CN204073781U - A kind of modularization organic waste gas purifying treatment system - Google Patents
A kind of modularization organic waste gas purifying treatment system Download PDFInfo
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- CN204073781U CN204073781U CN201420570100.3U CN201420570100U CN204073781U CN 204073781 U CN204073781 U CN 204073781U CN 201420570100 U CN201420570100 U CN 201420570100U CN 204073781 U CN204073781 U CN 204073781U
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Abstract
The utility model relates to a kind of modularization organic waste gas purifying treatment system, comprises two subsystems, and a road is adsorption treatment subsystem; Another road is desorption processing subsystem, wherein adsorption treatment subsystem comprises air-washer, filter, adsorbent bed module and absorption blower fan, filter is connected in the outlet of air-washer, the absorption import of multiple adsorbent bed module is connected side by side in the outlet of filter, at absorption outlet connection absorption blower fan of multiple adsorbent bed module, the other end of this absorption blower fan connects high altitude discharge chimney, described desorption processing subsystem comprises adsorbent bed module, catalytic combustion bed and desorption blower fan, forms a closed de-adsorption cycle loop.Native system, by gas washing, filtration, absorption and catalytic combustion integrated disposal processing, improves the purification efficiency of organic exhaust gas, extends the service life of adsorbent, saved the energy, improves the economy that equipment runs.
Description
Technical field
The utility model belongs to field of Environment Protection, relates to the purified treatment of organic exhaust gas, especially a kind of modularization organic waste gas purifying treatment system.
Background technology
A large amount of organic gas pollutant is produced sometimes in the industry operation process such as application, printing, petroleum and chemical industry industry, working environment and atmospheric environment are made a big impact and destroys, need to carry out administering and processing, to reduce the harm of these pollutants to atmospheric environment and field personnel's personal safety.Organic pollution in air is mainly VOC (VOC), generally refers to and holds volatile organic compound at ambient temperature, as hydro carbons, halogenated hydrocarbons, nitrogen hydrocarbon, oxygen-containing hydrocarbon, sulphur hydrocarbon, aliphatic hydrocarbon, aromatic hydrocarbon etc.Most of VOC class material has neurotoxicity, kidney and hepatotoxicity, some even has carcinogenesis, and blood circulation system and cardiovascular system can be damaged, gastrointestinal disturbance, immune system, internal system and the disease of hematopoietic system etc. that cause because sucking excessive VOC gas in addition also happen occasionally.Long Term Contact and these gases of excessive suction, also can cause metabolic deficiency and genetic disease.Research has proved the nervous system that aromatics and fats hydrocarbon energy loss victimize, chlorohydrocarbons etc. can cause human liver renal damage and slow poisoning, and ketone and based organic solvent pollutant can cause human respiratory tract's inflammation, bronchial astehma and allergic dermatitis, eczema, conjunctivitis etc.
The VOC class material atmosphere pollution pollutant kind of broad sense is various, wide material sources, control and difficulty of governance larger.In industrial environment, VOC material also has a great difference because of solvent kind, volatile matter source difference, is also not quite similar to the harm that operator and atmospheric environment may cause.As furniture, install additional, lacquer spraying waste gas that the workshop section of spraying paint of application etc. produces, wherein pollutant is a large amount of benzene, toluene equal solvent other organic pollution materials that painting process produces, and has stronger toxicity, easily causes very serious injury to human body.Implement spray paint spraying process in, these organic substances are sprayed away as solvent, and a part is adsorbed in the surface for the treatment of coat, play effect of spraying paint and are separately partially suspended among air, and may inhale by operating worker people, enter its respiratory system of people.The benzene that toxicity is very strong, toluene etc. can cause serious injury the respiratory tract of operator, once this type of noxious material reaches finite concentration, more can cause major injury to the central nervous system such as human brain, spinal cord and hemopoietic system, very easily cause workman poisoning, and cause the disease that a series of refractories such as alpastic anemia heal, cause great damage to poisoner.Even if when the organic substance concentrations such as benzene are lower, harmful organic substance gas in environment also can cause certain injury to long-term work operating personnel in the environment, if harmful gas concentration is not high in operator's working environment, workers with long time works in such circumstances, though do not have obvious toxic reaction, but after the long period, occur feeling sick still unavoidably, dizzy, vomiting, the obnubilation even symptom such as neurasthenia, this be all due to nervous system impaired caused by, and the cause of poisoning is all the long-term induced gas breathed containing organic harmful toxic matter.In addition, also injury in various degree can be caused to respiratory tract and retina etc. containing organic lacquer spraying waste gas such as a large amount of benzene, toluene.Therefore very important, very urgent to the improvement of this type of waste gas.
