CN204656023U - Heat pump driven supergravity field enhanced evaporation system - Google Patents
Heat pump driven supergravity field enhanced evaporation system Download PDFInfo
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Abstract
本实用新型公开了一种热泵驱动的超重力场强化蒸发系统,它由溶液储罐(1)、一级回热除湿器(2)、预热器(3)、超重力强化蒸发室(4)、二级回热除湿器(5)、除湿填料塔(6)、结晶器(7)、复叠式热泵系统(8)、泵(9)、热水箱(10)、管道风机(11)等组成。本实用新型的制热制冷量全部来源于热泵系统,在蒸发室中利用超重力旋转场和液体加热循环气体的方式提高气体载湿能力,高温载湿气体经一级、二级回热除湿器除湿换热后进入除湿填料塔,降温除湿后再次进入超重力强化蒸发室循环载湿。本实用新型有独立的回热除湿设备,更加节能,同时也可以实现低温蒸发、热敏性物质蒸发。
The utility model discloses a heat pump-driven supergravity field enhanced evaporation system, which comprises a solution storage tank (1), a first-stage heat recovery dehumidifier (2), a preheater (3), and a supergravity enhanced evaporation chamber (4) ), two-stage regenerative dehumidifier (5), packed dehumidification tower (6), crystallizer (7), cascade heat pump system (8), pump (9), hot water tank (10), pipeline fan (11 ) and other components. The heating and cooling capacity of the utility model all comes from the heat pump system. In the evaporation chamber, the supergravity rotating field and the liquid heating circulating gas are used to improve the humidity carrying capacity of the gas. The high temperature humidity carrying gas passes through the primary and secondary heat recovery dehumidifiers. After dehumidification and heat exchange, it enters the dehumidification packed tower, and after cooling and dehumidification, it enters the supergravity enhanced evaporation chamber to circulate humidity again. The utility model has independent heat recovery and dehumidification equipment, which is more energy-saving, and can also realize low-temperature evaporation and evaporation of heat-sensitive substances.
Description
技术领域technical field
本发明涉及一种热泵驱动的超重力场强化蒸发系统,广泛应用于石油化工、食品、轻工、制药、污水处理、海水淡化等行业。The invention relates to a heat pump-driven supergravity field enhanced evaporation system, which is widely used in petrochemical, food, light industry, pharmaceutical, sewage treatment, seawater desalination and other industries.
背景技术Background technique
近年来,人类生存环境日趋恶化,如何改善生存环境已经成为了一个重要课题。随着工业化行业的不断发展,生产过程不可避免造成的污水对环境的污染日趋严重。一些工业行业所产生的废水污染浓度越来越高,成分越来越复杂,排放量越来越大,这些废水中除了含有有机污染物外,还含有大量的无机盐。这些高盐、高有机物废水,若未经处理直接排放,势必会对水体生物、生活饮用水和工农业生产用水产生极大的危害。In recent years, the living environment of human beings has been deteriorating day by day, and how to improve the living environment has become an important issue. With the continuous development of industrialized industries, the pollution of the environment caused by the unavoidable sewage in the production process is becoming more and more serious. The pollution concentration of wastewater produced by some industrial industries is getting higher and higher, the composition is more and more complex, and the discharge volume is increasing. In addition to organic pollutants, these wastewater also contain a large amount of inorganic salts. If these high-salt, high-organic waste water is discharged directly without treatment, it will inevitably cause great harm to aquatic organisms, drinking water, and industrial and agricultural production water.
目前较多的污水处理依旧采用生化处理和物理化学处理方法,两种方法都是只对有机物和重金属离子有去除作用,而对于水体中的无机盐类则缺少相应的处理工艺。因此应用蒸发脱盐处理工艺对处理后的废水进行脱盐治理就显得非常重要了。At present, more sewage treatment still adopts biochemical treatment and physical and chemical treatment methods. Both methods can only remove organic matter and heavy metal ions, but lack corresponding treatment processes for inorganic salts in water bodies. Therefore, it is very important to apply evaporative desalination treatment process to desalinate the treated wastewater.
目前应用比较广泛的有多级闪蒸技术和机械式蒸汽再压缩技术。热源主要采用源源不断的锅炉生蒸,对于需要外购蒸汽的企业,随着市场蒸汽价格的上涨,蒸汽运行成本越来越高,企业负担急剧增大,如何减少装置蒸汽运行成本,节约能源是目前亟待解决的问题。At present, multi-stage flash evaporation technology and mechanical vapor recompression technology are widely used. The heat source mainly adopts the continuous raw steam of the boiler. For enterprises that need to purchase steam, as the market steam price rises, the steam operation cost is getting higher and higher, and the burden on the enterprise is increasing sharply. How to reduce the steam operation cost of the device and save energy is the key current problem to be solved.
