Concentrate the device of Biodine
Technical field
The utility model relates to and a kind of Biodine being concentrated, in order to subsequent transportation, processing and the device that utilizes again.
Background technology
Polaroid is the critical elements in the optical articles, and itself is for containing polyvinyl alcohol (polyvinyl alcohol, diaphragm PVA) (FILM); Polaroid needs to handle through extending (contain and contaminate or dyeing) and washing in the process of producing, can produce waste water or waste liquid in the processing procedure, include in this waste water or the waste liquid and possess the iodine and the boron that can be utilized value, a large amount of Biodine (waste water or waste liquid), do not reclaim the waste that not only causes resource if having, can impact simultaneously yet environment.
The manufacturer that produces polaroid at present normally entrusts discarded object wind up company to handle with the cause discarded object for the processing method of aforementioned Biodine, its processing mode is that Biodine is handled in the incineration mode, yet, based on the law of conservation of matter, iodine after incinerating can't disappear without foundation, but with toxic emission to atmosphere, the value of not only having strangled iodine to be recycled, and, be a major injury to environment just as pollutant is transferred in the air.
The utility model content
Main purpose of the present utility model is to solve at present the not environmental protection of processing mode for Biodine (waste water or waste liquid), and has strangled the problem of the value that iodine can be recycled.
Feature of the present utility model, be in Biodine, to add alkali its pH value (pH-value) is improved to avoid the iodine vapor volatilization, and then with in the input container for evaporation after this Biodine preheating, by thin film evaporator the moisture content in the Biodine in the container for evaporation is evaporated, stored utilization more to be recycled behind the concentrated solution to be formed; In addition, characteristics of the present utility model are to utilize steam-jet ejector to fill the latent heat that part recovery thin film evaporator evaporation Biodine produces secondary steam, give thin film evaporator heats except that providing again, and the preheating heat exchanger that carries out in this concentrated processing procedure is provided, avoid the waste of energy.
Based on this, the device of the concentrated Biodine that the utility model provides includes the conditioning machine; The preheating heat exchanger that connects this conditioning machine; Be equipped with thin film evaporator and connect the container for evaporation of this preheating heat exchanger; The steam-jet ejector that connects this thin film evaporator and container for evaporation; The heat exchanger that connects this thin film evaporator; The condensate draining that connects this heat exchanger, thin film evaporator and preheating heat exchanger; And the finished product storage tank that connects this container for evaporation.
By aforesaid device, Biodine is added into alkali and stirs in this conditioning machine after, the pH value of Biodine is increased to more than 9, after making Biodine pass through this preheating heat exchanger heating again, import in this container for evaporation, utilize this thin film evaporator that the water evaporates of Biodine is formed indirect steam, make this indirect steam enter this steam-jet ejector and import this thin film evaporator again after vapor mixing becomes mixed vapour with giving birth to, the moisture content of this Biodine after becoming concentrated solution, is transfused to this finished product storage tank through evaporation; The superfluous mixed vapour of an aforesaid part is imported into this heat exchanger; import this condensate draining after making this mixed vapour be condensed into water; and the condensed water that described thin film evaporator produces also imports this condensate draining, again the condensed water in this condensate draining is delivered to this preheating heat exchanger and carries out heat exchange.
The utility model is used for improving the alkali of the pH value of iodine solution, can be NaOH or KOH.
In order to make evaporation rate faster, the utility model is possessed water yield top with what thin film evaporator was located at container for evaporation.
The utility model is provided with pump in container for evaporation, utilize the running of this pump that the water yield of possessing in the container for evaporation is circulated.
When the pressure of the living steam of the utility model steam-jet ejector utilization discharges the flow velocity of the steam of making a living, produce negative pressure and also suck secondary steam, the pressure that makes container for evaporation can reduce the boiling point of water less than an atmospheric pressure, to reach the effect that energy-conservation charcoal subtracts.
Description of drawings
Fig. 1 shows that the utility model concentrates the schematic representation of apparatus of Biodine.
