CN202881008U - Emergency treatment system for organic pollutant pollution of drinking water - Google Patents

Emergency treatment system for organic pollutant pollution of drinking water Download PDF

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CN202881008U
CN202881008U CN 201220523688 CN201220523688U CN202881008U CN 202881008 U CN202881008 U CN 202881008U CN 201220523688 CN201220523688 CN 201220523688 CN 201220523688 U CN201220523688 U CN 201220523688U CN 202881008 U CN202881008 U CN 202881008U
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water
reverse osmosis
nanofiltration
cleaning
regulating valve
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吴礼光
周志军
陈欢林
胡妙生
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Zhejiang Gongshang University
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Abstract

本实用新型公开了一种饮用水有机污染物污染的应急处理系统,包括预处理单元、相互并联并位于预处理单元下游的纳膜处理单元和反渗透膜处理单元;纳滤膜处理单元和反渗透膜处理单元相互并联后通过一输水总管与预处理单元相连;纳滤膜处理单元包括依次连接的纳滤进水调节阀、纳滤膜装置和纳滤产水电磁阀;反渗透膜处理单元包括依次连接的反渗透进水调节阀、反渗透膜装置和反渗透产水电磁阀;输水总管上自预处理单元依次设有第二调节阀、保安过滤器和进水切换阀。将被有机污染物污染的饮用水进行预处理后,根据所述有机污染物的分子量将预处理后的饮用水选择性的进行纳滤处理或反渗透处理。

Figure 201220523688

The utility model discloses an emergency treatment system for drinking water organic pollutant pollution, which comprises a pretreatment unit, a nanomembrane treatment unit and a reverse osmosis treatment unit connected in parallel and located downstream of the pretreatment unit; The osmotic membrane treatment units are connected in parallel to each other and connected to the pretreatment unit through a main water pipe; the nanofiltration membrane treatment unit includes a nanofiltration water inlet regulating valve, a nanofiltration membrane device and a nanofiltration water production solenoid valve connected in sequence; the reverse osmosis membrane treatment The unit includes a reverse osmosis water inlet regulating valve, a reverse osmosis membrane device and a reverse osmosis water production electromagnetic valve connected in sequence; a second regulating valve, a security filter and a water inlet switching valve are sequentially arranged on the main water delivery pipe from the pretreatment unit. After the drinking water polluted by organic pollutants is pretreated, the pretreated drinking water is selectively subjected to nanofiltration treatment or reverse osmosis treatment according to the molecular weight of the organic pollutants.

Figure 201220523688

Description

一种饮用水有机污染物污染的应急处理系统An emergency treatment system for drinking water organic pollutant pollution

技术领域technical field

本实用新型涉及饮用水深度处理技术领域,具体涉及一种饮用水水源地遭受突发性有机物污染事故情况下的安全、高效应急处理系统。The utility model relates to the technical field of advanced treatment of drinking water, in particular to a safe and efficient emergency treatment system when drinking water sources suffer from sudden organic pollution accidents.

背景技术Background technique

近年来,我国接连发生多起突发性水污染事件,事件发生频率及带来的危害呈逐年上升之势,给居民的饮水安全带来了隐患。据统计,我国2001年到2004年间发生水污染事故3988件,2005年松花江重大污染事故以后,水污染事故平均两至三天发生一起。2008年,经环保部直接调度处理的突发环境事件达135起,其中威胁群众饮用水源安全的有46起。可以说,我国正处于环境突发事件的高发期。In recent years, there have been many sudden water pollution incidents in my country, and the frequency of incidents and the harm caused by them are increasing year by year, which has brought hidden dangers to the safety of drinking water for residents. According to statistics, there were 3,988 water pollution accidents in my country from 2001 to 2004. After the Songhua River major pollution accident in 2005, an average of one water pollution accident occurred every two to three days. In 2008, there were 135 environmental emergencies directly dispatched and handled by the Ministry of Environmental Protection, 46 of which threatened the safety of drinking water sources for the public. It can be said that my country is in a period of high incidence of environmental emergencies.

我国多数水厂采用“混凝+过滤+沉淀+消毒”的处理工艺,这种工艺可以满足常规状况下持续性污染或微污染水源处理的需要,但是水厂现有工艺措施的抗冲击能力差,难以应对突发性、难处理、短时间高浓度的水质污染状况。另一方面,我国多数城市采用单一水源,一旦发生突发性水源污染,水源水质在短时间内可能无法满足供水水质的需要,而水厂的内储水能力通常只能维持几小时的供水。Most water plants in my country adopt the treatment process of "coagulation + filtration + sedimentation + disinfection", which can meet the needs of persistently polluted or slightly polluted water sources under normal conditions, but the existing process measures of water plants have poor impact resistance , It is difficult to deal with sudden, difficult to deal with, high-concentration water pollution in a short period of time. On the other hand, most cities in my country use a single water source. Once sudden water source pollution occurs, the water quality of the water source may not meet the needs of water supply in a short period of time, and the internal water storage capacity of the water plant can only maintain water supply for a few hours.

突发性水污染事件的污染物种类多样,应当根据污染物的特性采取相应的处理方法。对于颗粒污染物,可采用强化混凝和沉淀的方法;对于有机污染物,可采用吸附或者氧化的技术;对于生物污染,可采用氧化灭活、澄清等方法去除;对于重金属污染物和一般无机有毒有害物质,可采用吸附、化学沉淀、离子交换等方法去除。There are various types of pollutants in sudden water pollution incidents, and corresponding treatment methods should be adopted according to the characteristics of the pollutants. For particulate pollutants, enhanced coagulation and precipitation methods can be used; for organic pollutants, adsorption or oxidation techniques can be used; for biological pollution, methods such as oxidation inactivation and clarification can be used to remove; for heavy metal pollutants and general inorganic Toxic and harmful substances can be removed by adsorption, chemical precipitation, ion exchange and other methods.

