A kind of new type water is processed air flotation pool
technical field
The utility model relates to a kind of new type water and processes air flotation pool.
background technology
Pressurized dissolved air flotation technique is divided into downflow system air-float technology and counter-current air floating technique at present.Downflow system air-float technology is in contact chamber, to adopt the mode of following current to make former water and dissolved air water carry out coflow, microbubble and suspended substance move in the same way in exposure chamber and complete collision and adhesion process, due to microbubble and upwards coflow of suspended substance, the duration of contact of microbubble and suspended substance is short, cause the adhesion effect of microbubble poor, especially the in the situation that in former water, the many and flco of oil or suspended particle being loose, downflow system air-float technology is difficult to effectively remove oil and suspended particle in water, and purifying water effect is undesirable.
Counter-current air floating technique is in contact chamber, to adopt the mode of adverse current to make former water carry out reverse contact with dissolved air water, microbubble and former water countercurrent flow, contact chamber bottom water outlet, the suspended substance of decline contacts with the microbubble of rising is reverse, makes microbubble and suspended substance collision.In counter-current process, microbubble and suspended substance are realized effective collision, adhesion process does not need too large flow dynamic, but because former water flows downward, be turbulent state, flow dynamic is large, and the microbubble after collision and suspended substance can not well adhere to form stable bubble flco or adhere to and under former water counter flow action, desorption phenomenon occur afterwards, cause steeping flco and can not well complete floating sepn process, occur " race alumen ustum ' phenomenon.Counter-current air floating technique is not strong to the adaptability of raw water quality variation and surface load, along with the carrying out of operation, purifying water effect variation, often obtain better water quality by increasing reflux ratio, increase microbubble concentration or increasing the air flotation pool degree of depth, but this way very consumes energy and economic benefit is not high.
utility model content
The technical problems to be solved in the utility model is to provide a kind of new type water and processes air flotation pool, and it significantly improves the interaction of microbubble-suspended substance, realizes microbubble and suspended substance effectively adheres to, and has improved opposing change of water quality risk ability and purifying water effect.
In order to solve the problems of the technologies described above, the technical solution of the utility model is:
A kind of new type water is processed air flotation pool, comprise pond body, the first division plate is set in the body of pond in turn, the second division plate and the 3rd division plate, the first division plate, the second division plate and the 3rd division plate are divided into pond collision exposure chamber in turn, adhere to exposure chamber, air flotation separating chamber and water conservancy diversion water-supplying chamber, collision exposure chamber and adhesion exposure chamber are communicated with at the bottom of pond by first channel, air flotation separating chamber and water conservancy diversion water-supplying chamber are communicated with at the bottom of pond by second passage, dissolved air release is all arranged in bottom, collision exposure chamber and bottom, adhesion exposure chamber, the former water inhalent siphon mouth of pipe is arranged on collision top, exposure chamber, top, collision exposure chamber arranges automatic control, air flotation separating chamber top arranges mechanical dreg removing system.
Above-mentioned new type water is processed air flotation pool, and the water flow velocity of collision exposure chamber is 15 ~ 25mm/s, and the flow velocity that adheres to exposure chamber is 5 ~ 15mm/s, and the flow rate of water flow of first channel is 10-20mm/s.
Above-mentioned new type water is processed air flotation pool, and the downward water flow velocity of air flotation separating chamber is 1 ~ 3mm/s, comprising dissolved air water quantity of reflux.
Above-mentioned new type water is processed air flotation pool, and collision exposure chamber and the dissolved air release adhering in exposure chamber are all positioned at 15-25cm place, first channel top.
Above-mentioned new type water is processed air flotation pool, and collision exposure chamber is connected with dissolved air water arm respectively with the dissolved air release adhering in exposure chamber, and two dissolved air water arms are connected with dissolved air water house steward, on two dissolved air water arms, control valve and flow measurement device are all set.
Above-mentioned new type water is processed air flotation pool, and the former water inhalent siphon mouth of pipe is not less than 1m with the vertical range of the dissolved air release that bottom, collision exposure chamber arranges, and the former water inhalent siphon mouth of pipe is not less than 30cm apart from collision exposure chamber liquid level vertical range.