One of mankind's environmental problem urgently to be resolved hurrily has now been become to the improvement of organic gas pollutant (VOCs) in air.At present, substantially can be divided into the purification techniques of VOCs material in air and reclaim and eliminate two large classes, absorption method mainly contains absorption method, condensation method, absorption process and membrane separation process etc.; Null method has the technology such as thermal oxide burning, catalytic combustion, biodegradation, photoelectric catalysis degrading.The method commonly used at present the purified treatment of lacquer spraying waste gas is that Production by Catalytic Combustion Process, adsorption treatment method, photochemical catalytic oxidation, plasma electric are from oxidation etc.Direct burning wherein refers to and is directly heated to uniform temperature to the waste gas containing pernicious gas, under the high temperature conditions, in waste gas, organic gas can react with oxygen in high temperature air, through after a period of time, in waste gas, the organic matter such as benzene, toluene can be burned complete, thus reach the object removing organic exhaust gas.The temperature that direct combustion method needs is higher, keeps higher temperature that the processing cost of waste gas can be made to increase, and there is secondary pollution in various degree sometimes.Production by Catalytic Combustion Process requires lower compared to its ignition temperature of direct combustion method, makes organic gas burning in waste gas at a lower temperature thus realize purification under the effect of catalyst.Catalytic combustion method is at present comparatively conventional lacquer spraying waste gas processing method, but also have that organic exhaust gas concentration is low, burning costly, catalyst easy in inactivation, the problem such as passivation.Treatment by Photocatalysis Oxidation is the most frequently used is at present Titanium Dioxide processing method, this technology utilizes titanium dioxide can produce a large amount of oxygen radical feature under action of ultraviolet radiation, by organic matter in the oxidation process waste gas of oxygen radical, but the oxidation of this technology is sometimes not thorough, there is the problem of secondary pollution.
Absorption method removes organic effective ways in lacquer spraying waste gas, and under the suction-operated of high-efficiency adsorbent, in waste gas, organic gas can constantly to adsorbent transfer, concentration can decline fast, reaches the object effectively removed.Adsorbent declines in efficiency or adsorbs saturated rear needs regeneration process and just can use further.Under the effects such as high temperature, adsorbent organic gas can discharge again, thus reaches the object of adsorbent reactivation.Therefore adsorption treatment is not only a kind of processing method of organic exhaust gas, is also the effective ways that a kind of waste gas concentrates.By absorption and the regeneration desorption of adsorbent, the concentration of organic exhaust gas can to a certain degree be greatly improved, again through burning process etc., not only increase treatment effeciency, due to the raising of organic exhaust gas concentration, release energy in combustion process and also can greatly improve, thus greatly reduce the energy ezpenditure in other combustion processes.
Although the processing method of above-mentioned organic exhaust gas reaches the object of cleaning organic waste gas all to a certain extent, purification efficiency is not high, and usually can only process the waste gas of a certain particular flow rate, and disposal ability is limited, versatility is bad.
Utility model content
The purpose of this utility model is to overcome the deficiencies in the prior art part, provide a kind of process exhaust gas flow wide ranges, good purification, purification efficiency high, equipment installs simple modularization organic waste gas purifying treatment system.
