CN202957152U - Mixed type super capacitor bank - Google Patents

Mixed type super capacitor bank Download PDF

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CN202957152U
CN202957152U CN 201220666209 CN201220666209U CN202957152U CN 202957152 U CN202957152 U CN 202957152U CN 201220666209 CN201220666209 CN 201220666209 CN 201220666209 U CN201220666209 U CN 201220666209U CN 202957152 U CN202957152 U CN 202957152U
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negative electrode
iron phosphate
activated carbon
lithium iron
electrode
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蔡克迪
何铁石
曲蛟
张庆国
魏颖
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Bohai University
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
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    • Y02E60/13Energy storage using capacitors

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Abstract

一种混合型超级电容器组,由活性炭负极,隔膜,有机电解液,磷酸铁锂正极,石墨负极,壳体与导线组成;所述活性炭负极、磷酸铁锂正极、石墨负极由左至右依次放置在壳体中,所述有机电解液通过隔膜设置在活性炭负极与与磷酸铁锂正极之间以及磷酸铁锂正极与石墨负极之间,所述导线分别连接在活性炭负极、磷酸铁锂正极和石墨负极上。其优点是:将混合型超级电容器与锂离子电池有机的结合成一个整体,从而可以保证一定功率特性的前提下,大幅提高超级电容器的能量密度,为不同用电器的放电需求提供保障。

A hybrid supercapacitor group consisting of an activated carbon negative electrode, a diaphragm, an organic electrolyte, a lithium iron phosphate positive electrode, a graphite negative electrode, a shell, and a wire; the activated carbon negative electrode, lithium iron phosphate positive electrode, and graphite negative electrode are placed in sequence from left to right In the casing, the organic electrolyte is arranged between the negative electrode of activated carbon and the positive electrode of lithium iron phosphate and between the positive electrode of lithium iron phosphate and the negative electrode of graphite through the diaphragm, and the wires are respectively connected to the negative electrode of activated carbon, the positive electrode of lithium iron phosphate and the graphite on the negative pole. Its advantages are: the hybrid supercapacitor and lithium-ion battery are organically combined into a whole, so that under the premise of ensuring a certain power characteristic, the energy density of the supercapacitor can be greatly improved, and the discharge demand of different electrical appliances can be guaranteed.

Description

混合型超级电容器组Hybrid Supercapacitor Bank

技术领域 technical field

本实用新型涉及一种超级电容器的新型结构,尤其涉及超级电容器与锂离子电池构成的混合型超级电容器组。 The utility model relates to a novel structure of a supercapacitor, in particular to a hybrid supercapacitor group composed of a supercapacitor and a lithium ion battery.

背景技术 Background technique

超级电容器是一种介于传统电容器与二次电池之间的新型储能元件,其通过极化电解质来储能,但在其储能的过程并不发生化学反应,这种储能过程是可逆的,也正因为此超级电容器可以反复充放电数十万次。超级电容器可以被视为悬浮在电解质中的两个无反应活性的多孔电极板,在极板上加电,正极板吸引电解质中的负离子,负极板吸引正离子,实际上形成两个容性存储层,被分离开的正离子在负极板附近,负离子在正极板附近。它具有充电时间短、使用寿命长、温度特性好、节约能源和绿色环保等特点。在智能仪表、电动汽车及风力发电等领域有着广泛的应用,近年来开始备受关注。 A supercapacitor is a new type of energy storage element between a traditional capacitor and a secondary battery. It stores energy through a polarized electrolyte, but no chemical reaction occurs during the energy storage process. This energy storage process is reversible. It is precisely because of this supercapacitor that it can be repeatedly charged and discharged hundreds of thousands of times. A supercapacitor can be regarded as two non-reactive porous electrode plates suspended in the electrolyte. When electricity is applied to the plates, the positive plate attracts negative ions in the electrolyte, and the negative plate attracts positive ions, actually forming two capacitive storage layer, the separated positive ions are near the negative plate, and the negative ions are near the positive plate. It has the characteristics of short charging time, long service life, good temperature characteristics, energy saving and environmental protection. It has a wide range of applications in the fields of smart meters, electric vehicles, and wind power generation, and has attracted much attention in recent years.