与当前主要采用的废水蒸发工艺相比,本发明利用热泵系统来驱动超重力场强化气体循环吸湿,利用气体的载湿能力来吸收液体中的水分,经多次循环吸收,吸收效率更高,无二次污染排放,更加环保。采用除湿填料塔对循环载湿气体进行冷凝除湿,冷凝水储存在除湿填料塔底部作为冷却介质循环使用,缩减了设备的体积。本发明采用一级和二级回热除湿器除湿的同时进行回热,大大降低了系统能耗,更加节能。而且本发明既可实现90℃高温高效蒸发,也可实现60℃以下的用于热敏性物质的低温蒸发,适用范围广,在医药、食品、海水淡化、精细化工等多个行业均可得到应用。Compared with the currently mainly used wastewater evaporation process, the present invention uses a heat pump system to drive a supergravity field to strengthen the gas circulation to absorb moisture, and uses the moisture-carrying capacity of the gas to absorb moisture in the liquid. After multiple cycles of absorption, the absorption efficiency is higher. No secondary pollution discharge, more environmentally friendly. The dehumidification packed tower is used to condense and dehumidify the circulating humidity-carrying gas, and the condensed water is stored at the bottom of the dehumidified packed tower as a cooling medium for recycling, which reduces the volume of the equipment. The invention adopts the first-level and second-level heat recovery dehumidifiers to dehumidify and perform heat recovery at the same time, which greatly reduces the energy consumption of the system and is more energy-saving. Moreover, the present invention can not only realize high-temperature and high-efficiency evaporation at 90°C, but also realize low-temperature evaporation below 60°C for heat-sensitive substances.
发明内容Contents of the invention
针对现有技术中存在的问题,本发明的热泵驱动的超重力场强化蒸发系统的制热制冷量全部来源于热泵系统,在蒸发室中利用超重力旋转场和液体加热循环气体的方式提高气体载湿能力,高温载湿气体经一级、二级回热除湿器除湿换热后进入除湿填料塔,降温除湿后再次进入超重力强化蒸发室循环载湿。该系统有独立的回热除湿设备,更加节能,同时也可以实现低温蒸发、热敏性物质蒸发。Aiming at the problems existing in the prior art, the heating and cooling capacity of the heat pump-driven supergravity field enhanced evaporation system of the present invention all comes from the heat pump system, and the method of using the supergravity rotating field and liquid to heat the circulating gas in the evaporation chamber improves the gas Humidity-carrying capacity, the high-temperature humidity-carrying gas is dehumidified and heat-exchanged by the first-stage and second-stage regenerative dehumidifiers, and then enters the dehumidification packed tower. After cooling down and dehumidifying, it enters the high-gravity enhanced evaporation chamber again to carry moisture. The system has independent heat recovery and dehumidification equipment, which is more energy-saving, and can also achieve low-temperature evaporation and evaporation of heat-sensitive substances.
本发明的目的是通过以下技术方案实现的,一种热泵驱动的超重力场强化蒸发系统,它由溶液储罐(1)、一级回热除湿器(2)、预热器(3)、超重力强化蒸发室(4)、二级回热除湿器(5)、除湿填料塔(6)、结晶器(7)、复叠式热泵系统(8)、进料泵(9)、热水箱(10)、管道风机(11)组成;包括1)液体注入过滤式溶液储罐除去固体后,由进料泵送入一级回热除湿器和预热器中加热;2)预热后的液体进入超重力强化蒸发室中加热循环气体;3)循环气体由管道风机吹入超重力强化蒸发室中,升温后,带走部分水蒸气;4)吸湿后的循环气体经一级、二级回热除湿器除湿换热后进入除湿调料塔由经热泵系统制冷后的冷水进行降温除湿;5)冷凝水流入除湿填料塔底部的冷凝水储室;6)低温低湿循环气体进入二级回热除湿器换热后温度升高再次进入超重力强化蒸发室;7)在超重力强化蒸发室底部,浓缩液经强制循环泵输送与溶液储罐经进料泵输送的液体混合,混合液经过一级回热除湿器和预热器加热后再次进入超重力强化蒸发室。The purpose of the present invention is achieved by the following technical solutions, a heat pump driven supergravity field enhanced evaporation system, which consists of a solution storage tank (1), a primary regenerative dehumidifier (2), a preheater (3), Supergravity enhanced evaporation chamber (4), secondary heat recovery dehumidifier (5), dehumidification packed tower (6), crystallizer (7), cascade heat pump system (8), feed pump (9), hot water box (10) and pipeline fan (11); including 1) the liquid is injected into the filter type solution storage tank to remove the solids, and then sent to the first-stage regenerative dehumidifier and preheater by the feed pump for heating; 2) after preheating The liquid enters the supergravity enhanced evaporation chamber to heat the circulating gas; 3) The circulating gas is blown into the supergravity enhanced evaporation chamber by the pipeline fan, and after heating up, part of the water vapor is taken away; 4) The moisture-absorbed circulating gas passes through the primary and secondary After dehumidification and heat exchange, the stage regenerative dehumidifier enters the dehumidification seasoning tower, and the cold water cooled by the heat pump system is used for cooling and dehumidification; 5) The condensed water flows into the condensed water storage room at the bottom of the dehumidification packed tower; 6) The low-temperature and low-humidity circulating gas enters the secondary return After the heat exchange of the heat dehumidifier, the temperature rises and enters the supergravity enhanced evaporation chamber again; 7) At the bottom of the supergravity enhanced evaporation chamber, the concentrated liquid is transported by the forced circulation pump and mixed with the liquid transported by the solution storage tank through the feed pump, and the mixed liquid passes through After being heated by the first-stage regenerative dehumidifier and preheater, it enters the supergravity enhanced evaporation chamber again.