The technical scheme that the utility model technical solution problem adopts is:
A kind of modularization organic waste gas purifying treatment system, comprise two subsystems, a road is adsorption treatment subsystem, another road is desorption processing subsystem, wherein adsorption treatment subsystem comprises air-washer, filter, adsorbent bed module and absorption blower fan, filter is connected in the outlet of air-washer, the absorption import of multiple adsorbent bed module is connected side by side in the outlet of filter, at absorption outlet connection absorption blower fan of multiple adsorbent bed module, the other end of this absorption blower fan connects high altitude discharge chimney, described desorption processing subsystem comprises adsorbent bed module, catalytic combustion bed and desorption blower fan, a desorption blower fan is connected in the import of catalytic combustion bed, the desorption of each adsorbent bed module is connected respectively at the other end of desorption blower fan, the desorption import of this adsorbent bed module is connected with the outlet of catalytic combustion bed, form a closed de-adsorption cycle loop thus.
And this system adopts Electronic Control, by PLC control cabinet centralized Control.
And the absorption import of described adsorbent bed module, absorption outlet, desorption import, desorption are all provided with magnetic valve.
And be provided with absorption filtering layer in each adsorbent bed module, this absorption filtering layer is that NACF is pressed into certain specification, shape, forms according to certain principle combinations.
And, described air-washer comprises tank body, sparge pipe and water-distributing device, a sparge pipe is connected at the top of tank body, a water-distributing device is connected at the other end of sparge pipe, this water-distributing device makes current form water curtain, shower water enters circulating water chennel, recycles after collecting, and is provided with desilting, desilting works bottom circulating water chennel.
And, multilayer silk flosssilk wadding filter is installed in described filter.
And the temperature of described catalytic combustion bed controls at 250-400 DEG C.
And be provided with in described catalytic combustion bed and start/mend warm heater, heating adopts Electric heating, and heater adopts electric heating heating rod or resistance wire.
And, in catalytic combustion bed, adopt various metals composite catalyst.
And, described composite catalyst be cerium, palladium, platinum, ruthenium, rhodium and copper, manganese etc. two or more with the use of, adopt Al2O3 fixedly change into honeycomb type or corrugated plate type, combination assemble.
Advantage of the present utility model and good effect are:
1, native system is by gas washing, filtration, absorption and catalytic combustion integrated disposal processing, improves the purification efficiency of organic exhaust gas, extends the service life of adsorbent, saved the energy, improves the economy that equipment runs.
2, the adsorption process of native system adopts modular to connect, the adsorbent bed module can closed according to gas flow size and pollutant levels height unlatching different groups of arrays carries out adsorption cleaning, each adsorbent bed module all can be adsorbed separately and be regenerated process, after partial adsorbates bed module is saturated, adsorption operations can be stopped, carry out regeneration process, part of module regeneration process does not affect the operation of other adsorbent bed module normal sorption.This model calling mode substantially increases the utilization rate of equipment, and simple installation, and it is controlled that exhaust-gas treatment weight range is wide, disposal ability is adjustable.
3, native system needs to carry out gas washing process before adsorption treatment, gas washing process can remove the solid pollutant in waste gas, as the solid matter such as dust, sand, reduce coating cloud in waste gas, solid shape coating agent which has to be dissolved in alcohol before use, paint group etc. simultaneously, these materials are avoided to stick to subsequent adsorbtion process sorbing material surface, blocking sorption channel, causes the problems such as the decline of adsorbent efficiency and surface passivation.
4, native system connects filter after air-washer, is provided with multilayer silk flosssilk wadding filter in filter, and this silk floss filter can remove the water smoke, foam etc. that produce in spray process, the performance of the adsorbent decline problem avoiding these materials to cause.
5, native system adopts various metals composite catalyst in catalytic combustion bed, first-selected cerium, palladium, platinum, ruthenium, rhodium and copper, manganese etc. two or more with the use of, adopt Al
2o
3fixedly change into honeycomb type or corrugated plate type, combination assembling, make the oxidation of organic exhaust gas more abundant, improve catalytic efficiency, catalyticing combustion process purification efficiency can reach more than 97%, improves the clean-up effect of whole system.
6, CO is generated after native system catalytic combustion
2and H
2o also discharges amount of heat, this heat is used for adding by heat exchanger in a catalytic combustion bed part high-concentration waste gas that thermal desorption goes out again, the air that a part of heating clamber is external is in addition made active carbon desorption gas and is used, and generally reaching desorption ~ catalytic combustion self-balancing process must start electric heater 1 ~ 2 hours.Can close electric heater unit after reaching thermal balance, such regeneration treatment system does fuel by the organic solvent in waste gas, need not external energy basis make regenerative process reach self-balancing circulation, greatly reduces energy consumption, and the generation of non-secondary pollution.
