CN203750548U - Continuous production equipment of catalysts - Google Patents

Continuous production equipment of catalysts Download PDF

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Publication number
CN203750548U
CN203750548U CN201420057401.6U CN201420057401U CN203750548U CN 203750548 U CN203750548 U CN 203750548U CN 201420057401 U CN201420057401 U CN 201420057401U CN 203750548 U CN203750548 U CN 203750548U
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China
Prior art keywords
pipeline
continuous
area
settling zone
helical axis
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Expired - Lifetime
Application number
CN201420057401.6U
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Chinese (zh)
Inventor
向华
黄文昭
国海光
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Shanghai Hejide Dynamic Hydrogen Machine Co Ltd
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SHANGHAI MOCHUN POWER TECHNOLOGY Co Ltd
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Priority to CN201420057401.6U priority Critical patent/CN203750548U/en
Application granted granted Critical
Publication of CN203750548U publication Critical patent/CN203750548U/en
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Abstract

The utility model discloses continuous production equipment of catalysts. Copper-based catalysts and the like are produced in continuous pipelines; the continuous pipelines sequentially comprise a sedimentation area, an aging area, a washing area, a drying area and a baking area. A pH meter automatic control pump arranged in the sedimentation area controls the pH value, and the uniform reaction in the sedimentation area is realized by magnetic stirring; in the aging area, the trend of slurry is of a snake shape, and grids are adopted in the aging area and the sedimentation area and are used for preventing slurry which is sedimented completely from entering the aging area. Multi-stage hydrocyclones are adopted for the washing area to separate solids and liquids; the solids and washing water are subjected to powerful magnetic stirring to achieve the aim of pulping. In the drying area and the baking area, a magnetic spiral shaft is adopted for pushing materials, and finally products are discharged from a pipeline outlet. The catalyst continuous production equipment disclosed by the utility model can achieve automatic control continuous production, reduce energy consumption, improve the production efficiency, reduce the cost, can produce high-quality catalyst products, meanwhile can effectively prevent harmful gases from diffusing into air, and is more environment-friendly.

