CN204848550U - Industrial waste water treatment system - Google Patents

Industrial waste water treatment system Download PDF

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Publication number
CN204848550U
CN204848550U CN201520512292.7U CN201520512292U CN204848550U CN 204848550 U CN204848550 U CN 204848550U CN 201520512292 U CN201520512292 U CN 201520512292U CN 204848550 U CN204848550 U CN 204848550U
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tank
treatment system
reverse osmosis
concentrated water
osmosis membrane
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杨金
李春梅
张兆昌
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BEIJING WEALTH ENVIRONMENTAL ENGINEERING Co Ltd
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BEIJING WEALTH ENVIRONMENTAL ENGINEERING Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/30Wastewater or sewage treatment systems using renewable energies
    • Y02W10/37Wastewater or sewage treatment systems using renewable energies using solar energy

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Abstract

本实用新型提供了一种工业废水处理系统,包括依次相连的调节池、混合池、混凝沉淀池、一级中间水池、陶瓷超滤膜组件、二级中间水池、反渗透膜组件、产品水箱;所述混凝沉淀池上分别设置有PAC加药装置、PAM加药装置和污泥池;所述污泥池还与板框压滤机连接;所述陶瓷超滤膜组件的一端设置有超滤膜清洗装置,另一端依次设置有浓水储存池、三效蒸发器和脱水机;所述反渗透膜组件一端设置有反渗透膜清洗装置,另一端依次设置有浓水储存池、三效蒸发器和脱水机。本实用新型的处理系统,不仅可去除废水中的氟离子、氮、磷、悬浮物等污染物质,还能实现出水氮、磷零排放,无浓水排放,工艺流程简单、操作方便。

The utility model provides an industrial wastewater treatment system, which comprises a regulating tank, a mixing tank, a coagulation sedimentation tank, a primary intermediate pool, a ceramic ultrafiltration membrane assembly, a secondary intermediate pool, a reverse osmosis membrane assembly, and a product water tank connected in sequence. ; The coagulation sedimentation tank is respectively provided with a PAC dosing device, a PAM dosing device and a sludge tank; the sludge tank is also connected with a plate and frame filter press; one end of the ceramic ultrafiltration membrane assembly is provided with an ultra Membrane cleaning device, the other end is provided with a concentrated water storage tank, a three-effect evaporator and a dehydrator in sequence; one end of the reverse osmosis membrane module is provided with a reverse osmosis membrane cleaning device, and the other end is sequentially provided with a concentrated water storage tank, a three-effect Evaporators and dehydrators. The treatment system of the utility model can not only remove pollutants such as fluorine ions, nitrogen, phosphorus, and suspended solids in wastewater, but also realize zero discharge of nitrogen and phosphorus in the effluent, no concentrated water discharge, simple process flow, and convenient operation.

Description

一种工业废水处理系统An industrial wastewater treatment system

技术领域technical field

本发明涉及一种工业废水处理系统,尤其是一种多晶硅生产废水处理系统。The invention relates to an industrial waste water treatment system, in particular to a polysilicon production waste water treatment system.

背景技术Background technique

目前,多晶硅是制造集成电路、光伏太阳能电池的关键基础材料,是国家发展信息产业和光伏新能源产业的重要基石。然而在生产过程中,多晶硅生产企业产生大量成分复杂的含氟、同时含氮、磷的工业废水,如不能很好的处理,势必严重污染水体,危害环境。随着新环保法和太湖流域管理条例的实施,尤其在我国南方环太湖流域地区,要求生产废水处理后氮、磷零排放。因此,如何处理生产废水实现氮、磷零排放成为多晶硅生产企业环境治理必须解决的一个重大课题。At present, polysilicon is the key basic material for manufacturing integrated circuits and photovoltaic solar cells, and is an important cornerstone for the development of the country's information industry and photovoltaic new energy industry. However, during the production process, polysilicon production enterprises produce a large amount of complex industrial wastewater containing fluorine, nitrogen, and phosphorus. If it cannot be treated well, it will seriously pollute the water body and endanger the environment. With the implementation of the new Environmental Protection Law and the Taihu Lake Basin Management Regulations, especially in the Taihu Lake Basin in southern my country, zero discharge of nitrogen and phosphorus after treatment of production wastewater is required. Therefore, how to treat production wastewater to achieve zero discharge of nitrogen and phosphorus has become a major issue that must be solved for environmental governance of polysilicon production enterprises.