Above-mentioned new type water is processed air flotation pool, collision exposure chamber and adhere to pond corresponding to exposure chamber at the bottom of arrange and remove sedimentary deslagging blow-down pipe at the bottom of pond.
Above-mentioned new type water is processed air flotation pool, and after the processing of water conservancy diversion water-supplying chamber, water is discharged by upflow tube, and upflow tube is provided with control valve.
Above-mentioned new type water is processed air flotation pool, and former water inhalent siphon is provided with under meter and control valve.
Above-mentioned new type water is processed air flotation pool, water treatment air supporting pond long-width ratio is 1:1 ~ 1:4, and collision exposure chamber is called exposure chamber together with adhering to exposure chamber, and exposure chamber's long-width ratio is 1:1 ~ 1:1.5, water treatment air supporting pond available depth is 1.5 ~ 2.0m, and the water treatment air supporting tank waterpower residence time is 10 ~ 15min.
Contact chamber of the present utility model is divided into two-stage, is respectively collision exposure chamber and adheres to exposure chamber, collision exposure chamber and adhere to exposure chamber and be communicated with at the bottom of pond by first channel, collision exposure chamber bottom and adhere to bottom, exposure chamber and all arrange dissolved air release.In collision exposure chamber, microbubble and former water countercurrent flow, complete the abundant collision of microbubble and suspended substance, the water outlet of then colliding exposure chamber enters and adheres to exposure chamber, adhering to exposure chamber, microbubble contacts with former water coflow, and the part microbubble of collision exposure chamber enters adhesion exposure chamber and increased adhesion exposure chamber microbubble concentration, the adhesion process of being convenient to complete in adhesion exposure chamber microbubble and suspended substance, forms stable bubble flocs float to air flotation separating chamber.Former water is flowed through in turn and is collided exposure chamber and adhere to exposure chamber, and the duration of contact of microbubble and suspended substance is long, has improved the adhesion effect of microbubble, can better reduce the generation of bubble flco desorption phenomenon, strengthening effluent quality.The utility model significantly improves the interaction of microbubble-suspended substance, realizes microbubble and suspended substance and fully collides and effectively adhere to, and reduces the probability of occurrence of bubble flco desorption phenomenon, has greatly improved air-float technology opposing change of water quality risk ability and purifying water effect.
brief description of the drawings
Below in conjunction with accompanying drawing to further detailed explanation of the utility model:
Fig. 1 is structural representation of the present utility model.
In figure: 1 first division plate, 2 second division plates, 3 the 3rd division plates, 4 collision exposure chambers, 5 adhere to exposure chamber, 6 air flotation separating chambers, 7 water conservancy diversion water-supplying chamber, 8 dissolved air releases, the 9 former water inhalent siphon mouths of pipe, 10 under meters.
Embodiment
Find by research, in air-float technology, microbubble and suspended substance adhesive bond mechanism are mainly followed collision adhesive mechanism, interaction process between microbubble and suspended substance can be decomposed into three subprocess: (1) collision process, between the two apart from being progressively contracted to the process of meeting; (2) adhere to, thickness of liquid film is thinned to and breaks between the two, finally forms the process of stable three-phase contact angle; (3) desorption, steeps separating again of flocculation zoarium, exceedes adhesion energy, just bubble, particle can separate again if shear kinetic energy (or other forms of disturbance energy).
Three bubble surface region differences that process occurs, required reactive force is also different.Collision process mainly occurs in liquid phase main flow area and the shear zone of microbubble, and Main Function power is the effect of flow dynamic, diffusion and electrical forces.Adhesion process mainly occurs in microbubble attachment zone, and Main Function power is surface force.Adhesion process does not need too large flow dynamic, prevents from steeping the generation of flco desorption phenomenon.
