CN204359766U - A kind of mud nitrification activity intelligent analysis system - Google Patents

A kind of mud nitrification activity intelligent analysis system Download PDF

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CN204359766U
CN204359766U CN201420638557.3U CN201420638557U CN204359766U CN 204359766 U CN204359766 U CN 204359766U CN 201420638557 U CN201420638557 U CN 201420638557U CN 204359766 U CN204359766 U CN 204359766U
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aeration
pump
pipe
solenoid valve
ammonia nitrogen
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魏磊
高永青
葛勇涛
陈桃生
孟春霖
冯雪菲
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Beijing Drainage Group Co Ltd
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Abstract

本实用新型提出一种污泥硝化活性智能分析系统,该系统包括控制面板、PLC控制器、安放在柜体内的反应装置,反应装置底部分别连接有排水管、排水电磁阀、曝气管、曝气头、曝气电磁阀,上部依次连接有进水管、进水电磁阀、进水泵,加药管、加药泵,曝气管一端与曝气头相连,另一端连有电磁阀及曝气泵,采用该系统采用连续一段时间内监测氨氮值变化的方式计算污泥硝化活性数值,数据分析软件以最小二乘法和模拟逼近法为基础进行分析计算,该系统适用于测定城市污水处理厂生物池中活性污泥的硝化活性,及活性污泥工艺的氨氮硝化速率,大大提高了检测速率和对氨氮硝化速率实时监测的效率。

The utility model proposes an intelligent analysis system for sludge nitrification activity. The system includes a control panel, a PLC controller, and a reaction device placed in the cabinet. The bottom of the reaction device is respectively connected with a drainage pipe, a drainage solenoid valve, an aeration pipe, Air head, aeration solenoid valve, the upper part is connected with water inlet pipe, water inlet solenoid valve, water inlet pump, dosing pipe and dosing pump in turn, one end of the aeration pipe is connected with the aeration head, and the other end is connected with the solenoid valve and aeration pump. pump, the system uses the method of monitoring the change of ammonia nitrogen value for a continuous period of time to calculate the sludge nitrification activity value, and the data analysis software uses the least square method and the simulation approximation method to analyze and calculate. This system is suitable for the determination of biological The nitrification activity of the activated sludge in the pool and the ammonia nitrogen nitrification rate of the activated sludge process have greatly improved the detection rate and the efficiency of real-time monitoring of the ammonia nitrogen nitrification rate.

Description

一种污泥硝化活性智能分析系统An intelligent analysis system for sludge nitrification activity

技术领域 technical field

本实用新型属于污水处理技术领域,尤其涉及一种污泥硝化活性智能分析系统。 The utility model belongs to the technical field of sewage treatment, in particular to an intelligent analysis system for sludge nitrification activity.

背景技术 Background technique

水体富营养化问题日益突出,氮磷排放标准日益严格。我国于2002年颁布的《城镇污水处理厂污染物排放标准》中增加了对总氮和总磷的排放浓度限制。目前我国污水处理行业发展水平仍落后于发达国家。我国污水处理行业目前所面临的主要问题是污水处理设施能源效率不高,污水处理达标率偏低等。统计数据显示,截至2009年,中国已建成的污水处理厂约有1993座。另外,我国提出在“十一五”期间单位GDP能耗降低20%左右的约束性指标,国家在“十二五”规划中,进一步提出了深化节能减排、单位GDP能耗降低16%的目标,节能降耗是当前我国急需解决的问题。为保证污水处理厂高效运行,减少能源资源消耗,改善周边地区环境质量,充分发挥污水处理系统的经济效益、环境效益和社会效益,促进经济建设的可持续发展,我国新建污水处理厂都需要在稳定达标的前提下实现节能降耗,大多数已建城市污水处理厂都有必要进行改造。 The problem of eutrophication of water bodies has become increasingly prominent, and the discharge standards for nitrogen and phosphorus have become increasingly stringent. my country promulgated in 2002 the "Urban Sewage Treatment Plant Pollutant Discharge Standards" to increase the emission concentration limits of total nitrogen and total phosphorus. At present, the development level of my country's sewage treatment industry still lags behind developed countries. The main problems currently faced by my country's sewage treatment industry are the low energy efficiency of sewage treatment facilities and the low compliance rate of sewage treatment. Statistics show that as of 2009, China has built about 1993 sewage treatment plants. In addition, my country proposed a binding target of reducing energy consumption per unit of GDP by about 20% during the "Eleventh Five-Year Plan" period. Goals, energy saving and consumption reduction is an urgent problem to be solved in our country. In order to ensure the efficient operation of sewage treatment plants, reduce the consumption of energy resources, improve the environmental quality of surrounding areas, give full play to the economic, environmental and social benefits of the sewage treatment system, and promote the sustainable development of economic construction, all new sewage treatment plants in my country need to be To achieve energy saving and consumption reduction under the premise of stably meeting the standards, most of the urban sewage treatment plants that have been built need to be transformed.

