CN203944281U - Flue gas desulfur device - Google Patents
Flue gas desulfur device Download PDFInfo
- Publication number
- CN203944281U CN203944281U CN201420375305.6U CN201420375305U CN203944281U CN 203944281 U CN203944281 U CN 203944281U CN 201420375305 U CN201420375305 U CN 201420375305U CN 203944281 U CN203944281 U CN 203944281U
- Authority
- CN
- China
- Prior art keywords
- gas
- elemental sulfur
- ball
- phase
- flue gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 239000003546 flue gas Substances 0.000 title claims abstract description 18
- 239000007789 gas Substances 0.000 claims abstract description 31
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 25
- 238000010574 gas phase reaction Methods 0.000 claims abstract description 14
- 239000007788 liquid Substances 0.000 claims abstract description 14
- 230000002745 absorbent Effects 0.000 claims abstract description 13
- 239000002250 absorbent Substances 0.000 claims abstract description 13
- 238000006243 chemical reaction Methods 0.000 claims abstract description 7
- 239000008262 pumice Substances 0.000 claims abstract description 7
- 238000010521 absorption reaction Methods 0.000 claims description 11
- 239000012071 phase Substances 0.000 abstract description 13
- 238000006477 desulfuration reaction Methods 0.000 abstract description 12
- 230000023556 desulfurization Effects 0.000 abstract description 9
- 238000000034 method Methods 0.000 abstract description 5
- 238000005516 engineering process Methods 0.000 abstract description 4
- 239000007791 liquid phase Substances 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 4
- 239000002912 waste gas Substances 0.000 abstract description 4
- 239000002699 waste material Substances 0.000 abstract description 4
- 239000007787 solid Substances 0.000 abstract description 2
- 229910052717 sulfur Inorganic materials 0.000 abstract description 2
- 239000011593 sulfur Substances 0.000 abstract description 2
- 238000004088 simulation Methods 0.000 description 6
- 239000000047 product Substances 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000004575 stone Substances 0.000 description 3
- 241000628997 Flos Species 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000005422 blasting Methods 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 235000001508 sulfur Nutrition 0.000 description 2
- PQUCIEFHOVEZAU-UHFFFAOYSA-N Diammonium sulfite Chemical compound [NH4+].[NH4+].[O-]S([O-])=O PQUCIEFHOVEZAU-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical class CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- GBAOBIBJACZTNA-UHFFFAOYSA-L calcium sulfite Chemical compound [Ca+2].[O-]S([O-])=O GBAOBIBJACZTNA-UHFFFAOYSA-L 0.000 description 1
- 235000010261 calcium sulphite Nutrition 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000505 pernicious effect Effects 0.000 description 1
- 238000005504 petroleum refining Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
Landscapes
- Treating Waste Gases (AREA)
Abstract
The utility model discloses a kind of flue gas desulfur device, tie up on traditional tubulent contact tower basis and improve and design and produce, its main innovation part is: change the liquid collecting room in traditional structure into elemental sulfur expansion chamber, change air chamber into gas-phase reaction chamber, the air inlet of air chamber changes two into by one, adopts natural pumice ball as rapid ball.Use the utility model to carry out flue gas desulfurization, can adopt H
2the gas phase absorbents such as S substitute solid, liquid phase absorbent, with SO
2in tower body, realize gas-gas phase and gas and liquid phase two-stage reaction, desulfuration efficiency is high; Natural pumice ball substitutes common rapid ball, acidproof, alkaline-resisting, heat-resisting, anti-wear performance is superior, and material is cheap and easy to get, has significantly reduced the cost of equipment operation sulfur removal technology; Desulfurization product is elemental sulfur, and selling market is extensive.For some, discharge SO simultaneously
2and H
2the enterprise of the waste gas such as S, application the utility model also can be realized the treatment of wastes with processes of wastes against one another, a tower is controlled two useless objects.
Description
Technical field
The utility model belongs to off-gas recovery treating apparatus, relates in particular to a kind of flue gas desulfur device.
Background technology
SO 2 from fume is the main pernicious gas that causes atmosphere pollution, its primary pollution source is industrial coal, non-ferrous metal metallurgy and petroleum refining industry, if it is directly entered to atmosphere, by the serious harm mankind's living environment, therefore before discharge, must be administered.Tubulent contact tower, as a kind of novel flue gas desulfurization device, is widely applied in industrial waste gas purifying field.Tradition tubulent contact tower is mainly comprised of six parts, is respectively from bottom to top
<1> liquid collecting room: be positioned at tower body bottom (or joining) outward, for collecting SO
2absorption liquid.
