CN203192455U - A flame-retardant and fire-resistant marine overall shielded instrument cable - Google Patents

A flame-retardant and fire-resistant marine overall shielded instrument cable Download PDF

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CN203192455U
CN203192455U CN201320141416.6U CN201320141416U CN203192455U CN 203192455 U CN203192455 U CN 203192455U CN 201320141416 U CN201320141416 U CN 201320141416U CN 203192455 U CN203192455 U CN 203192455U
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flame
retardant
cable core
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fire
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李永江
陆云春
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Jiangsu Yuanyang Dongze Cable Co Ltd
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Abstract

本实用新型涉及一种阻燃耐火船用整体屏蔽仪表电缆,绞合铜导体外周挤包有阻燃耐火乙丙橡胶绝缘层构成绝缘线芯,绝缘线芯两两绞合形成对绞线对,对绞线对的缝隙填充有阻燃非吸湿性纤维填芯,多组对绞线对绞合构成缆芯,缆芯的外周由内向外依次包裹有低强度无纺布纵包层、内护套和铜箔聚酯复合带屏蔽层,铜箔聚酯复合带屏蔽层的内侧设有镀锡绞合铜丝引流线,铜箔聚酯复合带屏蔽层的外周包覆有铠装编织层,铠装编织层的外周挤包有外护套。低强度无纺布纵包层完全与缆芯的外形相吻合,消除了低强度无纺布纵包层与缆芯之间的空隙,便于阻止火焰向内绵延;同时确保内护套与绝缘线芯之间不粘连,便于施工过程剥除护套时不伤害绝缘线芯。

Figure 201320141416

The utility model relates to a flame-retardant and fire-resistant marine overall shielded instrument cable. The outer periphery of the stranded copper conductor is extruded with a flame-retardant and fire-resistant ethylene-propylene rubber insulating layer to form an insulating core, and the insulating cores are twisted in pairs to form a pair of twisted wires. The gaps of the twisted wire pairs are filled with flame-retardant non-hygroscopic fiber cores, and multiple pairs of twisted wire pairs are twisted to form a cable core. and copper foil polyester composite tape shielding layer, the inner side of the copper foil polyester composite tape shielding layer is provided with tinned stranded copper wire drain wire, the outer periphery of the copper foil polyester composite tape shielding layer is covered with an armored braiding layer, and the armored The outer periphery of the braided layer is extruded with an outer sheath. The longitudinal cladding of low-strength non-woven fabric completely conforms to the shape of the cable core, eliminating the gap between the longitudinal cladding of low-strength non-woven fabric and the cable core, which is convenient to prevent the flame from extending inward; There is no adhesion between the cores, so that the insulated cores will not be damaged when the sheath is stripped off during the construction process.

Figure 201320141416

Description

一种阻燃耐火船用整体屏蔽仪表电缆A flame-retardant and fire-resistant marine overall shielded instrument cable

技术领域 technical field

本实用新型涉及一种整体屏蔽仪表电缆,特别涉及一种阻燃耐火船用整体屏蔽仪表电缆。 The utility model relates to an integrally shielded instrument cable, in particular to an integrally shielded instrument cable for flame-retardant and fire-resistant ships.

背景技术 Background technique

目前耐火船用整体屏蔽仪表电缆一般采用云母带绕包导体、矿物绝缘以及挤包耐火硅橡胶外编织玻璃纤维丝组合绝缘等几种结构,但这几种结构的耐火电缆又有着很大的弊端: At present, fire-resistant marine overall shielded instrument cables generally adopt several structures such as mica tape wrapped conductor, mineral insulation, and extruded refractory silicone rubber outer braided glass fiber wire combination insulation, etc., but these types of fire-resistant cables have great disadvantages:

云母带绕包耐火电缆是在导体外重叠绕包云母带,由于船用电缆芯数多,采用云母带绕包会造成成品电缆外径大、重量重,不利于船舶负载。 Mica tape wrapped fire-resistant cables are wrapped with mica tapes overlapping outside the conductor. Due to the large number of cores in marine cables, wrapping with mica tapes will result in large outer diameter and heavy weight of the finished cable, which is not conducive to ship loads.

矿物绝缘电缆的显著特点是在导体外面包覆一层无机耐火矿物绝缘层达到耐火目的,耐火性能优异,但其敷设效率低下,弯曲性能很差,无法达到船舶狭小空间对电缆的柔韧性要求,并且电缆封头终端制作工艺复杂,电缆造价昂贵。 The remarkable feature of mineral insulated cables is that the conductor is covered with a layer of inorganic refractory mineral insulating layer to achieve fire resistance. It has excellent fire resistance, but its laying efficiency is low, and its bending performance is very poor, which cannot meet the flexibility requirements of the cable in the narrow space of the ship. Moreover, the manufacturing process of the cable head terminal is complicated, and the cable manufacturing cost is expensive.