污水处理厂总氮去除率有待进一步提高,并且污水处理厂鼓风机能耗占全厂能耗30%-60%。总氮去除率的提高和鼓风机能耗的降低都与曝气量有关,设定合理的供气范围很重要。而污泥硝化活性即氨氮硝化速率是计算和控制供气量设定值的关键参数。本实用新型污泥硝化活性智能分析系统可以实时的自动测定生物池中的氨氮硝化速率,能够及时反应硝化速率变化,帮助调整供气量参数,并保证氨氮完全去除。 The total nitrogen removal rate of the sewage treatment plant needs to be further improved, and the blower energy consumption of the sewage treatment plant accounts for 30%-60% of the total plant energy consumption. The improvement of total nitrogen removal rate and the reduction of blower energy consumption are related to the aeration volume, so it is very important to set a reasonable air supply range. The nitrification activity of sludge, that is, the nitrification rate of ammonia nitrogen, is the key parameter for calculating and controlling the set value of air supply. The intelligent analysis system for sludge nitrification activity of the utility model can automatically measure the ammonia nitrogen nitrification rate in the biological pool in real time, can respond to the change of the nitrification rate in time, helps to adjust the gas supply parameters, and ensures the complete removal of ammonia nitrogen.

实用新型内容 Utility model content

本实用新型由一套全自动反应装置和一套数据分析软件组成,全自动反应装置模拟实现生物池中活性污泥对氨氮的完整硝化过程,并监测采集氨氮、溶解氧数据。数据分析软件负责将所采集的数据进行分析处理,计算出污泥硝化活性氨氮硝化速率数值。 The utility model is composed of a set of automatic reaction device and a set of data analysis software. The automatic reaction device simulates the complete nitrification process of ammonia nitrogen by activated sludge in the biological pool, and monitors and collects ammonia nitrogen and dissolved oxygen data. The data analysis software is responsible for analyzing and processing the collected data, and calculating the nitrification rate value of sludge nitrification activity ammonium nitrogen.

本实用新型目的是针对污水处理厂生物池中污泥微生物活性分析和氨氮硝化速率测定提供一种污泥硝化活性智能分析系统,该方法能够满足对氨氮硝化速率进行实时监测。 The purpose of the utility model is to provide an intelligent analysis system for sludge nitrification activity for the analysis of sludge microbial activity and the measurement of ammonia nitrogen nitrification rate in the biological pool of sewage treatment plant. The method can meet the real-time monitoring of ammonia nitrogen nitrification rate.

本实用新型采用连续一段时间内监测氨氮值变化的方式计算污泥硝化活性(氨氮硝化速率)数值,数据分析软件以最小二乘法和模拟逼近法为基础进行分析计算,该系统适用于测定城市污水处理厂生物池中活性污泥的硝化活性,及活性污泥工艺的氨氮硝化速率。 The utility model calculates the value of sludge nitrification activity (ammonia nitrogen nitrification rate) by monitoring the change of ammonia nitrogen value in a continuous period of time. The data analysis software analyzes and calculates based on the least square method and the simulation approximation method. The system is suitable for measuring urban sewage The nitrification activity of activated sludge in the biological pool of the treatment plant, and the ammonia nitrogen nitrification rate of the activated sludge process.