7, native system adopts Electronic Control, and by PLC control cabinet centralized Control, gas washing, filtration, absorption, regeneration, catalytic combustion etc. all adopt programme-control, ensure that the stability of system cloud gray model, reliability and economy.
Accompanying drawing explanation
Fig. 1 is the anatomical connectivity schematic diagram of native system.
Detailed description of the invention
Below in conjunction with accompanying drawing, also by specific embodiment, the utility model is described in further detail, and following examples are descriptive, are not determinate, can not limit protection domain of the present utility model with this.
A kind of modularization organic waste gas purifying treatment system, comprise two subsystems, a road is adsorption treatment subsystem; Another road is desorption processing subsystem, wherein adsorption treatment subsystem comprises air-washer 1, filter 2, adsorbent bed module 3 and absorption blower fan 6, filter is connected in the outlet of air-washer, the absorption import of multiple adsorbent bed module is connected side by side in the outlet of filter, at absorption outlet connection absorption blower fan of multiple adsorbent bed module, the other end of this absorption blower fan connects high altitude discharge chimney 5.Described desorption processing subsystem comprises adsorbent bed module, catalytic combustion bed 12 and desorption blower fan 11, a desorption blower fan is connected in the import of catalytic combustion bed, the desorption of each adsorbent bed module is connected respectively at the other end of desorption blower fan, the desorption import of this adsorbent bed module is connected with the outlet of catalytic combustion bed, forms a closed de-adsorption cycle loop thus.
In Fig. 1, solid line represents adsorption treatment flow process, and broken string represents desorption handling process.
Native system adopts Electronic Control, and by PLC control cabinet 7 centralized Control, gas washing, filtration, absorption, regeneration, catalytic combustion etc. all adopt programme-control, ensure that the stability of plant running, reliability and economy.
The absorption import of described adsorbent bed module, absorption outlet, desorption import, desorption are all provided with magnetic valve 4.In each adsorbent bed module, be provided with absorption filtering layer, this absorption filtering layer is that NACF is pressed into certain specification, shape, forms according to certain principle combinations.Gas by time to adsorb and organic gas exchanges and processes by completing with NACF surface contact, remove the VOC such as benzene, dimethylbenzene in waste gas.
After the absorption filtering layer in adsorbent bed reaches capacity, needing hot air treatment to regenerate, in order to introduce outside air, de-adsorption cycle loop connecting an outside air intake valve 10.Outside air is drawn in catalytic combustion bed by desorption blower fan, enters into each adsorbent bed module in catalytic combustion bed after being heated.
Described air-washer comprises tank body, sparge pipe and water-distributing device, connects a sparge pipe at the top of tank body, connects a water-distributing device at the other end of sparge pipe, and this water-distributing device makes current form water curtain, increases the contact area with waste gas.The solid pollutant in waste gas is removed in the effect of this air-washer, as the solid matter such as dust, sand, reduce coating cloud in waste gas, solid shape coating agent which has to be dissolved in alcohol before use, paint group etc. simultaneously, these materials are avoided to stick to subsequent adsorbtion process sorbing material surface, blocking sorption channel, causes the problems such as the decline of adsorbent efficiency and surface passivation.Shower water enters circulating water chennel, recycles after collecting, and is provided with desilting, desilting works, irregularly manually can carries out sand discharge process bottom circulating water chennel.
In order to remove the water smoke, foam etc. that produce in spray process, the performance of the adsorbent decline problem avoiding these materials to cause, is connected with a filter after air-washer, is provided with multilayer silk flosssilk wadding filter in filter, after Multi-channel filtering, water smoke, foam can be removed completely.
The temperature of described catalytic combustion bed controls at 250-400 DEG C, inside establishes and starts/mend warm heater, and heating adopts Electric heating, and heater adopts electric heating heating rod or resistance wire, first-selected Resistant heating.Catalyst adopts various metals composite catalyst, first-selected cerium, palladium, platinum, ruthenium, rhodium and copper, manganese etc. two or more with the use of, adopt Al2O3 fixedly to change into honeycomb type or corrugated plate type, combination is assembled.