<2> air chamber: be positioned on liquid collecting room, its effect is to realize gas uniform with stable.
<3> supports column plate: be positioned at tower body middle part, have Process on plate, for uniform distribution air-flow and the rapid ball of support.
The rapid ball of <4> and rapid ball layer: be positioned at and support on column plate; Rapid ball is the filler in tower body, is the hollow rapid ball with certain particle size, density, diameter, and its material generally adopts plastics, polyesters, and minority enterprise makes rapid ball with foamed ceramic float stone (being artificial float stone); The fluidized-bed consisting of rapid ball and nozzles spray absorption liquid is out rapid ball layer.
<5> absorption liquid nozzle: be used for spraying, supply with absorption liquid.
<6> demister: be positioned at tower body top, the water smoke of carrying secretly for removing flue gas.
Compare with similar flue gas desulfurization device, tubulent contact tower has the features such as the unimpeded nothing of gas passage is stopped up, tower resistance is little, power absorption process fast, absorption liquid saturation degree is high, strong adaptability.However, it still exists many deficiencies: <1> to be not suitable for adopting gaseous substance to make absorbent; <2> plastics, the rapid ball acid and alkali resistance of polyesters, heat, mill poor performance, the rapid ball of foamed ceramic float stone is expensive, and equipment operating cost is high; <3> desulfurization product (gypsum, calcium sulfite, ammonium sulfite, ammonium sulfate, sodium sulfite, sodium sulphate, ammoniacal liquor etc.) lacks selling market, and even serious accumulation forms secondary pollution.
Utility model content
The technical problems to be solved in the utility model is to provide a kind of economical and practical, combination property is superior, desulfuration efficiency is high flue gas desulfur device.
For solving the problems of the technologies described above, the utility model is by the following technical solutions: flue gas desulfur device, comprise tubulent contact tower body, tubulent contact tower body bottom is the gentle phase reaction chamber of elemental sulfur expansion chamber, elemental sulfur expansion chamber is positioned under gas-phase reaction chamber, and exhaust gas entrance and gas phase absorbent entrance are established in gas-phase reaction chamber; Tubulent contact tower body middle part is rapid ball layer, and rapid ball adopts natural pumice ball.
Elemental sulfur expansion chamber is connected by pipeline through filter, circulating pump with absorption liquid nozzle.
The problem existing for traditional tubulent contact tower, inventor improves on its basis and has designed and produced a kind of flue gas desulfur device, relative existing equipment, the main innovation part of this device is:
<1> changes the liquid collecting room in traditional tubulent contact tower structure into elemental sulfur expansion chamber, mainly as sedimentation elemental sulfur;
<2> changes the air chamber in traditional tubulent contact tower structure into gas-phase reaction chamber, mainly as SO
2carry out the space of oxidation reaction with gas phase absorbents such as hydrogen sulfide, natural gas, ethanes; The air inlet of air chamber changes two into by one, and exhaust gas entrance is used for blasting sulphur-containing exhaust gas, and gas phase absorbent entrance is used for blasting gas phase absorbent;
<3> adopts natural pumice ball as rapid ball.
Use the utility model to carry out flue gas desulfurization, can adopt H
2the gas phase absorbents such as S substitute solid, liquid phase absorbent, with SO
2in tower body, realize gas-gas phase and gas and liquid phase two-stage reaction, desulfuration efficiency is high; Natural pumice ball substitutes common rapid ball, acidproof, alkaline-resisting, heat-resisting, anti-wear performance is superior, and material is cheap and easy to get, has significantly reduced the cost of equipment operation sulfur removal technology; Desulfurization product is elemental sulfur, and selling market is extensive.For some, discharge SO simultaneously
2and H
2the enterprise of the waste gas such as S (as oil plant), application the utility model also can be realized the treatment of wastes with processes of wastes against one another, a tower is controlled two useless objects.
Accompanying drawing explanation
Fig. 1 is the structural representation of the utility model flue gas desulfur device, in figure: 1 pure qi (oxygen) floss hole, 2 demisters, 3 tubulent contact tower bodies, 4 circulating pumps, 5 filters, 6 rapid ball layers, 7 exhaust gas entrances, 8 gas-phase reaction chambers, 9 elemental sulfur expansion chambers, 10 gas phase absorbent entrances.