耐火硅橡胶外编织玻璃纤维丝组合绝缘的耐火电缆,其耐火层为双重复合结构,内层为挤包可陶瓷化硅橡胶耐火层,外层为阻燃玻璃纤维丝编织层。可陶瓷化硅橡胶的基材是硅橡胶,主要成分是有机硅和无机二氧化硅,并配合陶瓷粉和环保型耐火剂。其在常温下柔软、加工性能优异,而在燃烧温度超过600℃时,就会在很短的时间内烧结生成坚硬的陶瓷状壳体。陶瓷状壳体受高温火焰煅烧生成可耐温不低于1100℃的二氧化硅坚硬陶瓷,隔绝阻挡火焰继续燃烧,从而起到防火的作用。但可陶瓷化硅橡胶分子之间引力小,且为非结晶结构,物理机械力学性能很差,根据GJB1916《舰船用低烟电缆和软线通用规范》以及JIS C3410《船用电气装备用电缆和软线》的规定,必须在硅橡胶绝缘外编织耐火玻璃纤维丝增强力学性能,使得成品电缆结构和生产工艺复杂;并且硅橡胶耐高温水蒸气性能和耐酸碱性能差,不利于船舶装备多酸碱腐蚀环境使用;另外硅橡胶价格昂贵,不符合产品经济性要求。 Fire-resistant silicone rubber outer braided glass fiber wire combined insulation fire-resistant cable, the fire-resistant layer is a double composite structure, the inner layer is extruded ceramizable silicone rubber refractory layer, and the outer layer is flame-retardant glass fiber wire braided layer. The base material of ceramizable silicone rubber is silicone rubber, the main components are organic silicon and inorganic silicon dioxide, and it is combined with ceramic powder and environmentally friendly refractory agent. It is soft at room temperature and has excellent processing performance, but when the combustion temperature exceeds 600°C, it will be sintered in a short time to form a hard ceramic shell. The ceramic-shaped shell is calcined by high-temperature flames to produce hard silica ceramics with a temperature resistance of not less than 1100°C, which can insulate and block the flame from continuing to burn, thus playing the role of fire prevention. However, the gravitational force between the ceramizable silicone rubber molecules is small, and it has an amorphous structure, and its physical and mechanical properties are very poor. According to the provisions of "Flexible Cord", refractory glass fiber wire must be braided outside the silicone rubber insulation to enhance the mechanical properties, which makes the structure and production process of the finished cable complicated; and the high temperature water vapor resistance and acid and alkali resistance of silicone rubber are poor, which is not conducive to the ship's equipment. It is used in acid and alkali corrosion environment; in addition, silicone rubber is expensive and does not meet the economic requirements of the product.

缆芯外周如果直接挤包内护套,内护套会粘接在绝缘线芯的表面,造成施工时很难剥除,在用电工刀切割时容易伤害绝缘线芯;普通电缆在缆芯外周沿缆芯圆周方向缠绕有绕包带,由于一根绕包带沿缆芯圆周方向连续缠绕,缠绕时绕包带的张力比较大,相邻两绝缘线芯之间的绕包带沿两绝缘线芯公切线的方向缠绕,因此在绕包带与绝缘线芯之间产生空隙,由于绕包带绷得很紧,绕包带外周挤包内护套时无法消除绕包带内侧的空隙,而该空隙可以成为火焰向前绵延传递的通道。 If the outer periphery of the cable core is directly extruded with the inner sheath, the inner sheath will be bonded to the surface of the insulated wire core, making it difficult to remove during construction, and it is easy to damage the insulated wire core when cutting with an electrician's knife; A wrapping tape is wound along the circumferential direction of the cable core. Since a wrapping tape is continuously wound along the circumferential direction of the cable core, the tension of the wrapping tape is relatively large during winding, and the wrapping tape between two adjacent insulated cores is The wire core is wound in the direction of the common tangent line, so there is a gap between the wrapping tape and the insulated core. Since the wrapping tape is tightly stretched, the inner sheath cannot be eliminated when the wrapping tape is wrapped around the outer periphery of the wrapping tape. And this gap can become a channel for the flame to spread forward.

实用新型内容 Utility model content

本实用新型的目的在于,克服现有技术中存在的问题,提供一种阻燃耐火船用整体屏蔽仪表电缆,阻燃性能好,内护套与缆芯之间不粘连,便于施工过程剥除护套时不伤害绝缘线芯。 The purpose of this utility model is to overcome the problems existing in the prior art, and provide a flame-retardant and fire-resistant marine overall shielded instrument cable, which has good flame-retardant performance, no adhesion between the inner sheath and the cable core, and is convenient for stripping the sheath during construction. Do not damage the insulated wire core when covering.

为实现以上目的,本实用新型所提供的一种阻燃耐火船用整体屏蔽仪表电缆,绞合铜导体外周挤包有阻燃耐火乙丙橡胶绝缘层构成绝缘线芯,绝缘线芯两两绞合形成对绞线对,所述对绞线对的缝隙填充有阻燃非吸湿性纤维填芯,各所述对绞线对采用各不相同的绞合节距,多组所述对绞线对绞合构成缆芯,所述缆芯的外周包裹有低强度无纺布纵包层,所述低强度无纺布纵包层的外周挤包有内护套,所述内护套的外周绕包有铜箔聚酯复合带屏蔽层且铜箔面向内,所述铜箔聚酯复合带屏蔽层的内侧设有镀锡绞合铜丝引流线,所述镀锡绞合铜丝引流线贯穿缆芯全长度并与铜箔面紧靠在一起;所述铜箔聚酯复合带屏蔽层的外周包覆有铠装编织层,所述铠装编织层的外周挤包有外护套。 In order to achieve the above objectives, the utility model provides a flame-retardant and fire-resistant marine overall shielded instrument cable. The outer periphery of the stranded copper conductor is extruded with a flame-retardant and fire-resistant ethylene-propylene rubber insulating layer to form an insulating core, and the insulating cores are twisted in pairs. A pair of twisted wires is formed, and the gaps of the pair of twisted wires are filled with a flame-retardant non-hygroscopic fiber core, and each pair of the twisted wires adopts a different twisting pitch, and multiple sets of the twisted wire pairs Twisted to form a cable core, the outer periphery of the cable core is wrapped with a low-strength non-woven longitudinal cladding, the outer periphery of the low-strength non-woven longitudinal cladding is extruded with an inner sheath, and the outer periphery of the inner sheath is wrapped Wrapped with a copper foil polyester composite tape shielding layer and the copper foil faces inward, the inner side of the copper foil polyester composite tape shielding layer is provided with a tinned stranded copper wire drainage wire, and the tinned stranded copper wire drainage wire runs through The entire length of the cable core is close to the copper foil surface; the outer periphery of the copper foil polyester composite tape shielding layer is covered with an armored braided layer, and the outer periphery of the armored braided layer is extruded with an outer sheath.