本发明利用气体升温后含湿量增大的特性实现液体蒸发,通过超重力旋转场来强化液体与循环气体(空气或氮气)的传质传热过程。本发明采用两级回热除湿的方式,载湿气体先与液体换热,再与低湿气体换热,从而大大降低系统所需能耗,经过两级除湿后的循环气体有利于强化在超重力强化蒸发室中的吸湿效果。The invention realizes liquid evaporation by using the property that the moisture content increases after the gas is heated up, and strengthens the mass transfer and heat transfer process between the liquid and the circulating gas (air or nitrogen) through the supergravity rotating field. The present invention adopts a two-stage heat recovery and dehumidification method. The humidity-carrying gas first exchanges heat with the liquid, and then exchanges heat with the low-humidity gas, thereby greatly reducing the energy consumption required by the system. The circulating gas after the two-stage dehumidification is conducive to strengthening Intensifies the moisture absorption effect in the evaporation chamber.
系统预热热水和冷凝冷水的热量由所述复叠式热泵系统8提供,所述复叠式热泵系统8分为低温段与高温段,所述低温段和高温段之间通过蒸发冷凝器804换热,该系统能产出大温差的冷热水。产出的高温热水能将液体预热到更高温度,有利于所述超重力强化蒸发室4中气体吸湿,提高系统蒸发效率。The heat for preheating hot water and condensing cold water in the system is provided by the cascade heat pump system 8. The cascade heat pump system 8 is divided into a low temperature section and a high temperature section, and the low temperature section and the high temperature section are separated by an evaporative condenser. 804 heat exchange, the system can produce hot and cold water with a large temperature difference. The high-temperature hot water produced can preheat the liquid to a higher temperature, which is conducive to the moisture absorption of the gas in the supergravity-enhanced evaporation chamber 4 and improves the evaporation efficiency of the system.
所述一种热泵驱动的超重力强化蒸发系统液体循环中,液体打入所述溶液储罐后经滤网滤去较大固体颗粒进入所述溶液储罐内部,随后经进料泵打入一级回热除湿器和预热器中加热,加热后的液体进入所述超重力强化蒸发室中与循环气体换热,部分水蒸汽被循环气体带走,浓缩液落至蒸发室底部经由循环泵输送与原液体混合再次预热后进入所述超重力强化蒸发室,高浓缩液体打入结晶器结晶。In the liquid circulation of the heat pump-driven high-gravity enhanced evaporation system, the liquid is poured into the solution storage tank, and then the larger solid particles are filtered through a filter screen and enter the solution storage tank, and then injected into a liquid storage tank through a feed pump. The heated liquid enters the supergravity enhanced evaporation chamber to exchange heat with the circulating gas, part of the water vapor is taken away by the circulating gas, and the concentrated liquid falls to the bottom of the evaporation chamber through the circulating pump After being transported and mixed with the original liquid and preheated again, it enters the supergravity enhanced evaporation chamber, and the highly concentrated liquid is poured into the crystallizer for crystallization.
所述一种热泵驱动的超重力强化蒸发系统水循环中,1)热水由所述热水箱打入所述冷凝器加热后进入所述预热器中预热液体,再进入热水箱,循环作用。2)冷凝水由所述除湿填料塔底部储室通过冷凝水循环泵打入所述结晶器中给高浓度浓缩液降温后打入进入蒸发器中降温,降温后的冷凝水进入所述除湿填料塔中直接与循环气体接触换热后落至所述除湿填料塔底部冷凝水储室,循环作用。In the water cycle of the heat pump-driven supergravity enhanced evaporation system, 1) hot water enters the condenser from the hot water tank for heating, then enters the preheater to preheat the liquid, and then enters the hot water tank, Circulation. 2) The condensed water is pumped into the crystallizer from the storage room at the bottom of the dehumidified packed tower through the condensed water circulation pump to cool down the high-concentration liquid, then pumped into the evaporator to cool down, and the cooled condensed water enters the dehumidified packed tower The condensed water storage room at the bottom of the packed dehumidification tower directly contacts with the circulating gas for heat exchange, and then circulates.
所述一种热泵驱动的超重力强化蒸发系统气体循环中,循环气体在鼓风机的作用下进入所述超重力强化蒸发室载湿后在引风机的作用下引出一级、二级回热除湿器,进入所述除湿填料塔中,被冷凝水降温后,循环气体含湿量减小,再次进入所述回热器加热后进入所述超重力强化蒸发室,循环作用。In the gas cycle of the heat pump-driven supergravity enhanced evaporation system, the circulating gas enters the supergravity enhanced evaporation chamber under the action of the blower to carry moisture, and then leads out to the primary and secondary heat recovery dehumidifiers under the action of the induced draft fan. , into the dehumidification packed tower, after being cooled by condensed water, the moisture content of the circulating gas decreases, enters the regenerator to be heated again, enters the supergravity enhanced evaporation chamber, and circulates.
所述一种热泵驱动的超重力强化蒸发系统中所需要的制热量与制冷量全部来源于热泵系统,针对不同的处理对象可以选用不同的热源,例如低品位蒸汽、太阳能等。The heating and cooling required in the heat pump-driven supergravity enhanced evaporation system all come from the heat pump system, and different heat sources can be selected for different processing objects, such as low-grade steam, solar energy, etc.
所述一种热泵驱动的超重力强化蒸发系统中循环气体针对不同的处理对象和处理要求的不同而不同,通常情况下可以选用空气,当涉及医药、食品等行业时可以选用氮气。The circulating gas in the heat pump-driven high-gravity enhanced evaporation system is different for different processing objects and processing requirements. Usually, air can be used, and nitrogen can be used when it involves industries such as medicine and food.
