CN204494794U - A kind of recovery used heat thermal fusion latent heat of solidification heat pump - Google Patents
A kind of recovery used heat thermal fusion latent heat of solidification heat pump Download PDFInfo
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Abstract
一种回收废热热融式凝固潜热热泵,属于热泵技术领域,包括压缩机、冷凝水箱干燥过滤器、节流装置、蒸发水箱、气液分离器、蒸发水箱循环泵、冷凝水箱循环泵、液位计、用户热利用系统、集水器、除污器、自来水电磁阀、排水电磁阀和控制器。与常规的污水源热泵系统相比,不仅实现了生活污水的深度利用,通过生活污水的废热融解除冰实现换热表面上交替冻冰与融冰的两个过程,降低了生活污水的温度,保证了热泵机组常年的正常启动和稳定运行,同时保证了低位热源所提供的热量满足用户用热负荷需求,结构简单,便于维护检修,制热效率高,可以广泛应用于供生活热水及供热领域。
A recovery waste heat thermal fusion solidification latent heat pump, belonging to the field of heat pump technology, including a compressor, a condensate tank dry filter, a throttling device, an evaporation water tank, a gas-liquid separator, an evaporation water tank circulation pump, a condensation water tank circulation pump, and a liquid level Meter, user heat utilization system, water collector, decontamination device, tap water solenoid valve, drain solenoid valve and controller. Compared with the conventional sewage source heat pump system, it not only realizes the deep utilization of domestic sewage, but also realizes the two processes of alternating freezing and melting ice on the heat exchange surface through the waste heat melting and deicing of domestic sewage, which reduces the temperature of domestic sewage. It ensures the normal startup and stable operation of the heat pump unit throughout the year, and at the same time ensures that the heat provided by the low-level heat source meets the heat load demand of the user. The structure is simple, easy to maintain and overhaul, and the heating efficiency is high. It can be widely used in domestic hot water and heat supply. field.
Description
技术领域technical field
本实用新型属于热泵领域,具体涉及一种利用废热显热除冰、利用废热显热和潜热作为热泵低位热源的凝固潜热热泵。The utility model belongs to the field of heat pumps, in particular to a solidification latent heat heat pump which utilizes waste heat sensible heat for deicing and utilizes waste heat sensible heat and latent heat as low-level heat sources of the heat pump.
背景技术Background technique
随着我国经济的快速发展、城镇化水平和人民生活水平的不断提高,家庭、宾馆、学校、医院、浴池等对生活热水的需求量也不断提高。目前,通常有以下几种方式用来制备生活热水:(A)利用高品位热源(如燃煤、燃油、燃气、电加热)的热水锅炉;(B)利用太阳能作为主热源、燃气锅炉或电加热作为辅助热源的热水系统;(C)水源热泵或空气源热泵等热泵热水系统等。由于生活热水利用后在排放时仍具有较高的温度(可以达到30℃以上),尽管利用高品位热源的热水锅炉尽管具有加热快、系统运行稳定的优点,但从我国能源政策及经济性角度看,热水锅炉不是最佳的制备热水的方式,不但消耗一次能源,而且运行费用高,同时产生的生活污水中蕴含的低位热能由于无法科学利用而被白白的浪费。太阳能是绿色的可再生能源,以其作为热源提供生活热水值得提倡,但太阳能具有不稳定性和分散性的缺点,使得太阳能热水系统的使用受到了较大的限制。对于热泵热水系统而言,江、河、湖、海水、城市污水等地表水源热泵由于具有制热系数高、初投资低等优点,被公认为是一项即节能又环保的优秀技术,然而地表水源热泵却一直没有得到普遍的推广,原因在于适合热泵水源的地表水并非处处都是,譬如,冬季江河湖海水的水温很低,最低在2~4℃左右,则可利用的显热能量空间已经很小,存在结冰冻结破坏或者堵塞管路的危险。With the rapid development of my country's economy, the level of urbanization and the continuous improvement of people's living standards, the demand for domestic hot water in families, hotels, schools, hospitals, baths, etc. is also increasing. At present, there are usually the following ways to prepare domestic hot water: (A) hot water boilers using high-grade heat sources (such as coal, oil, gas, electric heating); (B) using solar energy as the main heat source, gas boilers Or a hot water system with electric heating as an auxiliary heat source; (C) heat pump hot water systems such as water source heat pumps or air source heat pumps, etc. Since domestic hot water still has a relatively high temperature (up to 30°C or higher) when it is discharged after utilization, although hot water boilers using high-grade heat sources have the advantages of fast heating and stable system operation, from the perspective of my country's energy policy and economic From a general point of view, hot water boilers are not the best way to prepare hot water. They not only consume primary energy, but also have high operating costs. At the same time, the low-level thermal energy contained in domestic sewage is wasted because it cannot be used scientifically. Solar energy is a green renewable energy source, and it is worth advocating to use it as a heat source to provide domestic hot water. However, solar energy has the disadvantages of instability and dispersion, which limits the use of solar water heating systems. For heat pump hot water systems, surface water source heat pumps such as rivers, rivers, lakes, seawater, and urban sewage are recognized as an excellent energy-saving and environmentally friendly technology due to their high heating coefficient and low initial investment. Surface water source heat pumps have not been widely promoted. The reason is that surface water suitable for heat pump water sources is not everywhere. The space is already small, and there is a danger of freezing damage or clogging the pipes.