例如,申请号为200910197861.2的中国发明专利申请公布了一种饮用水强化处理去除水中有机污染物的方法,具体步骤为:向待处理水中投加具有氧化性的化学药剂,反应0.5分钟~10分钟,采用改性颗粒滤料滤床过滤;其中:每升待处理水中化学药剂的加入量为0.2~5mg。使用经铁、锰、铝等金属的氧化物进行表面改性的石英砂、沸石、堇青石、陶粒等滤床过滤颗粒滤料,在过滤前向待过滤的水中加入一定浓度的氧化性混合药剂,水在滤床中停留一定时间后流出滤床时,水中天然有机物和微量有机污染物能够被高效去除,同时投加的药剂不会穿透滤层。该发明方法对水中天然有机物、尤其是在一般情况下高锰酸钾、臭氧、双氧水难以快速氧化去除的难降解微量有机污染物去除效果较好。For example, the Chinese invention patent application with the application number 200910197861.2 discloses a method for the enhanced treatment of drinking water to remove organic pollutants in water. The specific steps are: add oxidizing chemicals to the water to be treated, and react for 0.5 minutes to 10 minutes , using a modified particle filter bed to filter; wherein: the amount of chemical agent added per liter of water to be treated is 0.2-5 mg. Use the quartz sand, zeolite, cordierite, ceramsite and other filter beds modified by iron, manganese, aluminum and other metal oxides to filter the granular filter material, and add a certain concentration of oxidizing mixture to the water to be filtered before filtering Chemicals, when the water stays in the filter bed for a certain period of time and then flows out of the filter bed, the natural organic matter and trace organic pollutants in the water can be efficiently removed, and the added chemical will not penetrate the filter layer. The method of the invention has a good removal effect on natural organic matter in water, especially refractory trace organic pollutants which are difficult to be quickly oxidized and removed by potassium permanganate, ozone and hydrogen peroxide under normal circumstances.

面对日益严峻的水安全形势,应尽早完善我国突发性水污染事件的应急体系,包括水源地的保护、应急管理机构、相关法律法规、应急监测设备、应急处理方法以及应急供水预案等。面对日益恶化的水源水质状况和随时可能发生的突发性水污染事件,水厂应当增加必要的应急措施,制定相应的应急方案。Facing the increasingly severe water security situation, the emergency response system for sudden water pollution incidents in my country should be improved as soon as possible, including protection of water sources, emergency management agencies, relevant laws and regulations, emergency monitoring equipment, emergency treatment methods, and emergency water supply plans. In the face of deteriorating water quality conditions and sudden water pollution incidents that may occur at any time, water plants should increase necessary emergency measures and formulate corresponding emergency plans.

实用新型内容Utility model content

本实用新型提供了一种饮用水有机污染物污染的应急处理系统,对饮用水水源地发生有机污染物污染时,根据有机污染物的分子量对饮用水进行应急处理,安全、高效。The utility model provides an emergency treatment system for organic pollutant pollution of drinking water. When organic pollutant pollution occurs in a drinking water source, emergency treatment is carried out for drinking water according to the molecular weight of the organic pollutant, which is safe and efficient.

一种饮用水有机污染物污染的应急处理系统,包括预处理单元、相互并联且位于所述预处理单元下游的纳滤膜处理单元和反渗透膜处理单元;所述纳滤膜处理单元和反渗透膜处理单元相互并联后通过一输水总管与所述预处理单元相连;所述纳滤膜处理单元包括依次连接的纳滤进水调节阀、纳滤膜装置和纳滤产水电磁阀;所述反渗透膜处理单元包括依次连接的反渗透进水调节阀、反渗透膜装置和反渗透产水电磁阀;所述输水总管上自所述预处理单元依次设有第二调节阀、保安过滤器和进水切换阀。An emergency treatment system for drinking water organic pollutant pollution, comprising a pretreatment unit, a nanofiltration membrane treatment unit and a reverse osmosis membrane treatment unit connected in parallel and located downstream of the pretreatment unit; the nanofiltration membrane treatment unit and the reverse osmosis treatment unit The osmotic membrane treatment units are connected in parallel with each other and connected to the pretreatment unit through a water delivery main; the nanofiltration membrane treatment unit includes a nanofiltration water inlet regulating valve, a nanofiltration membrane device and a nanofiltration water production solenoid valve connected in sequence; The reverse osmosis membrane treatment unit includes a reverse osmosis water inlet regulating valve, a reverse osmosis membrane device and a reverse osmosis water production electromagnetic valve connected in sequence; the water main pipe is sequentially provided with a second regulating valve, a Security filter and water inlet switching valve.

本实用新型的系统用于饮用水水源地受有机污染物污染后的应急处理,若水源水遭受的有机污染物分子量大于或等于200道尔顿时,将预处理单元的出水切换至纳滤膜处理单元进行深度处理,去除水中的有机污染物,产水存于相应的储水池中;若水源水遭受的有机污染物分子量小于200道尔顿时,将预处理单元的出水切换至反渗透膜处理单元进行深度处理,去除水中的有机污染物,产水存于相应的储水池中。The system of the utility model is used for emergency treatment after drinking water sources are polluted by organic pollutants. If the molecular weight of organic pollutants in the source water is greater than or equal to 200 Daltons, the effluent of the pretreatment unit is switched to nanofiltration membrane treatment The unit performs advanced treatment to remove organic pollutants in the water, and the produced water is stored in the corresponding storage tank; if the molecular weight of organic pollutants encountered in the source water is less than 200 Daltons, switch the effluent from the pretreatment unit to the reverse osmosis membrane treatment unit Advanced treatment is carried out to remove organic pollutants in the water, and the produced water is stored in the corresponding storage tank.