所述超重力强化蒸发室顶部设有变频电机,与中通管相连接,同心圆框架式填料盘与中通管焊接为一整体,并在变频电机带动下一起旋转形成超重力场,中通管壁面分布一定数量的通孔,便于液体喷洒进入填料盘中,表面均布通孔的波纹板成特定角度插入在同心圆框架式填料盘上,液体进口管伸入至中通管中心,向其壁面喷洒液体;所述超重力强化蒸发室内部顶部设有除沫器防止循环气体中液体的夹带,内部底部为储液腔体,用于临时储存浓缩液体。The top of the supergravity enhanced evaporation chamber is equipped with a frequency conversion motor, which is connected with the central tube. The concentric circular frame-type packing plate and the central tube are welded as a whole, and are driven by the frequency conversion motor to rotate together to form a supergravity field. A certain number of through holes are distributed on the pipe wall to facilitate the liquid spraying into the packing pan. The corrugated plate with evenly distributed through holes on the surface is inserted into the concentric circular frame packing pan at a specific angle. The wall is sprayed with liquid; the top of the supergravity enhanced evaporation chamber is equipped with a demister to prevent the entrainment of liquid in the circulating gas, and the bottom of the interior is a liquid storage chamber for temporary storage of concentrated liquid.
为了进一步降低进入所述超重力强化蒸发室4的循环气体的含湿量,增强循环气体在所述超重力强化蒸发室4中的吸湿效果,将来自所述二级回热除湿器5降温后的循环气体(c)通入所述除湿填料塔6中,利用所述复叠式热泵8产生的低温冷水进一步降温,从而达到降低循环气体的含湿量的目的,来自所述二级回热除湿器5的循环气体(c)在所述除湿填料塔6中温度降低,冷凝水析出,流入所述除湿填料塔6底部的冷凝水储室,用于补充制冷的冷水。所述除湿填料塔在塔体底部设有冷凝水储室,冷凝水储室设有溢流口,冷凝水由所述除湿填料塔底部出口管流入储室中,当冷凝水量过多时,从溢流口溢出。In order to further reduce the moisture content of the circulating gas entering the supergravity enhanced evaporation chamber 4, and enhance the moisture absorption effect of the circulating gas in the supergravity enhanced evaporation chamber 4, after cooling the secondary heat recovery dehumidifier 5, The circulating gas (c) is passed into the dehumidification packed tower 6, and the low-temperature cold water generated by the cascade heat pump 8 is used to further reduce the temperature, so as to achieve the purpose of reducing the moisture content of the circulating gas. The temperature of the circulating gas (c) of the dehumidifier 5 is lowered in the dehumidification packed tower 6, and the condensed water is precipitated, and flows into the condensed water storage chamber at the bottom of the dehumidified packed tower 6 to supplement cold water for refrigeration. The packed dehumidification tower is provided with a condensed water storage chamber at the bottom of the tower, and the condensed water storage chamber is provided with an overflow port. The condensed water flows into the storage chamber from the outlet pipe at the bottom of the packed dehumidified tower. Mouth overflowing.
本发明与一种利用太阳能的废水蒸发系统(CN 104118918 A)区别在于:The present invention differs from a waste water evaporation system (CN 104118918 A) utilizing solar energy in that:
(1)一种利用太阳能的废水蒸发系统(CN 104118918 A)中的所有制热量与制冷量均来源于太阳能驱动的溴化锂制冷系统,本发明采用电驱动的复叠式热泵系统,相比于太阳能驱动的溴化锂制冷系统,运行更加稳定。(1) All the heating capacity and cooling capacity in a waste water evaporation system utilizing solar energy (CN 104118918 A) are derived from solar-driven lithium bromide refrigeration systems. Advanced lithium bromide refrigeration system, more stable operation.
(2)一种利用太阳能的废水蒸发系统(CN 104118918 A)中没有独立的回热设备,本发明采用一级回热除湿器和二级回热除湿器作为回热除湿设备,在所述一级回热除湿器2中,来自超重力旋转蒸发室4的高温载湿气体a与来自所述溶液储罐1和来自所述超重力强化蒸发室4混合后的混合液进行换热,换热后,来自超重力强化蒸发室4的高温载湿气体a温度降低,并有冷凝水析出,同时放出大量的热量,来自所述溶液储罐1和来自所述超重力强化蒸发室4混合后的混合液吸收该热量,温度升高,从而降低了热泵系统所需提供的制热量;在所述二级回热除湿器5中,来自所述一级回热除湿器2降温后的较高温度的载湿气体b与来自所述除湿填料塔6即将进入所述超重力强化蒸发室4的低温低湿气体d换热,换热后,来自所述一级回热除湿器2降温后的较高温度的载湿气体b温度进一步降低,冷凝水析出,并放出大量热量,该载湿气体温度的降低有利于减少其在所述除湿填料塔6中降温时热泵系统所需提供的制冷量,来自所述除湿填料塔6即将进入所述超重力强化蒸发室4的低温低湿气体d吸收热量,温度升高,温度升高后的低温低湿气体d有利于提高其在所述超重力强化蒸发室4中的吸湿能力。(2) There is no independent heat recovery device in a wastewater evaporation system utilizing solar energy (CN 104118918 A). The present invention adopts a primary heat recovery dehumidifier and a secondary heat recovery dehumidifier as heat recovery dehumidification equipment. In the stage regenerative dehumidifier 2, the high-temperature humidity-carrying gas a from the high-gravity rotary evaporation chamber 4 exchanges heat with the mixed liquid from the solution storage tank 1 and the high-gravity enhanced evaporation chamber 4. Finally, the temperature of the high-temperature humidity-carrying gas a from the supergravity enhanced evaporation chamber 4 decreases, and condensed water is precipitated, and a large amount of heat is released at the same time. The mixed liquid absorbs the heat, and the temperature rises, thereby reducing the heating capacity required by the heat pump system; The humidity-carrying gas b from the dehumidification packed tower 6 exchanges heat with the low-temperature and low-humidity gas d that is about to enter the supergravity enhanced evaporation chamber 4. After the heat exchange, the higher The temperature of the humidity-carrying gas b is further reduced, condensed water is precipitated, and a large amount of heat is released. The reduction of the temperature of the humidity-carrying gas is conducive to reducing the cooling capacity required by the heat pump system when it is cooled in the dehumidification packed tower 6, from The dehumidification packed tower 6 is about to enter the high-gravity enhanced evaporation chamber 4. The low-temperature and low-humidity gas d absorbs heat, and the temperature rises. moisture absorption capacity.