具体而言,本实用新型在于提出一种污泥硝化活性智能分析系统,该分析系统包括柜体,安装在柜前门上的控制面板,安装在柜体后内壁上的PLC控制器,安放在柜体内的反应装置,其中,反应装置底部分别连接有排水管、排水电磁阀、曝气管、曝气头、曝气电磁阀,上部依次连接有进水管、进水电磁阀、进水泵,加药管、加药泵,曝气管一端与曝气头相连,另一端连有电磁阀及曝气泵;反应装置中,安装有氨氮测量仪、溶解氧测量仪及液位传感器,所有的电磁阀、进水泵、在线氨氮测量仪、溶 Specifically, the utility model is to propose an intelligent analysis system for sludge nitrification activity. The analysis system includes a cabinet, a control panel installed on the front door of the cabinet, a PLC controller installed on the rear inner wall of the cabinet, and placed in the cabinet. The reaction device in the body, wherein the bottom of the reaction device is connected with drain pipe, drain solenoid valve, aeration pipe, aeration head, and aeration solenoid valve, and the upper part is connected with water inlet pipe, water inlet solenoid valve, water inlet pump in turn, and the dosing One end of the aeration pipe is connected to the aeration head, and the other end is connected to a solenoid valve and an aeration pump; the reaction device is equipped with an ammonia nitrogen measuring instrument, a dissolved oxygen measuring instrument and a liquid level sensor, and all the solenoid valves , water inlet pump, online ammonia nitrogen measuring instrument, solvent

解氧测量仪和液位传感器与PLC控制器相连接,PLC控制器与控制面板相连接,在线氨氮测量仪、溶解氧测量仪与自动清洗装置相连。 The oxygen solution measuring instrument and the liquid level sensor are connected with the PLC controller, the PLC controller is connected with the control panel, and the online ammonia nitrogen measuring instrument and the dissolved oxygen measuring instrument are connected with the automatic cleaning device.

进一步地,本实用新型提供的曝气泵为变频泵。 Further, the aeration pump provided by the utility model is a frequency conversion pump.

本污泥硝化活性智能分析系统具有的特点和有益效果: The characteristics and beneficial effects of the sludge nitrification activity intelligent analysis system:

1).测定过程中可随时从显示器上对后续测定过程进行调整,并查看历史分析测量数据。 1). During the measurement process, the subsequent measurement process can be adjusted from the display at any time, and the historical analysis measurement data can be viewed.

2).操作简单,完全智能化运行。 2). Simple operation, fully intelligent operation.

3).本污泥硝化活性智能分析系统可广泛应用于污水处理厂的生物池沿程硝化速率测定,便于技术人员及时了解掌握生物池中微生物活性和生化反应进程。 3). This intelligent analysis system for sludge nitrification activity can be widely used in the determination of nitrification rate along the biological pool of sewage treatment plants, which is convenient for technicians to understand the microbial activity and biochemical reaction process in the biological pool in time.

4).污泥硝化活性智能分析系统安装在生物池厌氧段的进水处,此处生物池中的氨氮值与进水相近。根据测定的污泥硝化活性,可以对好氧池中的曝气量进行调节,如果污泥硝化活性高,好氧池中的曝气量可以适当降低,污泥硝化活性差,可以适当提高曝气量,有助于污泥硝化活性的恢复。 4). The intelligent analysis system for sludge nitrification activity is installed at the water inlet of the anaerobic section of the biological pool, where the ammonia nitrogen value in the biological pool is similar to that of the incoming water. According to the measured sludge nitrification activity, the aeration rate in the aerobic tank can be adjusted. If the sludge nitrification activity is high, the aeration rate in the aerobic tank can be appropriately reduced. If the sludge nitrification activity is poor, the aeration rate can be appropriately increased. Gas volume, contribute to the recovery of sludge nitrification activity.

5).污泥硝化活性智能分析系统与在线氨氮仪、在线溶解氧仪等在线仪表配合使用,可以更好的实现对曝气量的优化控制,更加精确的根据氨氮硝化需求供给气量,达到降低曝气能耗,稳定出水水质的目的。该系统的使用可以使污水处理厂在日常运行中对参数的调整更加科学,有据可依,帮助技术人员分析和预测生物池处理能力变化,确保出水水质安全达标。 5). The intelligent analysis system for sludge nitrification activity is used in conjunction with online instruments such as online ammonia nitrogen meter and online dissolved oxygen meter, which can better realize the optimal control of aeration volume, and more accurately supply air volume according to the demand of ammonia nitrogen nitrification, so as to reduce the Aeration energy consumption, the purpose of stabilizing effluent water quality. The use of this system can make the adjustment of parameters in the daily operation of sewage treatment plants more scientific and evidence-based, and help technicians analyze and predict changes in the treatment capacity of biological pools to ensure that the effluent water quality is safe and up to standard.

