Summary of the invention
Technical problem to be solved in the utility model is to provide a kind of separation and concentration system that can ensure for a long time the sampling quantitative precision.
The purpose of this utility model is achieved through the following technical solutions:
A kind of separation and concentration system comprises the sample introduction pipeline, the threeway that connects with the sample introduction pipeline, the fluid driver module that connects with threeway, and described threeway also is connected with volume pump, is connected with stop valve between described threeway and fluid driver module.
Further, described fluid driver module comprises peristaltic pump, and described threeway is connected to described peristaltic pump by stop valve.
Further, described separation and concentration system comprises separating concentration device and reductive agent pipe, and described reductive agent pipe is followed described separating concentration device UNICOM by peristaltic pump; The first port of described separating concentration device is connected with the carrier gas pipe; Its second port is connected with the reductive agent pipe by peristaltic pump, and its 3rd port is connected with the waste liquid remover; Its 4th port is connected with the enrichment delivery line.The technical program is transported to separating concentration device with unifications such as sample, current-carrying, reductive agents, realized separating of gas and liquid by separating concentration device, simplified system architecture, reduced failure rate, improved maintainability.All fluids are all unified to process by separating concentration device, the leakage that also is not easy to produce reagent and steam.
Further, described waste liquid remover comprises the sewer pipe that connects with the 3rd port of separating concentration device.
Further, described waste liquid remover comprises the waist valve that connects with the 3rd port of separating concentration device, the sewer pipe that connects with waist valve.
Further, described stop valve and waist valve are any one in pinch valve, Valve for compressing tubular liner, stop valve or the flow solenoid valve with liquid flow path cutoff function.
Further, described waste liquid remover comprises sewer pipe, and described sewer pipe one end is connected to the 3rd port of described separating concentration device, and the other end is connected to described peristaltic pump.
Further, described volume pump is any one in syringe pump, ram pump, membrane pump or the Ceramic piston volume pump with accurate measurement function.
Further, described stop valve is any one in pinch valve, Valve for compressing tubular liner or the flow solenoid valve with liquid flow path cutoff function.
Further, described fluid driver module comprises peristaltic pump, and described threeway is connected to described peristaltic pump by stop valve; Described separation and concentration system also comprises separating concentration device and reductive agent pipe, and described reductive agent pipe is followed described separating concentration device UNICOM by peristaltic pump; The first port of described separating concentration device is connected with the carrier gas pipe; Its second port is connected with the reductive agent pipe by peristaltic pump, and its 3rd port is connected with the waste liquid remover; Its 4th port is connected with the enrichment delivery line.Described stop valve is any one in pinch valve, Valve for compressing tubular liner or the flow solenoid valve with liquid flow path cutoff function; Described volume pump is any one in syringe pump, ram pump, membrane pump or the Ceramic piston volume pump with accurate measurement function.
The utility model first turn-offs stop valve owing to having adopted volume pump in the time of system works, volume pump accurately extracts needed reagent from the sample introduction pipeline, and then stop valve is closed, and the fluid of sample introduction pipeline transfers out by the fluid driver module again.Because the process of quantitative collection is to be completed by volume pump, can accurately control, even if also can not affect sampling precision after long-term work causes the fluid driver module aging.The separation and concentration device that the utility model provides is used for atomic fluorescence spectrometer, can realize the automatic configuration standard series of single concentration point, online enriched sample is carried out the advanced automation functions such as automatic dilution.The gas incision forms eddy flow makes target component be able to enrichment, and effectively separates with interfering component, steady air current, and the performance index such as the sensitivity of instrument, precision and detection limit all are greatly improved, and analytical effect is better.
Embodiment
The utility model discloses a kind of separation and concentration system.The separation and concentration system comprises the sample introduction pipeline, the threeway that connects with the sample introduction pipeline, the fluid driver module that connects with threeway, and threeway also is connected with volume pump, is connected with stop valve between threeway and fluid driver module.