设置预处理单元的目的是为了去除水中的悬浮物、颗粒物、胶体和细菌等,就所述预处理单元本身而言,可以是现有的常规预处理工艺,本实用新型中,优选地,所述预处理单元包括依次连接的自清洗过滤器、超滤装置和水箱,所述输水总管与水箱相连。The purpose of arranging the pretreatment unit is to remove suspended solids, particles, colloids and bacteria in the water. As far as the pretreatment unit itself is concerned, it can be an existing conventional pretreatment process. In the present utility model, preferably, the The pretreatment unit includes a self-cleaning filter, an ultrafiltration device and a water tank connected in sequence, and the water main pipe is connected with the water tank.

所述自清洗过滤器使用微孔膜,膜孔径为50-150μm,自清洗过滤器具有结构紧凑,标准模块化设计,灵活方便,占地面积小等特点。The self-cleaning filter uses a microporous membrane with a pore size of 50-150 μm. The self-cleaning filter has the characteristics of compact structure, standard modular design, flexibility and convenience, and small footprint.

所述的超滤装置中使用的超滤膜材质包括聚偏氟乙烯、聚氯乙烯、聚砜、聚醚砜、聚丙烯、聚乙烯膜,超滤膜孔径为0.01-0.1μm,超滤膜形式为中空纤维膜。The ultrafiltration membrane material used in the ultrafiltration device includes polyvinylidene fluoride, polyvinyl chloride, polysulfone, polyethersulfone, polypropylene, polyethylene membrane, the ultrafiltration membrane pore size is 0.01-0.1 μm, and the ultrafiltration membrane In the form of hollow fiber membranes.

为了减少水的用量,控制处理成本,所述预处理单元设有一套自清洗系统,用超滤处理后的清水反冲洗超滤装置,即:In order to reduce water consumption and control treatment costs, the pretreatment unit is provided with a set of self-cleaning system, and the ultrafiltration device is backwashed with clean water after ultrafiltration treatment, namely:

所述水箱与超滤装置间设有超滤反冲洗水管,所述超滤反冲洗水管上沿水流方向依次设有反冲洗进水调节阀和反冲洗水泵。An ultrafiltration backwashing water pipe is provided between the water tank and the ultrafiltration device, and a backwashing water inlet regulating valve and a backwashing water pump are sequentially arranged on the ultrafiltration backwashing water pipe along the water flow direction.

更优选地,所述超滤反冲洗水管上还设有清洗剂投加装置。More preferably, the ultrafiltration backwash water pipe is also provided with a cleaning agent dosing device.

所述的超滤装置采用全量过滤,自动反洗,恒流控制运行方式,运行中定期对超滤膜进行反冲洗和化学强化反洗,根据进入超滤系统的水质情况,确定反冲洗频率、反冲洗时间和反冲洗强度,反冲洗频率一般为1-2次/hr,反冲洗时间为30-60s/次,反冲洗强度为30-60L/m2.hr。根据进入超滤系统的水质情况,确定化学强化反洗频率和合适的化学清洗剂,化学强化反洗频率一般为6-12次/年,化学清洗剂一般为酸及氧化性清洗剂,如盐酸或有机酸,次氯酸钠和氢氧化钠溶液。在化学强化反洗过程中,将化学清洗液的pH值控制在2-12之间,温度不超过45℃,通过短时间(5-15min)的浸泡和循环清洗后将化学清洗液排出,超滤膜的性能得以恢复。The ultrafiltration device adopts full volume filtration, automatic backwashing, and constant flow control mode of operation. During operation, the ultrafiltration membrane is regularly backwashed and chemically enhanced backwashed. According to the water quality entering the ultrafiltration system, the backwashing frequency, Backwashing time and backwashing intensity, the backwashing frequency is generally 1-2 times/hr, the backwashing time is 30-60s/time, and the backwashing intensity is 30-60L/m 2 .hr. According to the water quality entering the ultrafiltration system, determine the frequency of chemically enhanced backwashing and the appropriate chemical cleaning agent. The frequency of chemically enhanced backwashing is generally 6-12 times per year. The chemical cleaning agent is generally acid and oxidizing cleaning agent, such as hydrochloric acid. or organic acids, sodium hypochlorite and sodium hydroxide solutions. In the process of chemically enhanced backwashing, the pH value of the chemical cleaning solution is controlled between 2-12, and the temperature does not exceed 45°C. The performance of the filter membrane was restored.

所述的纳滤膜处理单元和反渗透膜处理单元也设置自动反洗,其反洗系统可以是每个处理单元独立设置,也可以是两个处理单元共用一套,本实用新型中,采用后一种方案,即:The nanofiltration membrane processing unit and the reverse osmosis membrane processing unit are also provided with automatic backwashing, and the backwashing system can be set independently for each processing unit, or can be shared by two processing units. In the utility model, adopt The latter option, namely:

还包括一自清洗系统,所述自清洗系统包括依次连接的清洗水箱、第三调节阀、化学清洗泵和清洗保安过滤器,所述清洗保安过滤器的出水管一路连接所述纳滤膜装置,一路连接所述反渗透膜装置,在连接所述纳滤膜装置和反渗透膜装置的管路上均设有调节阀,所述纳滤膜装置和反渗透膜装置上均设有浓水排放电磁阀。It also includes a self-cleaning system, the self-cleaning system includes a cleaning water tank connected in sequence, a third regulating valve, a chemical cleaning pump and a cleaning security filter, and the outlet pipe of the cleaning security filter is connected to the nanofiltration membrane device all the way , one way is connected to the reverse osmosis membrane device, a regulating valve is provided on the pipeline connecting the nanofiltration membrane device and the reverse osmosis membrane device, and the concentrated water discharge is provided on the nanofiltration membrane device and the reverse osmosis membrane device The electromagnetic valve.

所述的纳滤膜装置中使用的纳滤膜为市售的Dow、GE、Hydranautics、东丽、北斗星、时代沃顿的4英寸或8英寸卷式纳滤膜组件,膜材质为芳香聚酰胺或聚哌嗪酰胺。The nanofiltration membrane used in the described nanofiltration membrane device is a commercially available Dow, GE, Hydranautics, Toray, Big Dipper, Times Wharton's 4-inch or 8-inch roll-type nanofiltration membrane module, and the membrane material is aromatic polyamide or polypiperazinamide.