Description

Catalyst continuous producing apparatus
Technical field
The utility model belongs to chemical process technical field, relates to a kind of Catalyst Production technique, relates in particular to a kind of catalyst continuous production processes; Meanwhile, the utility model also relates to a kind of catalyst continuous producing apparatus.
Background technology
At present, Catalyst Production is substantially all to use tank reactor, and the shortcoming of the method is the discontinuous production being interrupted, and between the each operation of existing production technology and equipments, is discontinuous substantially, realizes between the equipment of each step and closely not connecting.
Tank reactor comprises intermittently tank reactor, continuous tank reactor.Intermittently tank reactor flexible operation, is easy to adapt to different operating condition and product variety, is applicable to the production that small lot, many kinds, reaction time are grown.The shortcoming of batch still is: need have the auxiliary operations such as charging and discharging, product quality is also difficult for stable.Tank reactor can be avoided the shortcoming of batch still continuously, but stirring action can cause the back-mixing of still inner fluid.Stirring the occasion violent, liquid viscosity is lower or mean residence time is grown, in still, material flow pattern can be regarded complete mixing flow as, and reactor is correspondingly called continuous stir reactor.Require conversion ratio high or have series connection side reaction occasion, the air-teturning mixed phenomenon in tank reactor is unfavorable factor.
No matter be intermittently tank reactor or continuously tank reactor, the reaction of each step is all carried out in the larger reactor of volume, is not easy to control the carrying out of reaction, generally need to consume very large energy, production efficiency is low, and human cost is high, and the catalyst quality of producing is lower.Along with maturation and the application of automatic technology, it is aobvious that the shortcoming of tank reactor is got over utility model.
As Chinese patent 201310296311.2 has disclosed the catalyst based preparation method of a kind of high dispersing copper based on non-precious metal, relate to the production technology of catalyst in medicine, dyestuff, first mantoquita, magnesium salts and aluminium salt are dissolved in deionized water to wiring solution-forming A; Precipitating reagent sodium carbonate and NaOH are dissolved in deionized water to wiring solution-forming B; Again solution A and solution B are dripped and in deionized water, carry out burin-in process, then the mixed liquor after aging is proceeded to and in stainless steel hydrothermal reaction kettle, carries out crystallization processing, filtration, washing, dry, roasting, reduction activation processing.
Meanwhile, the product that each reactor forms need to be by Pipeline transport to other reactors, also can lot of energy.In addition, existing production technology can produce more pernicious gas, easily diffuses in air welding.
In view of this, nowadays in the urgent need to designing a kind of new Catalyst Production technique, to overcome the above-mentioned defect of existing Catalyst Production technique.
Utility model content
Technical problem to be solved in the utility model is: a kind of catalyst continuous producing apparatus is provided, can realizes automation control and produce continuously, reduce power consumption, raise the efficiency, reduce costs, can produce high-quality catalyst prod.
For solving the problems of the technologies described above, the utility model adopts following technical scheme:
A kind of catalyst continuous producing apparatus, described production equipment comprises continuous pipeline, material container, the measuring pump of sealing;
Described continuous pipeline is divided into settling zone, aging district, scrubbing section, dry section, roast area, and settling zone, aging district, scrubbing section, dry section, roast area connect successively;
Described settling zone is provided with pipeline entrance, and measuring pump is connected to pipeline entrance by pipeline; Material container connects measuring pump, by measuring pump, raw material is pumped into continuous-tube road;
Described continuous pipeline comprises the first continuous pipeline, the second continuous pipeline, scrubbing section pipeline, and the first continuous pipeline comprises settling zone, aging district, and the second continuous pipeline comprises dry section, roast area; The outlet of the first continuous pipeline connects the entrance of scrubbing section pipeline by connecting line, the outlet of scrubbing section pipeline connects the entrance of the second continuous pipeline by connecting line;
The described first continuous pipeline is provided with the first magnetic helical axis, and the second continuous pipeline is provided with the second magnetic helical axis; The first magnetic helical axis, the second magnetic helical axis drive by magnetic drive mechanism separately respectively;
In settling zone, be provided with pH meter Self-controlled pump, thereby control pH value in order to control flow, the first magnetic helical axis be partly or entirely arranged at settling zone;
In aging district, be provided with slurry passage, slurry channel design is linear pattern or spirality, and aging district and settling zone are separated by barrier;