目前,多晶硅生产企业废水处理一般采取的方法是简单的调节、中和、混合和絮凝沉淀、过滤等工艺,不能实现废水氮、磷零排放,且如采用普通的超滤膜过滤,还需砂滤、碳滤等预处理工艺,工艺流程长,操作复杂,膜过滤存在浓水问题,直接排放会污染环境。At present, the wastewater treatment methods of polysilicon production enterprises generally adopt simple adjustment, neutralization, mixing, flocculation sedimentation, filtration and other processes, which cannot achieve zero discharge of nitrogen and phosphorus in wastewater, and if ordinary ultrafiltration membrane filtration is used, sand is required. Filtration, carbon filtration and other pretreatment processes, the process is long and the operation is complicated. Membrane filtration has the problem of concentrated water, and direct discharge will pollute the environment.

实用新型内容Utility model content

为了克服现有技术的上述缺点,本实用新型提供一种工业废水处理系统,不仅可去除废水中的氟离子、氮、磷、悬浮物等污染物质,还能实现出水氮、磷零排放,无浓水排放,工艺流程简单、操作方便、膜使用寿命长,无二次污染。In order to overcome the above-mentioned shortcomings of the prior art, the utility model provides an industrial wastewater treatment system, which can not only remove fluoride ions, nitrogen, phosphorus, suspended solids and other pollutants in the wastewater, but also realize zero discharge of nitrogen and phosphorus in the effluent, without Concentrated water discharge, simple process flow, convenient operation, long service life of membrane, no secondary pollution.

本实用新型的目的是通过以下方案实现:The purpose of this utility model is to realize by following scheme:

一种工业废水处理系统,包括依次相连的调节池、混合池、混凝沉淀池、一级中间水池、陶瓷超滤膜组件、二级中间水池、反渗透膜组件、产品水箱;所述混凝沉淀池上分别设置有PAC加药装置、PAM加药装置和污泥池;所述污泥池还与板框压滤机连接;所述陶瓷超滤膜组件的一端设置有超滤膜清洗装置,另一端依次设置有浓水储存池、三效蒸发器和脱水机;所述反渗透膜组件一端设置有反渗透膜清洗装置,另一端依次设置有浓水储存池、三效蒸发器和脱水机。An industrial wastewater treatment system, comprising a regulating tank, a mixing tank, a coagulation sedimentation tank, a primary intermediate pool, a ceramic ultrafiltration membrane module, a secondary intermediate pool, a reverse osmosis membrane module, and a product water tank connected in sequence; the coagulation A PAC dosing device, a PAM dosing device and a sludge tank are respectively arranged on the sedimentation tank; the sludge tank is also connected with a plate and frame filter press; one end of the ceramic ultrafiltration membrane assembly is provided with an ultrafiltration membrane cleaning device, The other end is provided with a concentrated water storage tank, a three-effect evaporator and a dehydrator in sequence; one end of the reverse osmosis membrane module is provided with a reverse osmosis membrane cleaning device, and the other end is provided with a concentrated water storage tank, a three-effect evaporator and a dehydrator in sequence .

优选地,所述混凝沉淀池与污泥池之间设置有污泥池提升泵。Preferably, a sludge tank lift pump is arranged between the coagulation sedimentation tank and the sludge tank.

优选地,所述污泥池与板框压滤机之间设置有污泥泵。Preferably, a sludge pump is provided between the sludge tank and the plate-and-frame filter press.

优选地,所述浓水储存池和三效蒸发器之间设置有浓水提升泵。Preferably, a concentrated water lift pump is arranged between the concentrated water storage tank and the three-effect evaporator.

优选地,所述二级中间水池和反渗透膜组件之间设置有反渗膜增压泵。Preferably, a reverse osmosis membrane booster pump is arranged between the secondary intermediate water tank and the reverse osmosis membrane module.

优选地,所述混合池上设置有能够进行PH值调节的加药装置。Preferably, the mixing tank is provided with a dosing device capable of adjusting the pH value.

优选地,所述一级中间水池和陶瓷超滤膜组件之间设置有超滤膜增压泵。Preferably, an ultrafiltration membrane booster pump is arranged between the first-stage intermediate water tank and the ceramic ultrafiltration membrane module.

优选地,所述陶瓷超滤膜组件和反渗透膜组件共用浓水储存池、三效蒸发器和脱水机。Preferably, the ceramic ultrafiltration membrane module and the reverse osmosis membrane module share a concentrated water storage tank, a three-effect evaporator and a dehydrator.