[main element symbol description]
1 ... the conditioning machine
2 ... preheating heat exchanger
3 ... container for evaporation
4 ... thin film evaporator
5 ... steam-jet ejector
6 ... heat exchanger
61 ... the cooling water inlet
62 ... coolant outlet
7 ... condensate draining
8 ... the finished product storage tank
W1 ... Biodine
W2 ... concentrated solution
W3 ... condensed water
S1 ... give birth to steam
S2 ... indirect steam
S3 ... mixed vapour
S4 ... superfluous mixed vapour
The specific embodiment
Below cooperate graphic and component symbol is done more detailed description to embodiment of the present utility model, make and have the knack of this skill person and after studying this specification carefully, can implement according to this.
As shown in Figure 1, the device of the concentrated Biodine that the utility model provides, its preferred embodiment includes conditioning machine 1; The preheating heat exchanger 2 that connects this conditioning machine 1; Be equipped with thin film evaporator 4 and connect the container for evaporation 3 of this preheating heat exchanger 2; The steam-jet ejector 5 that connects this thin film evaporator 4 and container for evaporation 3; The heat exchanger 6 that connects this thin film evaporator 4; The condensate draining 7 that connects this heat exchanger 6, thin film evaporator 4 and preheating heat exchanger 2; And the finished product storage tank 8 that connects this container for evaporation 3.
Wherein, be provided with at least one blade (not shown) that drives by motor in the conditioning machine 1, after Biodine W1 is transported in the conditioning machine 1, promptly adding an amount of alkali to scale enters in the conditioning machine 1, after the blade rotation stirs, the pH value of Biodine W1 is brought up to more than 9 then, this purpose is to stop iodine steam volatilization in the solution by the chemical characteristic of high pH value; Described alkali can be NaOH(NaOH) or KOH(potassium hydroxide).Biodine W1 after the raising pH value then heats in advance by preheating heat exchanger 2, delivers in the container for evaporation 3 again; Biodine W1 is earlier through the purpose of preheating, is to improve Biodine to enter temperature before the container for evaporation 3 and make the evaporation rate can be faster, promotes evaporation efficiency; Must keep a certain amount of Biodine W1(in the container for evaporation 3 and promptly possess the water yield) keeping running, and in the container for evaporation 3 the pump (not shown) is set, utilize the running of pump that the water yields of possessing in the container for evaporation 3 are circulated.
Steam-jet ejector 5 is that the primary steam that is connected to the boiler generation is called living steam S1, when giving birth to steam S1 by steam-jet ejector 5, because the pressure of giving birth to steam is greater than an atmospheric pressure, according to white effort principle, discharge and give birth to steam pressure simultaneously, indirect steam S2 end is the shape negative pressure, make indirect steam be inhaled into steam-jet ejector 5 and give birth to steam S1 and be mixed into mixed vapour S3 after, be transported to 4 couples of Biodine W1 of thin film evaporator and carry out heating evaporation; In order to make evaporation rate faster, thin film evaporator 4 preferably is located at possessing above the water yield of container for evaporation 3, moisture content among the Biodine W1 in the container for evaporation 3 forms indirect steam S2 after evaporating, after making indirect steam S2 enter steam-jet ejector 5 and giving birth to steam S1 and be mixed into mixed vapour S3, make mixed vapour S3 input thin film evaporator 4 again; The moisture content of Biodine W1 can improve concentration and become concentrated solution W2, and then export finished product storage tank 8 to from the bottom of container for evaporation 3 after evaporation.In addition, the utility model is also further with the superfluous mixed vapour S4 delivery heat exchanger 6 in the thin film evaporator 4,6 of heat exchangers are 61 input cooling waters from the cooling water inlet, allow cooling water and superfluous mixed vapour S4 carry out heat exchange, make superfluous mixed vapour S4 condense into condensed water W3 and enter condensate draining 7, the cooling water behind the absorption heat is then discharged from coolant outlet 62; In addition, the condensed water W3 that produces during thin film evaporator 4 runnings also imports this condensate draining 7, and the condensed water W3 in the condensate draining 7 is delivered to preheating heat exchanger 2 again and carries out heat exchange, and condensed water W3 is discharged from preheating heat exchanger 2.
The utility model utilizes aforesaid method and apparatus, can fill the latent heat that part recycling Biodine is concentrated secondary steam in the process, and reclaims the utility in the Biodine, reaches carbon reduction and antipollution purpose.
The above person only is in order to explain preferred embodiment of the present utility model; be not that the attempt tool is to do any pro forma restriction to the utility model; be with; all have in that identical utility model spirit is following do relevant any modification of the present utility model or change, all must be included in the category of the utility model intention protection.