相对于现有技术,本实用新型取得了以下有益效果:本实用新型的电缆采用低强度无纺布纵包层,纵包的特点只能是将一定宽度的无纺布分割成若干段,沿缆芯轴线方向一段接一段包裹,低强度无纺布纵包层在圆周方向的张力非常小,挤包内护套时很容易将低强度无纺布纵包层压在绝缘线芯外表面,即低强度无纺布纵包层的形状完全与绝缘线芯的外形相吻合,消除了低强度无纺布纵包层与绝缘线芯之间的空隙,便于燃烧条件下阻止火焰向内部的绵延传递,并可增强抵御潮气的浸渍;同时低强度无纺布纵包层可以确保内护套与绝缘线芯之间不粘连,便于施工过程剥除护套时不伤害绝缘线芯;屏蔽层在内护套外保证了屏蔽不受内护套向内的压力,保证了屏蔽材料中铜箔的整体连续性,有利于屏蔽效果的实现。 Compared with the prior art, the utility model has achieved the following beneficial effects: the cable of the utility model adopts the longitudinal cladding of low-strength non-woven fabric, and the feature of the longitudinal cladding can only be that the non-woven fabric of a certain width is divided into several sections, along which The axial direction of the cable core is wrapped one by one. The tension of the low-strength non-woven longitudinal cladding in the circumferential direction is very small. When the inner sheath is squeezed, it is easy to press the low-strength non-woven longitudinal cladding on the outer surface of the insulating core. That is, the shape of the longitudinal cladding of the low-strength non-woven fabric completely matches the shape of the insulated wire core, eliminating the gap between the longitudinal cladding of the low-strength non-woven fabric and the insulating wire core, which is convenient for preventing the flame from extending to the inside under burning conditions transmission, and can enhance the resistance to moisture impregnation; at the same time, the low-strength non-woven longitudinal cladding can ensure that there is no adhesion between the inner sheath and the insulated wire core, so that the insulated wire core is not damaged when the sheath is stripped during the construction process; the shielding layer is in the The outside of the inner sheath ensures that the shielding is not subject to the inward pressure of the inner sheath, ensures the overall continuity of the copper foil in the shielding material, and is conducive to the realization of the shielding effect.

作为本实用新型的优选方案,所述低强度无纺布纵包层的厚度为0.05~0.1mm,沿缆芯轴线方向依次搭接纵包,每段所述低强度无纺布纵包层的宽度为缆芯直径的3.5~3.8倍。 As a preferred solution of the present utility model, the thickness of the longitudinal cladding of the low-strength non-woven fabric is 0.05-0.1mm, and the longitudinal cladding is sequentially overlapped along the axis of the cable core, and the longitudinal cladding of the low-strength non-woven fabric in each section is The width is 3.5~3.8 times the diameter of the cable core.

附图说明 Description of drawings

图1为本实用新型阻燃耐火船用整体屏蔽仪表电缆的结构示意图。 Fig. 1 is a structural schematic diagram of a flame-retardant and fire-resistant marine overall shielded instrument cable of the present invention.

图中:1.绝缘线芯;1a.绞合铜导体;1b.阻燃耐火乙丙橡胶绝缘层;2.阻燃非吸湿性纤维填芯;3.低强度无纺布纵包层;4.内护套;5.铜箔聚酯复合带屏蔽层;5a.镀锡绞合铜丝引流线; 6.铠装编织层;7.外护套。  In the figure: 1. Insulated wire core; 1a. Stranded copper conductor; 1b. Flame-retardant and fire-resistant ethylene-propylene rubber insulation layer; 2. Flame-retardant non-hygroscopic fiber core; 3. Longitudinal cladding of low-strength non-woven fabric; 4 .Inner sheath; 5. Copper foil polyester composite tape shielding layer; 5a. Tinned stranded copper wire drainage wire; 6. Armored braiding layer; 7. Outer sheath. the

具体实施方式 Detailed ways

实施例一 Embodiment one

如图1所示,本实用新型的阻燃耐火船用整体屏蔽仪表电缆,依次包括以下步骤:绞合铜导体1a外周挤包阻燃耐火乙丙橡胶绝缘层1b构成绝缘线芯1,将绝缘线芯1两两绞合形成对绞线对,对绞线对的缝隙填充有阻燃非吸湿性纤维填芯2,各对绞线对采用各不相同的绞合节距,将多组对绞线对绞合构成缆芯,在缆芯的外周包裹低强度无纺布纵包层3,然后在低强度无纺布纵包层3的外周挤包内护套4,在内护套4的外周绕包铜箔聚酯复合带屏蔽层5且铜箔面向内,铜箔聚酯复合带屏蔽层5的内侧设有镀锡绞合铜丝引流线5a,镀锡绞合铜丝引流线5a贯穿缆芯全长度并与铜箔面紧靠在一起;接着在铜箔聚酯复合带屏蔽层5的外周编织铠装编织层6,最后在铠装编织层6的外周挤包外护套7。低强度无纺布纵包层3的厚度为0.05mm,沿缆芯轴线方向依次搭接纵包,每段低强度无纺布纵包层的宽度为缆芯直径的3.5倍。内护套4与外护套7均采用氧指数不低于32的柔软性高阻燃护套料。 As shown in Figure 1, the overall shielded instrument cable for flame-retardant and fire-resistant ships of the present utility model includes the following steps in turn: extrude the outer periphery of the stranded copper conductor 1a to wrap the flame-retardant and fire-resistant ethylene-propylene rubber insulating layer 1b to form the insulating core 1, and the insulating wire The core 1 is twisted in pairs to form a pair of twisted wires, and the gap between the pair of twisted wires is filled with a flame-retardant non-hygroscopic fiber core 2, each pair of twisted wires adopts a different twisting pitch, and multiple pairs are twisted Wire pairs are twisted to form a cable core, and the outer periphery of the cable core is wrapped with a low-strength non-woven longitudinal cladding 3, and then an inner sheath 4 is extruded on the outer periphery of the low-strength non-woven longitudinal cladding 3, and the inner sheath 4 The outer circumference is wrapped with copper foil polyester composite tape shielding layer 5 and the copper foil faces inward. The inner side of the copper foil polyester composite tape shielding layer 5 is provided with a tinned stranded copper wire drain wire 5a, and a tinned stranded copper wire drain wire 5a Run through the entire length of the cable core and close to the copper foil surface; then braid the armor braid 6 on the outer periphery of the copper foil polyester composite tape shielding layer 5, and finally extrude the outer sheath 7 on the outer periphery of the armor braid 6 . The thickness of the low-strength non-woven longitudinal cladding 3 is 0.05mm, and the longitudinal cladding is sequentially overlapped along the axis of the cable core. The width of each segment of the low-strength non-woven longitudinal cladding is 3.5 times the diameter of the cable core. Both the inner sheath 4 and the outer sheath 7 are made of a flexible and highly flame-resistant sheathing material with an oxygen index not lower than 32.