纳滤膜组件在运行一定时间后会受到污染,造成膜性能的下降,如此需要对纳滤膜进行化学清洗,以恢复其正常的性能。根据进入纳滤膜处理系统的水质情况,确定化学清洗的频率和合适的化学清洗剂,化学清洗频率一般为3-6次/年,化学清洗剂一般为盐酸或有机酸或氢氧化钠溶液。在化学清洗过程中,将化学清洗液的pH值控制在2-12之间,温度不超过45℃,通过短时间(5-10min)的浸泡和循环清洗后将化学清洗液排出,纳滤膜的性能得以恢复。The nanofiltration membrane module will be polluted after running for a certain period of time, resulting in a decline in membrane performance, so it is necessary to chemically clean the nanofiltration membrane to restore its normal performance. According to the water quality entering the nanofiltration membrane treatment system, determine the frequency of chemical cleaning and the appropriate chemical cleaning agent. The frequency of chemical cleaning is generally 3-6 times per year. The chemical cleaning agent is generally hydrochloric acid or organic acid or sodium hydroxide solution. During the chemical cleaning process, the pH value of the chemical cleaning solution is controlled between 2-12, the temperature does not exceed 45°C, and the chemical cleaning solution is discharged after a short time (5-10min) soaking and circular cleaning, and the nanofiltration membrane performance is restored.

反渗透膜装置中使用的反渗透膜为市售的Dow、GE、Hydranautics、东丽、北斗星、时代沃顿的4英寸或8英寸卷式反渗透膜组件,膜材质为芳香聚酰胺。The reverse osmosis membrane used in the reverse osmosis membrane device is a commercially available 4-inch or 8-inch roll-type reverse osmosis membrane module from Dow, GE, Hydranautics, Toray, Big Dipper, and Times Wharton. The membrane material is aromatic polyamide.

反渗透膜组件在运行一定时间后会受到污染,造成膜性能的下降,如此需要对反渗透膜进行化学清洗,以恢复其正常的性能。根据进入反渗透膜处理系统的水质情况,确定化学清洗的频率和合适的化学清洗剂,化学清洗频率一般为3-6次/年,化学清洗剂一般为盐酸或有机酸或氢氧化钠溶液。在化学清洗过程中,将化学清洗液的pH值控制在2-12之间,温度不超过45℃,通过短时间(5-10min)的浸泡和循环清洗后将化学清洗液排出,反渗透膜的性能得以恢复。The reverse osmosis membrane module will be polluted after running for a certain period of time, resulting in a decline in membrane performance, so it is necessary to chemically clean the reverse osmosis membrane to restore its normal performance. According to the water quality entering the reverse osmosis membrane treatment system, determine the frequency of chemical cleaning and the appropriate chemical cleaning agent. The frequency of chemical cleaning is generally 3-6 times per year. The chemical cleaning agent is generally hydrochloric acid or organic acid or sodium hydroxide solution. During the chemical cleaning process, the pH value of the chemical cleaning solution is controlled between 2-12, the temperature does not exceed 45°C, and the chemical cleaning solution is discharged after a short time (5-10min) of immersion and circulation cleaning, the reverse osmosis membrane performance is restored.

更优选地,所述输水总管上还设有阻垢剂投加装置。阻垢剂投加装置中投加的阻垢剂为市售纳滤膜用阻垢剂。More preferably, an antiscalant dosing device is also provided on the water main pipe. The scale inhibitor added to the scale inhibitor dosing device is commercially available nanofiltration membrane scale inhibitor.

优选地,所述自清洗过滤器前设有混凝剂投加装置。混凝剂投加装置中投加的混凝剂包括三氯化铁、硫酸铝和聚合铝,增强自清洗过滤器的过滤效果。Preferably, a coagulant dosing device is provided before the self-cleaning filter. The coagulant added in the coagulant dosing device includes ferric chloride, aluminum sulfate and polyaluminum to enhance the filtering effect of the self-cleaning filter.

本实用新型利用纳滤膜或反渗透膜对有机物的高去除特性,在饮用水水源地遭受突发性有机物污染事故情况下,能及时、高效的获得安全、合格的饮用水。The utility model utilizes the high organic removal characteristics of the nanofiltration membrane or the reverse osmosis membrane, and can obtain safe and qualified drinking water in a timely and efficient manner when drinking water sources suffer from sudden organic pollution accidents.

附图说明Description of drawings

图1是本实用新型的工艺流程简图;Fig. 1 is a schematic diagram of the technical process of the present utility model;

图2是本实用新型的结构示意图。Fig. 2 is a schematic structural view of the utility model.

图中所示附图标记如下:The reference signs shown in the figure are as follows:

1-污染水储水池  2-第一进水调节阀  3-第一增压水泵1-Polluted water storage tank 2-The first water inlet regulating valve 3-The first booster pump

4-自清洗过滤器  5-排水调节阀  6-超滤进水调节阀4-Self-cleaning filter 5-Drain regulating valve 6-Ultrafiltration water inlet regulating valve

7-超滤装置  8-超滤产水电磁阀  9-反冲洗排水阀7-Ultrafiltration device 8-Ultrafiltration water production solenoid valve 9-Backwash drain valve

10-水箱  11-第二进水调节阀  12-第二增压水泵10-Water tank 11-Second water inlet regulating valve 12-Second booster pump

13-保安过滤器  14-高压水泵  15-进水切换阀13-Security filter 14-High pressure water pump 15-Inlet switching valve

16-纳滤进水调节阀  17-纳滤膜装置  18-纳滤产水电磁阀16-Nanofiltration water inlet regulating valve 17-Nanofiltration membrane device 18-Nanofiltration water production solenoid valve

