CN203582552U - Nickel ion resin adsorption device - Google Patents
Nickel ion resin adsorption device Download PDFInfo
- Publication number
- CN203582552U CN203582552U CN201320760420.0U CN201320760420U CN203582552U CN 203582552 U CN203582552 U CN 203582552U CN 201320760420 U CN201320760420 U CN 201320760420U CN 203582552 U CN203582552 U CN 203582552U
- Authority
- CN
- China
- Prior art keywords
- reaction tube
- rotating disk
- turntable
- reaction cylinder
- bracket
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 239000011347 resin Substances 0.000 title claims abstract description 13
- 229920005989 resin Polymers 0.000 title claims abstract description 13
- 229910001453 nickel ion Inorganic materials 0.000 title claims abstract description 12
- 238000001179 sorption measurement Methods 0.000 title abstract 2
- 238000006243 chemical reaction Methods 0.000 claims abstract description 79
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 238000010521 absorption reaction Methods 0.000 claims description 10
- 230000013011 mating Effects 0.000 claims description 6
- 239000010865 sewage Substances 0.000 abstract description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- 230000008676 import Effects 0.000 description 15
- 238000000034 method Methods 0.000 description 12
- 238000005342 ion exchange Methods 0.000 description 8
- 238000001556 precipitation Methods 0.000 description 7
- 238000005189 flocculation Methods 0.000 description 6
- 230000016615 flocculation Effects 0.000 description 6
- 239000013049 sediment Substances 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 5
- 238000005649 metathesis reaction Methods 0.000 description 5
- 230000020477 pH reduction Effects 0.000 description 5
- 239000001117 sulphuric acid Substances 0.000 description 5
- 235000011149 sulphuric acid Nutrition 0.000 description 5
- 230000008569 process Effects 0.000 description 4
- 238000000746 purification Methods 0.000 description 4
- 239000002351 wastewater Substances 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 238000009713 electroplating Methods 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000003729 cation exchange resin Substances 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
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- Separation Of Suspended Particles By Flocculating Agents (AREA)
Abstract
The utility model discloses a nickel ion resin adsorption device which comprises a turntable, wherein the outer edge of the turntable is of an involute gear shape and is in meshing connection with a driving gear; the lower side of the driving gear is connected with a first power device; a rotary shaft is arranged at the center of the turntable; the lower side of the rotary shaft is mounted on the base through a bearing; five reaction cylinders are annually distributed at equal intervals at the upper part of the turntable along the center; an annular reaction cylinder roller slot is formed at the bottom of each reaction cylinder; a turntable roller slot matched with the reaction cylinder roller slot is also formed in the corresponding position on the turntable below each reaction cylinder; a roller is arranged between the reaction cylinder roller slot and the turntable roller slot; a reaction cylinder rotary shaft is vertically arranged at the bottom center of the reaction cylinder; one end of the reaction cylinder rotary shaft is fixedly connected with the bottom center of the reaction cylinder, and the other end penetrates through the turntable and is connected with a second power device below the turntable. The device disclosed by the utility model achieves the aims of labor saving, remarkable improvement of sewage treatment efficiency, accurate control, small floor area and space saving.
Description
Technical field
The invention belongs to technology for treating industrial waste water field, relate to a kind of nickel ion resin absorption device.
background technology
In China, electroplating wastewater processing was through the development of more than 50 years, main treatment process has: chemical method, ion exchange method, electrolytic process and membrane separation technique etc., in these treatment processs, ion exchange method be between ion in liquid phase and solid phase intermediate ion, carry out a kind of reversibility chemical reaction, some ion in liquid phase is when comparatively ion-exchange solid is liked, just can be by ion-exchange solid absorption, for maintaining the electric neutrality of the aqueous solution, so ion-exchange solid must disengage in ion back dissolving liquid of equal value.Ion exchange method has effluent quality good, recyclable useful matter, and technique is simple, less investment, the advantage such as effective.In wastewater treatment, ion-exchange is mainly used in reclaiming and remove the heavy metal ion such as nickel in waste water, copper, zinc.In recent years, along with people are more and more denseer to the interest of electroplating wastewater resource, ion exchange technique causes people's attention once again as the deep treatment method of electroplating wastewater.And existing hydrogen type cation exchange resin is slow except the equipment of nickel impurity exists speed of response, need human assistance many, waste of manpower, can not discharge precipitation automatically, cleans the problem of trouble.
Summary of the invention
For above-mentioned situation, the utility model provides a kind of nickel ion resin absorption device, adopt rotary-disk type structure to replace traditional linear type structure, what adopt that some reaction tubes carry out continuous rotation advanceable completes alkalinisation treatment successively, replacement(metathesis)reaction, after acidification, generate the steps such as precipitation, reaction tube on rotating disk also can rotate, can accelerate speed of reaction, automatically remove flocculation sediment, automated job, in a large amount of sewage disposals, use, reach and save manually, greatly improve sewage treating efficiency, control precisely, the little space-saving object of floor space, simultaneously, in reaction process, flocculation sediment and discharge water purification carry out simultaneously, saved greatly the sewage disposal cycle, improved sewage treating efficiency.