其中,阻燃耐火乙丙橡胶绝缘层所用绝缘橡胶的制备步骤如下:(1)按以下组分及重量含量准备原料,三元乙丙橡胶4045M:20份;硫化剂过氧化二异丙苯(硫化剂DCP):0.5份;共硫化剂三烯丙基氰脲酸酯(共硫化剂TAC):0.2份;防老剂2-硫醇基苯并咪唑(防老剂MB):0.1份;防老剂2,2,4-三甲基-1,2-二氢化喹啉聚合体(防老剂RD):0.1份;偶联剂乙烯基三(β-甲氧基乙氧基)硅烷(硅烷偶联剂A-172):0.1份;阻燃剂氢氧化铝(即Al2O3·3H2O水合氧化铝):15份;耐火剂陶瓷玻璃粉:3份;增塑剂1000号蒸汽汽缸油:1份;填充剂微细滑石粉:6份;补强剂水合二氧化硅:4份;补强剂煅烧陶土:5份。 Among them, the preparation steps of the insulating rubber used in the flame-retardant and fire-resistant ethylene-propylene rubber insulating layer are as follows: (1) Prepare raw materials according to the following components and weight content, EPDM rubber 4045M: 20 parts; vulcanizing agent dicumyl peroxide ( Vulcanizing agent DCP): 0.5 parts; co-curing agent triallyl cyanurate (co-curing agent TAC): 0.2 parts; anti-aging agent 2-mercaptobenzimidazole (anti-aging agent MB): 0.1 parts; anti-aging agent 2,2,4-trimethyl-1,2-dihydroquinoline polymer (antiaging agent RD): 0.1 part; coupling agent vinyl tris(β-methoxyethoxy)silane (silane coupling agent A-172): 0.1 parts; flame retardant aluminum hydroxide (that is, Al 2 O 3 3H 2 O hydrated alumina): 15 parts; refractory agent ceramic glass powder: 3 parts; plasticizer No. 1000 steam cylinder oil : 1 part; filler fine talcum powder: 6 parts; reinforcing agent hydrated silica: 4 parts; reinforcing agent calcined clay: 5 parts.

(2)先将密炼机温度升至160℃,接着加入三元乙丙橡胶4045M混炼1分钟,再依次加入上述防老剂2-硫醇基苯并咪唑、防老剂2,2,4-三甲基-1,2-二氢化喹啉聚合体、偶联剂乙烯基三(β-甲氧基乙氧基)硅烷、阻燃剂氢氧化铝、耐火剂陶瓷玻璃粉、增塑剂1000号蒸汽汽缸油、填充剂微细滑石粉、补强剂水合二氧化硅和补强剂煅烧陶土,进行混炼7分钟后卸料,在干燥洁净的空间晾放24小时以上;将胶料投进温度为80℃的密炼机上再混炼2分钟,并在最后20秒加入硫化剂过氧化二异丙苯和共硫化剂三烯丙基氰脲酸酯,将混炼料上三辊开炼机进行薄通,三辊开炼机的辊距为1.5mm,打三角包和方包各四次后出片备用。 (2) First raise the temperature of the internal mixer to 160°C, then add EPDM rubber 4045M and mix for 1 minute, then add the above-mentioned anti-aging agent 2-mercaptobenzimidazole, anti-aging agent 2,2,4- Trimethyl-1,2-dihydroquinoline polymer, coupling agent vinyl tris(β-methoxyethoxy)silane, flame retardant aluminum hydroxide, fire-resistant ceramic glass powder, plasticizer 1000 No. steam cylinder oil, filler fine talc powder, reinforcing agent hydrated silica and reinforcing agent calcined clay, mixed for 7 minutes, unloaded, and left in a dry and clean space for more than 24 hours; put the rubber into Mix on an internal mixer at a temperature of 80°C for another 2 minutes, and add the vulcanizing agent dicumyl peroxide and co-vulcanizing agent triallyl cyanurate in the last 20 seconds, and put the mixed material on three rolls for kneading Machine is carried out thin pass, and the roller pitch of three-roller mill is 1.5mm, and each four times of beating triangular bag and square bag are discharged sheet standby.

所述绝缘橡胶挤出时挤橡机采用冷喂料方式,挤橡机螺杆的长径比为15:1,机身温度为55℃,机头温度90℃,模具温度为120℃,挤橡机螺杆冷却方式为水冷却,挤出模具的模芯承线长度与挤出外径之比为1: 1,模套定型段的长度为2mm。 When the insulating rubber is extruded, the extruder adopts the cold feeding method, the length-to-diameter ratio of the extruder screw is 15:1, the body temperature is 55°C, the head temperature is 90°C, and the mold temperature is 120°C. The cooling method of the machine screw is water cooling, the ratio of the length of the core line of the extrusion die to the outer diameter of the extrusion is 1: 1, and the length of the shaping section of the die sleeve is 2mm.