附图说明 Description of drawings

图1是根据本实用新型的一个实施例的一种污泥硝化活性智能分析系统示意图; Fig. 1 is a schematic diagram of an intelligent analysis system for sludge nitrification activity according to an embodiment of the present invention;

图中:1.柜体;2.控制面板;3.PLC控制器;4.反应装置;5.排水管;6.排水电磁阀;7.曝气管;8.曝气头;9.曝气电磁阀;10.进水管;11.进水电磁阀;12.进水泵;13.加药管;14.加药泵;15.曝气泵;16.在线氨氮测量仪;17.溶解氧测量仪;18.液位传感器;19.清洗装置。  In the figure: 1. cabinet body; 2. control panel; 3. PLC controller; 4. reaction device; 5. drainage pipe; 6. drainage solenoid valve; 7. aeration pipe; 8. aeration head; 9. exposure Gas solenoid valve; 10. Water inlet pipe; 11. Water inlet solenoid valve; 12. Water inlet pump; 13. Dosing pipe; 14. Dosing pump; 15. Aeration pump; 16. Online ammonia nitrogen measuring instrument; 17. Dissolved oxygen Measuring instrument; 18. Liquid level sensor; 19. Cleaning device. the

具体实施方式 Detailed ways

下面详细描述本实用新型的实施例,所述实施例的示例在附图中示出,其中自始至终相同或类似的标号表示相同或类似的元件或具有相同或类似功能的元件。下面通过参考附图描述的实施例是示例性的,仅用于解释本实用新型,而不能理解为对本实用新型的限制。 Embodiments of the present invention are described in detail below, examples of which are shown in the drawings, wherein the same or similar reference numerals represent the same or similar elements or elements having the same or similar functions throughout. The embodiments described below with reference to the accompanying drawings are exemplary and are only used to explain the present utility model, but should not be construed as limiting the present utility model.

在本实用新型的描述中,需要理解的是,术语“中心”、“纵向”、“横向”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”“内”、“外”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本实用新型和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本实用新型的限制。 In describing the present utility model, it should be understood that the terms "center", "longitudinal", "transverse", "upper", "lower", "front", "rear", "left", "right", The orientations or positional relationships indicated by "vertical", "horizontal", "top", "bottom", "inner", "outer", etc. are based on the orientation or positional relationships shown in the drawings, and are only for the convenience of describing the utility model and simplified descriptions, rather than indicating or implying that the device or element referred to must have a specific orientation, be constructed and operated in a specific orientation, and therefore should not be construed as limiting the invention.

此外,术语“第一”、“第二”仅用于描述目的,而不能理解为指示或暗示相对重要性。 In addition, the terms "first" and "second" are used for descriptive purposes only, and should not be understood as indicating or implying relative importance.

在本实用新型的描述中,需要说明的是,除非另有明确的规定和限定,术语“安装”、“相连”、“连接”应做广义理解,例如,可以是固定连接,一体地连接,也可以是可拆卸连接;可以是机械连接或电连接,也可以是两个元件内部的连通;可以是直接相连,也可以通过中间媒介间接相连,对于本领域的普通技术人员而言,可以根据具体情况理解上述术语的具体含义。 In the description of the present utility model, it should be noted that, unless otherwise clearly stipulated and limited, the terms "installation", "connection" and "connection" should be understood in a broad sense, for example, it can be a fixed connection, an integral connection, It can also be a detachable connection; it can be a mechanical connection or an electrical connection, or it can be the internal communication of two components; it can be directly connected or indirectly connected through an intermediary. For those of ordinary skill in the art, it can be based on Understand the specific meaning of the above terms in specific situations.