To achieve these goals, the technical solution of the utility model is as follows:
Nickel ion resin absorption device, comprise rotating disk, rotating disk outer rim becomes involute tooth colyliform, rotating disk outer rim and driving toothed gear are connected with a joggle, driving toothed gear below is connected with the first power set, center of turntable is provided with turning axle, turning axle below is arranged on base by bearing, rotating disk top is along center of circle annular five reaction tubes that have been spacedly distributed, reaction tube bottom is provided with annular reaction tube roller groove, on the rotating disk of reaction tube below, corresponding position is also provided with the rotating disk roller groove mating with reaction tube roller groove, between described reaction tube roller groove and rotating disk roller groove, be provided with roller, described reaction tube bottom centre is vertically provided with reaction tube rotating shaft, reaction tube rotating shaft one end is fixedly connected with reaction tube bottom centre, the other end runs through rotating disk and is connected with the second power set of rotating disk below.
Further, be provided with two groups of bearings between described reaction tube rotating shaft and rotating disk, described bearing is taper roller bearing or angular contact ball bearing.
Further, the outer side wall of described reaction tube is arranged with bracket, described bracket is annular, bracket bottom is fixedly mounted on rotating disk, bracket inwall is provided with the projection of a ring shape, on reaction tube, be provided with the groove mating with projection, running fit between described bracket and reaction tube with the corresponding position of projection.
Further, described reaction tube bottom is provided with blow-off line, and blow-off line is provided with wash water valve.
Further, five described reaction tubes, wherein front four reaction tubes of sequence top is respectively equipped with sewage import, sodium hydroxide import, sulphuric acid soln import, pure water inlet clockwise; Sewage import, sodium hydroxide import, sulphuric acid soln import, pure water inlet are corresponding respectively enters sewage station, alkalinisation treatment replacement(metathesis)reaction station, acidification generates precipitation station, water purification is discharged station, the 5th reaction tube position of sequence remains flocculation sediment for discharging clockwise, and the station cleaning.After the 5th station completes, clean reaction tube rotates again to entering sewage station, circulates.
The utility model has the advantages that: adopt rotary-disk type structure to replace traditional linear type structure, what adopt that some reaction tubes carry out continuous rotation advanceable completes alkalinisation treatment successively, replacement(metathesis)reaction, after acidification, generate the steps such as precipitation, reaction tube on rotating disk also can rotate, can accelerate speed of reaction, automatically remove flocculation sediment, automated job, in a large amount of sewage disposals, use, reach and save manually, greatly improve sewage treating efficiency, control precisely, the little space-saving object of floor space, simultaneously, in reaction process, flocculation sediment and discharge water purification carry out simultaneously, saved greatly the sewage disposal cycle, improved sewage treating efficiency.
Accompanying drawing explanation
Fig. 1 is that master of the present utility model looks schematic diagram.
Fig. 2 is schematic top plan view of the present utility model.
In the drawings: 1-rotating disk; 2-driving toothed gear; 3-the first power set; 4-turning axle; 5-base; 6-reaction tube; 7-roller; The rotating shaft of 8-reaction tube; 9-the second power set; 10-bracket; 11-projection; 12-bearing.
Embodiment
For technique means, creation characteristic that the utility model is realized, reach object and effect is easy to understand, below in conjunction with concrete diagram, further set forth the utility model.
Referring to Fig. 1 ~ Fig. 2, nickel ion resin absorption device, comprise rotating disk, rotating disk outer rim becomes involute tooth colyliform, rotating disk outer rim and driving toothed gear are connected with a joggle, driving toothed gear below is connected with the first power set, center of turntable is provided with turning axle, turning axle below is arranged on base by bearing, rotating disk top is along center of circle annular five reaction tubes that have been spacedly distributed, reaction tube bottom is provided with annular reaction tube roller groove, on the rotating disk of reaction tube below, corresponding position is also provided with the rotating disk roller groove mating with reaction tube roller groove, between described reaction tube roller groove and rotating disk roller groove, be provided with roller, described reaction tube bottom centre is vertically provided with reaction tube rotating shaft, reaction tube rotating shaft one end is fixedly connected with reaction tube bottom centre, the other end runs through rotating disk and is connected with the second power set of rotating disk below.
Further, described the first power set is connected with control device.Described control device can be controlled the velocity of rotation of the first power set, start-stop time, the parametric variables such as interval time.
Further, be provided with two groups of bearings between described reaction tube rotating shaft and rotating disk, described bearing is taper roller bearing or angular contact ball bearing.
Further, the outer side wall of described reaction tube is arranged with bracket, described bracket is annular, bracket bottom is fixedly mounted on rotating disk, bracket inwall is provided with the projection of a ring shape, on reaction tube, be provided with the groove mating with projection, running fit between described bracket and reaction tube with the corresponding position of projection.