(3)一种利用太阳能的废水蒸发系统(CN 104118918 A)中,表冷器用于循环气体的降温除湿,循环气体与冷水间壁换热,析出的冷凝水直接排入冷凝水储罐中,本发明采用除湿填料塔进行降温除湿,冷水与循环气体直接接触,逆流换热,调料塔中排布填料,强化换热过程,使得换热效率更高,冷凝水析出后与冷水混合流入除湿填料塔底部冷凝水储室补充原制冷用冷水。(3) In a waste water evaporation system using solar energy (CN 104118918 A), the surface cooler is used to cool and dehumidify the circulating gas, the circulating gas exchanges heat with the cold water partition, and the precipitated condensed water is directly discharged into the condensed water storage tank. The invention adopts the dehumidification packing tower for cooling and dehumidification, the cold water is in direct contact with the circulating gas, and the heat is exchanged countercurrently, and the packing is arranged in the seasoning tower to strengthen the heat exchange process, so that the heat exchange efficiency is higher, and the condensed water is separated out and mixed with cold water to flow into the dehumidification packing tower The condensed water storage chamber at the bottom replenishes the cold water used for refrigeration.
(4)一种利用太阳能的废水蒸发系统(CN 104118918 A)中蒸发室采用平直丝网缠绕在中通管上作为填料,容易堵塞需要经常清洗更换,本发明超重力强化蒸发室填料盘采用多层同心圆框架式结构,内层框架同心圆半径较小,外层较大,同心圆之间用辐条链接,上下框架用拉杆固定,同心圆框架中以特定角度插入表面均布通孔的波纹板,内层数量较少,外层数量较多,保证通道间隙更加均匀,不易堵塞,更加有利于循环气体与液体进行换热。(4) A waste water evaporation system utilizing solar energy (CN 104118918 A) in which the evaporation chamber adopts a straight wire mesh wound on the middle pipe as filler, which is easy to be blocked and needs to be cleaned and replaced frequently. Multi-layer concentric frame structure, the inner frame has a smaller concentric radius and the outer layer is larger, the concentric circles are connected by spokes, the upper and lower frames are fixed by tie rods, and the concentric frame is inserted at a specific angle The corrugated plate has fewer inner layers and more outer layers to ensure that the channel gap is more uniform and not easy to be blocked, which is more conducive to heat exchange between circulating gas and liquid.
本发明一种热泵驱动的超重力强化蒸发系统,具有以下优点或者效益:本发明采用复叠式热泵系统作为热源能将液体升高至较高温度,实现高效蒸发。本发明采用一级和二级回热除湿器除湿的同时进行回热,大大降低了系统能耗,更加节能。而且本发明既可实现90℃高温高效蒸发,也可实现60℃以下的用于热敏性物质的低温蒸发,适用范围广,在医药、食品、海水淡化、精细化工等多个行业均可得到应用。The heat pump-driven supergravity enhanced evaporation system of the present invention has the following advantages or benefits: the present invention uses a cascaded heat pump system as a heat source to raise the liquid to a higher temperature and realize efficient evaporation. The invention adopts the first-level and second-level heat recovery dehumidifiers to dehumidify and perform heat recovery at the same time, which greatly reduces the energy consumption of the system and is more energy-saving. Moreover, the present invention can not only realize high-temperature and high-efficiency evaporation at 90°C, but also realize low-temperature evaporation below 60°C for heat-sensitive substances.
附图说明Description of drawings
图1为本发明热泵驱动的超重力场强化蒸发系统原理图。Fig. 1 is a schematic diagram of the heat pump driven supergravity field enhanced evaporation system of the present invention.
图2为本发明热泵驱动的超重力场强化蒸发系统示意图。Fig. 2 is a schematic diagram of the heat pump driven supergravity field enhanced evaporation system of the present invention.
图3为本发明实施例中二级回热除湿器芯体装配图。Fig. 3 is an assembly diagram of the core body of the secondary heat recovery dehumidifier in the embodiment of the present invention.
图4为本发明实施例中二级回热除湿器芯体分解图。Fig. 4 is an exploded view of the core body of the two-stage regenerative dehumidifier in the embodiment of the present invention.
具体实施方式Detailed ways
以下结合附图对本发明进一步说明,应理解该实施例仅用于说明本发明而不用于限制本发明的范围,在阅读本发明之后,本领域技术人员对本发明的各种等价形式的修改或应用范围的拓展均落于本申请所附权利要求所限定的范围。The present invention will be further described below in conjunction with the accompanying drawings. It should be understood that this embodiment is only used to illustrate the present invention and is not intended to limit the scope of the present invention. After reading the present invention, those skilled in the art may modify or modify various equivalent forms of the present invention The expansion of the scope of application all falls within the scope defined by the appended claims of the present application.