Based on above-mentioned result of study, as shown in Figure 1, water treatment air supporting pond comprises pond body, the first division plate 1, the second division plate 2 and the 3rd division plate 3, the first division plates, the second division plate and the 3rd division plate are set in the body of pond to be in turn divided into pond in turn collision exposure chamber 4, to adhere to exposure chamber 5, air flotation separating chamber 6 and water conservancy diversion water-supplying chamber 7.Collision exposure chamber and adhesion exposure chamber are communicated with at the bottom of pond by first channel, and air flotation separating chamber and water conservancy diversion water-supplying chamber are communicated with at the bottom of pond by second passage.Dissolved air release 8 is all arranged in bottom, collision exposure chamber and bottom, adhesion exposure chamber, the former water inhalent siphon mouth of pipe 9 is arranged on collision top, exposure chamber, for the scum silica frost of collecting the floating generation of collision exposure chamber arranges waterpower dreg collecting slot above exposure chamber, by controlling air flotation pool liquid level, realize the excessive slag of collision exposure chamber waterpower.Air flotation separating chamber top arranges mechanical dreg removing system, flows to air flotation separating chamber complete solid-liquid separation through the bubble flco effectively adhering to, and the scum silica frost that floats up to liquid level is collected by slag scraper, discharges from mechanical ash pit.
Collision exposure chamber and the dissolved air release adhering in exposure chamber are all positioned at 15-25cm place, first channel top.
In order to prevent that former water water inlet flow force from rushing the broken scum silica frost that has floated up to liquid level, the former water inhalent siphon mouth of pipe is positioned at below collision liquid level 30 cm of exposure chamber.
Collision exposure chamber is connected with dissolved air water arm respectively with the dissolved air release adhering in exposure chamber, and two dissolved air water arms are connected with dissolved air water house steward, and valve and under meter 10 are all set on two dissolved air water arms.Valve is all set on two dissolved air water arms and can realizes the flexible switching of downflow system air-float technology, counter-current air floating technique and adverse current-following current (mixing streaming) air-float technology and control the size of dissolved air water reflux ratio, strengthened the adaptive faculty of air flotation pool to change of water quality.
Collision exposure chamber and adhere to pond corresponding to exposure chamber at the bottom of arrange and remove sedimentary deslagging blow-down pipe at the bottom of pond.
After the processing of water conservancy diversion water-supplying chamber, water is discharged by upflow tube, and upflow tube is provided with control valve, regulates air flotation pool median water level height by control valve, realizes the hydraulic slag discharging of collision exposure chamber.
Former water inhalent siphon is provided with under meter and control valve, controls former water and enters water.
The flow rate of water flow of collision exposure chamber is 15-25mm/s, and the flow rate of water flow that adheres to exposure chamber is 5-15mm/s, and the flow rate of water flow of first channel is 10-20mm/s.Collision exposure chamber turbulent state is tending towards the transformation of laminar flow regime to adhesion zone of action, compared with collision exposure chamber, adhere to exposure chamber's flow velocity slower, the valid circulation area that adheres to exposure chamber is greater than the valid circulation area that collides exposure chamber, be beneficial to like this bubble adhesion particle, reduce the generation of desorption simultaneously.
Water technology of the present utility model is as follows: former water is after flocculation process, first enter collision exposure chamber, in collision exposure chamber, microbubble and former water countercurrent flow, complete the abundant collision of microbubble and suspended substance, and preliminary adhesion form bubble flocs float to the liquid level that density is less than water and become scum silica frost, to be discharged by automatic control, water quality obtains rough purification.Fail the stable flco floating and suspended substance under the effect of water impact, enter and adhere to exposure chamber, adhering to exposure chamber, microbubble contacts with former water coflow, completes effective adhesion process, and the bubble flocs float that formation density is less than water enters air flotation separating chamber, scum silica frost is collected by mechanical dreg removing system, water purification enters water conservancy diversion water-supplying chamber, and then overflow enters next stage reactor, completes dissolved air flotation process.In exposure chamber (collision exposure chamber and adhesion exposure chamber), it is the further intensive treatment after collision contact that microbubble-suspended substance adheres to contact, in raising contact effect, effectively completes the adhesion process of particle, thereby has reached the object of strengthening air supporting water outlet.
embodiment 1
Draw yellow water below taking somewhere as example, raw water turbidity is 7.52NTU, COD
mn, UV
254, TOC is respectively 4.59mg/L, 0.053,5.668mg/L, chlorophyll a is 18.13mg/L, algae is counted as pH value 7.93 ~ 8.44,10.8 ~ 11.6 DEG C of water temperatures.