为了解决低位热源显热能量空间小的问题,人们考虑制取流体冰来提取凝固潜热以满足工程负荷的需要。实用新型专利(申请号为CN 200610009617.5)提出了一种利用低位热源供水显热进行除霜的凝固潜热型热泵,利用空气与水互不相溶,流动性好的特点,以空气作为中介制冷流体,以此来制取“无根冰”。空气与水进行直接换热之后,再与热泵蒸发器内的制冷剂进行换热,因此,该热泵本质上属于空气源热泵。由于空气与水直接换热后的温度在0℃左右,且非常接近饱和状态,则该凝固热潜热型热泵在提取凝固潜热的过程中,蒸发器表面容易结霜,为提高热泵的制热效率,该实用新型利用部分低位热源水显热进行除霜。该实用新型很好地利用了低位热源水的潜热,同时有效地解决了蒸发器除霜的问题。另外,为了解决风冷热泵在环境气温较低时,其工作效率低甚至无法正常运行的问题,实用新型专利(申请号为CN 200910184024.6)提出了一种双热源热泵,该热泵具有两种运行模式,在环境气温较高时采用空气源作为热源,在环境温度较低时采用水的部分潜热作为热源,从而保证了热泵系统在环境温度较低时具有较高的工作效率,但如何制取流动冰,以满足连续从水中提取凝固热的需求是该热泵系统能否稳定运行的关键。在提取凝固热的过程中,为了在满足经济效益的情况下使结的冰及时从换热表面上被剥离,并且使冰水无堵塞地在管道中流动,实用新型专利(专利号为CN 200610009616.0,CN200610009740.7)提出了刮刀式凝固热采集装置,以机械“刮”的形式将冻结在换热管上的冰从壁面上剥离下来,与水混合形成冰絮并随水带走,从而不断的采集凝固热,但采用机械除冰的方法存在设备结构复杂、成本高的问题。In order to solve the problem of small sensible heat energy space of low-level heat sources, people consider making fluid ice to extract solidification latent heat to meet the needs of engineering loads. A utility model patent (application number CN 200610009617.5) proposes a solidification latent heat pump that uses sensible heat from a low-level heat source to supply water for defrosting. It utilizes the characteristics of incompatibility between air and water and good fluidity, and uses air as the intermediary cooling fluid. , to make "rootless ice". After the air exchanges heat directly with water, it then exchanges heat with the refrigerant in the heat pump evaporator. Therefore, the heat pump is essentially an air source heat pump. Since the temperature after direct heat exchange between air and water is about 0°C and is very close to the saturation state, the surface of the evaporator is prone to frosting during the process of extracting the latent heat of solidification heat pump. In order to improve the heating efficiency of the heat pump, The utility model uses the sensible heat of part of the low-level heat source water to defrost. The utility model makes good use of the latent heat of the low-level heat source water, and at the same time effectively solves the problem of defrosting of the evaporator. In addition, in order to solve the problem that the air-cooled heat pump has low working efficiency or even cannot operate normally when the ambient temperature is low, a utility model patent (application number CN 200910184024.6) proposes a dual heat source heat pump, which has two operating modes , the air source is used as the heat source when the ambient temperature is high, and part of the latent heat of water is used as the heat source when the ambient temperature is low, thus ensuring that the heat pump system has a high working efficiency when the ambient temperature is low, but how to prepare the flow Ice is the key to the stable operation of the heat pump system to meet the demand of continuously extracting the heat of condensation from water. In the process of extracting the solidification heat, in order to make the frozen ice be stripped from the heat exchange surface in time while meeting the economic benefits, and to make the ice water flow in the pipeline without blockage, a utility model patent (patent number CN 200610009616.0 , CN200610009740.7) proposed a scraper-type solidification heat collection device, which peels off the ice frozen on the heat exchange tube from the wall in the form of mechanical "scraping", mixes with water to form ice flocs and takes them away with the water, thus continuously However, the method of mechanical deicing has the problems of complex equipment structure and high cost.