19-纳滤浓水排放电磁 20-反渗透进水调节阀 21-反渗透膜装置19-Nanofiltration Concentrated Water Discharge Electromagnetic 20-Reverse Osmosis Inlet Regulating Valve 21-Reverse Osmosis Membrane Device

valve

22-反渗透产水电磁阀 23-反渗透浓水排放电 24-饮用水储水池22-Reverse osmosis water production solenoid valve 23-Reverse osmosis concentrated water discharge electricity 24-Drinking water storage tank

磁阀Solenoid valve

25-混凝剂投加装置  26-反冲洗进水调节阀 27-清洗剂投加装置25-Coagulant dosing device 26-Backwash water inlet regulating valve 27-Cleaning agent dosing device

28-反冲洗水泵  29-阻垢剂投加装置  30-清洗水箱28-Backwashing water pump 29-Scale inhibitor dosing device 30-Cleaning water tank

31-第三进水调节阀  32-化学清洗泵  33-清洗保安过滤器31-The third water inlet regulating valve 32-Chemical cleaning pump 33-Cleaning security filter

34-第四进水调节阀  35-第五进水调节阀。34-the fourth water inlet regulating valve 35-the fifth water inlet regulating valve.

具体实施方式Detailed ways

如图2所示,一种饮用水有机物污染的应急处理系统,包括污染水储水池1、预处理单元、位于预处理单元下游且相互并联的纳滤膜处理单元和反渗透膜处理单元、饮用水储水池24。As shown in Figure 2, an emergency treatment system for drinking water organic matter pollution includes a polluted water storage tank 1, a pretreatment unit, a nanofiltration membrane treatment unit and a reverse osmosis membrane treatment unit located downstream of the pretreatment unit and connected in parallel, a drinking water Water reservoir 24.

预处理单元包括自清洗过滤器4和超滤膜处理单元,超滤膜处理单元包括超滤装置7和水箱10及反清洗设备,污染水储水池1、自清洗过滤器4、超滤装置7和水箱10之间依次通过输水管连接,在污染水储水池1和自清洗过滤器4之间的输水管上沿水流方向依次设置第一进水调节阀2、混凝剂投加装置25和第一增压水泵3,通过第一进水调节阀2调节进入自清洗过滤器4中的水量,通过第一增压水泵3将污染水储水池1中的水泵入自清洗过滤器4中,通过混凝剂投加装置25向该部分输水管中投加混凝剂。The pretreatment unit includes a self-cleaning filter 4 and an ultrafiltration membrane treatment unit, the ultrafiltration membrane treatment unit includes an ultrafiltration device 7, a water tank 10 and backwashing equipment, a polluted water storage tank 1, a self-cleaning filter 4, and an ultrafiltration device 7 and the water tank 10 are sequentially connected by a water delivery pipe, and the first water inlet regulating valve 2, the coagulant dosing device 25 and the The first booster water pump 3 adjusts the amount of water entering the self-cleaning filter 4 through the first water inlet regulating valve 2, and pumps the water in the polluted water storage tank 1 into the self-cleaning filter 4 through the first booster water pump 3, A coagulant is added to this part of the water delivery pipe through a coagulant dosing device 25 .

自清洗过滤器4带有排水调节阀5,在自清洗过滤器4与超滤装置7之间的输水管上设置超滤进水调节阀6,超滤进水调节阀6调节进入超滤装置7中的水量,在超滤装置7与水箱10之间的输水管上设置超滤产水电磁阀8。The self-cleaning filter 4 is equipped with a drainage regulating valve 5, and an ultrafiltration water inlet regulating valve 6 is set on the water delivery pipe between the self-cleaning filter 4 and the ultrafiltration device 7, and the ultrafiltration water inlet regulating valve 6 regulates the water entering the ultrafiltration device The amount of water in 7, on the water delivery pipe between ultrafiltration device 7 and water tank 10, ultrafiltration produced water solenoid valve 8 is set.

水箱10与超滤装置7之间还设置一根超滤反冲洗水管,通过该超滤反冲洗水管向超滤装置7中输送反清洗水,在超滤反冲洗水管上且沿反清洗水流动方向依次设置反冲洗进水调节阀26、清洗剂投加装置27和反冲洗水泵28,超滤装置7带有反冲洗排水阀9,反冲洗进水调节阀26调节反冲洗水的流量,清洗剂投加装置27向超滤反冲洗水管中投加清洗剂,反冲洗水泵28将水箱10中的清水泵入超滤装置7中对超滤装置7进行反冲洗,反冲洗后的浓水由反冲洗排水阀9流出。An ultrafiltration backwashing water pipe is also arranged between the water tank 10 and the ultrafiltration device 7, and the backwashing water is delivered to the ultrafiltration device 7 through the ultrafiltration backwashing water pipe, and flows along the backwashing water on the ultrafiltration backwashing water pipe The backwash water inlet regulating valve 26, the cleaning agent dosing device 27 and the backwash water pump 28 are set in turn in the direction, the ultrafiltration device 7 has a backwash drain valve 9, and the backwash water inlet regulating valve 26 regulates the flow of backwash water, cleaning The agent dosing device 27 adds cleaning agent to the ultrafiltration backwashing water pipe, and the backwashing water pump 28 pumps the clear water in the water tank 10 into the ultrafiltration device 7 to backwash the ultrafiltration device 7, and the concentrated water after backwashing is Backwash drain valve 9 flows out.

水箱10通过一根输水总管连接至并联的纳滤膜处理单元和反渗透膜处理单元,在该输水管总上沿水流方向依次设置第二进水调节阀11、阻垢剂投加装置29、第二增压水泵12、保安过滤器13、高压水泵14和进水切换阀15,该进水切换阀15采用球阀,在进水切换阀15处通过两输水支管并联纳滤膜处理单元和反渗透膜处理单元,两输水支管并联后汇总连接至饮用水储水池24。The water tank 10 is connected to the parallel nanofiltration membrane treatment unit and the reverse osmosis membrane treatment unit through a main water delivery pipe, and the second water inlet regulating valve 11 and the antiscalant dosing device 29 are sequentially arranged on the water delivery pipe along the water flow direction , the second booster water pump 12, the security filter 13, the high-pressure water pump 14 and the water inlet switching valve 15, the water inlet switching valve 15 adopts a ball valve, and the nanofiltration membrane processing unit is connected in parallel at the water inlet switching valve 15 through two water delivery branches and the reverse osmosis membrane treatment unit, the two water delivery branch pipes are connected in parallel and connected to the drinking water storage tank 24 together.