本实用新型的有益效果:The beneficial effects of the utility model:

1、采用该实用新型的系统,不仅可去除废水中的氟离子、悬浮物等污染物质,还能去除废水中的氮、磷,实现出水氮、磷零排放;1. The system of this utility model can not only remove pollutants such as fluoride ions and suspended solids in wastewater, but also remove nitrogen and phosphorus in wastewater, and realize zero discharge of nitrogen and phosphorus in the effluent;

2、本实用新型采用陶瓷膜组件,工艺流程简单,省去超滤膜前的砂滤、碳滤等预处理单元,减少水的提升、节约投资和电耗;2. The utility model adopts the ceramic membrane module, the technological process is simple, and the pretreatment units such as sand filter and carbon filter before the ultrafiltration membrane are omitted, which reduces the lifting of water, saves investment and power consumption;

3、陶瓷膜组件,抗污染、抗酸碱能力更强,膜使用寿命更长;3. The ceramic membrane module has stronger anti-pollution, anti-acid and alkali capabilities, and longer service life of the membrane;

4、陶瓷膜组件,抗冲击负荷和抗机械剪切能力更强,不易结垢;4. The ceramic membrane module has stronger impact resistance and mechanical shear resistance, and is not easy to scale;

5、采用三效蒸发器处理浓水,实现浓水零排放,无二次污染。5. Three-effect evaporator is used to treat the concentrated water to realize zero discharge of concentrated water and no secondary pollution.

附图说明Description of drawings

图1是本实用新型系统的结构框图;Fig. 1 is the structural block diagram of the utility model system;

1、调节池;2、混合池;3、加药装置;4、混凝沉淀池;5、PAC加药装置;6、PAM加药装置;7、污泥池提升泵;8、污泥池;9、污泥泵;10、板框压滤机;11、一级中间水池;12、陶瓷超滤膜组件;13、超滤膜增压泵;14、超滤膜清洗装置;15、二级中间水池;16、反渗膜增压泵;17、反渗透膜组件;18、反渗透膜清洗装置;19、产品水箱;20、浓水储存池;21、浓水提升泵;22、三效蒸发器;23、脱水机。1. Regulating tank; 2. Mixing tank; 3. Dosing device; 4. Coagulation sedimentation tank; 5. PAC dosing device; 6. PAM dosing device; 7. Sludge tank lift pump; 8. Sludge tank ; 9. Sludge pump; 10. Plate and frame filter press; 11. First-level intermediate pool; 12. Ceramic ultrafiltration membrane module; 13. Ultrafiltration membrane booster pump; 14. Ultrafiltration membrane cleaning device; 15. Two 16. Reverse osmosis membrane booster pump; 17. Reverse osmosis membrane module; 18. Reverse osmosis membrane cleaning device; 19. Product water tank; 20. Concentrated water storage tank; 21. Concentrated water lift pump; 22. Three Efficient evaporator; 23. Dehydrator.

具体实施方式Detailed ways

下面结合附图,对本实用新型进行详细的解释。Below in conjunction with accompanying drawing, the utility model is explained in detail.

参见附图,生产废水首先进入调节池1,进水水量水质的调节,然后进入混合池2,通过加药装置3投加酸或碱等药剂,调节废水的PH值,进行混合反应,为后序絮凝沉淀创造有利条件。Referring to the accompanying drawings, the production wastewater first enters the regulating tank 1, the influent water quality is adjusted, and then enters the mixing tank 2, and the acid or alkali is added through the dosing device 3 to adjust the PH value of the wastewater and perform a mixed reaction for the subsequent Sequential flocculation and sedimentation create favorable conditions.

然后废水进入混凝沉淀池4,通过PAC加药装置5投加PAC(聚合氯化铝),PAM加药装置6投加PAM(聚丙烯酰胺),使废水通过压缩双电层、吸附电中和、吸附架桥、沉淀和网捕等作用,快速形成密实的矾花和较大的絮体,在离心力作用下,密实的矾花和较大的絮体颗粒进行沉淀,从而去除废水中的大量悬浮物、氟离子和磷酸根离子等,沉淀后的上清液进入一级中间水池11。混凝沉淀池4产生的污泥通过污泥提升泵7,提升至污泥池8,再通过污泥泵9提升至板框压滤机10,进行污泥脱水,污泥脱水后的滤液回到调节池再处理,脱水后的泥饼外运做无害化处理。Then the waste water enters the coagulation sedimentation tank 4, PAC (polyaluminum chloride) is added through the PAC dosing device 5, and PAM (polyacrylamide) is added by the PAM dosing device 6, so that the waste water passes through the compressed electric double layer and the adsorption electrode. And, adsorption bridging, sedimentation and net capture, etc., quickly form dense alum flowers and larger flocs, and under the action of centrifugal force, the dense alum flowers and larger floc particles are precipitated to remove the waste water A large amount of suspended solids, fluoride ions and phosphate ions, etc., and the supernatant after precipitation enter the first-level intermediate pool 11 . The sludge produced in the coagulation sedimentation tank 4 is lifted to the sludge tank 8 through the sludge lifting pump 7, and then lifted to the plate and frame filter press 10 through the sludge pump 9 for sludge dehydration, and the filtrate after the sludge dehydration is returned to It is reprocessed in the regulating tank, and the dehydrated mud cake is transported outside for harmless treatment.