实施例二 Embodiment two

如图1所示,本实用新型的阻燃耐火船用整体屏蔽仪表电缆,依次包括以下步骤:绞合铜导体1a外周挤包阻燃耐火乙丙橡胶绝缘层1b构成绝缘线芯1,将绝缘线芯1两两绞合形成对绞线对,对绞线对的缝隙填充有阻燃非吸湿性纤维填芯2,各对绞线对采用各不相同的绞合节距,将多组对绞线对绞合构成缆芯,在缆芯的外周包裹低强度无纺布纵包层3,然后在低强度无纺布纵包层3的外周挤包内护套4,在内护套4的外周绕包铜箔聚酯复合带屏蔽层5且铜箔面向内,铜箔聚酯复合带屏蔽层5的内侧设有镀锡绞合铜丝引流线5a,镀锡绞合铜丝引流线5a贯穿缆芯全长度并与铜箔面紧靠在一起;接着在铜箔聚酯复合带屏蔽层5的外周编织铠装编织层6,最后在铠装编织层6的外周挤包外护套7。低强度无纺布纵包层3的厚度为0.08mm,沿缆芯轴线方向依次搭接纵包,每段低强度无纺布纵包层的宽度为缆芯直径的3.7倍。内护套4与外护套7均采用氧指数不低于32的柔软性高阻燃护套料。 As shown in Figure 1, the overall shielded instrument cable for flame-retardant and fire-resistant ships of the present utility model includes the following steps in turn: extrude the outer periphery of the stranded copper conductor 1a to wrap the flame-retardant and fire-resistant ethylene-propylene rubber insulating layer 1b to form the insulating core 1, and the insulating wire The core 1 is twisted in pairs to form a pair of twisted wires, and the gap between the pair of twisted wires is filled with a flame-retardant non-hygroscopic fiber core 2, each pair of twisted wires adopts a different twisting pitch, and multiple pairs are twisted Wire pairs are twisted to form a cable core, and the outer periphery of the cable core is wrapped with a low-strength non-woven longitudinal cladding 3, and then an inner sheath 4 is extruded on the outer periphery of the low-strength non-woven longitudinal cladding 3, and the inner sheath 4 The outer circumference is wrapped with copper foil polyester composite tape shielding layer 5 and the copper foil faces inward. The inner side of the copper foil polyester composite tape shielding layer 5 is provided with a tinned stranded copper wire drain wire 5a, and a tinned stranded copper wire drain wire 5a Run through the entire length of the cable core and close to the copper foil surface; then braid the armor braid 6 on the outer periphery of the copper foil polyester composite tape shielding layer 5, and finally extrude the outer sheath 7 on the outer periphery of the armor braid 6 . The thickness of the low-strength non-woven longitudinal cladding 3 is 0.08mm, and the longitudinal cladding is sequentially overlapped along the axis of the cable core. The width of each segment of the low-strength non-woven longitudinal cladding is 3.7 times the diameter of the cable core. Both the inner sheath 4 and the outer sheath 7 are made of a flexible and highly flame-retardant sheathing material with an oxygen index not lower than 32.

其中,阻燃耐火乙丙橡胶绝缘层所用绝缘橡胶的制备步骤如下:(1)按以下组分及重量含量准备原料,三元乙丙橡胶4045M:20份;硫化剂过氧化二异丙苯:0.55份;共硫化剂三烯丙基氰脲酸酯:0.25份;防老剂2-硫醇基苯并咪唑:0.2份;防老剂2,2,4-三甲基-1,2-二氢化喹啉聚合体:0.2份;偶联剂乙烯基三(β-甲氧基乙氧基)硅烷:0.15份;阻燃剂氢氧化铝:18份;耐火剂陶瓷玻璃粉:4份;增塑剂1000号蒸汽汽缸油:1.2份;填充剂微细滑石粉:7份;补强剂水合二氧化硅:5份;补强剂煅烧陶土:7份。 Among them, the preparation steps of the insulating rubber used in the flame-retardant and fire-resistant ethylene-propylene rubber insulating layer are as follows: (1) Prepare raw materials according to the following components and weight content, EPDM rubber 4045M: 20 parts; vulcanizing agent dicumyl peroxide: 0.55 parts; co-vulcanizing agent triallyl cyanurate: 0.25 parts; anti-aging agent 2-mercaptobenzimidazole: 0.2 parts; anti-aging agent 2,2,4-trimethyl-1,2-dihydrogenation Quinoline polymer: 0.2 parts; coupling agent vinyl tris(β-methoxyethoxy) silane: 0.15 parts; flame retardant aluminum hydroxide: 18 parts; refractory ceramic glass powder: 4 parts; plasticizer Agent No. 1000 steam cylinder oil: 1.2 parts; filler fine talcum powder: 7 parts; reinforcing agent hydrated silica: 5 parts; reinforcing agent calcined clay: 7 parts.

(2)先将密炼机温度升至170℃,接着加入三元乙丙橡胶4045M混炼1.2分钟,再依次加入上述防老剂2-硫醇基苯并咪唑、防老剂2,2,4-三甲基-1,2-二氢化喹啉聚合体、偶联剂乙烯基三(β-甲氧基乙氧基)硅烷、阻燃剂氢氧化铝、耐火剂陶瓷玻璃粉、增塑剂1000号蒸汽汽缸油、填充剂微细滑石粉、补强剂水合二氧化硅和补强剂煅烧陶土,进行混炼7.5分钟后卸料,在干燥洁净的空间晾放24小时以上;将胶料投进温度为90℃的密炼机上再混炼2.5分钟,并在最后20秒加入硫化剂过氧化二异丙苯和共硫化剂三烯丙基氰脲酸酯,将混炼料上三辊开炼机进行薄通,三辊开炼机的辊距为1.8mm,打三角包和方包各四次后出片备用。 (2) First raise the temperature of the internal mixer to 170°C, then add EPDM rubber 4045M and mix for 1.2 minutes, then add the above-mentioned anti-aging agent 2-mercaptobenzimidazole, anti-aging agent 2,2,4- Trimethyl-1,2-dihydroquinoline polymer, coupling agent vinyl tris(β-methoxyethoxy)silane, flame retardant aluminum hydroxide, fire-resistant ceramic glass powder, plasticizer 1000 No. steam cylinder oil, filler fine talc powder, reinforcing agent hydrated silica and reinforcing agent calcined clay, mixed for 7.5 minutes, unloaded, and left in a dry and clean space for more than 24 hours; put the rubber into Mix on the internal mixer at 90°C for another 2.5 minutes, add the vulcanizing agent dicumyl peroxide and co-vulcanizing agent triallyl cyanurate in the last 20 seconds, and put the mixed material on three rolls for kneading Machine is carried out thin pass, and the roller pitch of three-roller mill is 1.8mm, and each four times of beating triangular bag and square bag are discharged sheet standby.