生活污水回收利用时,具有废热温度高、蕴含的热能丰富等显著特点(可以达到30℃以上),但以此作为水源热泵的低位热源,通过水源热泵机组加热生活热水时,会出现以下问题:(1)在冬季气温较低的地区,冬季自来水温度较低,如5℃左右,而废热的温度在30℃左右,利用30℃左右的低位热源通过热泵将5℃左右的自来水加热到满足生活用水温度要求时,热泵机组在该工况下无法正常启动。(2)热泵在加热生活热水的过程中,由于冷凝侧冷水温度逐渐升高,导致冷凝温度逐渐升高,同时由于污水水量不足,需要将生活污水通过蓄水箱蓄存起来,则蒸发侧污水温度逐渐降低,导致蒸发温度逐渐减低,在热泵机组整个的运行过程中,冷凝温度和蒸发温度变化范围大,则热泵机组运行的稳定性差。(3)通过热泵机组将5℃左右的自来水加热到满足生活用水温度要求时,仅回收生活污水的显热,无法满足冷凝侧用户的用热负荷需要。因此,在国际社会普遍要求节能减排的呼声下,如何有效的解决上述问题,从而合理、有效地利用生活废水等废热资源,实现为用户提供连续稳定的用热需求具有重大意义。When domestic sewage is recycled, it has the remarkable characteristics of high waste heat temperature and rich heat energy (it can reach above 30°C), but when it is used as a low-level heat source of water source heat pump, when domestic hot water is heated by water source heat pump unit, the following problems will occur : (1) In areas where the temperature is low in winter, the temperature of tap water is low in winter, such as about 5°C, while the temperature of waste heat is about 30°C. Use a low-level heat source at about 30°C to heat the tap water at about 5°C through a heat pump to meet When the domestic water temperature is required, the heat pump unit cannot start normally under this working condition. (2) When the heat pump is heating domestic hot water, the temperature of the cold water on the condensing side gradually increases, resulting in a gradual increase in the condensing temperature. At the same time, due to insufficient sewage water, domestic sewage needs to be stored in the water storage tank, and the evaporating side The temperature of the sewage gradually decreases, resulting in a gradual decrease in the evaporation temperature. During the entire operation of the heat pump unit, the condensing temperature and evaporation temperature vary widely, and the stability of the heat pump unit operation is poor. (3) When the tap water at about 5°C is heated to meet the temperature requirements of domestic water through the heat pump unit, only the sensible heat of domestic sewage is recovered, which cannot meet the heat load needs of users on the condensation side. Therefore, under the general call of the international community for energy conservation and emission reduction, how to effectively solve the above problems, so as to rationally and effectively utilize domestic waste water and other waste heat resources, and achieve continuous and stable heat demand for users is of great significance.
实用新型内容Utility model content
本实用新型要解决的技术问题是实现生活污水的合理、有效利用,采用污水的部分低温显热和凝固潜热作为热源,同时利用废水的部分显热通过热融法实现换热表面上交替进行冻冰与融冰的两个过程,以维持热泵机组的蒸发温度在一个比较稳定的范围之内运行,保证热泵机组的正常稳定地运行,并且保证低位热源所提供的热量满足用户用热负荷需求而提供的一种回收废热热融式凝固潜热热泵。The technical problem to be solved by the utility model is to realize reasonable and effective utilization of domestic sewage, adopt part of the low-temperature sensible heat and solidification latent heat of sewage as heat sources, and use part of the sensible heat of waste water to achieve alternate freezing on the heat exchange surface through the heat-thawing method. The two processes of ice and ice melting are used to maintain the evaporation temperature of the heat pump unit within a relatively stable range, to ensure the normal and stable operation of the heat pump unit, and to ensure that the heat provided by the low-level heat source meets the heat load demand of the user. Provided is a recovery waste heat heat melting solidification latent heat heat pump.