The utility model first turn-offs stop valve owing to having adopted volume pump in the time of system works, volume pump accurately extracts needed reagent from the sample introduction pipeline, and then stop valve is closed, and the fluid of sample introduction pipeline transfers out by the fluid driver module again.Because the process of quantitative collection is to be completed by volume pump, can accurately control, even if also can not affect sampling precision after long-term work causes the fluid driver module aging.The separation and concentration device that the utility model provides is used for atomic fluorescence spectrometer, can realize the automatic configuration standard series of single concentration point, online enriched sample is carried out the advanced automation functions such as automatic dilution.The gas incision forms eddy flow makes target component be able to enrichment, and effectively separates with interfering component, steady air current, and the performance index such as the sensitivity of instrument, precision and detection limit all are greatly improved, and analytical effect is better.
The utility model is described in further detail below in conjunction with accompanying drawing and preferred embodiment.
Embodiment one
As shown in Figure 1, the separation and concentration system of the present embodiment comprises sample introduction pipeline 1, the threeway 2 that connects with sample introduction pipeline 1, the fluid driver module that connects with threeway 2, the separating concentration device 8 that connects with the fluid driver module; Threeway 2 also is connected with volume pump 3, is connected with stop valve between threeway 2 and fluid driver module, and the fluid driver module comprises peristaltic pump 6, and threeway 2 is connected to peristaltic pump 6 by stop valve.
The separation and concentration system comprises separating concentration device 8 and reductive agent pipe 5, and reductive agent pipe 5 passes through peristaltic pump 6 with separating concentration device 8 UNICOMs; The first port of separating concentration device 8 is connected with carrier gas pipe 7; Its second port is connected with reductive agent pipe 5 by peristaltic pump 7, and its 3rd port is connected with sewer pipe 10; Its 4th port is connected with enrichment delivery line 9.
Stop valve is any one in pinch valve, Valve for compressing tubular liner or the flow solenoid valve with liquid flow path cutoff function; Volume pump 3 is any one in syringe pump, ram pump, membrane pump or Ceramic piston volume pump 3 with accurate measurement function.
Below introduce the workflow of the present embodiment separation and concentration system.
At first the monitoring software of operating system, make to be full of current-carrying (cleaning fluid) in sample channel, makes in reductive agent pipe 5 to be full of reductive agent.
The first step, stop valve 4 turn-offs, and peristaltic pump 6 quits work, and volume pump 3 is drawn the current-carrying of specified amounts, utilizes air negative pressure that the sample of specified amount is introduced sample introduction pipeline 1, and automatic or experimenter switches in current-carrying sample introduction pipeline 1 by hand by automatic sampler.
Second step, the stop valve conducting, volume pump 3 is not worked, and peristaltic pump 6 begins to rotate, draw current-carrying from sample introduction pipeline 1, under the drainage of peristaltic pump 6, the reductive agent that the sample in sample introduction pipeline 1 and reductive agent pipe 5 are introduced converges, and enters separating concentration device 8, and form eddy flow under the promotion of the argon gas that carrier gas pipe 7 is cut, required composition is that the gaseous state thing rises by enrichment, derived by enrichment delivery line 9, and nearly all interference component all is retained in liquid by sewer pipe 10 discharges.
The 3rd step, stop valve 4 conductings, peristaltic pump 6 rotates, and sample feeding pipe is drawn current-carrying, and volume pump 3 wherein liquid is released, detergent line.
The present embodiment is transported to separating concentration device with unifications such as sample, current-carrying, reductive agents, realized separating of gas and liquid by separating concentration device, simplified system architecture, reduced failure rate, improved maintainability; All fluids are all unified to process by separating concentration device, the leakage that also is not easy to produce reagent and steam.The present embodiment is in conjunction with the advantage of the sampling devices such as existing flow injection, Generation-Atomic Fluorescence Spectrometry, sequential injection, interrupted injection, can eliminate again simultaneously the shortcoming that existing apparatus exists, realize more accurate quantitative sample injection, higher sensitivity, more reliable and more stable decentralised control, less reaction pulsation, improved the analytical performance of instrument, stream is simple, is easy to safeguard.
Embodiment two
As shown in Figure 2, the separation and concentration system of the present embodiment comprises sample introduction pipeline 1, the threeway 2 that connects with sample introduction pipeline 1, the fluid driver module that connects with threeway 2, the separating concentration device 8 that connects with the fluid driver module; Threeway 2 also is connected with volume pump 3, is connected with stop valve between threeway 2 and fluid driver module, and the fluid driver module comprises peristaltic pump 6, and threeway 2 is connected to peristaltic pump 6 by stop valve.