纳滤膜处理单元包括纳滤膜装置17,在纳滤膜装置17进水测的输水支管上设有纳滤进水调节阀16,在纳滤膜装置17出水测的输水支管上设置纳滤产水电磁阀18。The nanofiltration membrane processing unit comprises a nanofiltration membrane device 17, a nanofiltration water inlet regulating valve 16 is arranged on the water delivery branch pipe of the nanofiltration membrane device 17 water inlet measurement, and a nanofiltration water inlet regulating valve 16 is arranged on the water delivery branch pipe of the nanofiltration membrane device 17 water outlet measurement. Nanofiltration produced water electromagnetic valve 18.

反渗透膜处理单元包括反渗透膜装置21,在反渗透膜装置21进水侧的输水支管上设置反渗透进水调节阀20,在反渗透膜装置21出水侧的输水支管上设置反渗透产水电磁阀22。The reverse osmosis membrane processing unit includes a reverse osmosis membrane device 21, a reverse osmosis water inlet regulating valve 20 is set on the water delivery branch pipe on the water inlet side of the reverse osmosis membrane device 21, and a reverse osmosis water inlet regulating valve 20 is set on the water delivery branch pipe on the water outlet side of the reverse osmosis membrane device 21. Permeate the electromagnetic valve 22 of product water.

纳滤膜处理单元和反渗透处理单元共用一套自清洗系统,自清洗系统包括由清洗水管依次连接的清洗水箱30、第三进水调节阀31、化学清洗泵32和清洗保安过滤器33,清洗保安过滤器33的出水分两路清洗水支管,分别连接纳滤膜装置17和反渗透膜装置21,在连接纳滤膜装置17的清洗水支管上设置第四进水调节阀34,在连接反渗透膜装置21的清洗水支管上设置第五进水调节阀35,纳滤膜装置17上设有纳滤浓水排放电磁阀19,反渗透膜装置21上设有反渗透浓水排放电磁阀23。The nanofiltration membrane treatment unit and the reverse osmosis treatment unit share a set of self-cleaning system. The self-cleaning system includes a cleaning water tank 30 connected in sequence by a cleaning water pipe, a third water inlet regulating valve 31, a chemical cleaning pump 32 and a cleaning security filter 33. Clean the two-way cleaning water branch pipes of the water outlet of the security filter 33, connect the nanofiltration membrane device 17 and the reverse osmosis membrane device 21 respectively, and set the fourth water inlet regulating valve 34 on the cleaning water branch pipe connected to the nanofiltration membrane device 17. The fifth water inlet regulating valve 35 is provided on the cleaning water branch pipe connected to the reverse osmosis membrane device 21, the nanofiltration concentrated water discharge solenoid valve 19 is provided on the nanofiltration membrane device 17, and the reverse osmosis concentrated water discharge valve 19 is provided on the reverse osmosis membrane device 21. Solenoid valve 23.

在超滤装置7、纳滤膜装置17和反渗透膜装置21处均设有电控系统,本实施方式的应急处理系统,可以设置为手动控制方式,也可以设置为自动控制方式,自动控制方式通过安装PLC控制系统实现。The ultrafiltration device 7, the nanofiltration membrane device 17 and the reverse osmosis membrane device 21 are all provided with an electronic control system. The emergency treatment system of this embodiment can be set to a manual control mode, or can be set to an automatic control mode. The way is realized by installing PLC control system.

本实用新型的工艺流程如下:The technological process of the present utility model is as follows:

如图1、图2所示,受有机物污染的水源水经常规自来水处理工艺处理后,存于污染水储水池1中,经第一增压水泵3泵入自清洗过滤器4和超滤装置7,出水储存于水箱10。As shown in Figure 1 and Figure 2, the source water polluted by organic matter is treated by conventional tap water treatment processes, stored in the polluted water storage tank 1, and pumped into the self-cleaning filter 4 and ultrafiltration device by the first booster pump 3 7. The outlet water is stored in the water tank 10.

根据进水水质情况,向自清洗过滤器4进水管中投加混凝剂,以提高自清洗过滤器4的过滤效果,减缓超滤膜的污染。采用超滤出水,通过反冲洗水泵28对超滤装置7的超滤膜进行定期反冲洗。必要时,通过向超滤反冲洗水管中投加化学清洗剂对超滤膜进行化学清洗。According to the water quality of the influent, a coagulant is added to the water inlet pipe of the self-cleaning filter 4 to improve the filtering effect of the self-cleaning filter 4 and slow down the pollution of the ultrafiltration membrane. The ultrafiltration water is used, and the ultrafiltration membrane of the ultrafiltration device 7 is periodically backwashed by the backwash water pump 28 . When necessary, the ultrafiltration membrane is chemically cleaned by adding chemical cleaning agent to the ultrafiltration backwash water pipe.

根据水源水遭受化学污染的有机物分子量大小,以确定是采用纳滤膜处理单元或反渗透膜处理单元作进一步的深度处理。当水源水遭受的有机污染物分子量大于或等于200道尔顿时,经第二进水调节阀11、第二增压水泵12、保安过滤器13、高压水泵14、再通过进水切换阀15将储于水箱10中的水引入纳滤膜装置17,纳滤产水经纳滤产水电磁阀18流入饮用水储水池24,纳滤浓水经纳滤浓水排放电磁阀19回流至污染水储水池1或排放。According to the molecular weight of the chemically polluted organic matter in the source water, it is determined whether to use a nanofiltration membrane treatment unit or a reverse osmosis membrane treatment unit for further advanced treatment. When the molecular weight of organic pollutants suffered by the source water is greater than or equal to 200 Daltons, the water will pass through the second water inlet regulating valve 11, the second booster water pump 12, the security filter 13, the high pressure water pump 14, and then through the water inlet switching valve 15. The water stored in the water tank 10 is introduced into the nanofiltration membrane device 17, the nanofiltration produced water flows into the drinking water storage tank 24 through the nanofiltration produced water solenoid valve 18, and the nanofiltration concentrated water flows back to the polluted water through the nanofiltration concentrated water discharge solenoid valve 19 Reservoir 1 or discharge.