实施例Example
本实施例热泵驱动的超重力场强化蒸发系统原理图如图1所示,气体温度升高后,含湿量增大,单位质量气体所带有的水蒸气质量增加,通过热泵系统产出的高温热水预先加热来自溶液储罐的液体,升温后的液体在超重力强化蒸发室中与用于携带水蒸气的循环气体换热,循环气体温度升高,载湿能力增强,带走更多的水蒸气,并通过超重力旋转场强化该换热过程,增强循环气体的吸湿效果。The principle diagram of the heat pump-driven supergravity field enhanced evaporation system in this embodiment is shown in Figure 1. After the gas temperature rises, the moisture content increases, and the water vapor mass per unit mass of gas increases, and the water vapor produced by the heat pump system High-temperature hot water preheats the liquid from the solution storage tank. The heated liquid exchanges heat with the circulating gas used to carry water vapor in the supergravity enhanced evaporation chamber. The temperature of the circulating gas increases, and the moisture carrying capacity increases, taking away more The heat exchange process is strengthened by the supergravity rotating field, and the moisture absorption effect of the circulating gas is enhanced.
本实施例是通过以下工作流程实现的,如图2所示,热泵驱动的超重力场强化蒸发系统示意图,系统由废液储罐1、一级除湿器2、预热器3、超重力强化蒸发室4、二级除湿器5、除湿填料塔6、结晶器7、复叠式热泵系统8、泵9、热水箱10、管道风机11等组成。其中带有箭头的实现均为管道,箭头方向代表管道内工质流动方向。This embodiment is realized through the following workflow, as shown in Figure 2, a schematic diagram of a heat pump driven supergravity field enhanced evaporation system, the system consists of a waste liquid storage tank 1, a primary dehumidifier 2, a preheater 3, and a supergravity enhanced Evaporation chamber 4, secondary dehumidifier 5, dehumidification packed tower 6, crystallizer 7, cascade heat pump system 8, pump 9, hot water tank 10, pipeline fan 11, etc. The implementations with arrows are pipelines, and the direction of the arrow represents the flow direction of the working medium in the pipeline.
系统采用两级回热除湿的方式,利用从所述超重力强化蒸发室4中出来的高温载湿气体(a)的余热(潜热和显热)先与来自所述溶液储罐1和所述超重力强化蒸发室4混合后的混合液换热,再与即将进入所述超重力强化蒸发室4的低温低湿气体(d)进行换热,该过程充分利用高温载湿气体(a)中的余热,降低整个系统能耗。The system adopts a two-stage heat recovery and dehumidification method, using the waste heat (latent heat and sensible heat) of the high-temperature humidity-carrying gas (a) coming out of the high-gravity enhanced evaporation chamber 4 to first combine with the heat from the solution storage tank 1 and the The mixed liquid in the supergravity enhanced evaporation chamber 4 exchanges heat, and then exchanges heat with the low-temperature and low-humidity gas (d) that is about to enter the supergravity enhanced evaporation chamber 4. This process makes full use of the high-temperature moisture-carrying gas (a) waste heat, reducing energy consumption of the entire system.
在所述一级回热除湿器2中,来自超重力强化蒸发室4的高温载湿气体(a)与来自所述溶液储罐1和来自所述超重力强化蒸发室4混合后的混合液进行换热,换热后,来自超重力强化蒸发室4的高温载湿气体(a)温度降低,并有冷凝水析出,同时放出大量的热量,来自所述溶液储罐1和来自所述超重力强化蒸发室4混合后的混合液吸收该热量,温度升高,从而降低了热泵系统所需提供的制热量。In the primary regenerative dehumidifier 2, the high-temperature humidity-carrying gas (a) from the supergravity enhanced evaporation chamber 4 is mixed with the mixed liquid from the solution storage tank 1 and the supergravity enhanced evaporation chamber 4 Carry out heat exchange, after heat exchange, the temperature of the high-temperature humidity-carrying gas (a) from the supergravity enhanced evaporation chamber 4 decreases, and condensed water is precipitated, and a large amount of heat is released at the same time, from the solution storage tank 1 and from the supergravity The mixed liquid mixed in the gravity-enhanced evaporation chamber 4 absorbs the heat, and the temperature rises, thereby reducing the heating capacity required to be provided by the heat pump system.
在所述二级回热除湿器5中,来自所述一级回热除湿器2降温后的较高温度的载湿气体(b)与来自所述除湿填料塔6即将进入所述超重力强化蒸发室4的低温低湿气体(d)换热,换热后,来自所述一级回热除湿器2降温后的较高温度的载湿气体(b)温度进一步降低,冷凝水析出,并放出大量热量,该载湿气体温度的降低有利于减少其在所述除湿填料塔6中降温时热泵系统所需提供的制冷量;来自所述除湿填料塔6即将进入所述超重力强化蒸发室4的低温低湿气体(d)吸收热量,温度升高,温度升高后的低温低湿气体(d)有利于提高其在所述超重力强化蒸发室4中的吸湿能力。In the secondary heat recovery dehumidifier 5, the higher temperature humidity-carrying gas (b) from the primary heat recovery dehumidifier 2 and the dehumidification packed tower 6 are about to enter the supergravity strengthening The low-temperature and low-humidity gas (d) in the evaporation chamber 4 is heat-exchanged. After the heat exchange, the temperature of the higher-temperature humidity-carrying gas (b) from the first-stage regenerative dehumidifier 2 is further reduced, and condensed water is precipitated and released. A large amount of heat, the reduction of the temperature of the humidity-carrying gas is conducive to reducing the cooling capacity that the heat pump system needs to provide when it cools down in the dehumidification packed tower 6; The low-temperature and low-humidity gas (d) absorbs heat, the temperature rises, and the low-temperature and low-humidity gas (d) after the temperature rise is conducive to improving its moisture absorption capacity in the supergravity enhanced evaporation chamber 4 .