本实用新型的技术方案如下:The technical scheme of the utility model is as follows:
一种回收废热热融式凝固潜热热泵,包括压缩机、冷凝水箱、干燥过滤器、节流装置、蒸发水箱、气液分离器、蒸发水箱循环泵、冷凝水箱循环泵、液位计、用户热利用系统、集水器、除污器、自来水电磁阀、排水电磁阀和控制器;压缩机排气口与冷凝水箱制冷剂侧、干燥过滤器、节流装置、蒸发水箱制冷剂侧通过管道依次连接,压缩机吸气口与气液分离器出口通过管道连接;自来水电磁阀通过自来水供水管道与冷凝水箱相连接,自来水供水管入口位置高于液位计顶端;排水电磁阀通过排水管与蒸发水箱相连接;用户热利用系统通过管路与冷凝水箱相连接;集水器、除污器与蒸发水箱通过管路依次连接;蒸发水箱循环泵的吸入口和出口通过管路与蒸发水箱连接,冷凝水箱循环泵的吸入口和出口通过管路与冷凝水箱连接;液位计安装在冷凝水箱外侧壁,其底端位置高于与用户热利用系统相连的出水口。A recovery waste heat thermal melting solidification latent heat pump, including a compressor, a condensed water tank, a dry filter, a throttling device, an evaporating water tank, a gas-liquid separator, a circulating pump for the evaporating water tank, a circulating pump for the condensed water tank, a liquid level gauge, and a user heat pump. Utilization system, water collector, decontamination device, tap water solenoid valve, drain solenoid valve and controller; the exhaust port of the compressor and the refrigerant side of the condensed water tank, the dry filter, the throttling device, and the refrigerant side of the evaporating water tank pass through the pipeline in sequence Connection, the suction port of the compressor is connected to the outlet of the gas-liquid separator through a pipeline; the tap water solenoid valve is connected to the condensate tank through a tap water supply pipe, and the inlet of the tap water supply pipe is higher than the top of the liquid level gauge; the drain solenoid valve is connected to the evaporator through a drain pipe The water tank is connected; the user's heat utilization system is connected to the condensed water tank through pipelines; the water collector, decontamination device and the evaporation water tank are connected in sequence through pipelines; the suction port and outlet of the circulation pump of the evaporation water tank are connected to the evaporation water tank through pipelines, The suction and outlet of the condensate tank circulation pump are connected to the condensate tank through pipelines; the liquid level gauge is installed on the outer wall of the condensate tank, and its bottom is higher than the water outlet connected to the user's heat utilization system.
本实用新型的运行模式为:控制器读取液位计的指示值并和冷凝水箱最低液位设定值比较,当指示值低于最低液位设定值时,自来水电磁阀打开给冷凝水箱充水,当指示值达到冷凝水箱最高液位设定值时,自来水电磁阀关闭,蒸发水箱循环泵、冷凝水箱循环泵启动,之后热泵机组启动,当冷凝水箱内的水温达到用户需求温度时,热泵机组停止运行,之后蒸发水箱循环泵、冷凝水箱循环泵停止运行;用户从冷凝水箱中取高温热水,利用后通过集水器将废水进行收集,通过除污器对废水进行物理除污处理之后,废水流入蒸发水箱进行蓄存,并对蒸发水箱制冷剂换热管外侧的固体冰进行融解,当水温低于排水温度下线设定值时,排水电磁阀打开排水,当水温高水排水温度上线设定值时,排水电磁阀关闭;当蒸发水箱内蓄水液面高于溢流口时,多余的废水从溢流排出。The operation mode of the utility model is: the controller reads the indication value of the liquid level gauge and compares it with the minimum liquid level setting value of the condensed water tank. Fill with water, when the indication value reaches the set value of the maximum liquid level of the condensed water tank, the tap water solenoid valve is closed, the circulating pump of the evaporating water tank and the circulating pump of the condensed water tank are started, and then the heat pump unit is started, and when the water temperature in the condensed water tank reaches the temperature required by the user, The heat pump unit stops running, and then the circulating pump of the evaporation water tank and the circulating pump of the condensed water tank stop running; the user takes high-temperature hot water from the condensed water tank, collects the waste water through the water collector after use, and performs physical decontamination treatment on the waste water through the decontamination device After that, the waste water flows into the evaporating water tank for storage, and melts the solid ice outside the refrigerant heat exchange tube of the evaporating water tank. When the water temperature is lower than the set value of the drainage temperature, the drain solenoid valve opens to drain water. When the water temperature is high, the water is drained. When the temperature is above the set value, the drain solenoid valve is closed; when the water storage level in the evaporation water tank is higher than the overflow port, the excess waste water is discharged from the overflow.