After catalytic combustion, volatile organic matter is oxidized to CO2 and water, and gas after process needs cooling just can enter in air, so external one mend low temperature valve 9 on de-adsorption cycle loop, this benefit low temperature valve is connected with low-temperature receiver, is connected an air bleeding valve 8 between de-adsorption cycle loop with high altitude discharge chimney.
The operation principle of native system is:
Waste gas is under the suction of absorption blower fan drives, first through air-washer, remove the solid pollutant such as dust, sand in waste gas, then filter is entered, the water smoke produced after filtering out gas washing, foam, enter multiple adsorbent bed module according to treating capacity again, the NACF in adsorbent bed module can adsorb the escaping gas such as benzene, dimethylbenzene in waste gas, and purifying air after absorption is discharged to outdoor by high altitude discharge chimney.Wherein, activated carbon fiber adsorbing substance declines at removal ability or adsorbs saturated rear needs and carries out regeneration process, regeneration treating method adopts thermal process regeneration, and regeneration process desorption temperature controls at 200-280 DEG C, and regeneration thermal source is from the catalytic combustion bed of the organic exhaust gas discharged in adsorbent reactivation process.The organic exhaust gas produced in adsorbent reactivation process carries out final purification process by catalytic combustion bed, and in catalyticing combustion process, at appropriate temperatures, volatile organic matter is oxidized to CO2 and water by catalyst.The heat energy that burning produces delivers to the adsorbent bed module needing regeneration process by desorption blower fan, carry out heating desorption regeneration, and the gas after process enters in air after cooling process.
Adsorption treatment workshop section is that many group adsorbent bed wired in parallel use, and each module all can be adsorbed separately and be regenerated process, and the adsorbent bed module can closed according to gas flow size and pollutant levels height unlatching different groups of arrays carries out adsorption cleaning.After partial adsorbates bed module is saturated, can stop adsorption operations, carry out regeneration process, part of module regeneration process does not affect the operation of other adsorbent bed module normal sorption.
The Characteristic Adsorption organic exhaust gas that the specific area of activated carbon fiber material is large, adsorption capacity is large is utilized to be the most effective industrial treatment means of one.Absorption can make organic waste-gas purification efficiency up to more than 90 ~ 95%, as the saturated rear available hot-air desorption and regeneration of active carbon adsorption material absorption makes sorbing material again come into operation, can by concentrated more than 10 ~ 20 times of organic exhaust gas concentration by controlling desorption process flow, the electric heater unit that desorption air-flow is established in catalytic bed is heated to about 300 DEG C, ignition under catalyst action, catalyticing combustion process purification efficiency can reach more than 97%, generate CO2 and H2O after burning and discharge amount of heat, this heat is used for adding by heat exchanger in a catalytic combustion bed part high-concentration waste gas that thermal desorption goes out again, the air that a part of heating clamber is external is in addition made active carbon desorption gas and is used, generally reach desorption ~ catalytic combustion self-balancing process and must start electric heater 1 ~ 2 hours.Can close electric heater unit after reaching thermal balance, such regeneration treatment system does fuel by the organic solvent in waste gas, need not external energy basis make regenerative process reach self-balancing circulation, greatly reduces energy consumption, and the generation of non-secondary pollution.A whole set of absorption and catalyticing combustion process are realized automatically controlling by PLC.
Embodiment 1:6000m
3/ h lacquer spraying waste gas cleaning treatment system
Pretreatment: air-washer adopts two groups of shower sprays, and filter adopts silk floss filter media, effective filtration area 1m
2.
Efficient adsorption process: efficient adsorption process adopts 6 adsorbent bed modules, the adsorption capacity of each adsorbent bed module is: 1m
3, effective adsorption cycle is 8h, and three open three for pattern, and three adsorbent bed modules of unlatching are opened one by one according to a definite sequence.
Catalytic combustion purified treatment: heating adopts Resistant heating, and resistive heater is four groups, maximum heating power 15KW, and temperature feedback inhibitory control can be adopted to regulate heating power, regulates and adopts transformation adjustment modes.Catalyst adopts cerium, palladium, platinum assembled highly-effective catalyst, and catalytic combustion temperature controls at 200-280 DEG C.