It is PAFC(aluminium iron polychloride that the flocculation stage is used flocculation agent), one-level flocculation stage G value 65S-1, secondary flocculation stage G value 40S-1, stirs 10min and obtains water to be clean.
(1) former water enters collision exposure chamber after flocculation process, water inlet flow velocity is 15mm/s, microbubble and water countercurrent flow to be clean that the dissolved air release being arranged by bottom, collision exposure chamber discharges, dissolved-air pressure is 0.35Mpa, collision exposure chamber is 1:2.5 with adhering to exposure chamber's dissolved air water allocation proportion, complete the abundant collision of suspended substance in microbubble and water to be clean, bubble flocs float to the liquid level that preliminary adhesion formation density is less than water becomes scum silica frost, discharged by automatic control, water quality obtains rough purification;
(2) in water to be clean, fail the stable flco floating or suspended substance under the effect of water impact, the part being communicated with bottom, adhesion exposure chamber by collision exposure chamber enters and adheres to exposure chamber, adhering to exposure chamber, the microbubble being discharged by the dissolved air release that adheres to the setting of bottom, exposure chamber contacts with water coflow to be clean, dissolved-air pressure, consistent in the volume proportion syn-collision exposure chamber of molten gas and water, complete effective adhesion process, the bubble flocs float that formation density is less than water enters air flotation separating chamber, scum silica frost is collected by mechanical dreg removing system, water purification enters water conservancy diversion water-supplying chamber, complete scavenging process, the total dissolved air water reflux ratio of this process is 8%.
Adopt above-mentioned process for purifying water, as shown in Figure 2, data are in table 1 for the relation of PAFC dosage and pollutent turbidity removal rate.
Table 1 PAFC dosage and various pollutants removal rate relation table
| With Al
3+Meter, flocculation agent addition (mg/L)
|
0.5 |
1 |
1.5 |
2 |
2.5 |
3 |
| NTU |
4.59 |
2.55 |
1.08 |
0.358 |
0.987 |
1.28 |
| Clearance |
0.390 |
0.661 |
0.856 |
0.952 |
0.869 |
0.830 |
| COD(mg/L) |
3.96 |
3.45 |
2.87 |
2.35 |
2.32 |
2.28 |
| Clearance |
0.137 |
0.248 |
0.375 |
0.488 |
0.495 |
0.503 |
| UV
254(cm
-1)
|
0.038 |
0.032 |
0.028 |
0.023 |
0.022 |
0.022 |
| Clearance |
0.283 |
0.396 |
0.472 |
0.566 |
0.585 |
0.585 |
| TOC(mg/L) |
4.752 |
4.235 |
3.679 |
3.087 |
2.997 |
2.986 |
| Clearance |
0.162 |
0.253 |
0.351 |
0.455 |
0.471 |
0.473 |
| Chlorophyll a |
13.67 |
9.58 |
5.66 |
3.71 |
3.84 |
4.09 |
| Clearance |
0.246 |
0.472 |
0.688 |
0.795 |
0.788 |
0.774 |
comparative example 1
Compare with embodiment 1, just the adverse current air supporting process in collision exposure chamber is omitted, only retain the following current air supporting processing of same treatment, the height that adheres to exposure chamber is doubled, to identical water to be clean after treatment, purifying water effect is in table 2.
Table 2 PAFC dosage and pollutent turbidity removal rate relation table
| With Al
3+Meter, flocculation agent addition (mg/L)
|
0.5 |
1 |
1.5 |
2 |
2.5 |
3 |
| NTU |
4.99 |
3.53 |
2.23 |
1.53 |
1.02 |
1.45 |
| Clearance |
0.336 |
0.231 |
0.514 |
0.667 |
0.778 |
0.678 |
| COD(mg/L) |
4.2 |
3.96 |
3.56 |
3.38 |
3.19 |
3.03 |
| Clearance |
0.085 |
0.137 |
0.224 |
0.264 |
0.305 |
0.340 |
| UV
254(cm
-1)
|
0.044 |
0.042 |
0.038 |
0.035 |
0.032 |
0.03 |
| Clearance |
0.170 |
0.208 |
0.283 |
0.340 |
0.396 |
0.434 |
| TOC(mg/L) |
4.979 |
4.532 |
4.31 |
3.9 |
3.554 |
3.386 |
| Clearance |
0.122 |
0.200 |
0.240 |
0.312 |
0.373 |
0.403 |
| Chlorophyll a |
15.87 |
12.56 |
9.54 |
7.88 |
6.32 |
5.89 |
| Clearance |
0.125 |
0.307 |
0.474 |
0.565 |
0.651 |
0.675 |
comparative example 2
Compare with embodiment 1, just the following current air supporting process adhering in exposure chamber is omitted, only retain the adverse current air supporting processing of same treatment, the height of collision exposure chamber is doubled, to identical water to be clean after treatment, purifying water effect is in table 3.