The separation and concentration system comprises separating concentration device 8 and reductive agent pipe 5, and reductive agent pipe 5 passes through peristaltic pump 6 with separating concentration device 8 UNICOMs; The first port of separating concentration device 8 is connected with carrier gas pipe 7; Its second port is connected with reductive agent pipe 5 by peristaltic pump 7, and its 3rd port is connected with the waste liquid remover; Its 4th port is connected with enrichment delivery line 9.The present embodiment is transported to separating concentration device with unifications such as sample, current-carrying, reductive agents, realized separating of gas and liquid by separating concentration device, simplified system architecture, reduced failure rate, improved maintainability.All fluids are all unified to process by separating concentration device, the leakage that also is not easy to produce reagent and steam.
The waste liquid remover comprises the waist valve 11 that connects with the 3rd port of separating concentration device 8, the sewer pipe 10 that connects with waist valve 11; Stop valve and waist valve 11 is any one in pinch valve, Valve for compressing tubular liner, stop valve or flow solenoid valve with liquid flow path cutoff function; Volume pump 3 is any one in syringe pump, ram pump, membrane pump or Ceramic piston volume pump 3 with accurate measurement function.
Below introduce the workflow of the present embodiment separation and concentration system.
At first the monitoring software of operating system, make to be full of current-carrying (cleaning fluid) in sample channel, makes in reductive agent pipe 5 to be full of reductive agent.
The first step, sample introduction pipeline 1 are in sample reagent solution, and stop valve turn-offs, and peristaltic pump 6 quits work; This moment, volume pump 3 was drawn quantitative reagent (be drawn into being ducted current-carrying in volume pump 3) in sample introduction pipeline 1, then sample introduction pipeline 1 by automatic sampler automatically or by experiment personnel switch to by hand in current-carrying, for second step work is prepared;
Second step, the stop valve conducting, waist valve 11 is closed, and volume pump 3 is not worked, peristaltic pump 6 begins to rotate, draw current-carrying from sample introduction pipeline 1, under the drainage of peristaltic pump 6, the reductive agent that the sample in sample introduction pipeline 1 and reductive agent pipe 5 are introduced converges, enter separating concentration device 8, and forming eddy flow under the promotion of the argon gas that carrier gas pipe 7 is cut, required composition is that the gaseous state thing rises by enrichment, is derived by enrichment delivery line 9.
The 3rd step, the stop valve conducting, waist valve 11 conductings, peristaltic pump 6 rotates again, draws current-carrying and enters 1 detergent line of sample introduction pipeline; Current-carrying is wherein released in volume pump 3 operations simultaneously, prepares for measure next time.And the waste liquid in separating concentration device 8 is discharged via waist valve 11 and sewer pipe 10.
The present embodiment is transported to separating concentration device with unifications such as sample, current-carrying, reductive agents, realized separating of gas and liquid by separating concentration device, simplified system architecture, reduced failure rate, improved maintainability; All fluids are all unified to process by separating concentration device, the leakage that also is not easy to produce reagent and steam.The present embodiment is in conjunction with the advantage of the sampling devices such as existing flow injection, Generation-Atomic Fluorescence Spectrometry, sequential injection, interrupted injection, can eliminate again simultaneously the shortcoming that existing apparatus exists, realize more accurate quantitative sample injection, higher sensitivity, more reliable and more stable decentralised control, less reaction pulsation, improved the analytical performance of instrument, stream is simple, is easy to safeguard.In addition, the present embodiment has increased waist valve between sewer pipe and separating concentration device, and the convenient state of controlling sewer pipe makes it keep air-tight state in detachment process, and keep conducting state in cleaning process.
Embodiment three
As shown in Figure 3, the separation and concentration system of the present embodiment comprises sample introduction pipeline 1, the threeway 2 that connects with sample introduction pipeline 1, the fluid driver module that connects with threeway 2, the separating concentration device 8 that connects with the fluid driver module; Threeway 2 also is connected with volume pump 3, is connected with stop valve between threeway 2 and fluid driver module.The fluid driver module comprises that peristaltic pump 6 threeways 2 are connected to peristaltic pump by stop valve.