与传统的二次电池相比,超级电容器具有长寿命、高功率密度的特点,但是能量密度较低。目前有许多研究工作都致力于改善超级电容器体系的能量密度,一个有效的途径是应用混合型超级电容器体系,即一个电极采用电极活性炭电极,而另一个电极采用赝电容电极材料或电池电极材料,通过提高电容器的工作电压,从而提高电容器的能量密度。针对提高混合型超级电容器能量密度的工作主要集中在采用具有氧化还原活性的材料与活性炭组成不对称超级电容器,如活性炭/石墨,活性炭/金属氧化物以及活性炭/聚合物等混合超级电容器。近年来,锂离子嵌入化合物以及锂离子电池碳材料作为混合超级电容器的正极材料得到了广泛的关注,锂离子电池电极材料作为正极,活性炭作为负极组成的混合型超级电容器。上述混合型超级电容器相比于活性炭/活性炭双电层电容器,在能量密度上可以得到一定程度的改善,但仍不能满足一些用电器的实际需求。 Compared with traditional secondary batteries, supercapacitors have the characteristics of long life and high power density, but lower energy density. At present, many research works are devoted to improving the energy density of the supercapacitor system. An effective way is to apply a hybrid supercapacitor system, that is, one electrode uses an electrode activated carbon electrode, and the other electrode uses a pseudocapacitive electrode material or a battery electrode material. By increasing the working voltage of the capacitor, the energy density of the capacitor is increased. The work aimed at improving the energy density of hybrid supercapacitors mainly focuses on the use of redox active materials and activated carbon to form asymmetric supercapacitors, such as activated carbon/graphite, activated carbon/metal oxide and activated carbon/polymer hybrid supercapacitors. In recent years, lithium-ion intercalation compounds and carbon materials for lithium-ion batteries have received widespread attention as positive electrode materials for hybrid supercapacitors, where lithium-ion battery electrode materials are used as positive electrodes and activated carbon is used as negative electrodes for hybrid supercapacitors. Compared with activated carbon/activated carbon electric double layer capacitors, the above-mentioned hybrid supercapacitors can be improved to a certain extent in terms of energy density, but they still cannot meet the actual needs of some electrical appliances.

发明内容 Contents of the invention

本实用新型是为了克服超级电容器在工作过程中能量密度较低的问题,提出一种混合型超级电容器组,将混合型超级电容器与锂离子电池有机的结合成一个整体,从而可以保证一定功率特性的前提下,大幅提高超级电容器的能量密度,为不同用电器的放电需求提供保障。 The utility model is to overcome the problem of low energy density of the supercapacitor in the working process, and proposes a hybrid supercapacitor bank, which organically combines the hybrid supercapacitor and lithium-ion battery into a whole, so that a certain power characteristic can be guaranteed Under the premise, the energy density of supercapacitors can be greatly increased to provide protection for the discharge needs of different electrical appliances.

本实用新型涉及的混合型超级电容器组,其特殊之处是:由活性炭负极1,隔膜2,有机电解液3,磷酸铁锂正极4,石墨负极5,壳体6与导线7组成,所述活性炭负极1、磷酸铁锂正极4、石墨负极5由左至右依次放置在壳体6中,所述有机电解液3通过隔膜2设置在活性炭负极1与与磷酸铁锂正极4之间以及磷酸铁锂正极4与石墨负极5之间,所述导线7分别连接在活性炭负极1、磷酸铁锂正极4和石墨负极5上。 The hybrid supercapacitor group involved in the utility model is characterized in that it is composed of an activated carbon negative electrode 1, a diaphragm 2, an organic electrolyte 3, a lithium iron phosphate positive electrode 4, a graphite negative electrode 5, a casing 6 and a wire 7. The activated carbon negative electrode 1, the lithium iron phosphate positive electrode 4, and the graphite negative electrode 5 are sequentially placed in the casing 6 from left to right, and the organic electrolyte 3 is arranged between the activated carbon negative electrode 1 and the lithium iron phosphate positive electrode 4 through the diaphragm 2, and the phosphoric acid Between the lithium iron positive electrode 4 and the graphite negative electrode 5 , the wires 7 are respectively connected to the activated carbon negative electrode 1 , the lithium iron phosphate positive electrode 4 and the graphite negative electrode 5 .

本实用新型将电池设计成活性炭电极、磷酸铁锂电极与石墨电极的三部分,其中磷酸铁锂电极为超级电容器的共用部分。这种混合超级电容器组在工作过程中,能够结合锂离子电池能量密度高与超级电容器功率特性好的特点,使得该电容器组在保证一定功率特性的前提下,有较好的能量密度,可以根据用电器的不同用电需求而连续工作。 In the utility model, the battery is designed as three parts of an activated carbon electrode, a lithium iron phosphate electrode and a graphite electrode, wherein the lithium iron phosphate electrode is a common part of the supercapacitor. During the working process of this hybrid supercapacitor bank, it can combine the characteristics of high energy density of lithium-ion battery and good power characteristics of supercapacitor, so that the capacitor bank has better energy density under the premise of ensuring certain power characteristics. It can work continuously according to the different power demands of electrical appliances.

附图说明 Description of drawings

图1是本实用新型的结构示意图。 Fig. 1 is a structural representation of the utility model.

图中:活性炭负极1,隔膜2,有机电解液3,磷酸铁锂正极4,石墨负极5,壳体6,导线7。 In the figure: activated carbon negative electrode 1, separator 2, organic electrolyte 3, lithium iron phosphate positive electrode 4, graphite negative electrode 5, casing 6, and wire 7.