Scrubbing section is provided with multi-stage water power cyclone, solid-liquid blender;
The second magnetic force helical axis is arranged at dry section, roast area, and roast area is provided with pipeline outlet, discharges product from pipeline outlet.
A kind of catalyst continuous producing apparatus, described production equipment comprises continuous pipeline, material container, the power transport establishment of sealing;
Described continuous pipeline is divided into settling zone, aging district, scrubbing section, dry section, roast area, and settling zone, aging district, scrubbing section, dry section, roast area connect successively;
In material container, hold raw material, material container connects power transport establishment by pipeline; Described power transport establishment is connected to pipeline entrance by pipeline, respectively raw material is pumped into pipeline.
As a kind of preferred version of the present utility model, described continuous pipeline comprises the first continuous pipeline, the second continuous pipeline, scrubbing section pipeline, and the first continuous pipeline comprises settling zone, aging district, and the second continuous pipeline comprises dry section, roast area;
The outlet of the first continuous pipeline connects the entrance of scrubbing section pipeline by connecting line, the outlet of scrubbing section pipeline connects the entrance of the second continuous pipeline by connecting line;
The described first continuous pipeline is provided with the first magnetic helical axis, and the second continuous pipeline is provided with the second magnetic helical axis; The first magnetic helical axis, the second magnetic helical axis drive by magnetic drive mechanism separately respectively.
As a kind of preferred version of the present utility model, in described settling zone, be provided with pH meter Self-controlled pump, thereby control pH value in order to control flow, the first magnetic helical axis be partly or entirely arranged at settling zone.
As a kind of preferred version of the present utility model, in aging district, be provided with slurry passage, slurry channel design is linear pattern or spirality, aging district and settling zone are separated by barrier.
As a kind of preferred version of the present utility model, scrubbing section is provided with multi-stage water power cyclone, solid-liquid blender.
As a kind of preferred version of the present utility model, the second magnetic force helical axis is arranged at dry section, roast area, and roast area is provided with pipeline outlet, discharges product from pipeline outlet.
The beneficial effects of the utility model are: catalyst continuous production processes and the equipment that the utility model proposes, and can realize automation control and produce continuously, reduce power consumption, enhance productivity, reduce costs, can produce high-quality catalyst prod; Can effectively avoid harmful gases diffusion to air, environmental protection more simultaneously.
Brief description of the drawings
Fig. 1 is the composition schematic diagram of the utility model catalyst continuous producing apparatus.
Fig. 2 is the flow chart of the utility model catalyst continuous production processes.
Fig. 3 is the composition schematic diagram of the utility model catalyst continuous producing apparatus in embodiment bis-.
Detailed description of the invention
Describe preferred embodiment of the present utility model in detail below in conjunction with accompanying drawing.
Embodiment mono-
Refer to Fig. 1, the utility model discloses a kind of catalyst continuous producing apparatus, can utilize this device fabrication copper-based catalysts, in the utility model, in the continuous pipeline of sealing, produce catalyst, described continuous pipeline is divided into settling zone 1, aging district 2, scrubbing section 3, dry section 4, roast area 5 successively.
Raw material comprises metal nitrate, precipitant solution.Metal nitrate comprises transition metal nitrate and rare-earth metal nitrate.Transition metal nitrate comprises that one or more in copper nitrate, zinc nitrate, aluminum nitrate, ferric nitrate (can also comprise other similar transition metal nitrate certainly, the scope of obtaining of transition metal nitrate should be envisioned that for those skilled in the art, lower same), rare-earth metal nitrate comprises one or more (certainly can also comprise other similar rare-earth metal nitrates) in lanthanum nitrate, zirconium nitrate; Precipitant solution comprises one or more (certainly can also comprise other similar precipitant solution) in ammoniacal liquor, sodium carbonate.
Raw material passes through respectively measuring pump (figure depending on) and pumps into the first continuous pipeline 11 from feeding mouth 14, successively passes through above-mentioned settling zone 1, aging district 2, scrubbing section 3, dry section 4, roast area 5, finally obtains catalyst.
Described continuous pipeline comprises that the first continuous pipeline 11, the second continuous pipeline 51, the continuous pipeline 11 of scrubbing section pipeline 31, the first comprise that settling zone 1, the continuous pipeline 51 in aging district 2, the second comprise dry section 4, roast area 5; The outlet of the first continuous pipeline 11 connects the entrance of scrubbing section pipeline 31 by connecting line, the outlet of scrubbing section pipeline 31 connects the entrance of the second continuous pipeline 51 by connecting line.