The separation and concentration system comprises separating concentration device 8 and reductive agent pipe 5, and reductive agent pipe 5 passes through peristaltic pump 6 with separating concentration device 8 UNICOMs; The first port of separating concentration device 8 is connected with carrier gas pipe 7, and connects with stop valve 4 by peristaltic pump 6; Its second port is connected with reductive agent pipe 5 by peristaltic pump 7, and its 3rd port is connected with the waste liquid remover; Its 4th port is connected with enrichment delivery line 9; The waste liquid remover comprises sewer pipe 10, and sewer pipe 10 1 ends are connected to the 4th port of separating concentration device 8, and the other end is connected to peristaltic pump 6;The present embodiment is transported to separating concentration device with unifications such as sample, current-carrying, reductive agents, realized separating of gas and liquid by separating concentration device, simplified system architecture, reduced failure rate, improved maintainability.All fluids are all unified to process by separating concentration device, the leakage that also is not easy to produce reagent and steam.
Stop valve is any one in pinch valve, Valve for compressing tubular liner, stop valve or the flow solenoid valve with liquid flow path cutoff function; Volume pump 3 is any one in syringe pump, ram pump, membrane pump or Ceramic piston volume pump 3 with accurate measurement function.
Below introduce the workflow of the present embodiment separation and concentration system.
At first the monitoring software of operating system, make to be full of current-carrying (cleaning fluid) in sample channel, makes in reductive agent pipe 5 to be full of reductive agent.
The first step, stop valve 4 turn-offs, and peristaltic pump 6 quits work, and volume pump 3 is drawn the current-carrying of specified amounts, utilizes air negative pressure that the sample of specified amount is introduced sample introduction pipeline 1, and automatic or experimenter switches in current-carrying sample introduction pipeline 1 by hand by automatic sampler.
Second step, the stop valve conducting, waist valve 11 is closed, volume pump 3 is not worked, peristaltic pump 6 begins to rotate, and draws current-carrying from sample introduction pipeline 1, under the drainage of peristaltic pump 6, the reductive agent that sample in sample introduction pipeline 1 and reductive agent pipe 5 are introduced converges, enter separating concentration device 8, and form eddy flow under the promotion of the argon gas that carrier gas pipe 7 is cut, required composition is that the gaseous state thing rises by enrichment, derived by enrichment delivery line 9, and nearly all interference component all is retained in liquid by sewer pipe 10 discharges.
The 3rd step, the stop valve conducting, peristaltic pump 6 rotates again, draws current-carrying and enters sample introduction pipeline 1 purging system pipeline, and waste liquid is discharged by peristaltic pump 6 by sewer pipe 10 simultaneously.
The present embodiment is transported to separating concentration device with unifications such as sample, current-carrying, reductive agents, realized separating of gas and liquid by separating concentration device, simplified system architecture, reduced failure rate, improved maintainability; All fluids are all unified to process by separating concentration device, the leakage that also is not easy to produce reagent and steam.The present embodiment is in conjunction with the advantage of the sampling devices such as existing flow injection, Generation-Atomic Fluorescence Spectrometry, sequential injection, interrupted injection, can eliminate again simultaneously the shortcoming that existing apparatus exists, realize more accurate quantitative sample injection, higher sensitivity, more reliable and more stable decentralised control, less reaction pulsation, improved the analytical performance of instrument, stream is simple, is easy to safeguard.In addition, the present embodiment is connected to peristaltic pump at sewer pipe, controls the flow state of waste liquid by peristaltic pump, makes its sewer pipe keep air-tight state in detachment process, and waste liquid can be discharged at the cleaning process peristaltic pump.
Above content is in conjunction with concrete preferred implementation further detailed description of the utility model, can not assert that concrete enforcement of the present utility model is confined to these explanations.For the utility model person of an ordinary skill in the technical field, without departing from the concept of the premise utility, can also make some simple deduction or replace, all should be considered as belonging to protection domain of the present utility model.