Further, described reaction tube bottom is provided with blow-off line, and blow-off line is provided with wash water valve.
Further, five described reaction tubes, wherein front four reaction tubes of sequence top is respectively equipped with sewage import, sodium hydroxide import, sulphuric acid soln import, pure water inlet clockwise; Sewage import, sodium hydroxide import, sulphuric acid soln import, pure water inlet are corresponding respectively enters sewage station, alkalinisation treatment replacement(metathesis)reaction station, acidification generates precipitation station, water purification is discharged station, the 5th reaction tube position of sequence remains flocculation sediment for discharging clockwise, and the station cleaning.After the 5th station completes, clean reaction tube rotates again to entering sewage station, circulates.
Further, in described sewage import, sodium hydroxide import, sulphuric acid soln import, be respectively equipped with under meter.
Except in nickel process, as follows at the chemical principle of alkalinisation treatment replacement(metathesis)reaction station and acidification generation precipitation station:
Hydrogen negative resin be A:
A-H+NaOH——A-Na+H2O
A-Na+Ni——A-Ni+Na
A-Ni+H2SO4——A-H+Ni2SO4
Ni2SO4 is precipitation, and removing Hydrogen negative resin is the nickel ion in A.
More than show and described ultimate principle of the present utility model, principal character and advantage of the present utility model.The technician of the industry should understand; the utility model is not restricted to the described embodiments; what in above-described embodiment and specification sheets, describe is principle of the present utility model; under the prerequisite that does not depart from the utility model spirit and scope, the utility model also has various changes and modifications, and these changes and improvements all fall in claimed scope of the present utility model.The protection domain that the utility model requires is defined by appending claims and equivalent thereof.
Claims (4)
1. nickel ion resin absorption device, it is characterized in that, comprise rotating disk, rotating disk outer rim becomes involute tooth colyliform, rotating disk outer rim and driving toothed gear are connected with a joggle, driving toothed gear below is connected with the first power set, center of turntable is provided with turning axle, turning axle below is arranged on base by bearing, rotating disk top is along center of circle annular five reaction tubes that have been spacedly distributed, reaction tube bottom is provided with annular reaction tube roller groove, on the rotating disk of reaction tube below, corresponding position is also provided with the rotating disk roller groove mating with reaction tube roller groove, between described reaction tube roller groove and rotating disk roller groove, be provided with roller, described reaction tube bottom centre is vertically provided with reaction tube rotating shaft, reaction tube rotating shaft one end is fixedly connected with reaction tube bottom centre, the other end runs through rotating disk and is connected with the second power set of rotating disk below.
2. nickel ion resin absorption device according to claim 1, is characterized in that, is provided with two groups of bearings between described reaction tube rotating shaft and rotating disk, and described bearing is taper roller bearing or angular contact ball bearing.
3. nickel ion resin absorption device according to claim 1, it is characterized in that, the outer side wall of described reaction tube is arranged with bracket, described bracket is annular, bracket bottom is fixedly mounted on rotating disk, bracket inwall is provided with the projection of a ring shape, on reaction tube, is provided with the groove mating with projection, running fit between described bracket and reaction tube with the corresponding position of projection.
4. nickel ion resin absorption device according to claim 1, is characterized in that, described reaction tube bottom is provided with blow-off line, and blow-off line is provided with wash water valve.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201320760420.0U CN203582552U (en) | 2013-11-28 | 2013-11-28 | Nickel ion resin adsorption device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201320760420.0U CN203582552U (en) | 2013-11-28 | 2013-11-28 | Nickel ion resin adsorption device |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN203582552U true CN203582552U (en) | 2014-05-07 |
Family
ID=50580502
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201320760420.0U Expired - Fee Related CN203582552U (en) | 2013-11-28 | 2013-11-28 | Nickel ion resin adsorption device |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN203582552U (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114984753A (en) * | 2022-06-29 | 2022-09-02 | 山东盛瑞达环境科技有限公司 | Accurate ammonia device that spouts of waste gas denitration |
| CN115121213A (en) * | 2022-07-06 | 2022-09-30 | 江苏洁欧康科技有限公司 | Rotary series circulating calcium exchange reaction device and method |
-
2013
- 2013-11-28 CN CN201320760420.0U patent/CN203582552U/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114984753A (en) * | 2022-06-29 | 2022-09-02 | 山东盛瑞达环境科技有限公司 | Accurate ammonia device that spouts of waste gas denitration |
| CN114984753B (en) * | 2022-06-29 | 2023-09-22 | 山东盛瑞达环境科技有限公司 | Accurate ammonia device that spouts of waste gas denitration |
| CN115121213A (en) * | 2022-07-06 | 2022-09-30 | 江苏洁欧康科技有限公司 | Rotary series circulating calcium exchange reaction device and method |
| CN115121213B (en) * | 2022-07-06 | 2023-11-10 | 江苏洁欧康科技有限公司 | Rotary tandem circulation calcium exchange reaction device and method |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20140507 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |