CN203079809U - Papermaking sewage advanced treatment system - Google Patents

Papermaking sewage advanced treatment system Download PDF

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CN203079809U
CN203079809U CN201320111060.1U CN201320111060U CN203079809U CN 203079809 U CN203079809 U CN 203079809U CN 201320111060 U CN201320111060 U CN 201320111060U CN 203079809 U CN203079809 U CN 203079809U
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陈琪琪
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Abstract

本实用新型涉及一种废水处理系统,提供一种可有效降解水中致色物质、有效去除高浓度污水色度的、COD去除率高的、污水可生化性高的、废水中的COD可达标排放的造纸污水深度处理系统,包括废水收集池、调节曝气池、生物接触氧化池、沉淀塔及回水池,所述沉淀塔包括沉淀塔体、设于沉淀塔体内中部的缓冲沉淀装置、过滤填料层及微电解填料筒,过滤填料层设于沉淀塔体内所述缓冲沉淀装置的上方,沉淀塔体内位于缓冲沉淀装置的下部设有缓冲槽,微电解填料筒内设有微电解填料,微电解填料筒依次穿过塔盖、过滤填料层、缓冲沉淀装置与沉淀塔体内的缓冲槽相连,微电解填料筒的底壁上均布有透水孔,进污水管穿过塔盖设于微电解填料筒上部。

Figure 201320111060

The utility model relates to a wastewater treatment system, which provides a system that can effectively degrade color-causing substances in water, effectively remove the chroma of high-concentration sewage, have a high COD removal rate, have high biodegradability of sewage, and can discharge COD in wastewater up to the standard. The advanced treatment system of papermaking wastewater includes a waste water collection tank, an adjustable aeration tank, a biological contact oxidation tank, a sedimentation tower and a return pond. The sedimentation tower includes a sedimentation tower body, a buffer sedimentation device located in the middle of the sedimentation tower body, and filter packing Layer and micro-electrolysis packing tube, the filter packing layer is set above the buffer sedimentation device in the sedimentation tower body, a buffer tank is located in the lower part of the buffer sedimentation device in the sedimentation tower body, micro-electrolysis filler tube is provided with micro-electrolysis filler, micro-electrolysis The packing cylinder passes through the tower cover, the filter packing layer, the buffer sedimentation device and the buffer tank in the sedimentation tower in turn. The bottom wall of the micro-electrolysis packing tube is evenly distributed with permeable holes, and the sewage inlet pipe passes through the tower cover and is installed in the micro-electrolysis packing. upper part of the barrel.

Figure 201320111060

Description

一种造纸污水深度处理系统A papermaking sewage advanced treatment system

技术领域 technical field

    本实用新型涉及一种废水处理系统,尤其是涉及造纸污水深度处理系统。 The utility model relates to a wastewater treatment system, in particular to an advanced treatment system for papermaking wastewater.

背景技术 Background technique

我国每年排放的污水量很大,经处理后排放的又不多,对环境造成很大破坏,我国各大水系都产生不同程度的污染,水环境严重恶化。长期以来,造纸废水一直是制约纸业快速发展的问题之一,造纸废水中污染物浓度高,成分较复杂,含有大量的造纸原料和化学药品,耗氧严重,致使造纸废水处理困难,成为严重污染环境的行业之一。如果造纸废水直接排出会严重污染环境,所以必须经过净化处理。而废纸造纸废水中的悬浮物SS及化学需氧量COD浓度较高,COD则由非溶解性COD和溶解性COD两部分组成,通常非溶解性COD占COD组成总量的大部分,当废水中SS被去除时,绝大部分非溶解性COD同时被去除。因此,废纸造纸废水处理要解决的主要问题是去除SS和COD,现有技术造纸废水系统中主要采用生物氧化脱色池内放置固定填料来降解废水中致色物质及悬浮物SS,这种处理池脱色效果不明显,不能有效降解水中致色物质,水中的有机物去除率低,处理后的废水泡沫现象严重,出水色度深,不能去除高浓度污水的色度,COD去除率低,污水的可生化性低,废水中的COD常常超标排放。 The amount of sewage discharged in our country is very large every year, and the amount discharged after treatment is not much, which has caused great damage to the environment. All major water systems in our country have produced varying degrees of pollution, and the water environment has seriously deteriorated. For a long time, papermaking wastewater has been one of the problems restricting the rapid development of the paper industry. The concentration of pollutants in papermaking wastewater is high, the composition is relatively complex, it contains a large amount of papermaking raw materials and chemicals, and the oxygen consumption is serious, which makes the treatment of papermaking wastewater difficult. One of the industries that pollute the environment. If the papermaking wastewater is directly discharged, it will seriously pollute the environment, so it must be purified. However, the concentration of suspended solids SS and chemical oxygen demand COD in waste paper and papermaking wastewater is relatively high, and COD is composed of insoluble COD and soluble COD. Usually, insoluble COD accounts for the majority of the total COD composition. When SS is removed from wastewater, most of the insoluble COD is removed at the same time. Therefore, the main problem to be solved in the treatment of waste paper and papermaking wastewater is to remove SS and COD. In the prior art papermaking wastewater system, fixed fillers are mainly placed in the biological oxidation decolorization tank to degrade the color-causing substances and suspended solids SS in the wastewater. This treatment tank The decolorization effect is not obvious, and the color-causing substances in the water cannot be effectively degraded. The removal rate of organic matter in the water is low. The biochemical property is low, and the COD in the wastewater is often discharged beyond the standard.

实用新型内容 Utility model content

因此,针对上述的问题,本实用新型提供了一种可有效降解水中致色物质、去除水中悬浮物,能有效去除高浓度污水色度的、COD去除率高的、污水可生化性高的、废水中的COD可达标排放的造纸污水深度处理系统。 Therefore, in view of the above-mentioned problems, the utility model provides a kind that can effectively degrade color-causing substances in water, remove suspended solids in water, can effectively remove the chroma of high-concentration sewage, has high COD removal rate, and has high biodegradability of sewage. The COD in the wastewater can reach the standard discharge papermaking wastewater advanced treatment system.

为达到上述目的,本实用新型是通过以下技术方案实现的:一种造纸污水深度处理系统,包括废水收集池、调节曝气池、生物接触氧化池、沉淀塔及回水池,所述废水收集池的出口连接于调节曝气池的进口,所述调节曝气池的上部设有叶轮转动曝气装置,所述调节曝气池的出口连接生物接触氧化池的进口,所述生物接触氧化池的出口连接于沉淀塔的进污水管,所述沉淀塔的出水口连接回水池的入水口,所述沉淀塔包括沉淀塔体、设于沉淀塔体上部的塔盖,所述沉淀塔体底部设有污泥收集斗,所述沉淀塔还包括设于沉淀塔体内中部让固体颗粒快速沉淀的缓冲沉淀装置、过滤填料层及微电解填料筒,所述过滤填料层设于沉淀塔体内所述缓冲沉淀装置的上方,所述沉淀塔体内位于缓冲沉淀装置的下部设有缓冲槽,所述微电解填料筒内设有微电解填料,所述微电解填料筒依次穿过塔盖、过滤填料层、缓冲沉淀装置与沉淀塔体内的缓冲槽相连,所述微电解填料筒的底壁上均布有透水孔,所述进污水管穿过塔盖设于微电解填料筒上部。 In order to achieve the above object, the utility model is achieved through the following technical solutions: a papermaking sewage advanced treatment system, including a waste water collection pool, an adjustable aeration pool, a biological contact oxidation pool, a sedimentation tower and a return pool, the waste water collection pool The outlet of the adjustment aeration tank is connected to the inlet of the adjustment aeration tank, the upper part of the adjustment aeration tank is provided with an impeller rotating aeration device, the outlet of the adjustment aeration tank is connected to the inlet of the biological contact oxidation tank, the biological contact oxidation tank The outlet is connected to the sewage inlet pipe of the sedimentation tower, and the water outlet of the sedimentation tower is connected to the water inlet of the return pool. The sedimentation tower includes a sedimentation tower body, a tower cover arranged on the upper part of the sedimentation tower body, and There is a sludge collection hopper, and the sedimentation tower also includes a buffer sedimentation device, a filter packing layer and a micro-electrolysis packing tube arranged in the middle of the sedimentation tower body to allow solid particles to settle quickly. Above the settling device, the lower part of the buffer settling device in the settling tower is provided with a buffer tank, and the micro-electrolysis packing tube is provided with a micro-electrolysis packing, and the micro-electrolysis packing tube passes through the tower cover, filter packing layer, The buffer sedimentation device is connected with the buffer tank in the sedimentation tower body, and the bottom wall of the micro-electrolysis packing tube is evenly distributed with permeable holes, and the sewage inlet pipe passes through the tower cover and is arranged on the upper part of the micro-electrolysis packing tube.

进一步改进的是:所述生物接触氧化池内下部铺设有气管,所述气管上均布有出气孔,所述气管的一端伸出池外与风机相连,所述生物接触氧化池内位于气管的出气口上部设有活性污泥填料。 It is further improved that a trachea is laid on the lower part of the biological contact oxidation tank, and air outlets are uniformly distributed on the trachea, and one end of the trachea extends out of the tank to connect with a fan, and the air outlet of the trachea is located in the biological contact oxidation tank The upper part is equipped with activated sludge filler.

进一步改进的是:所述缓冲沉淀装置包括设置在沉淀塔体内侧的外圆柱筒体及设于外圆柱筒体内侧的中部设有供微电解填料筒插入穿孔的内圆柱筒体,所述外圆柱筒体与内圆柱筒体之间沿径向方向斜置均布有复数个缓冲沉淀斜板。 A further improvement is that: the buffer sedimentation device includes an outer cylindrical body arranged on the inside of the sedimentation tower body and an inner cylindrical body arranged in the middle of the inner side of the outer cylindrical body for inserting the micro-electrolysis filler cartridge into a hole, the outer cylindrical body Between the cylinder body and the inner cylinder body, a plurality of buffering and sedimentation sloping plates are arranged obliquely and evenly in the radial direction.

进一步改进的是:所述微电解填料为铁碳微电解填料。 A further improvement is: the micro-electrolytic filler is an iron-carbon micro-electrolytic filler.

进一步改进的是:所述回水池内位于入水口的下部还设有活性碳纤维丝过滤层。 A further improvement is that: the lower part of the water inlet in the return pool is also provided with an activated carbon fiber filter layer.

通过采用前述技术方案,本实用新型的有益效果是:本新型造纸污水深度处理系统,包括沉淀塔,所述沉淀塔内中心设置微电解填料筒,污水从进污水管进入微电解填料筒内,经微电解填料筒内的铁碳微电解填料电解处理,去除重金属、毒性污染物、磷等后流入缓冲槽,经缓冲槽缓冲后向四周扩散,然后平稳的向塔顶流动,污水在上升过程中,密度大于水的固体悬浮物如造填料、细小纤维、泥纱等无机颗粒不断的下沉并通过缓冲沉淀装置,加速沉淀,缓冲沉淀装置的每两块缓冲沉淀斜板相当于一个很小的沉淀池,使颗粒沉淀时间大为缩短,利用竖流原理,达到快速沉淀的目的;沉淀塔体内所述缓冲沉淀装置的上方设有过滤填料层,从缓冲沉淀装置流过的污水可经过滤填料层进一步生物氧化、吸附及过滤后通过沉淀塔顶端出水口流出出水管进入回水池。本新型造纸污水深度处理系统,能利用填充在废水中的微电解材料自身产生1.2V电位差对废水进行电解处理,以达到降解有机污染物的目的。通水后,微电解填料筒内会形成无数的微电池系统,在其作用空间构成一个电场。在处理过程中产生的新生态[H] 、Fe2 + 等能与废水中的许多组分发生氧化还原反应,比如能破坏有色废水中的有色物质的发色基团或助色基团,甚至断链,达到降解脱色的作用;生成的Fe2 + 进一步氧化成Fe3 +,它们的水合物具有较强的吸附、絮凝活性,特别是在加碱调pH 值后生成氢氧化亚铁和氢氧化铁胶体絮凝剂,它们的吸附能力远远高于一般药剂水解得到的氢氧化铁胶体,能大量吸附水中分散的微小颗粒,金属粒子及有机大分子,其工作原理基于电化学、氧化、还原、物理吸附以及絮凝沉淀的共同作用对废水进行处理.具有适用范围广、处理效果好、成本低廉、操作维护方便,不需消耗电力资源等优点。该造纸污水深度处理系统可用于难降解高色度废水的处理,不但能大幅度地降低COD和色度,而且可大大提高废水的可生化性。进一步改进的是:所述生物接触氧化池内下部铺设有气管,所述气管上均布有出气孔,所述气管的一端伸出池外与风机相连,所述生物接触氧化池内位于气管的出气口上部设有活性污泥填料,由此风机可通过气管向生物接触氧化池内输送气体,使生物接触氧化池内的废水不断运动,使废水与池内的活性污泥互相触碰,使活性污泥与废水充分接触反应,增加活性污泥与污水之间的接触吸附机会,有效提高降解能力,可有效降解水中致色物质、去除水中悬浮物,提高污水有机物的去除率,使废水中的COD可达标排放。 By adopting the aforementioned technical scheme, the beneficial effects of the utility model are: the advanced treatment system of the papermaking sewage of the new type includes a sedimentation tower, and the center of the sedimentation tower is provided with a micro-electrolysis packing cylinder, and the sewage enters the micro-electrolysis packing cylinder from the sewage inlet pipe, After the electrolytic treatment of the iron-carbon micro-electrolytic filler in the micro-electrolytic filler cylinder, heavy metals, toxic pollutants, phosphorus, etc. are removed, and then flow into the buffer tank. After being buffered by the buffer tank, it diffuses around, and then flows smoothly to the top of the tower. In the process, solid suspended matter with a density greater than water, such as fillers, fine fibers, mud yarn and other inorganic particles, sinks continuously and passes through the buffer sedimentation device to accelerate the sedimentation. Every two buffer sedimentation inclined plates of the buffer sedimentation device is equivalent to a small The settling tank greatly shortens the particle settling time, and uses the principle of vertical flow to achieve the purpose of rapid settling; the upper part of the buffer settling device in the settling tower is provided with a filter packing layer, and the sewage flowing through the buffer settling device can be filtered After the packing layer is further biologically oxidized, adsorbed and filtered, it flows out of the outlet pipe through the outlet at the top of the sedimentation tower and enters the return pool. The novel papermaking sewage advanced treatment system can use the micro-electrolytic material filled in the waste water to generate a potential difference of 1.2V to electrolyze the waste water to achieve the purpose of degrading organic pollutants. After passing through the water, countless micro-battery systems will be formed in the micro-electrolysis packing cylinder, forming an electric field in its action space. The new ecology [H] and Fe2 + produced during the treatment process can undergo redox reactions with many components in the wastewater, such as the chromophores or auxochromes that can destroy the colored substances in the colored wastewater, and even break Chain, to achieve the effect of degradation and decolorization; the generated Fe2 + is further oxidized into Fe3 +, and their hydrates have strong adsorption and flocculation activities, especially after adding alkali to adjust the pH value, ferrous hydroxide and ferric hydroxide colloids are formed Flocculants, their adsorption capacity is much higher than that of ferric hydroxide colloids obtained by hydrolysis of general pharmaceuticals, and can adsorb a large number of tiny particles, metal particles and organic macromolecules dispersed in water. Their working principles are based on electrochemical, oxidation, reduction, and physical adsorption. And the combined effect of flocculation and sedimentation to treat wastewater. It has the advantages of wide application range, good treatment effect, low cost, convenient operation and maintenance, and no need to consume power resources. The papermaking sewage advanced treatment system can be used for the treatment of refractory high chroma wastewater, not only can greatly reduce COD and chroma, but also can greatly improve the biodegradability of wastewater. It is further improved that a trachea is laid on the lower part of the biological contact oxidation tank, and air outlets are uniformly distributed on the trachea, and one end of the trachea extends out of the tank to connect with a fan, and the air outlet of the trachea is located in the biological contact oxidation tank The upper part is equipped with activated sludge filler, so that the fan can deliver gas to the biological contact oxidation tank through the air pipe, so that the wastewater in the biological contact oxidation tank can move continuously, so that the wastewater and the activated sludge in the tank can touch each other, so that the activated sludge and wastewater Fully contact reaction, increase the contact adsorption opportunity between activated sludge and sewage, effectively improve the degradation ability, can effectively degrade color-causing substances in water, remove suspended solids in water, improve the removal rate of organic matter in sewage, and make COD in wastewater discharge up to the standard .

附图说明 Description of drawings

图1是本实用新型实施例的流程示意图。 Fig. 1 is a schematic flow chart of the utility model embodiment.

图2是本实用新型实施例沉淀塔的A-A剖视图。 Fig. 2 is the AA sectional view of the sedimentation tower of the embodiment of the utility model.

具体实施方式 Detailed ways

  下面结合附图对本实用新型作进一步说明: The utility model will be further described below in conjunction with the accompanying drawings:

实施例: Example:

参考图1,本实施例公开一种造纸污水深度处理系统,包括废水收集池1、调节曝气池2、生物接触氧化池3、沉淀塔4及回水池5,所述废水收集池1的出口连接于调节曝气池2的进口,所述调节曝气池2的上部设有叶轮转动曝气装置21,所述调节曝气池2的出口连接生物接触氧化池3的进口,所述接触氧化池3的出口连接于沉淀塔的进污水管47,所述沉淀塔的出水口连接回水池5的入水口,其中: Referring to Fig. 1, the present embodiment discloses a papermaking wastewater advanced treatment system, comprising a waste water collection tank 1, an adjustable aeration tank 2, a biological contact oxidation tank 3, a sedimentation tower 4 and a backwater tank 5, the outlet of the waste water collection tank 1 Connected to the inlet of the adjustment aeration tank 2, the top of the adjustment aeration tank 2 is provided with an impeller rotating aeration device 21, the outlet of the adjustment aeration tank 2 is connected to the inlet of the biological contact oxidation tank 3, and the contact oxidation The outlet of pond 3 is connected to the sewage inlet pipe 47 of sedimentation tower, and the water outlet of said sedimentation tower is connected to the water inlet of backwater pool 5, wherein:

所述沉淀塔包括沉淀塔体41、设于沉淀塔体41上部的塔盖42,所述沉淀塔体41底部设有污泥收集斗411,所述沉淀塔还包括设于沉淀塔体41内中部让固体颗粒快速沉淀的缓冲沉淀装置43、过滤填料层44及微电解填料筒45,所述过滤填料层44于沉淀塔体41内所述缓冲沉淀装置43的上方,所述沉淀塔体41内位于缓冲沉淀装置43的下部设有缓冲槽46,所述微电解填料筒45内设有铁碳微电解填料451,所述微电解填料筒45依次穿过塔盖42、过滤填料层44、缓冲沉淀装置43与沉淀塔体41内的缓冲槽46相连,所述微电解填料筒45的底壁上均布有透水孔,所述进污水管47穿过塔盖42设于微电解填料筒45的上部。 Described settling tower comprises settling tower body 41, is located at the tower cover 42 of settling tower body 41 tops, and the bottom of described settling tower body 41 is provided with sludge collecting bucket 411, and described settling tower also includes being located in settling tower body 41 The buffer sedimentation device 43, the filter packing layer 44 and the micro-electrolysis packing cylinder 45 that allow the solid particles to settle quickly in the middle, the filter packing layer 44 is above the buffer sedimentation device 43 in the sedimentation tower body 41, and the sedimentation tower body 41 Be positioned at the bottom of buffer precipitation device 43 and be provided with buffer tank 46, be provided with iron-carbon micro-electrolysis filler 451 in described micro-electrolysis filler cylinder 45, described micro-electrolysis filler cylinder 45 passes through tower cover 42, filter packing layer 44, The buffer sedimentation device 43 is connected to the buffer tank 46 in the sedimentation tower body 41, and the bottom wall of the micro-electrolysis packing tube 45 is evenly distributed with permeable holes, and the sewage inlet pipe 47 passes through the tower cover 42 and is arranged in the micro-electrolysis packing tube 45 upper part.

所述生物接触氧化池3内下部铺设有气管31,所述气管31上均布有出气孔,所述气管31的一端伸出池外与风机6相连,所述生物接触氧化池3内位于气管31的出气口上部设有活性污泥填料32。风机可通过气管向生物接触氧化池内输送气体,使生物接触氧化池内的废水不断运动,使废水与池内的活性污泥互相触碰,使活性污泥与废水充分接触反应,增加活性污泥与污水之间的接触吸附机会,有效提高降解能力,可有效降解水中致色物质、去除水中悬浮物,提高污水有机物的去除率,使废水中的COD可达标排放。 The lower part of the biological contact oxidation tank 3 is laid with a trachea 31, and the air outlets are evenly distributed on the trachea 31. One end of the trachea 31 stretches out of the pool and is connected with the fan 6. The biological contact oxidation tank 3 is located in the trachea. The upper part of the air outlet of 31 is provided with activated sludge filler 32. The fan can deliver gas to the biological contact oxidation tank through the air pipe, so that the wastewater in the biological contact oxidation tank moves continuously, so that the wastewater and the activated sludge in the tank touch each other, so that the activated sludge and wastewater can fully contact and react, and increase the amount of activated sludge and sewage. The contact adsorption opportunities between them can effectively improve the degradation ability, can effectively degrade the color-causing substances in water, remove suspended solids in water, improve the removal rate of organic matter in sewage, and make COD in wastewater discharge up to the standard.

所述缓冲沉淀装置43包括设置在沉淀塔体内侧的外圆柱筒体431及设于外圆柱筒体431内侧的中部设有供微电解填料筒插入穿孔的内圆柱筒体432,所述外圆柱筒体431与内圆柱筒体432之间沿径向方向斜置均布有复数个缓冲沉淀斜板433。废水经生物接触氧化池处理后从进污水管进入沉淀塔体内后经缓冲槽缓冲后向四周扩散,然后平稳的向塔顶流动,污水在上升过程中,密度大于水的固体悬浮物如造填料、细小纤维、泥纱等无机颗粒不断的下沉并通过快速沉淀装置,加速沉淀,缓冲沉淀装置的每两块缓冲沉淀斜板相当于一个很小的沉淀池,使颗粒沉淀时间大为缩短,利用竖流原理,达到快速沉淀的目的,从缓冲沉淀装置流过的污水经过滤填料层进一步过滤后从塔体上部的出水口流入回收池。 Described buffer sedimentation device 43 comprises the outer cylindrical shell 431 that is arranged on the inside of the sedimentation tower body and the middle part that is located at the inner side of outer cylindrical shell 431 is provided with the inner cylindrical shell 432 that inserts perforation for the micro-electrolysis filler tube, and described outer cylindrical shell Between the cylinder body 431 and the inner cylindrical cylinder body 432 , a plurality of buffer sedimentation sloping plates 433 are uniformly arranged obliquely along the radial direction. After the wastewater is treated by the biological contact oxidation tank, it enters the sedimentation tower from the sewage inlet pipe, and after being buffered by the buffer tank, it diffuses to the surroundings, and then flows smoothly to the top of the tower. During the rising process of the sewage, solid suspended matter with a density greater than water, such as filler Inorganic particles such as fine fibers, mud yarn, etc. sink continuously and pass through the rapid sedimentation device to accelerate the sedimentation. Every two buffer sedimentation inclined plates of the buffer sedimentation device are equivalent to a small sedimentation tank, which greatly shortens the particle sedimentation time. Using the principle of vertical flow to achieve the purpose of rapid sedimentation, the sewage flowing from the buffer sedimentation device is further filtered through the filter packing layer and then flows into the recovery tank from the water outlet on the upper part of the tower body.

所述回水池5内位于入水口的下部还设有活性碳纤维丝过滤层51。活性可进一步截流水中的悬浮物及生物絮体,保证出水质量。 The lower part of the water inlet in the return pool 5 is also provided with an activated carbon fiber filter layer 51 . The activity can further intercept the suspended solids and biological flocs in the water to ensure the quality of the effluent.

本新型造纸污水深度处理系统,包括沉淀塔,所述沉淀塔内中心设置微电解填料筒,污水从进污水管进入微电解填料筒内,经微电解填料筒内的铁碳微电解填料电解处理,去除重金属、毒性污染物、磷等后流入缓冲槽,经缓冲槽缓冲后向四周扩散,然后平稳的向塔顶流动,污水在上升过程中,密度大于水的固体悬浮物如造填料、细小纤维、泥纱等无机颗粒不断的下沉并通过缓冲沉淀装置,加速沉淀,缓冲沉淀装置的每两块缓冲沉淀斜板相当于一个很小的沉淀池,使颗粒沉淀时间大为缩短,利用竖流原理,达到快速沉淀的目的;沉淀塔体内所述缓冲沉淀装置的上方设有过滤填料层,从缓冲沉淀装置流过的污水可经过滤填料层进一步生物氧化、吸附及过滤后通过沉淀塔顶端出水口流出出水管进入回水池。本新型造纸污水深度处理系统,能利用填充在废水中的微电解材料自身产生1.2V电位差对废水进行电解处理,以达到降解有机污染物的目的。通水后,微电解填料筒内会形成无数的微电池系统,在其作用空间构成一个电场。在处理过程中产生的新生态[H] 、Fe2 + 等能与废水中的许多组分发生氧化还原反应,比如能破坏有色废水中的有色物质的发色基团或助色基团,甚至断链,达到降解脱色的作用;生成的Fe2 + 进一步氧化成Fe3 +,它们的水合物具有较强的吸附、絮凝活性,特别是在加碱调pH 值后生成氢氧化亚铁和氢氧化铁胶体絮凝剂,它们的吸附能力远远高于一般药剂水解得到的氢氧化铁胶体,能大量吸附水中分散的微小颗粒,金属粒子及有机大分子,其工作原理基于电化学、氧化、还原、物理吸附以及絮凝沉淀的共同作用对废水进行处理.具有适用范围广、处理效果好、成本低廉、操作维护方便,不需消耗电力资源等优点。该沉淀分离塔可用于难降解高色度废水的处理,不但能大幅度地降低COD和色度,而且可大大提高废水的可生化性。 The new papermaking wastewater advanced treatment system includes a sedimentation tower, and the center of the sedimentation tower is equipped with a micro-electrolysis packing cylinder. The sewage enters the micro-electrolysis packing cylinder from the sewage inlet pipe, and is electrolyzed by the iron-carbon micro-electrolysis packing in the micro-electrolysis packing cylinder. After removing heavy metals, toxic pollutants, phosphorus, etc., it flows into the buffer tank, diffuses around after being buffered by the buffer tank, and then flows smoothly to the top of the tower. During the rising process of sewage, solid suspended matter with a density greater than water, such as fillers, fine Inorganic particles such as fiber and mud yarn sink continuously and pass through the buffer sedimentation device to accelerate the sedimentation. Every two buffer sedimentation inclined plates of the buffer sedimentation device are equivalent to a small sedimentation tank, which greatly shortens the particle sedimentation time. Flow principle, to achieve the purpose of rapid sedimentation; above the buffer sedimentation device in the sedimentation tower, there is a filter packing layer, and the sewage flowing through the buffer sedimentation device can be further biologically oxidized, adsorbed and filtered through the filter packing layer, and then pass through the top of the sedimentation tower The water outlet flows out of the water outlet pipe and enters the return pool. The novel papermaking sewage advanced treatment system can use the micro-electrolytic material filled in the waste water to generate a potential difference of 1.2V to electrolyze the waste water to achieve the purpose of degrading organic pollutants. After passing through the water, countless micro-battery systems will be formed in the micro-electrolysis packing cylinder, forming an electric field in its action space. The new ecology [H] and Fe2 + produced during the treatment process can undergo redox reactions with many components in the wastewater, such as the chromophores or auxochromes that can destroy the colored substances in the colored wastewater, and even break Chain, to achieve the effect of degradation and decolorization; the generated Fe2 + is further oxidized into Fe3 +, and their hydrates have strong adsorption and flocculation activities, especially after adding alkali to adjust the pH value, ferrous hydroxide and ferric hydroxide colloids are formed Flocculants, their adsorption capacity is much higher than that of ferric hydroxide colloids obtained by hydrolysis of general pharmaceuticals, and can adsorb a large number of tiny particles, metal particles and organic macromolecules dispersed in water. Their working principles are based on electrochemical, oxidation, reduction, and physical adsorption. And the combined effect of flocculation and sedimentation to treat wastewater. It has the advantages of wide application range, good treatment effect, low cost, convenient operation and maintenance, and no need to consume power resources. The precipitation separation tower can be used for the treatment of refractory high chroma wastewater, not only can greatly reduce COD and chroma, but also can greatly improve the biodegradability of wastewater.

以上所记载,仅为利用本创作技术内容的实施例,任何熟悉本项技艺者运用本创作所做的修饰、变化,皆属本创作主张的专利范围,而不限于实施例所揭示者。 The above records are only examples of using the technical content of this creation. Any modifications and changes made by those who are familiar with this technology using this creation belong to the scope of patents claimed by this creation, and are not limited to those disclosed in the examples.

Claims (5)

1.一种造纸污水深度处理系统,包括废水收集池、调节曝气池、生物接触氧化池、沉淀塔及回水池,所述废水收集池的出口连接于调节曝气池的进口,所述调节曝气池的上部设有叶轮转动曝气装置,所述调节曝气池的出口连接生物接触氧化池的进口,所述生物接触氧化池的出口连接于沉淀塔的进污水管,所述沉淀塔的出水口连接回水池的入水口,所述沉淀塔包括沉淀塔体、设于沉淀塔体上部的塔盖,所述沉淀塔体底部设有污泥收集斗,其特征在于:所述沉淀塔还包括设于沉淀塔体内中部让固体颗粒快速沉淀的缓冲沉淀装置、过滤填料层及微电解填料筒,所述过滤填料层设于沉淀塔体内所述缓冲沉淀装置的上方,所述沉淀塔体内位于缓冲沉淀装置的下部设有缓冲槽,所述微电解填料筒内设有微电解填料,所述微电解填料筒依次穿过塔盖、过滤填料层、缓冲沉淀装置与沉淀塔体内的缓冲槽相连,所述微电解填料筒的底壁上均布有透水孔,所述进污水管穿过塔盖设于微电解填料筒上部。 1. A paper-making wastewater advanced treatment system, comprising a waste water collection tank, a regulated aeration tank, a biological contact oxidation tank, a sedimentation tower and a backwater tank, the outlet of the waste water collection tank is connected to the inlet of the regulated aeration tank, and the regulated The upper part of the aeration tank is provided with an impeller rotating aeration device, the outlet of the regulating aeration tank is connected to the inlet of the biological contact oxidation tank, and the outlet of the biological contact oxidation tank is connected to the sewage inlet pipe of the sedimentation tower, and the sedimentation tower The outlet of the settling tower is connected to the water inlet of the backwater tank. The settling tower includes a settling tower body and a tower cover arranged on the upper part of the settling tower body. A sludge collection bucket is provided at the bottom of the settling tower body. It is characterized in that: the settling tower It also includes a buffer sedimentation device, a filter packing layer and a micro-electrolysis packing tube arranged in the middle of the sedimentation tower body to allow solid particles to quickly settle, the filter packing layer is arranged above the buffer sedimentation device in the sedimentation tower body, and the sedimentation tower body A buffer tank is located at the lower part of the buffer sedimentation device, and the micro electrolysis filler cylinder is provided with a micro electrolysis filler, and the micro electrolysis filler cylinder sequentially passes through the tower cover, the filter packing layer, the buffer sedimentation device and the buffer tank in the sedimentation tower body Connected, the bottom wall of the micro-electrolysis packing tube is evenly distributed with permeable holes, and the sewage inlet pipe passes through the tower cover and is arranged on the upper part of the micro-electrolysis packing tube. 2.根据权利要求1所述的造纸污水深度处理系统:所述生物接触氧化池内下部铺设有气管,所述气管上均布有出气孔,所述气管的一端伸出池外与风机相连,所述生物接触氧化池内位于气管的出气口上部设有活性污泥填料。 2. The papermaking sewage advanced treatment system according to claim 1: a trachea is laid in the lower part of the biological contact oxidation tank, and air outlet holes are evenly distributed on the trachea, and one end of the trachea stretches out of the pool and is connected with a fan, so The activated sludge filler is arranged on the upper part of the air outlet of the trachea in the biological contact oxidation tank. 3.根据权利要求1或2所述的造纸污水深度处理系统,其特征在于:所述缓冲沉淀装置包括设置在沉淀塔体内侧的外圆柱筒体及设于外圆柱筒体内侧的中部设有供微电解填料筒插入穿孔的内圆柱筒体,所述外圆柱筒体与内圆柱筒体之间沿径向方向斜置均布有复数个缓冲沉淀斜板。 3. The papermaking sewage advanced treatment system according to claim 1 or 2, characterized in that: the buffer sedimentation device includes an outer cylindrical body arranged on the inner side of the sedimentation tower body and a middle part arranged on the inner side of the outer cylindrical body A perforated inner cylinder body is used for inserting the micro-electrolysis packing cylinder, and a plurality of buffer sedimentation slant plates are evenly arranged obliquely along the radial direction between the outer cylinder body and the inner cylinder body. 4.根据权利要求1所述的造纸污水深度处理系统,其特征在于:所述微电解填料为铁碳微电解填料。 4. The papermaking sewage advanced treatment system according to claim 1, characterized in that: the micro-electrolytic filler is iron-carbon micro-electrolytic filler. 5.根据权利要求1所述的造纸污水深度处理系统,其特征在于:所述回水池内位于入水口的下部还设有活性碳纤维丝过滤层。 5. The papermaking wastewater advanced treatment system according to claim 1, characterized in that: the bottom of the water inlet in the return pool is also provided with an activated carbon fiber filter layer.
CN201320111060.1U 2013-03-12 2013-03-12 Papermaking sewage advanced treatment system Expired - Fee Related CN203079809U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114890593A (en) * 2022-04-08 2022-08-12 江苏济冠通环保科技股份有限公司 A kind of treatment method of paper industry wastewater

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114890593A (en) * 2022-04-08 2022-08-12 江苏济冠通环保科技股份有限公司 A kind of treatment method of paper industry wastewater

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