所述绝缘橡胶挤出时挤橡机采用冷喂料方式,挤橡机螺杆的长径比为18:1,机身温度为60℃,机头温度95℃,模具温度为125℃,挤橡机螺杆冷却方式为水冷却,挤出模具的模芯承线长度与挤出外径之比为1:1.1,模套定型段的长度为3mm。 When the insulating rubber is extruded, the extruder adopts the cold feeding method, the length-to-diameter ratio of the extruder screw is 18:1, the body temperature is 60°C, the head temperature is 95°C, and the mold temperature is 125°C. The cooling method of the machine screw is water cooling, the ratio of the length of the core support line of the extrusion mold to the outer diameter of the extrusion is 1:1.1, and the length of the shaping section of the mold sleeve is 3mm.

实施例三 Embodiment three

如图1所示,本实用新型的阻燃耐火船用整体屏蔽仪表电缆,依次包括以下步骤:绞合铜导体1a外周挤包阻燃耐火乙丙橡胶绝缘层1b构成绝缘线芯1,将绝缘线芯1两两绞合形成对绞线对,对绞线对的缝隙填充有阻燃非吸湿性纤维填芯2,各对绞线对采用各不相同的绞合节距,将多组对绞线对绞合构成缆芯,在缆芯的外周包裹低强度无纺布纵包层3,然后在低强度无纺布纵包层3的外周挤包内护套4,在内护套4的外周绕包铜箔聚酯复合带屏蔽层5且铜箔面向内,铜箔聚酯复合带屏蔽层5的内侧设有镀锡绞合铜丝引流线5a,镀锡绞合铜丝引流线5a贯穿缆芯全长度并与铜箔面紧靠在一起;接着在铜箔聚酯复合带屏蔽层5的外周编织铠装编织层6,最后在铠装编织层6的外周挤包外护套7。低强度无纺布纵包层3的厚度为0.1mm,沿缆芯轴线方向依次搭接纵包,每段低强度无纺布纵包层的宽度为缆芯直径的3.8倍。内护套4与外护套7均采用氧指数不低于32的柔软性高阻燃护套料。 As shown in Figure 1, the overall shielded instrument cable for flame-retardant and fire-resistant ships of the present utility model includes the following steps in turn: extrude the outer periphery of the stranded copper conductor 1a to wrap the flame-retardant and fire-resistant ethylene-propylene rubber insulating layer 1b to form the insulating core 1, and the insulating wire The core 1 is twisted in pairs to form a pair of twisted wires, and the gap between the pair of twisted wires is filled with a flame-retardant non-hygroscopic fiber core 2, each pair of twisted wires adopts a different twisting pitch, and multiple pairs are twisted Wire pairs are twisted to form a cable core, and the outer periphery of the cable core is wrapped with a low-strength non-woven longitudinal cladding 3, and then an inner sheath 4 is extruded on the outer periphery of the low-strength non-woven longitudinal cladding 3, and the inner sheath 4 The outer circumference is wrapped with copper foil polyester composite tape shielding layer 5 and the copper foil faces inward. The inner side of the copper foil polyester composite tape shielding layer 5 is provided with a tinned stranded copper wire drain wire 5a, and a tinned stranded copper wire drain wire 5a Run through the entire length of the cable core and close to the copper foil surface; then braid the armor braid 6 on the outer periphery of the copper foil polyester composite tape shielding layer 5, and finally extrude the outer sheath 7 on the outer periphery of the armor braid 6 . The thickness of the low-strength non-woven longitudinal cladding 3 is 0.1 mm, and the longitudinal cladding is sequentially overlapped along the axis of the cable core. The width of each segment of the low-strength non-woven longitudinal cladding is 3.8 times the diameter of the cable core. Both the inner sheath 4 and the outer sheath 7 are made of a flexible and highly flame-retardant sheathing material with an oxygen index not lower than 32.

其中,阻燃耐火乙丙橡胶绝缘层所用绝缘橡胶的制备步骤如下:(1)按以下组分及重量含量准备原料,三元乙丙橡胶4045M:20份;硫化剂过氧化二异丙苯:0.6份;共硫化剂三烯丙基氰脲酸酯:0.3份;防老剂2-硫醇基苯并咪唑:0.3份;防老剂2,2,4-三甲基-1,2-二氢化喹啉聚合体:0.3份;偶联剂乙烯基三(β-甲氧基乙氧基)硅烷:0.2份;阻燃剂氢氧化铝:20份;耐火剂陶瓷玻璃粉:6份;增塑剂1000号蒸汽汽缸油:1.5份;填充剂微细滑石粉:8份;补强剂水合二氧化硅:7份;补强剂煅烧陶土: 8份。 Among them, the preparation steps of the insulating rubber used in the flame-retardant and fire-resistant ethylene-propylene rubber insulating layer are as follows: (1) Prepare raw materials according to the following components and weight content, EPDM rubber 4045M: 20 parts; vulcanizing agent dicumyl peroxide: 0.6 parts; co-vulcanizing agent triallyl cyanurate: 0.3 parts; anti-aging agent 2-mercaptobenzimidazole: 0.3 parts; anti-aging agent 2,2,4-trimethyl-1,2-dihydrogenation Quinoline polymer: 0.3 parts; coupling agent vinyl tris(β-methoxyethoxy) silane: 0.2 parts; flame retardant aluminum hydroxide: 20 parts; refractory ceramic glass powder: 6 parts; plasticizer Agent No. 1000 steam cylinder oil: 1.5 parts; filler fine talcum powder: 8 parts; reinforcing agent hydrated silica: 7 parts; reinforcing agent calcined clay: 8 parts.

(2)先将密炼机温度升至180℃,接着加入三元乙丙橡胶4045M混炼1.5分钟,再依次加入上述防老剂2-硫醇基苯并咪唑、防老剂2,2,4-三甲基-1,2-二氢化喹啉聚合体、偶联剂乙烯基三(β-甲氧基乙氧基)硅烷、阻燃剂氢氧化铝、耐火剂陶瓷玻璃粉、增塑剂1000号蒸汽汽缸油、填充剂微细滑石粉、补强剂水合二氧化硅和补强剂煅烧陶土,进行混炼8分钟后卸料,在干燥洁净的空间晾放24小时以上;将胶料投进温度为100℃的密炼机上再混炼3分钟,并在最后20秒加入硫化剂过氧化二异丙苯和共硫化剂三烯丙基氰脲酸酯,将混炼料上三辊开炼机进行薄通,三辊开炼机的辊距为2mm,打三角包和方包各四次后出片备用。 (2) First raise the temperature of the internal mixer to 180°C, then add EPDM rubber 4045M and mix for 1.5 minutes, then add the above-mentioned anti-aging agent 2-mercaptobenzimidazole, anti-aging agent 2,2,4- Trimethyl-1,2-dihydroquinoline polymer, coupling agent vinyl tris(β-methoxyethoxy)silane, flame retardant aluminum hydroxide, fire-resistant ceramic glass powder, plasticizer 1000 No. steam cylinder oil, filler fine talc powder, reinforcing agent hydrated silica and reinforcing agent calcined clay, mixed for 8 minutes, unloaded, and left in a dry and clean space for more than 24 hours; put the rubber into Mix on an internal mixer at a temperature of 100°C for another 3 minutes, add the vulcanizing agent dicumyl peroxide and co-vulcanizing agent triallyl cyanurate in the last 20 seconds, and put the mixed material on three rolls for kneading Machine is carried out thin pass, and the roller pitch of three-roller mill is 2mm, and each four times of beating triangular bag and square bag are discharged sheet for subsequent use.

所述绝缘橡胶挤出时挤橡机采用冷喂料方式,挤橡机螺杆的长径比为20:1,机身温度为65℃,机头温度100℃,模具温度为130℃,挤橡机螺杆冷却方式为水冷却,挤出模具的模芯承线长度与挤出外径之比为1:1.2,模套定型段的长度为4mm。 When the insulating rubber is extruded, the extruder adopts the cold feeding method, the length-to-diameter ratio of the extruder screw is 20:1, the body temperature is 65°C, the head temperature is 100°C, and the mold temperature is 130°C. The cooling method of the machine screw is water cooling, the ratio of the length of the core line of the extrusion mold to the outer diameter of the extrusion is 1:1.2, and the length of the mold sleeve shaping section is 4mm.

对实施例一至实施例三中绝缘橡胶老化前机械性能测试结果如表1: The mechanical performance test results before aging of the insulating rubber in Examples 1 to 3 are shown in Table 1:

表 1 Table 1

Figure DEST_PATH_IMAGE001
Figure DEST_PATH_IMAGE001

对实施例一至实施例三中绝缘橡胶烘箱老化后的机械性能测试结果如表2,老化条件:温度135±2℃,时间:168h。 Table 2 shows the mechanical performance test results of the insulating rubber ovens in Examples 1 to 3. Aging conditions: temperature 135±2° C., time: 168 hours.

表 2 Table 2

Figure DEST_PATH_IMAGE002
Figure DEST_PATH_IMAGE002

对实施例一至实施例三中绝缘橡胶空气弹老化后的机械性能测试结果如表3,老化条件:温度127±1℃,时间40h,压力56 N/mm2。 Table 3 shows the mechanical performance test results of the insulating rubber air elastics in Examples 1 to 3. Aging conditions: temperature 127±1°C, time 40h, pressure 56 N/mm2.

表 3 table 3

Figure DEST_PATH_IMAGE003
Figure DEST_PATH_IMAGE003

对实施例一至实施例三中绝缘橡胶的绝缘电阻(20℃时)测试结果如表4所示。 Table 4 shows the test results of the insulation resistance (at 20° C.) of the insulating rubber in Examples 1 to 3.

表 4 Table 4

Figure DEST_PATH_IMAGE004
Figure DEST_PATH_IMAGE004

对实施例一至实施例三中绝缘橡胶浸入50℃水后交流电容增加率测试结果如表5。表中记录的数值分别为第14天与第1天、第7天的差值。 Table 5 shows the test results of the AC capacitance increase rate of the insulating rubber in Examples 1 to 3 after being immersed in 50°C water. The values recorded in the table are the difference between the 14th day and the 1st day and the 7th day respectively.