Table 3 PAFC dosage and pollutent turbidity removal rate relation table
| With Al
3+Meter, flocculation agent addition (mg/L)
|
0.5 |
1 |
1.5 |
2 |
2.5 |
3 |
| NTU |
5.22 |
4.05 |
3.26 |
2.58 |
1.86 |
2.06 |
| Clearance |
0.306 |
0.461 |
0.566 |
0.657 |
0.753 |
0.726 |
| COD(mg/L) |
4.36 |
4.15 |
3.88 |
3.69 |
3.36 |
3.29 |
| Clearance |
0.050 |
0.096 |
0.155 |
0.196 |
0.268 |
0.283 |
| UV
254(cm
-1)
|
0.045 |
0.043 |
0.04 |
0.037 |
0.034 |
0.033 |
| Clearance |
0.151 |
0.189 |
0.245 |
0.302 |
0.358 |
0.377 |
| TOC(mg/L) |
5.126 |
4.854 |
4.456 |
4.156 |
3.764 |
3.534 |
| Clearance |
0.096 |
0.144 |
0.214 |
0.267 |
0.336 |
0.376 |
| Chlorophyll a |
16.37 |
13.18 |
10.32 |
9.66 |
8.53 |
7.08 |
| Clearance |
0.097 |
0.273 |
0.431 |
0.467 |
0.530 |
0.609 |
Sum up: according to the result in embodiment 1, comparative example 1, comparative example 2, discovery mixed flow air-float technology, in removal effect, is compared conventional concurrent, adverse current air-float technology, and outlet effect is good, and medicament PAFC is adding less, and cleaning water is high, effective.
The utility model takes full advantage of the advantage in downflow system air flotation pool and counter-current air floating pond, integrate adverse current collision and following current adhesion process, relatively existing air-float technology, extend the collision adhesion time of microbubble and suspended substance, the former glassware for drinking water of different quality is had to good treatment effect, strengthened the ability of technique reply change of water quality, can not only remove turbidity particulate matter, and there is the good algae organic matter removal ability of removing, this Technology advantage is summarized as follows:
1) collision efficiency of microbubble-suspended substance improves greatly: the collision Yuan Shui of exposure chamber flows from the top down, the microbubble that reliever produces moves from bottom to top, both rely on waterpower mixing effect to complete the abundant collision of microbubble and suspended substance, in collision there is waterpower demixing phenomenon in exposure chamber, be followed successively by from top to bottom scum layer, suspended layer and transition layer, the collision effect of suspended layer microbubble and suspended substance is best.
2) collection efficiency of particulate matter is improved greatly: under the effect of water impact, enter and adhere to exposure chamber through the water quality of collision exposure chamber's preliminary treatment, reliever produces microbubble and moves upward, under the effect of laminar flow regime flow force, complete effective adhesion of microbubble and suspended substance, exposure chamber is divided into two-stage, extend microbubble and suspended substance duration of contact, strengthened effluent quality.
3) adaptive faculty raw water quality being changed significantly strengthens: valve is all set can realizes the flexible switching of downflow system air-float technology, counter-current air floating technique and adverse current-counter-current air floating technique on dissolved air release gas manifold, strengthen the adaptive faculty of air flotation pool to change of water quality, strengthened the ability of technique reply change of water quality risk.
4) effectively reduce flocculant dosage: rely on hydraulic action to mix fully at collision exposure chamber microbubble with suspended substance, in experimentation, find in air supporting process, needn't form flco large as precipitating action, collide in exposure chamber copolymerizing and air-float phenomenon obvious simultaneously.