The described first continuous pipeline 11 is provided with the continuous pipeline 51 of the first magnetic helical axis 12, the second and is provided with the second magnetic helical axis 52; The first magnetic helical axis 11, the second magnetic helical axis 51 drive by magnetic drive mechanism 13,53 separately respectively.
In settling zone 1, be provided with pH meter Self-controlled pump, thereby control pH value by pH meter Self-controlled pump control flow, realized the homogeneous reaction of settling zone by magnetic agitation.
In aging district 2, be provided with slurry passage 21, slurry passage 21 structures are linear pattern or snakelike or spirality, and in the present embodiment, slurry passage 21 is serpentine configuration, and separate by barrier 16 with settling zone 1 in aging district 2, avoids precipitating slurry completely and enter aging district.
Scrubbing section 3 is provided with multi-stage water power cyclone, solid-liquid blender, realizes Separation of Solid and Liquid by multi-stage water power cyclone, and solid and washings are realized the object of making beating by the powerful magnetic agitation of solid-liquid blender.
Dry section 4, roast area 5 are provided with the second magnetic force helical axis 52, in order to promote material.Be provided with outlet 54, second row gas port 55 in the roast area 5 of the second continuous pipeline 51.
More than introduced catalyst continuous producing apparatus of the present utility model, the utility model also discloses a kind of technique of utilizing above-mentioned continuous producing apparatus to produce catalyst in disclosing the said equipment.
Refer to Fig. 2, utilize the production technology of the utility model production equipment production of copper catalyst based (can certainly be other catalyst) specifically to comprise the steps:
Step S0, feeding step: raw material passes through respectively measuring pump (figure depending on) and pumps into the first continuous pipeline 11 from feeding mouth 14
Step S1, settling step: the built-in pH meter Self-controlled pump in settling zone 1, thus control pH value by pH meter Self-controlled pump control flow, pH value is controlled to 5~11, stir by the first magnetic helical axis 12 homogeneous reaction that realizes settling zone; The temperature of settling zone 1 is controlled at 35~85 DEG C, and pressure does not have particular requirement, can under normal pressure, carry out, and can be also other pressure.
Step S2, aging step: aging district 2 slurry pipelines be shaped as linear or snakelike or spirality, in the present embodiment, aging district 2 adopts barrier 16 intervals with settling zone 1, avoids precipitating slurry completely and enters aging district 2; The Temperature Setting in aging district 2 is 35~85 DEG C.The gas that reaction is produced is discharged the first continuous pipeline 11 by first row gas port 15.
Step S3, washing step: be provided with multi-stage water power cyclone, solid-liquid blender at scrubbing section 3; Realize Separation of Solid and Liquid by multi-stage water power cyclone, solid and washings are realized the object of making beating by the powerful magnetic agitation of solid-liquid blender; The Temperature Setting of scrubbing section 3 is room temperature~85 DEG C, can be also below-20 DEG C, certainly temperature be more than 0 DEG C effect more.
Step S4, drying steps: adopt the second magnetic force helical axis to promote material at dry section 4; The Temperature Setting of dry section is 100~160 DEG C;
Step S5, calcination steps: adopt the second magnetic force helical axis to promote material in roast area 5, finally discharge product from the outlet 54 of the second continuous pipeline 51; The Temperature Setting of roast area is 160-850 DEG C.The gas that reaction is produced is discharged the first continuous pipeline 51 by second row gas port 55.
Embodiment bis-
Refer to Fig. 3, the present embodiment is in the difference of embodiment mono-, and in the present embodiment, interior slurry passage 21 structures in aging district 2 can be for except snakelike other shapes of thinking, in the present embodiment, and the structure similar of slurry passage 21 and settling zone 1.
In sum, catalyst continuous production processes and the equipment that the utility model proposes, can realize automation control and produce continuously, reduces power consumption, enhances productivity, and reduces costs, and can produce high-quality catalyst prod; Can effectively avoid harmful gases diffusion to air, environmental protection more simultaneously.
Reaction pipeline of the present utility model, simultaneously as transfer pipeline, can reduce the power consumption in conveying, improves the production efficiency of catalyst.
Here description of the present utility model and application is illustrative, not wants scope of the present utility model to limit in the above-described embodiments.Here the distortion of disclosed embodiment and change is possible, and for those those of ordinary skill in the art, the various parts of the replacement of embodiment and equivalence are known.Those skilled in the art are noted that in the situation that not departing from spirit of the present utility model or substantive characteristics, and the utility model can be with other form, structure, layout, ratio, and realize with other assembly, material and parts.In the situation that not departing from the utility model scope and spirit, can carry out other distortion and change to disclosed embodiment here.