为了对本发明一种热泵驱动的超重力强化蒸发系统充分的理解,下面以某工厂生产后35℃的500t/d工业废水为例进行介绍。生产后的工业废水主要包含硫酸镁,质量分数为20%,处理后废液中硫酸镁质量分数达到40%。In order to fully understand the heat pump-driven supergravity enhanced evaporation system of the present invention, the following is an example of 500t/d industrial wastewater produced by a certain factory at 35°C. The industrial wastewater after production mainly contains magnesium sulfate with a mass fraction of 20%, and the mass fraction of magnesium sulfate in the treated waste liquid reaches 40%.
将工业废水通过溶液储罐进口管注入到过滤式溶液储罐1中,过滤除去固体,系统启动时,首先启动热泵系统8、超重力强化蒸发室4顶部电机和管道风机,打开进料阀,液体由进料泵901输送经一级回热除湿器2进入预热器3,通过被热泵系统工质加热的热水对预热器中液体预热,液体预热后进入超重力强化蒸发室4,通过溶液进口管喷洒进入电机所带动旋转的同心圆框架式填料盘中,与循环气体换热,水分被带走,浓缩液落入蒸发室底部,输送一定量液体后,关闭进料阀,打开循环阀,液体在循环泵作用下再次经一级回热除湿器2和预热器3中预热后进入超重力强化蒸发室4中,如此往复,循环运行,直至蒸发室底部液体达到工况要求浓度,载湿后的循环气体在引风机作用下首先进入一级回热除湿器2中降温除湿,放出的大量热量用来加热液体,接着进入二级回热除湿器5中给即将进入超重力强化蒸发室4的低温低湿循环气体加热,然后进入除湿填料塔6降温除湿,从所述除湿填料塔6降温除湿后的低温低湿气体进入二级回热除湿器2中加热后进入超重力强化蒸发室4,如此循环作用。系统稳定运行时,同时打开进料阀,循环阀和出料阀,进料和出料同时进行,系统处于持续运行状态,气体循环为闭式循环,系统控制简单稳定。Inject industrial waste water into the filter type solution storage tank 1 through the inlet pipe of the solution storage tank, and filter to remove solids. When the system is started, first start the heat pump system 8, the top motor and pipeline fan of the supergravity enhanced evaporation chamber 4, and open the feed valve. The liquid is transported by the feed pump 901 and enters the preheater 3 through the first-stage heat recovery dehumidifier 2. The liquid in the preheater is preheated by the hot water heated by the working fluid of the heat pump system. After the liquid is preheated, it enters the supergravity enhanced evaporation chamber 4. Spray through the solution inlet pipe into the concentric circular frame packing pan driven by the motor to exchange heat with the circulating gas, the water is taken away, the concentrated solution falls into the bottom of the evaporation chamber, and after a certain amount of liquid is delivered, the feed valve is closed , open the circulation valve, the liquid is preheated in the first-stage heat recovery dehumidifier 2 and the preheater 3 again under the action of the circulation pump, and then enters the supergravity enhanced evaporation chamber 4, reciprocating in this way, and circulates until the liquid at the bottom of the evaporation chamber reaches The working condition requires concentration, and the circulating gas after the humidity load first enters the first-stage heat recovery dehumidifier 2 for cooling and dehumidification under the action of the induced draft fan, and the large amount of heat released is used to heat the liquid, and then enters the secondary heat recovery dehumidifier 5 to give The low-temperature and low-humidity circulating gas entering the supergravity enhanced evaporation chamber 4 is heated, and then enters the dehumidification packed tower 6 for cooling and dehumidification. Gravity strengthens the evaporation chamber 4, so the circulation effect. When the system is running stably, open the feed valve, circulation valve and discharge valve at the same time, the feed and discharge are carried out at the same time, the system is in continuous operation, the gas circulation is a closed cycle, and the system control is simple and stable.
超重力强化蒸发室4顶部设有变频电机,与中通管相连接,同心圆框架式填料盘与中通管焊接为一整体,并在变频电机带动下一起旋转形成超重力场,中通管壁面分布一定数量的通孔,便于液体喷洒进入填料盘中,表面均布通孔的波纹板成特定角度插入在同心圆框架式填料盘上,液体进口管伸入至中通管中心,向其壁面喷洒液体;超重力强化蒸发室4内部顶部设有除沫器防止循环气体中液体的夹带,内部底部为储液腔体,用于临时储存浓缩液体。超重力强化蒸发室4的中通管填料盘为多层同心圆框架结构,内层框架同心圆半径较小,外层较大,同心圆之间用辐条链接,上下框架用拉杆固定,表面均布通孔的波纹板以特定角度插入所述同心圆框架中,内层数量较少,外层数量较多,保证通道间隙更加均匀,利于循环气体与液体进行换热。The top of the super-gravity enhanced evaporation chamber 4 is equipped with a frequency conversion motor, which is connected with the center tube. The concentric circular frame-type packing plate and the center tube are welded as a whole, and rotate together under the drive of the frequency conversion motor to form a supergravity field. The center tube A certain number of through holes are distributed on the wall to facilitate liquid spraying into the packing pan. The corrugated plate with evenly distributed through holes on the surface is inserted into the concentric circular frame packing pan at a specific angle. The wall is sprayed with liquid; the top of the supergravity enhanced evaporation chamber 4 is provided with a demister to prevent entrainment of liquid in the circulating gas, and the bottom of the interior is a liquid storage chamber for temporary storage of concentrated liquid. The filling plate of the central tube in the supergravity enhanced evaporation chamber 4 is a multi-layer concentric frame structure. The concentric circles of the inner frame have a smaller radius and the outer layer is larger. The concentric circles are connected by spokes, and the upper and lower frames are fixed by tie rods. The corrugated plates with through-holes are inserted into the concentric frame at a specific angle. The number of inner layers is small and the number of outer layers is large, so as to ensure a more uniform channel gap and facilitate heat exchange between circulating gas and liquid.