Embodiment 2:10000m
3/ h lacquer spraying waste gas cleaning treatment system
Pretreatment: air-washer adopts two groups of shower sprays, and filter adopts silk floss filter media, effective filtration area 2m
2.
Efficient adsorption process: efficient adsorption process adopts 6 adsorbent bed modules, each adsorbent bed module adsorption capacity is: 1m
3, effective adsorption cycle is 8h, and three open three for pattern, and three unit of unlatching are opened one by one according to a definite sequence.
Catalytic combustion purified treatment: heating adopts Resistant heating, and resistive heater is four groups, maximum heating power 42KW, and temperature feedback inhibitory control can be adopted to regulate heating power, regulates and adopts transformation adjustment modes.Catalyst adopts cerium, palladium, platinum assembled highly-effective catalyst, and catalytic combustion temperature controls at 200-280 DEG C.
Above-described is only preferred embodiment of the present utility model; it should be pointed out that for the person of ordinary skill of the art, under the prerequisite not departing from utility model design; can also make some distortion and improvement, these all belong to protection domain of the present utility model.
Claims (10)
1. a modularization organic waste gas purifying treatment system, comprises two subsystems, and a road is adsorption treatment subsystem, another road is desorption processing subsystem, it is characterized in that: wherein adsorption treatment subsystem comprises air-washer, filter, adsorbent bed module and absorption blower fan, filter is connected in the outlet of air-washer, the absorption import of multiple adsorbent bed module is connected side by side in the outlet of filter, at absorption outlet connection absorption blower fan of multiple adsorbent bed module, the other end of this absorption blower fan connects high altitude discharge chimney, described desorption processing subsystem comprises adsorbent bed module, catalytic combustion bed and desorption blower fan, a desorption blower fan is connected in the import of catalytic combustion bed, the desorption of each adsorbent bed module is connected respectively at the other end of desorption blower fan, the desorption import of this adsorbent bed module is connected with the outlet of catalytic combustion bed, form a closed de-adsorption cycle loop thus.
2. modularization organic waste gas purifying treatment system according to claim 1, is characterized in that: this system adopts Electronic Control, by PLC control cabinet centralized Control.
3. modularization organic waste gas purifying treatment system according to claim 1, is characterized in that: the absorption import of described adsorbent bed module, absorption outlet, desorption import, desorption are all provided with magnetic valve.
4. modularization organic waste gas purifying treatment system according to claim 1, is characterized in that: in each adsorbent bed module, be provided with absorption filtering layer, and this absorption filtering layer is that NACF is pressed into certain specification, shape, forms according to certain principle combinations.
5. modularization organic waste gas purifying treatment system according to claim 1, it is characterized in that: described air-washer comprises tank body, sparge pipe and water-distributing device, a sparge pipe is connected at the top of tank body, a water-distributing device is connected at the other end of sparge pipe, this water-distributing device makes current form water curtain, shower water enters circulating water chennel, recycles after collecting, and is provided with desilting, desilting works bottom circulating water chennel.
6. modularization organic waste gas purifying treatment system according to claim 1, is characterized in that: be provided with multilayer silk flosssilk wadding filter in described filter.
7. modularization organic waste gas purifying treatment system according to claim 1, is characterized in that: the temperature of described catalytic combustion bed controls at 250-400 DEG C.
8. modularization organic waste gas purifying treatment system according to claim 1, is characterized in that: be provided with in described catalytic combustion bed and start/mend warm heater, and heating adopts Electric heating, and heater adopts electric heating heating rod or resistance wire.
9. modularization organic waste gas purifying treatment system according to claim 1, is characterized in that: in catalytic combustion bed, adopt various metals composite catalyst.
10. modularization organic waste gas purifying treatment system according to claim 9, it is characterized in that: described composite catalyst be cerium, palladium, platinum, ruthenium, rhodium and copper, manganese etc. two or more with the use of, Al2O3 is adopted fixedly to change into honeycomb type or corrugated plate type, combination assembling.
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