具体实施方式 Detailed ways

如图所示,该混合型超级电容器组由活性炭负极1,隔膜2,有机电解液3,磷酸铁锂正极4,石墨负极5,壳体6与导线7组成,所述活性炭负极1、磷酸铁锂正极4、石墨负极5由左至右依次放置在壳体6中,所述有机电解液3通过隔膜2设置在活性炭负极1与与磷酸铁锂正极4之间以及磷酸铁锂正极4与石墨负极5之间,所述导线7分别连接在活性炭负极1、磷酸铁锂正极4和石墨负极5上。 As shown in the figure, the hybrid supercapacitor group consists of an activated carbon negative electrode 1, a diaphragm 2, an organic electrolyte 3, a lithium iron phosphate positive electrode 4, a graphite negative electrode 5, a casing 6 and a wire 7. The activated carbon negative electrode 1, iron phosphate The lithium positive electrode 4 and the graphite negative electrode 5 are placed in the housing 6 in turn from left to right, and the organic electrolyte 3 is arranged between the activated carbon negative electrode 1 and the lithium iron phosphate positive electrode 4 and between the lithium iron phosphate positive electrode 4 and the graphite through the diaphragm 2. Between the negative electrodes 5, the wires 7 are respectively connected to the activated carbon negative electrode 1, the lithium iron phosphate positive electrode 4 and the graphite negative electrode 5.

工作原理:当磷酸铁锂正极4与石墨负极5组成的锂离子电池工作时,具有较高的能量密度,而当活性炭负极1与磷酸铁锂正极4组成的超级电容器工作时,具有较高的功率特性,该混合型超级电容器组将两者通过共用的磷酸铁锂正极有效的结合起来,不仅结构简单,而且具有较高的能量密度和功率特性,为不同用电器的放电需求提供保障。 Working principle: When the lithium ion battery composed of lithium iron phosphate positive electrode 4 and graphite negative electrode 5 works, it has a high energy density, and when the supercapacitor composed of activated carbon negative electrode 1 and lithium iron phosphate positive electrode 4 works, it has high energy density. Power characteristics. The hybrid supercapacitor bank effectively combines the two through the shared lithium iron phosphate positive electrode. It not only has a simple structure, but also has high energy density and power characteristics, providing protection for the discharge needs of different electrical appliances.

Claims (1)

1.一种混合型超级电容器组,其特征是:由活性炭负极,隔膜,有机电解液,磷酸铁锂正极,石墨负极,壳体与导线组成;所述活性炭负极、磷酸铁锂正极、石墨负极由左至右依次放置在壳体中,所述有机电解液通过隔膜设置在活性炭负极与与磷酸铁锂正极之间以及磷酸铁锂正极与石墨负极之间,所述导线分别连接在活性炭负极、磷酸铁锂正极和石墨负极上。 1. A hybrid supercapacitor bank is characterized in that: it is made up of activated carbon negative pole, diaphragm, organic electrolyte, lithium iron phosphate positive pole, graphite negative pole, shell and lead; Described activated carbon negative pole, lithium iron phosphate positive pole, graphite negative pole Placed in the housing in turn from left to right, the organic electrolyte is set between the negative electrode of activated carbon and the positive electrode of lithium iron phosphate and between the positive electrode of lithium iron phosphate and the negative electrode of graphite through the diaphragm, and the wires are respectively connected to the negative electrode of activated carbon, Lithium iron phosphate positive electrode and graphite negative electrode.
CN 201220666209 2012-12-06 2012-12-06 Mixed type super capacitor bank Expired - Fee Related CN202957152U (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104466259A (en) * 2014-12-06 2015-03-25 西南科技大学 Preparation method of single hybrid energy storage unit based on lithium ion capacitor and lithium battery
US9601278B2 (en) 2014-08-26 2017-03-21 Analog Devices, Inc. Super-capacitor with separator and method of producing the same
CN107210136A (en) * 2015-01-09 2017-09-26 美国亚德诺半导体公司 Integrated circuit with shared electrode energy storage device
US10102981B2 (en) 2014-08-26 2018-10-16 Analog Devices, Inc. Method of producing a super-capacitor
US10468201B2 (en) 2014-10-08 2019-11-05 Analog Devices, Inc. Integrated super-capacitor

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9601278B2 (en) 2014-08-26 2017-03-21 Analog Devices, Inc. Super-capacitor with separator and method of producing the same
US10102981B2 (en) 2014-08-26 2018-10-16 Analog Devices, Inc. Method of producing a super-capacitor
US10373766B2 (en) 2014-08-26 2019-08-06 Analog Devices, Inc. Method of producing a super-capacitor
US10468201B2 (en) 2014-10-08 2019-11-05 Analog Devices, Inc. Integrated super-capacitor
CN104466259A (en) * 2014-12-06 2015-03-25 西南科技大学 Preparation method of single hybrid energy storage unit based on lithium ion capacitor and lithium battery
CN107210136A (en) * 2015-01-09 2017-09-26 美国亚德诺半导体公司 Integrated circuit with shared electrode energy storage device
US10050320B2 (en) 2015-01-09 2018-08-14 Analog Devices, Inc. Integrated circuit with shared electrode energy storage devices
CN107210136B (en) * 2015-01-09 2019-05-31 美国亚德诺半导体公司 Integrated circuit with shared electrode energy storage device

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Granted publication date: 20130529

Termination date: 20131206