陶瓷超滤膜组件12连接超滤膜增压泵13,从一级中间水池11中提升水至陶瓷超滤膜组件12,进行过滤,去除悬浮物等污染物质,出水进入二级中间水池15,设反渗膜增压泵16与反渗透膜组件17连接,将二级中间水池15中的水提升至反渗透膜组件17,进行过滤处理,去除水中的氮、磷等各种无机盐污染物质。The ceramic ultrafiltration membrane module 12 is connected to the ultrafiltration membrane booster pump 13, and the water is lifted from the primary intermediate pool 11 to the ceramic ultrafiltration membrane module 12 for filtration to remove suspended solids and other pollutants, and the effluent enters the secondary intermediate pool 15. The reverse osmosis membrane booster pump 16 is connected to the reverse osmosis membrane module 17, and the water in the secondary intermediate pool 15 is lifted to the reverse osmosis membrane module 17 for filtration treatment to remove various inorganic salt pollutants such as nitrogen and phosphorus in the water .

陶瓷超滤膜组件12连接有陶瓷超滤膜清洗装置14,反渗透膜组件17连接有反渗透膜清洗装置18,可分别定时定期对陶瓷超滤膜和反渗膜膜组件进行自动在线清洗和化学清洗,减少膜污染堵塞,延长膜使用寿命。The ceramic ultrafiltration membrane module 12 is connected with a ceramic ultrafiltration membrane cleaning device 14, and the reverse osmosis membrane module 17 is connected with a reverse osmosis membrane cleaning device 18, which can perform automatic online cleaning and Chemical cleaning reduces membrane fouling and clogging and prolongs membrane life.

陶瓷超滤膜组件12和反渗透膜组件17过滤废水中产生的浓水排入浓水储存池20,通过浓水提升泵21,直接提升至三效蒸发器22,进行盐水蒸发分离,蒸发后的过饱和晶浆经离心脱水机23处理,脱水后结晶固体外运处理,最终实现浓水和废水中氮、磷零排放。Ceramic ultrafiltration membrane module 12 and reverse osmosis membrane module 17 filter the concentrated water produced in the wastewater and discharge it into the concentrated water storage tank 20. The concentrated water is lifted directly to the three-effect evaporator 22 through the concentrated water lift pump 21 for evaporation and separation of brine. The supersaturated magma is processed by the centrifugal dehydrator 23, and the crystalline solid is transported outside for treatment after dehydration, and finally realizes zero discharge of nitrogen and phosphorus in concentrated water and wastewater.

以上所述,仅为本实用新型较佳的具体实施方式,但本实用新型的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本实用新型披露的技术范围内,可轻易想到的变化或替换,都应该涵盖在本实用新型的保护范围之内。因此,本实用新型的保护范围应该以权利要求书的保护范围为准。The above is only a preferred embodiment of the utility model, but the scope of protection of the utility model is not limited thereto, and any person familiar with the technical field can easily think of All changes or replacements should fall within the protection scope of the present utility model. Therefore, the protection scope of the present utility model should be based on the protection scope of the claims.

Claims (8)

1.一种工业废水处理系统,其特征在于,包括依次相连的调节池、混合池、混凝沉淀池、一级中间水池、陶瓷超滤膜组件、二级中间水池、反渗透膜组件、产品水箱;所述混凝沉淀池上分别设置有PAC加药装置、PAM加药装置和污泥池;所述污泥池还与板框压滤机连接;所述陶瓷超滤膜组件的一端设置有超滤膜清洗装置,另一端依次设置有浓水储存池、三效蒸发器和脱水机;所述反渗透膜组件一端设置有反渗透膜清洗装置,另一端依次设置有浓水储存池、三效蒸发器和脱水机。1. A kind of industrial wastewater treatment system, it is characterized in that, comprises the regulating pond, mixing pond, coagulation sedimentation pond, one-level intermediate pond, ceramic ultrafiltration membrane assembly, two-stage intermediate pond, reverse osmosis membrane assembly, product water tank; the coagulation sedimentation tank is respectively provided with a PAC dosing device, a PAM dosing device and a sludge tank; the sludge tank is also connected with a plate and frame filter press; one end of the ceramic ultrafiltration membrane assembly is provided with Ultrafiltration membrane cleaning device, the other end is provided with a concentrated water storage tank, a three-effect evaporator and a dehydrator in sequence; one end of the reverse osmosis membrane module is provided with a reverse osmosis membrane cleaning device, and the other end is sequentially provided with a concentrated water storage tank, three Evaporator and dehydrator. 2.根据权利要求1所述工业废水处理系统,其特征在于,所述混凝沉淀池与污泥池之间设置有污泥池提升泵。2. The industrial wastewater treatment system according to claim 1, characterized in that a sludge tank lift pump is arranged between the coagulation sedimentation tank and the sludge tank. 3.根据权利要求1所述工业废水处理系统,其特征在于,所述污泥池与板框压滤机之间设置有污泥泵。3. The industrial wastewater treatment system according to claim 1, wherein a sludge pump is arranged between the sludge tank and the plate-and-frame filter press. 4.根据权利要求1所述工业废水处理系统,其特征在于,所述浓水储存池和三效蒸发器之间设置有浓水提升泵。4. The industrial wastewater treatment system according to claim 1, wherein a concentrated water lift pump is arranged between the concentrated water storage tank and the three-effect evaporator. 5.根据权利要求1所述工业废水处理系统,其特征在于,所述二级中间水池和反渗透膜组件之间设置有反渗膜增压泵。5. The industrial wastewater treatment system according to claim 1, wherein a reverse osmosis membrane booster pump is arranged between the secondary intermediate pool and the reverse osmosis membrane module. 6.根据权利要求1所述工业废水处理系统,其特征在于,所述混合池上设置有能够进行PH值调节的加药装置。6. The industrial wastewater treatment system according to claim 1, characterized in that, the mixing tank is provided with a dosing device capable of adjusting the pH value. 7.根据权利要求1所述工业废水处理系统,其特征在于,所述一级中间水池和陶瓷超滤膜组件之间设置有超滤膜增压泵。7. The industrial wastewater treatment system according to claim 1, characterized in that an ultrafiltration membrane booster pump is arranged between the first-stage intermediate pool and the ceramic ultrafiltration membrane assembly. 8.根据权利要求1所述工业废水处理系统,其特征在于,所述陶瓷超滤膜组件和反渗透膜组件共用浓水储存池、三效蒸发器和脱水机。8. The industrial wastewater treatment system according to claim 1, wherein the ceramic ultrafiltration membrane module and the reverse osmosis membrane module share a concentrated water storage tank, a three-effect evaporator and a dehydrator.
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106630360A (en) * 2017-03-01 2017-05-10 苏州澄江环境科技有限公司 Treatment system of surface treatment wastewater and use method thereof
CN108298737A (en) * 2018-04-13 2018-07-20 江西金达莱环保股份有限公司 A kind for the treatment of method and apparatus of organosilicon production industry screenings waste water
CN109607965A (en) * 2019-01-09 2019-04-12 湖北君集水处理有限公司 A system and method for deep denitrification and dephosphorization of tail water of sewage treatment plant
CN110451691A (en) * 2019-08-23 2019-11-15 北京正和顺汽车部件有限公司 A kind of sewage disposal device of unpowered agitation
CN111689616A (en) * 2020-06-30 2020-09-22 山东九思新材料科技有限责任公司 Sewage treatment recovery device and treatment method

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106630360A (en) * 2017-03-01 2017-05-10 苏州澄江环境科技有限公司 Treatment system of surface treatment wastewater and use method thereof
CN108298737A (en) * 2018-04-13 2018-07-20 江西金达莱环保股份有限公司 A kind for the treatment of method and apparatus of organosilicon production industry screenings waste water
CN109607965A (en) * 2019-01-09 2019-04-12 湖北君集水处理有限公司 A system and method for deep denitrification and dephosphorization of tail water of sewage treatment plant
CN110451691A (en) * 2019-08-23 2019-11-15 北京正和顺汽车部件有限公司 A kind of sewage disposal device of unpowered agitation
CN111689616A (en) * 2020-06-30 2020-09-22 山东九思新材料科技有限责任公司 Sewage treatment recovery device and treatment method

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