为实现上述目的,本实用新型采取了如下技术方案: In order to achieve the above object, the utility model has taken the following technical solutions:

一种污泥硝化活性智能分析系统,该分析系统包括柜体1,安装在柜前门上的控制面板2,安装在柜体后内壁上的PLC控制器3,安放在柜体内的反应装置4。其中,反应装置4底部分别连接有排水管5、排水电磁阀6、曝气管7、曝气头8、曝气电磁阀9,上部依次连接有进水管10、进水电磁阀11、进水泵12,加药管13、加药泵14。曝气管7一端与曝气头8相连,另一端连有电磁阀9及曝气泵15。反应装置4中,安装有氨氮测量仪16、溶解氧测量仪17及液位传感器18。所有的电磁阀、进水泵7、在线氨氮测量仪16、溶解氧测量仪17和液位传感器18与PLC控制器3相连接,PLC控制器3与控制面板2相连接。在线氨氮测量仪16、溶解氧测量仪18与自动清洗装置19相连。其中,曝气泵优选为变频泵。 An intelligent analysis system for sludge nitrification activity, the analysis system includes a cabinet 1, a control panel 2 installed on the front door of the cabinet, a PLC controller 3 installed on the rear inner wall of the cabinet, and a reaction device 4 placed in the cabinet. Among them, the bottom of the reaction device 4 is respectively connected with the drain pipe 5, the drain solenoid valve 6, the aeration pipe 7, the aeration head 8, and the aeration solenoid valve 9, and the upper part is connected with the water inlet pipe 10, the water inlet solenoid valve 11, and the water inlet pump in turn. 12, dosing tube 13, dosing pump 14. One end of the aeration pipe 7 is connected with the aeration head 8, and the other end is connected with a solenoid valve 9 and an aeration pump 15. In the reaction device 4, an ammonia nitrogen measuring instrument 16, a dissolved oxygen measuring instrument 17 and a liquid level sensor 18 are installed. All solenoid valves, water inlet pump 7 , online ammonia nitrogen measuring instrument 16 , dissolved oxygen measuring instrument 17 and liquid level sensor 18 are connected with PLC controller 3 , and PLC controller 3 is connected with control panel 2 . The online ammonia nitrogen measuring instrument 16 and the dissolved oxygen measuring instrument 18 are connected with the automatic cleaning device 19 . Among them, the aeration pump is preferably a variable frequency pump.

采用本实用新型所述的一种污泥硝化活性智能分析系统,根据测定的污泥硝化活性,可以对好氧池中的曝气量进行调节,如果污泥硝化活性高,好氧池中的曝气量可以适当降低,污泥硝化活性差,可以适当提高曝气量,有助于污泥硝化活性的恢复,并且本实用新型采用污泥硝化活性智能分析系统与在线氨氮仪、在线溶解氧仪等在线仪表配合使用,可以更好的实现对曝气量的优化控制,更加精确的根据氨氮硝化需求供给气量,达到降低曝气能耗,稳定出水水质的目的。该系统的使用可以使污水处理厂的日常运行中对参数的调整更加科学,有据可依,帮助技术人员分析和预测生物池处理能力变化,确保出水水质安全达标。 Adopt a kind of sludge nitrification activity intelligent analysis system described in the utility model, according to the measured sludge nitrification activity, can adjust the aeration rate in the aerobic pool, if the sludge nitrification activity is high, the aeration rate in the aerobic pool The amount of aeration can be appropriately reduced, and the nitrification activity of the sludge is poor. The aeration amount can be increased appropriately, which is helpful for the recovery of the nitrification activity of the sludge, and the utility model adopts an intelligent analysis system for the nitrification activity of the sludge, an online ammonia nitrogen meter, an online dissolved oxygen With the use of on-line instruments such as a meter, it can better realize the optimal control of the aeration volume, and more accurately supply the air volume according to the demand for ammonia nitrogen nitrification, so as to reduce the energy consumption of aeration and stabilize the water quality of the effluent. The use of this system can make the adjustment of parameters in the daily operation of sewage treatment plants more scientific and evidence-based, and help technicians analyze and predict changes in the treatment capacity of biological pools to ensure that the effluent water quality is safe and up to standard.

在不脱离本实用新型的原理和宗旨的情况下可以对这些实施例进行多种变化、修改、替换和变型,本实用新型的范围由权利要求及其等同物限定。 Various changes, modifications, replacements and modifications can be made to these embodiments without departing from the principle and purpose of the utility model, and the scope of the utility model is defined by the claims and their equivalents.