根据处理量和处理要求复叠式热泵低温段采用工质R410a,高温段采用工质R134a,能产出85℃热水。废液经热水加热至80℃进入蒸发室,蒸发室中,相对湿度20%,35℃的空气增温吸湿后温度升高至75℃,相对湿度为95%。一级除湿器中,75℃空气降至53℃,加热混合废液至70℃。蒸发室底部40℃浓缩液经循环泵与原35℃废液混合进入回热器。预热器中混合废液被加热至80℃吸收1600kW热量,热泵COP为3.17,电机功率500kW,蒸发1吨水消耗48度电。According to the processing capacity and processing requirements, the low-temperature section of the cascade heat pump uses working fluid R410a, and the high-temperature section uses working fluid R134a, which can produce 85°C hot water. The waste liquid is heated to 80°C by hot water and enters the evaporation chamber. In the evaporation chamber, the relative humidity is 20%. After the air at 35°C is warmed and absorbs moisture, the temperature rises to 75°C and the relative humidity is 95%. In the primary dehumidifier, the air at 75°C is reduced to 53°C, and the mixed waste liquid is heated to 70°C. The 40°C concentrated liquid at the bottom of the evaporation chamber is mixed with the original 35°C waste liquid through the circulation pump and enters the regenerator. The mixed waste liquid in the preheater is heated to 80°C to absorb 1600kW of heat, the COP of the heat pump is 3.17, the power of the motor is 500kW, and the evaporation of 1 ton of water consumes 48 kWh of electricity.
本发明利用气体升温后含湿量增大的特性实现液体蒸发,通过超重力旋转场来强化液体与循环气体(空气或氮气)的传质传热过程,高效环保,无二次污染排放。本发明采用除湿填料塔对循环载湿气体进行冷凝除湿,冷凝水储存在除湿填料塔底部作为冷却介质循环使用,缩减了设备的体积。本发明采用一级和二级回热除湿器,除湿的同时进行回热,大大降低了系统能耗,更加节能。而且本发明既可实现90℃高温高效蒸发,也可实现60℃以下用于热敏性物质的低温蒸发,适用范围广,在医药、食品、海水淡化、精细化工等多个行业均可得到应用。The invention realizes liquid evaporation by using the characteristic of increasing moisture content after the gas is heated up, and strengthens the mass transfer and heat transfer process between the liquid and the circulating gas (air or nitrogen) through the supergravity rotating field, which is highly efficient and environmentally friendly, and has no secondary pollution discharge. The invention uses a dehumidification packing tower to condense and dehumidify the circulating humidity-carrying gas, and the condensed water is stored at the bottom of the dehumidification packing tower and used as a cooling medium for recycling, thereby reducing the volume of the equipment. The present invention adopts one-stage and two-stage heat recovery dehumidifiers, and performs heat recovery at the same time of dehumidification, which greatly reduces energy consumption of the system and is more energy-saving. Moreover, the present invention can not only realize high-temperature and high-efficiency evaporation at 90°C, but also realize low-temperature evaporation for heat-sensitive substances below 60°C. It has a wide range of applications and can be applied in many industries such as medicine, food, seawater desalination, and fine chemical industry.
所述二级除湿器为翅片板换热器,其芯体装配图和分解图分别如图3和图4所示,温度较高的载湿气体从回热器顶部进口管进入,底部出口管流出,预热从所述填料除湿塔顶部流出的低温循环气体,从而起到回热节能的作用。The secondary dehumidifier is a finned plate heat exchanger, the assembly diagram and exploded diagram of its core body are shown in Figure 3 and Figure 4 respectively, the humidity-carrying gas with a higher temperature enters from the top inlet pipe of the regenerator, and the bottom outlet The pipe flows out, preheating the low-temperature circulating gas flowing out from the top of the packed dehumidification tower, so as to play the role of heat recovery and energy saving.
以上所述仅为本发明的较佳实施例,并不用以限制本发明,凡在本发明精神和原则之内的,所做的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the present invention. Any modifications, equivalent replacements, improvements, etc. made within the spirit and principles of the present invention shall be included in the scope of the present invention. within the scope of protection.
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| CN104689584A (en) * | 2015-03-17 | 2015-06-10 | 南京工业大学 | Heat pump driven supergravity field enhanced evaporation system |
| CN114719459A (en) * | 2022-03-08 | 2022-07-08 | 东南大学 | Deep dehumidification system driven by cascade heat pump and its application |
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| CN114719459A (en) * | 2022-03-08 | 2022-07-08 | 东南大学 | Deep dehumidification system driven by cascade heat pump and its application |
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