Fig. 2 is the simulation test device structural representation of the utility model flue gas desulfur device, in figure: 1SO
2generating means, 2H
2s generating means, 3 simulation gas-phase reaction chambers, the rapid ball layer of 4 simulation.
The specific embodiment
As shown in Figure 1, the utility model flue gas desulfur device, comprises tubulent contact tower body 3, and tubulent contact tower body bottom is the gentle phase reaction chamber 8 of elemental sulfur expansion chamber 9, elemental sulfur expansion chamber is positioned under gas-phase reaction chamber, and exhaust gas entrance 7 and gas phase absorbent entrance 10 are established in gas-phase reaction chamber; Tubulent contact tower body middle part is rapid ball layer 6, and rapid ball adopts natural pumice ball; Tubulent contact tower body top is provided with absorption liquid nozzle and demister 2; Tubulent contact tower body top is pure qi (oxygen) floss hole 1.Wherein, elemental sulfur expansion chamber is connected by pipeline through filter 5, circulating pump 4 with absorption liquid nozzle.
Operation principle and process
<1> adopts blower fan by SO
2and H
2the waste gas such as S blast gas-phase reaction chamber from exhaust gas entrance and the gas phase absorbent entrance of tubulent contact tower body respectively, utilize SO
2weak oxide oxidation H
2s, the elemental sulfur of generation falls after rise in elemental sulfur expansion chamber;
<2> is due to the indoor gas pressure of gas-phase reaction, SO
2and H
2s mix waste gas moves upward, during through rapid ball layer, and SO
2, H
2s is dissolved in the water, and the turbulence rotation by rapid ball under certain gas speed and collision mutually, form fluidized-bed, makes SO in the aqueous solution
2with H
2the materials such as S fully contact and carry out chemical reaction, thereby complete flue gas desulfurization course, and the elemental sulfur of generation falls after rise to elemental sulfur expansion chamber with absorption liquid;
Purge gas after <3> desulfurization is stressed to affect and continues to move upward, and (heats) emptying after demister is deviate from water smoke;
Slip in <4> elemental sulfur expansion chamber is filtered, and filter cake is elemental sulfur product, and filtrate is sprayed in circulating pump is delivered to tower.
For at laboratory proofing the utility model, inventor has designed a set of simulation test device, as shown in Figure 2.
Simulated test step and result:
<1> utilizes SO
2generating means 1 produces SO
2gas (Na
2sO
3+ H
2sO
4(rare)-SO
2+ Na
2sO
4+ H
2o);
<2> utilizes H
2s generating means 2 produces H
2s gas (Na
2s+H
2sO4 (rare)-Na
2sO
4+ H
2s);
The SO that <3> produces
2and H
2s enters simulation gas-phase reaction chamber 3 simultaneously, mixes the promoting the circulation of qi-gas-phase reaction of going forward side by side;
<4> introduces the rapid ball layer 4 of simulation, SO by mist
2and H
2s is dissolved in the water, and by means of aqueous medium, carries out chemical reaction, generates elemental sulfur and is deposited on container bottom.
By test, 2min obtains 2.7 grams of dry product elemental sulfurs altogether.
Claims (2)
1. a flue gas desulfur device, comprises tubulent contact tower body, it is characterized in that: described tubulent contact tower body bottom is the gentle phase reaction chamber of elemental sulfur expansion chamber, and elemental sulfur expansion chamber is positioned under gas-phase reaction chamber, and exhaust gas entrance and gas phase absorbent entrance are established in gas-phase reaction chamber; Rapid ball in described tubulent contact tower body structure adopts natural pumice ball.