表 5 table 5

Figure DEST_PATH_IMAGE005
Figure DEST_PATH_IMAGE005

实施例一至实施例三中,三元乙丙橡胶4045M优选日本三井化学株式会社生产的的“三井EPT”牌三元乙丙橡胶4045M。硫化剂过氧化二异丙苯(硫化剂DCP)可以选用烟台恒诺化工科技有限公司或上海方锐达化学品有限公司产品。共硫化剂三烯丙基氰脲酸酯(共硫化剂TAC)可以选用烟台恒诺化工科技有限公司或上海方锐达化学品有限公司产品。防老剂2-硫醇基苯并咪唑(防老剂MB)可以选用上海橡胶助剂厂有限公司或青岛特诺商贸有限公司产品。防老剂2,2,4-三甲基-1,2-二氢化喹啉聚合体(防老剂RD)可以选用江苏省海安石油化工厂或南京友好助剂化工有限责任公司的产品。偶联剂乙烯基三(β-甲氧基乙氧基)硅烷(硅烷偶联剂A-172)可以选用南京向前化工有限公司或南京锘建新材料有限公司的产品。阻燃剂氢氧化铝(即Al2O3·3H2O水合氧化铝)可以选用石家庄鑫源化工有限责任公司或深圳市宏泰基实业有限公司的产品。耐火剂陶瓷玻璃粉可以选用石家庄韵石新型建材有限公司的产品。增塑剂1000号蒸汽汽缸油可以选用盐城华齐石油制品有限公司或山东日出东方石油化工有限公司的产品。填充剂微细滑石粉选用符合《GB 15342-1994 滑石粉》标准中规定的产品。补强剂水合二氧化硅可以选用广州吉必盛科技实业有限公司或太仓市欣鸿化工有限公司的产品。补强剂煅烧陶土广州市耿达贸易有限公司或茂名市茂南金鹏瓷土厂的产品。本实用新型所用原料,除以上厂家外,均可以选用市场上其它符合要求的同类产品。 In Embodiment 1 to Embodiment 3, the EPDM 4045M is preferably "Mitsui EPT" brand EPDM 4045M produced by Mitsui Chemicals Co., Ltd. of Japan. The vulcanizing agent dicumyl peroxide (vulcanizing agent DCP) can be selected from Yantai Hengnuo Chemical Technology Co., Ltd. or Shanghai Fangruida Chemicals Co., Ltd. The co-vulcanizing agent triallyl cyanurate (co-vulcanizing agent TAC) can be selected from Yantai Hengnuo Chemical Technology Co., Ltd. or Shanghai Fangruida Chemical Co., Ltd. The anti-aging agent 2-mercaptobenzimidazole (anti-aging agent MB) can be selected from Shanghai Rubber Auxiliaries Factory Co., Ltd. or Qingdao Tenuo Trading Co., Ltd. The anti-aging agent 2,2,4-trimethyl-1,2-dihydroquinoline polymer (anti-aging agent RD) can be selected from the products of Jiangsu Haian Petrochemical Plant or Nanjing Youhao Auxiliary Chemical Co., Ltd. The coupling agent vinyl tris(β-methoxyethoxy)silane (silane coupling agent A-172) can be selected from Nanjing Qianqian Chemical Co., Ltd. or Nanjing Nuojian New Material Co., Ltd. Flame retardant aluminum hydroxide (namely Al 2 O 3 ·3H 2 O hydrated alumina) can be selected from Shijiazhuang Xinyuan Chemical Co., Ltd. or Shenzhen Hongtaiji Industrial Co., Ltd. products. The refractory ceramic glass powder can be selected from the products of Shijiazhuang Yunshi New Building Materials Co., Ltd. Plasticizer No. 1000 steam cylinder oil can be selected from Yancheng Huaqi Petroleum Products Co., Ltd. or Shandong Sunrise Dongfang Petrochemical Co., Ltd. products. The filler fine talcum powder is selected from products that meet the requirements of the "GB 15342-1994 Talc Powder" standard. The reinforcing agent hydrated silica can be selected from the products of Guangzhou Jibisheng Technology Industrial Co., Ltd. or Taicang Xinhong Chemical Co., Ltd. Reinforcing agent calcined clay is the product of Guangzhou Gengda Trading Co., Ltd. or Maoming Maonan Jinpeng Porcelain Clay Factory. The raw materials used in the utility model, except the above manufacturers, can be selected from other similar products that meet the requirements on the market.

以上所述仅为本实用新型之较佳可行实施例而已,非因此局限本实用新型的专利保护范围。除上述实施例外,本实用新型还可以有其他实施方式。凡采用等同替换或等效变换形成的技术方案,均落在本实用新型要求的保护范围内。 The above descriptions are only preferred feasible embodiments of the present utility model, and are not intended to limit the patent protection scope of the present utility model. In addition to the above embodiments, the utility model can also have other implementations. All technical solutions formed by equivalent replacement or equivalent transformation fall within the scope of protection required by the utility model.

Claims (2)

1. flame-retardant bulk shielding instrument cable peculiar to vessel, it is characterized in that: the twisted copper conductors periphery is extruded with the ethylene propylene rubber insulated layer of flame-retardant and constitutes insulated wire cores, insulated wire cores stranded formation twisted pair wire in twos is right, the right slit of described twisted pair wire is filled with fire-retardant non-hygroscopic fiber and fills out core, the twisting pitch that each described twisted pair wire has nothing in common with each other to employing, the described twisted pair wire strand of many groups constitutes cable core, the periphery of described cable core is enclosed with the vertical covering of low-intensity nonwoven fabrics, the periphery of the vertical covering of described low-intensity nonwoven fabrics is extruded with inner sheath, the periphery of described inner sheath be surrounded with Copper Foil polyester composite band screen and copper-clad surface inside, the inboard of described Copper Foil polyester composite band screen is provided with zinc-plated stranded copper wire drainage thread, and described zinc-plated stranded copper wire drainage thread runs through the cable core overall length and abuts against with copper-clad surface; The periphery of described Copper Foil polyester composite band screen is coated with the armouring braid, and the periphery of described armouring braid is extruded with oversheath.
2. flame-retardant according to claim 1 bulk shielding instrument cable peculiar to vessel, it is characterized in that, the thickness of the vertical covering of described low-intensity nonwoven fabrics is 0.05 ~ 0.1mm, overlap vertical bag successively along the cable core axis direction, the width of every section vertical covering of described low-intensity nonwoven fabrics is 3.5 ~ 3.8 times of cable core diameter.
CN201320141416.6U 2013-03-26 2013-03-26 A flame-retardant and fire-resistant marine overall shielded instrument cable Expired - Fee Related CN203192455U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103227003A (en) * 2013-03-26 2013-07-31 江苏远洋东泽电缆股份有限公司 Integral shielding instrument cable for flame-retardant fireproof boat and manufacturing method thereof
CN103943190A (en) * 2014-03-26 2014-07-23 无为县金华电缆材料有限公司 Tensile armored drainage wire used for aviation

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103227003A (en) * 2013-03-26 2013-07-31 江苏远洋东泽电缆股份有限公司 Integral shielding instrument cable for flame-retardant fireproof boat and manufacturing method thereof
CN103227003B (en) * 2013-03-26 2015-07-08 江苏远洋东泽电缆股份有限公司 Integral shielding instrument cable for flame-retardant fireproof boat and manufacturing method thereof
CN103943190A (en) * 2014-03-26 2014-07-23 无为县金华电缆材料有限公司 Tensile armored drainage wire used for aviation

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