility model.
Embodiment 1
A kind of liquid phase alloy and seawater react the device (as shown in Figure 1) preparing hydrogen, described device comprises: liquid phase alloy fuel and seawater carry out the reaction tank 2 reacted, the liquid phase alloy fuel replenishing basin 1 be connected with described reaction tank inlet end respectively and seawater replenishing basin 4, and the hydrogen chamber 8 be connected with described reaction tank exit end respectively and pond for recovering 9;
The inwall of described reaction tank 2 is uneven surface; Well heater 6 and agitator 7 is provided with in reaction tank;
Described liquid phase alloy fuel replenishing basin 1 is connected with reaction tank 3 with the liquid phase alloy fuel replenishing basin pipeline 11 of valve 12 by being provided with the external pump of liquid phase alloy fuel replenishing basin;
Described seawater replenishing basin 4 is connected with reaction tank 3 with the reaction tank external pipe 31 of valve 32 by being provided with the external pump of reaction tank; Described seawater replenishing basin 4 is also connected with seawater with the seawater replenishing basin external pipe 41 of valve 42 by being provided with the external pump of seawater replenishing basin; On described pipeline 41, be provided with aperture 500nm non-corrosibility plastic filter screen;
Be provided with the separator 91 for separating of liquid metal in described pond for recovering 9, described separator 91 is also connected with liquid phase alloy fuel replenishing basin 1 with the liquid metal recovery channel 93 of valve 94 by being provided with liquid metal recovery pump;
Also be provided with the electrolysis electrode 92 obtaining producing hydrogen metal for electrolytic reduction in described pond for recovering 9, anode and cathode is the Graphite Electrodes of 5mm × 15mm; The product hydrogen metal that electrolytic reduction obtains exports by being provided with the product hydrogen metal recovery pipeline 96 producing hydrogen metal recovery pump and valve 95.
Embodiment 2
Compared with embodiment 1, difference is only: the aperture of described filter screen is 20nm.
Although above with general explanation, embodiment and test, done detailed description to the utility model, on the utility model basis, can make some modifications or improvements it, this will be apparent to those skilled in the art.Therefore, these modifications or improvements on the basis of not departing from the utility model spirit, all belong to the scope that the utility model is claimed.
Claims (8)
1. a liquid phase alloy and seawater react the device preparing hydrogen, it is characterized in that, described device comprises: reaction tank, the liquid phase alloy fuel replenishing basin be connected with described reaction tank inlet end respectively and seawater replenishing basin, and the hydrogen chamber be connected with described reaction tank exit end respectively and pond for recovering.
2. device according to claim 1, is characterized in that, described liquid phase alloy fuel replenishing basin is connected with reaction tank with the pipeline of valve respectively by being provided with pump with seawater replenishing basin.
3. device according to claim 1 and 2, is characterized in that, described seawater replenishing basin is also connected with seawater with the pipeline of valve by being provided with pump;
On the described pipeline be connected with seawater, be provided with the non-corrosibility plastic filter screen of 20nm ~ 20, aperture μm.
4. device according to claim 3, is characterized in that, on the described pipeline be connected with seawater, is provided with the non-corrosibility plastic filter screen of aperture 500nm.
5. device according to claim 1, is characterized in that, the inwall of described reaction tank is uneven surface.
6. device according to claim 5, is characterized in that, is provided with well heater and agitator in described reaction tank.
7. device according to claim 1, is characterized in that, is provided with separator and electrolysis electrode in described pond for recovering.
8. device according to claim 7, is characterized in that, described separator is also connected with described liquid phase alloy fuel replenishing basin by liquid metal recovery channel.
Priority Applications (1)
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CN201520431780.5U CN204873820U (en) | 2015-06-19 | 2015-06-19 | Device for preparing hydrogen by reacting liquid phase alloy with seawater |
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CN201520431780.5U CN204873820U (en) | 2015-06-19 | 2015-06-19 | Device for preparing hydrogen by reacting liquid phase alloy with seawater |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105417495A (en) * | 2015-12-29 | 2016-03-23 | 杜善骥 | Underwater-type magnesium-gallium-alloy hydrogen production device working method |
CN106315509A (en) * | 2015-06-19 | 2017-01-11 | 中国科学院理化技术研究所 | Method and device for preparing hydrogen by reacting liquid phase alloy with seawater |
CN106744679A (en) * | 2016-12-29 | 2017-05-31 | 云南靖创液态金属热控技术研发有限公司 | Hydrogen production process and mechanism |
-
2015
- 2015-06-19 CN CN201520431780.5U patent/CN204873820U/en active Active
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106315509A (en) * | 2015-06-19 | 2017-01-11 | 中国科学院理化技术研究所 | Method and device for preparing hydrogen by reacting liquid phase alloy with seawater |
CN105417495A (en) * | 2015-12-29 | 2016-03-23 | 杜善骥 | Underwater-type magnesium-gallium-alloy hydrogen production device working method |
CN106744679A (en) * | 2016-12-29 | 2017-05-31 | 云南靖创液态金属热控技术研发有限公司 | Hydrogen production process and mechanism |
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