2. flue gas desulfur device according to claim 1, is characterized in that: described elemental sulfur expansion chamber is connected by pipeline through filter, circulating pump with absorption liquid nozzle.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201420375305.6U CN203944281U (en) | 2014-07-08 | 2014-07-08 | Flue gas desulfur device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201420375305.6U CN203944281U (en) | 2014-07-08 | 2014-07-08 | Flue gas desulfur device |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN203944281U true CN203944281U (en) | 2014-11-19 |
Family
ID=51886343
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201420375305.6U Expired - Fee Related CN203944281U (en) | 2014-07-08 | 2014-07-08 | Flue gas desulfur device |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN203944281U (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108273363A (en) * | 2018-04-10 | 2018-07-13 | 苏州舜沃环保科技有限公司 | A kind of attached waste gas containing fluoride processing unit of double suction |
| CN109529580A (en) * | 2017-09-21 | 2019-03-29 | 中国石油化工股份有限公司 | The process unit and process of sulfur dioxide and hydrogen sulfide liquid phase reactor desulfurization |
| CN113144828A (en) * | 2021-05-14 | 2021-07-23 | 中冶焦耐(大连)工程技术有限公司 | Tail gas cleaning tower |
| CN113209785A (en) * | 2021-04-02 | 2021-08-06 | 宁波泽瑞环保科技有限公司 | High-efficient sulphur is retrieved and tail gas processing apparatus |
-
2014
- 2014-07-08 CN CN201420375305.6U patent/CN203944281U/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109529580A (en) * | 2017-09-21 | 2019-03-29 | 中国石油化工股份有限公司 | The process unit and process of sulfur dioxide and hydrogen sulfide liquid phase reactor desulfurization |
| CN109529580B (en) * | 2017-09-21 | 2021-07-09 | 中国石油化工股份有限公司 | Process device and process method for desulfurizing sulfur dioxide and hydrogen sulfide through liquid-phase reaction |
| CN108273363A (en) * | 2018-04-10 | 2018-07-13 | 苏州舜沃环保科技有限公司 | A kind of attached waste gas containing fluoride processing unit of double suction |
| CN113209785A (en) * | 2021-04-02 | 2021-08-06 | 宁波泽瑞环保科技有限公司 | High-efficient sulphur is retrieved and tail gas processing apparatus |
| CN113144828A (en) * | 2021-05-14 | 2021-07-23 | 中冶焦耐(大连)工程技术有限公司 | Tail gas cleaning tower |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103239985B (en) | Efficient fuel coal flue gas desulfurizing and hydrargyrum-removing method and device thereof | |
| CN201454396U (en) | Spray desulfurization tower integrating absorption, oxidation, crystallization, demisting and cooling | |
| CN108325317A (en) | A kind of method of operation of Pollutant in Coal Burning Boiler minimum discharge | |
| CN108671723B (en) | An integrated device for ultrasonic synchronous desulfurization and dust removal | |
| CN204320062U (en) | A kind of high effective flue gas cleaning system | |
| CN203944281U (en) | Flue gas desulfur device | |
| CN201959716U (en) | Combination ammonia desulfurization tower | |
| CN106422713A (en) | Method for desulfuration, denitration and dust removal through ultrasonic atomization | |
| CN207614642U (en) | A kind of system suitable for high/low temperature gaseous recombination desulfurization denitration method | |
| CN105363340A (en) | Activated carbon dry-method smoke purifying method and device capable of achieving simultaneous desulfurization and denitrification | |
| CN105032173A (en) | Device and process of ammonia-soda-process combined desulfurization and denitrification | |
| CN203469805U (en) | Absorption tower device capable of simultaneously desulfurizing and denitrifying smoke through bubbling and spraying | |
| CN103801185B (en) | Metallic fume treatment and purification system | |
| Yu et al. | Alkaline absorbents for SO2 and SO3 removal: A comprehensive review | |
| CN205796820U (en) | A kind of desulfurating dust-removing equipment | |
| CN106422712A (en) | High-pressure spray desulfurization, denitration and dust removal method | |
| CN104941420A (en) | Flue gas desulfurization comprehensive treatment system and method | |
| CN204502800U (en) | A kind of ammonia-soda process combined desulfurization and denitration device | |
| CN201930709U (en) | Novel semi-dry process flue gas desulfurization device | |
| CN109833748A (en) | A kind of near-zero release flue gas coordinated desulfurization denitration dust collecting group technology | |
| CN204134470U (en) | A kind of carbide slag-gypsum dynamic wave flue gas desulphurization system | |
| CN204933237U (en) | Spray spray is exposed to the sun the anti-release apparatus of desulfurization and dedusting | |
| CN203899445U (en) | Exhaust gas purification system for recovering NOx | |
| CN207102319U (en) | SDA alkali adding method deep desulfuration dedustings and wastewater zero discharge flue gas processing device | |
| CN209302509U (en) | A kind of flue gas multiple pollutant cooperative control system |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20141119 Termination date: 20150708 |
|
| EXPY | Termination of patent right or utility model |