本实用新型与常规的污水源热泵系统相比,不仅实现了生活污水的热回收利用,而且通过生活污水的废热融解除冰实现换热表面上交替冻冰与融冰的两个过程,降低了生活污水的温度,保证了热泵机组常年的正常启动和稳定运行。该装置实现了废水凝固热利用,保证了低位热源所提供的热量满足用户用热负荷需求,提高了热泵的制热效率,并且本实用新型结构简单,便于维护检修,可以广泛应用于供生活热水及供热领域。Compared with the conventional sewage source heat pump system, the utility model not only realizes the heat recovery and utilization of domestic sewage, but also realizes the two processes of alternately freezing and melting ice on the heat exchange surface through the waste heat melting and deicing of domestic sewage, which reduces the The temperature of domestic sewage ensures the normal start-up and stable operation of the heat pump unit all year round. The device realizes the utilization of waste water coagulation heat, ensures that the heat provided by the low-level heat source meets the heat load demand of the user, and improves the heating efficiency of the heat pump. The utility model has a simple structure, is convenient for maintenance and repair, and can be widely used in domestic hot water supply. and heating areas.
附图说明Description of drawings
附图是本实用新型的结构示意图。Accompanying drawing is the structural representation of the utility model.
图中:1压缩机,2冷凝水箱,3干燥过滤器,4节流装置,5蒸发水箱,6气液分离器,7蒸发水箱循环泵,8冷凝水箱循环泵,9液位计,10用户热利用系统,11集水器,12除污器,13自来水电磁阀,14排水电磁阀,15控制器。In the figure: 1 compressor, 2 condensed water tank, 3 dry filter, 4 throttling device, 5 evaporating water tank, 6 gas-liquid separator, 7 evaporating water tank circulating pump, 8 condensed water tank circulating pump, 9 liquid level gauge, 10 user Heat utilization system, 11 water collector, 12 decontamination device, 13 tap water solenoid valve, 14 drain solenoid valve, 15 controller.
具体实施方式Detailed ways
以下结合技术方案和附图详细叙述本实用新型的具体实施例。The specific embodiment of the utility model is described in detail below in conjunction with technical scheme and accompanying drawing.
实现本实用新型时,压缩机1、冷凝水箱2、干燥过滤器3、节流装置4、蒸发水箱5、气液分离器6依次连接,其工作原理与一般的水源热泵基本相同;自来水电磁阀13通过自来水供水管道与冷凝水箱2相连接;排水电磁阀通过排水管14与蒸发水箱5相连接;用户热利用系统10通过管路与冷凝水箱2相连接;集水器11、除污器12与蒸发水箱5通过管路依次连接;蒸发水箱循环泵7的吸入口和出口通过管路与蒸发水箱5连接,冷凝水箱循环泵8的吸入口和出口通过管路与冷凝水箱2连接;液位计9安装在冷凝水箱2外侧壁,其底端位置高于与用户热利用系统10相连的出水口。蒸发水箱5内的换热管既可以是光滑铜管,也可以是翅片管;冷凝水箱2既可以是附图1所示的直接式系统,冷凝水箱2自来水管入口位置高于液位计9的顶端。同时冷凝水箱2也可以采用冷凝器代替,形成间接式系统。When realizing the utility model, the compressor 1, the condensed water tank 2, the drier filter 3, the throttling device 4, the evaporation water tank 5, and the gas-liquid separator 6 are connected in sequence, and its working principle is basically the same as that of a general water source heat pump; 13 is connected to the condensed water tank 2 through the tap water supply pipe; the drain solenoid valve is connected to the evaporated water tank 5 through the drain pipe 14; the user heat utilization system 10 is connected to the condensed water tank 2 through the pipeline; the water collector 11 and the decontamination device 12 It is connected with the evaporation water tank 5 in turn through pipelines; the suction port and outlet of the evaporation water tank circulation pump 7 are connected with the evaporation water tank 5 through pipelines, and the suction inlet and outlet of the condensation water tank circulation pump 8 are connected with the condensation water tank 2 through pipelines; Meter 9 is installed on the outer wall of condensed water tank 2, and its bottom position is higher than the water outlet that links to each other with user's heat utilization system 10. The heat exchange tube in the evaporating water tank 5 can be a smooth copper tube or a finned tube; the condensed water tank 2 can be a direct system as shown in accompanying drawing 1, and the inlet position of the tap water pipe of the condensed water tank 2 is higher than that of the liquid level gauge 9 tops. At the same time, the condensed water tank 2 can also be replaced by a condenser to form an indirect system.