当水源水遭受的有机污染物分子量小于200道尔顿时,经第二进水调节阀11、第二增压水泵12、保安过滤器13、高压水泵14、再通过进水切换阀15将储于水箱10中的水引入反渗透膜装置21,反渗透产水经反渗透产水电磁阀22流入饮用水储水池24,反渗透浓水经反渗透浓水排放电磁阀23回至污染水储水池1或排放。When the molecular weight of organic pollutants suffered by the source water is less than 200 Daltons, the water will be stored in the The water in the water tank 10 is introduced into the reverse osmosis membrane device 21, the reverse osmosis produced water flows into the drinking water storage tank 24 through the reverse osmosis produced water solenoid valve 22, and the reverse osmosis concentrated water returns to the polluted water storage tank through the reverse osmosis concentrated water discharge solenoid valve 23 1 or discharge.

实施例Example

邻苯二甲酸酯(Phthalic acid esters,PAEs)作为增塑剂广泛应用于塑料制品的加工,另外还可作为食品包装、农药、化妆品、儿童玩具、以及医药产品的生产原料。邻苯二甲酸酯在生产和使用过程中将不可避免的进入水环境,特别是生产和使用企业及运输工具在遭受突发事故时,进入水环境的风险更大。邻苯二甲酸酯是一类典型的内分泌干扰物,对人体有很强的危害作用。我国新的饮用水国家标准(GB5749-2006)中就包含有邻苯二甲酸二乙酯、邻苯二甲酸二丁酯、和邻苯二甲酸二(2-乙基己基)酯3项指标。Phthalic acid esters (PAEs) are widely used as plasticizers in the processing of plastic products, and can also be used as raw materials for the production of food packaging, pesticides, cosmetics, children's toys, and pharmaceutical products. Phthalates will inevitably enter the water environment during production and use, especially when production and use enterprises and transportation vehicles suffer accidents, the risk of entering the water environment is greater. Phthalates are a typical class of endocrine disruptors, which have a strong harmful effect on the human body. my country's new national standard for drinking water (GB5749-2006) includes three indicators of diethyl phthalate, dibutyl phthalate, and bis(2-ethylhexyl) phthalate.

根据本实用新型提供的方法和系统,设计并制造了一套处理能力为500m3/d的基于纳滤或反渗透为核心的安全、高效饮用水应急处理设备,用于水源水遭受突发性邻苯二甲酸酯污染情况下的安全饮用水处理。According to the method and system provided by the utility model, a set of safe and efficient drinking water emergency treatment equipment with a treatment capacity of 500m 3 /d based on nanofiltration or reverse osmosis as the core is designed and manufactured, which is used for water source water suffering sudden Safe drinking water treatment in the presence of phthalate contamination.

应急处理设备中的自清洗过滤器选用北京洁明之晨新能源技术有限公司的JY2-3型盘式过滤器,过滤精度为100μm。超滤膜处理单元中的超滤膜采用北京坎普尔环保技术有限公司生产的SVU-1060-C型膜组件。超滤膜处理单元的出水水质:浊度≤0.5NTU,SDI≤3,悬浮物<5mg/L。运行中超滤膜的反冲洗频率为2次/hr,反冲洗时间为30秒/次,反洗强度为45L/m2.hr。运行中超滤膜的化学强化反洗频率一般为0.5次/天,化学清洗剂为200ppm次氯酸钠溶液。在化学强化反洗过程中,通过1min的浸泡和1min循环清洗后将化学清洗液排出,超滤膜的性能得以恢复。The self-cleaning filter in the emergency treatment equipment is the JY2-3 disc filter of Beijing Jiemingzhichen New Energy Technology Co., Ltd., with a filtration accuracy of 100 μm. The ultrafiltration membrane in the ultrafiltration membrane treatment unit adopts the SVU-1060-C membrane module produced by Beijing Kanpur Environmental Protection Technology Co., Ltd. The effluent water quality of the ultrafiltration membrane treatment unit: turbidity ≤ 0.5NTU, SDI ≤ 3, suspended solids < 5mg/L. The backwashing frequency of the ultrafiltration membrane during operation is 2 times/hr, the backwashing time is 30 seconds/time, and the backwashing intensity is 45L/m 2 .hr. The chemically enhanced backwash frequency of the ultrafiltration membrane during operation is generally 0.5 times per day, and the chemical cleaning agent is 200ppm sodium hypochlorite solution. In the process of chemically enhanced backwashing, the performance of the ultrafiltration membrane can be restored by discharging the chemical cleaning solution after soaking for 1 minute and cyclic cleaning for 1 minute.

当水源水遭受邻苯二甲酸二乙酯污染,水中邻苯二甲酸二乙酯浓度为1mg.L-1时,由于邻苯二甲酸二丁酯的分子量是222.2道尔顿,大于200道尔顿,因此采用纳滤膜处理系统进行深度处理。纳滤膜选用GE公司的DK4040膜组件,采用一级二段法,一段的运行压力为1.8MPa,水的回收率≥70%,邻苯二甲酸二乙酯的去除率≥75.0%。When the source water is polluted by diethyl phthalate and the concentration of diethyl phthalate in the water is 1mg.L -1 , since the molecular weight of dibutyl phthalate is 222.2 daltons, it is greater than 200 daltons Therefore, a nanofiltration membrane treatment system is used for advanced treatment. The nanofiltration membrane uses DK4040 membrane module of GE Company, adopts one-stage two-stage method, the operating pressure of the first stage is 1.8MPa, the recovery rate of water is ≥70%, and the removal rate of diethyl phthalate is ≥75.0%.