Claims (2)

1.一种污泥硝化活性智能分析系统,其特征在于,该分析系统包括柜体(1),安装在柜前门上的控制面板(2),安装在柜体后内壁上的PLC控制器(3),安放在柜体内的反应装置(4),其中,反应装置(4)底部分别连接有排水管(5)、排水电磁阀(6)、曝气管(7)、曝气头(8)、曝气电磁阀(9),上部依次连接有进水管(10)、进水电磁阀(11)、进水泵(12),加药管(13)、加药泵(14),曝气管(7)一端与曝气头(8)相连,另一端连有电磁阀(9)及曝气泵(15);反应装置(4)中,安装有氨氮测量仪(16)、溶解氧测量仪(17)及液位传感器(18),所有的电磁阀、进水泵(7)、在线氨氮测量仪(16)、溶解氧测量仪(17)和液位传感器(18)与PLC控制器(3)相连接,PLC控制器(3)与控制面板(2)相连接,在线氨氮测量仪(16)、溶解氧测量仪(18)与自动清洗装置(19)相连。1. a sludge nitrification activity intelligent analysis system, is characterized in that, this analysis system comprises cabinet body (1), is installed on the control panel (2) on the cabinet front door, is installed on the PLC controller ( 3), the reaction device (4) placed in the cabinet, wherein the bottom of the reaction device (4) is respectively connected with a drain pipe (5), a drain solenoid valve (6), an aeration pipe (7), an aeration head (8 ), the aeration solenoid valve (9), the upper part is connected with the water inlet pipe (10), the water inlet solenoid valve (11), the water inlet pump (12), the dosing pipe (13), the dosing pump (14), and the aeration One end of the pipe (7) is connected to the aeration head (8), and the other end is connected to a solenoid valve (9) and an aeration pump (15); in the reaction device (4), an ammonia nitrogen measuring instrument (16), a dissolved oxygen measuring instrument (16), and a dissolved oxygen measuring instrument (16) are installed. Instrument (17) and liquid level sensor (18), all solenoid valves, water inlet pump (7), online ammonia nitrogen measuring instrument (16), dissolved oxygen measuring instrument (17), liquid level sensor (18) and PLC controller ( 3) are connected, the PLC controller (3) is connected with the control panel (2), and the online ammonia nitrogen measuring instrument (16), dissolved oxygen measuring instrument (18) is connected with the automatic cleaning device (19). 2.根据权利要求1所述的智能分析系统,其特征在于,曝气泵(15)为变频泵。2. The intelligent analysis system according to claim 1, characterized in that the aeration pump (15) is a variable frequency pump.
CN201420638557.3U 2014-10-31 2014-10-31 A kind of mud nitrification activity intelligent analysis system Expired - Lifetime CN204359766U (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104407100A (en) * 2014-10-31 2015-03-11 北京城市排水集团有限责任公司 Intelligent analysis system of sludge nitrification activity, and analysis method thereof
CN105548296A (en) * 2015-12-07 2016-05-04 清华大学 Activated sludge ammonia utilizing rate on-line detection device and detection method
CN107505219A (en) * 2017-10-16 2017-12-22 南京大学 A kind of device and method of quick measure nitrification microbial inoculum performance
CN116559393A (en) * 2022-09-30 2023-08-08 五邑大学 A method for detecting ammonia nitrogen content by nitrification biological reaction

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104407100A (en) * 2014-10-31 2015-03-11 北京城市排水集团有限责任公司 Intelligent analysis system of sludge nitrification activity, and analysis method thereof
CN105548296A (en) * 2015-12-07 2016-05-04 清华大学 Activated sludge ammonia utilizing rate on-line detection device and detection method
CN105548296B (en) * 2015-12-07 2018-08-28 清华大学 A kind of activated sludge ammonia nitrogen utilizes rate on-line measuring device and detection method
CN107505219A (en) * 2017-10-16 2017-12-22 南京大学 A kind of device and method of quick measure nitrification microbial inoculum performance
CN107505219B (en) * 2017-10-16 2024-11-12 南京大学 A device and method for quickly determining the performance of nitrifying bacteria agent
CN116559393A (en) * 2022-09-30 2023-08-08 五邑大学 A method for detecting ammonia nitrogen content by nitrification biological reaction
CN116559393B (en) * 2022-09-30 2024-02-09 五邑大学 Method for detecting ammonia nitrogen content by utilizing nitrifying biological reaction

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