Claims (7)

1. a catalyst continuous producing apparatus, is characterized in that, described production equipment comprises continuous pipeline, material container, the measuring pump of sealing;
Described continuous pipeline is divided into settling zone, aging district, scrubbing section, dry section, roast area, and settling zone, aging district, scrubbing section, dry section, roast area connect successively;
Described settling zone is provided with pipeline entrance, and measuring pump is connected to pipeline entrance by pipeline; Material container connects measuring pump, by measuring pump, raw material is pumped into continuous-tube road;
Described continuous pipeline comprises the first continuous pipeline, the second continuous pipeline, scrubbing section pipeline, and the first continuous pipeline comprises settling zone, aging district, and the second continuous pipeline comprises dry section, roast area; The outlet of the first continuous pipeline connects the entrance of scrubbing section pipeline by connecting line, the outlet of scrubbing section pipeline connects the entrance of the second continuous pipeline by connecting line;
The described first continuous pipeline is provided with the first magnetic helical axis, and the second continuous pipeline is provided with the second magnetic helical axis; The first magnetic helical axis, the second magnetic helical axis drive by magnetic drive mechanism separately respectively;
In settling zone, be provided with pH meter Self-controlled pump, thereby control pH value in order to control flow, the first magnetic helical axis be partly or entirely arranged at settling zone;
In aging district, be provided with slurry passage, slurry channel design is linear pattern or spirality, and aging district and settling zone are separated by barrier;
Scrubbing section is provided with multi-stage water power cyclone, solid-liquid blender;
The second magnetic force helical axis is arranged at dry section, roast area, and roast area is provided with pipeline outlet, discharges product from pipeline outlet.
2. a catalyst continuous producing apparatus, is characterized in that, described production equipment comprises continuous pipeline, material container, the power transport establishment of sealing;
Described continuous pipeline is divided into settling zone, aging district, scrubbing section, dry section, roast area, and settling zone, aging district, scrubbing section, dry section, roast area connect successively;
In material container, hold raw material, material container connects power transport establishment by pipeline; Described power transport establishment is connected to pipeline entrance by pipeline, respectively raw material is pumped into pipeline.
3. catalyst continuous producing apparatus according to claim 2, is characterized in that:
Described continuous pipeline comprises the first continuous pipeline, the second continuous pipeline, scrubbing section pipeline, and the first continuous pipeline comprises settling zone, aging district, and the second continuous pipeline comprises dry section, roast area;
The outlet of the first continuous pipeline connects the entrance of scrubbing section pipeline by connecting line, the outlet of scrubbing section pipeline connects the entrance of the second continuous pipeline by connecting line;
The described first continuous pipeline is provided with the first magnetic helical axis, and the second continuous pipeline is provided with the second magnetic helical axis; The first magnetic helical axis, the second magnetic helical axis drive by magnetic drive mechanism separately respectively.
4. catalyst continuous producing apparatus according to claim 2, is characterized in that:
In described settling zone, be provided with pH meter Self-controlled pump, thereby control pH value in order to control flow, the first magnetic helical axis be partly or entirely arranged at settling zone.
5. catalyst continuous producing apparatus according to claim 2, is characterized in that:
In aging district, be provided with slurry passage, slurry channel design is linear pattern or spirality, and aging district and settling zone are separated by barrier.
6. catalyst continuous producing apparatus according to claim 2, is characterized in that:
Scrubbing section is provided with multi-stage water power cyclone, solid-liquid blender.
7. catalyst continuous producing apparatus according to claim 2, is characterized in that:
The second magnetic force helical axis is arranged at dry section, roast area, and roast area is provided with pipeline outlet, discharges product from pipeline outlet.
CN201420057401.6U 2014-01-29 2014-01-29 Continuous production equipment of catalysts Expired - Lifetime CN203750548U (en)

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103816945A (en) * 2014-01-29 2014-05-28 上海摩醇动力技术有限公司 Continuous catalyst production process and equipment
CN104645995A (en) * 2015-02-12 2015-05-27 上海摩醇动力技术有限公司 Preparation process of copper-based catalyst

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103816945A (en) * 2014-01-29 2014-05-28 上海摩醇动力技术有限公司 Continuous catalyst production process and equipment
CN104645995A (en) * 2015-02-12 2015-05-27 上海摩醇动力技术有限公司 Preparation process of copper-based catalyst

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Effective date of registration: 20190328

Address after: Building A, Building 18, 1500 Lane, Xinfei Road, Songjiang District, Shanghai, 20112

Patentee after: SHANGHAI HYDROGEN MOBILE REFRMER INSTRUMENT Co.,Ltd.

Address before: 201216 First Floor, No. 19, 1500 Lane, Xinfei Road, Songjiang District, Shanghai

Patentee before: SHANGHAI MOCHUN POWER TECHNOLOGY Co.,Ltd.

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Effective date of registration: 20210918

Granted publication date: 20140806

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Date of cancellation: 20240129

Granted publication date: 20140806

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