本实用新型的运行模式为:控制器15读取冷凝水箱2液位计9的指示值并和冷凝水箱2最低液位设定值比较,当指示值低于最低液位设定值时,自来水电磁阀13打开给冷凝水箱2充水,当指示值达到冷凝水箱2最高液位设定值时,自来水电磁阀13关闭,蒸发水箱循环泵8、冷凝水箱循环泵9启动,之后热泵机组启动,当冷凝水箱2内的水温达到用户需求温度时,热泵机组停止运行,之后蒸发水箱循环泵8、冷凝水箱循环泵7停止运行;用户从冷凝水箱2中取高温热水,高温热水利用后通过集水器11将废水进行收集,通过除污器12对废水进行物理除污处理之后,废水流入蒸发水箱进行蓄存,并对蒸发水箱5制冷剂换热管外侧的固体冰进行融解,当水温低于排水温度下线设定值时,排水电磁阀14打开排水,当水温高水排水温度上线设定值时,排水电磁阀14关闭;当蒸发水箱5内蓄水液面高于溢流口时,多余的废水从溢流排出。The operating mode of the present utility model is: the controller 15 reads the indicated value of the liquid level gauge 9 of the condensed water tank 2 and compares it with the minimum liquid level setting value of the condensed water tank 2. When the indicated value is lower than the minimum liquid level set value, the tap water The solenoid valve 13 is opened to fill the condensed water tank 2 with water. When the indicated value reaches the maximum liquid level setting value of the condensed water tank 2, the tap water solenoid valve 13 is closed, the circulating pump 8 of the evaporating water tank and the circulating pump 9 of the condensed water tank are started, and then the heat pump unit is started. When the water temperature in the condensed water tank 2 reaches the temperature required by the user, the heat pump unit stops running, and then the circulating pump 8 of the evaporating water tank and the circulating pump 7 of the condensed water tank stop running; the user takes high-temperature hot water from the condensed water tank 2, and the hot water passes through The water collector 11 collects the waste water. After the waste water is physically decontaminated by the decontamination device 12, the waste water flows into the evaporation water tank for storage, and melts the solid ice outside the refrigerant heat exchange tube of the evaporation water tank 5. When the water temperature When the water discharge temperature is lower than the lower-line set value, the drain electromagnetic valve 14 is opened to drain water, and when the water temperature is higher than the upper-line set value of the water drain temperature, the drain electromagnetic valve 14 is closed; , excess waste water is discharged from the overflow.
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| CN201520092406.7U CN204494794U (en) | 2015-02-09 | 2015-02-09 | A kind of recovery used heat thermal fusion latent heat of solidification heat pump |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104654573A (en) * | 2015-02-09 | 2015-05-27 | 大连理工大学 | A solidification latent heat heat pump for recycling waste heat |
| CN106225313A (en) * | 2016-08-31 | 2016-12-14 | 深圳市丹耐斯机械有限公司 | A kind of air energy water chiller/heater |
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2015
- 2015-02-09 CN CN201520092406.7U patent/CN204494794U/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104654573A (en) * | 2015-02-09 | 2015-05-27 | 大连理工大学 | A solidification latent heat heat pump for recycling waste heat |
| CN106225313A (en) * | 2016-08-31 | 2016-12-14 | 深圳市丹耐斯机械有限公司 | A kind of air energy water chiller/heater |
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| CF01 | Termination of patent right due to non-payment of annual fee |