采用以DK8040纳滤膜为核心制造的应急处理设备处理后的饮用水中邻苯二甲酸二乙酯的浓度小于0.25mg.L-1,低于我国生活饮用水卫生标准(GB5749-2006)中设定的邻苯二甲酸二乙酯指标值。纳滤处理后的饮用水相关水质参数与GB5749-2006标准的对比结果如表1。The concentration of diethyl phthalate in the drinking water treated by the emergency treatment equipment manufactured with DK8040 nanofiltration membrane as the core is less than 0.25mg.L -1 , which is lower than the sanitary standard for drinking water in China (GB5749-2006). Set index value of diethyl phthalate. The comparison results of drinking water-related water quality parameters after nanofiltration treatment and GB5749-2006 standard are shown in Table 1.

表1Table 1

Figure BDA00002241580600081
Figure BDA00002241580600081

当水源水遭受邻苯二甲酸二甲酯污染,水中邻苯二甲酸二甲酯浓度为1mg.L-1时,由于邻苯二甲酸二甲酯的分子量是194.2,小于200道尔顿,因此采用反渗透膜处理系统进行深度处理。反渗透膜选用杭州北斗星膜制品有限公司生产的BDX8040B-375膜组件,采用一级二段法,一段的运行压力为1.8MPa,水的回收率≥70%,邻苯二甲酸二甲酯的去除率≥95.0%。处理后的饮用水中邻苯二甲酸二甲酯的浓度小于0.05mg.L-1。反渗透处理后的饮用水相关水质参数与GB5749-2006标准的对比结果如表2。When the source water is polluted by dimethyl phthalate, and the concentration of dimethyl phthalate in the water is 1 mg.L -1 , since the molecular weight of dimethyl phthalate is 194.2, which is less than 200 Daltons, therefore The reverse osmosis membrane treatment system is used for advanced treatment. The reverse osmosis membrane adopts BDX8040B-375 membrane module produced by Hangzhou Beidouxing Membrane Products Co., Ltd., adopts one-stage two-stage method, the operating pressure of the first stage is 1.8MPa, the water recovery rate is ≥ 70%, and the removal of dimethyl phthalate Rate ≥ 95.0%. The concentration of dimethyl phthalate in the treated drinking water is less than 0.05 mg.L -1 . Table 2 shows the comparison results of drinking water-related water quality parameters after reverse osmosis treatment and the GB5749-2006 standard.

表2Table 2

Figure BDA00002241580600091
Figure BDA00002241580600091

由表1和表2的结果可知,由本实用新型的应急处理系统和工艺处理水源受有机污染物污染的饮用水,方便快捷,处理后的饮用水均符合GB5749-2006的标准。From the results of Table 1 and Table 2, it can be seen that the emergency treatment system and process of the present invention treat drinking water polluted by organic pollutants, which is convenient and quick, and the treated drinking water meets the standard of GB5749-2006.

Claims (7)

1.一种饮用水有机污染物污染的应急处理系统,其特征在于,包括预处理单元、相互并联且位于所述预处理单元下游的纳滤膜处理单元和反渗透膜处理单元;  1. an emergency treatment system of drinking water organic pollutant pollution, it is characterized in that, comprise pretreatment unit, be connected in parallel with each other and be positioned at the nanofiltration membrane treatment unit and the reverse osmosis membrane treatment unit of described pretreatment unit downstream; 所述纳滤膜处理单元和反渗透膜处理单元相互并联后通过一输水总管与所述预处理单元相连;  The nanofiltration membrane treatment unit and the reverse osmosis membrane treatment unit are connected in parallel with each other and connected to the pretreatment unit through a water main pipe; 所述纳滤膜处理单元包括依次连接的纳滤进水调节阀、纳滤膜装置和纳滤产水电磁阀;  The nanofiltration membrane processing unit includes a nanofiltration water inlet regulating valve, a nanofiltration membrane device and a nanofiltration water production electromagnetic valve connected in sequence; 所述反渗透膜处理单元包括依次连接的反渗透进水调节阀、反渗透膜装置和反渗透产水电磁阀;  The reverse osmosis membrane processing unit includes a reverse osmosis water inlet regulating valve, a reverse osmosis membrane device and a reverse osmosis water production electromagnetic valve connected in sequence; 所述输水总管上自所述预处理单元依次设有第二调节阀、保安过滤器和进水切换阀。  The main water delivery pipe is sequentially provided with a second regulating valve, a security filter and a water inlet switching valve from the pretreatment unit. the 2.根据权利要求1所述的应急处理系统,其特征在于,所述预处理单元包括依次连接的自清洗过滤器、超滤装置和水箱,所述输水总管与水箱相连。  2. The emergency treatment system according to claim 1, wherein the pretreatment unit comprises a self-cleaning filter, an ultrafiltration device and a water tank connected in sequence, and the water main pipe is connected to the water tank. the 3.根据权利要求2所述的应急处理系统,其特征在于,所述水箱与超滤装置间设有超滤反冲洗水管,所述超滤反冲洗水管上沿水流方向依次设有反冲洗进水调节阀和反冲洗水泵。  3. The emergency treatment system according to claim 2, characterized in that, an ultrafiltration backwash water pipe is provided between the water tank and the ultrafiltration device, and a backwash inlet is sequentially provided on the ultrafiltration backwash water pipe along the water flow direction. Water regulating valve and backwash water pump. the 4.根据权利要求3所述的应急处理系统,其特征在于,所述超滤反冲洗水管上还设有清洗剂投加装置。  4. The emergency treatment system according to claim 3, characterized in that, the ultrafiltration backwash water pipe is also provided with a cleaning agent dosing device. the 5.根据权利要求1~4任一所述的应急处理系统,其特征在于,还包括一自清洗系统,所述自清洗系统包括依次连接的清洗水箱、第三调节阀、化学清洗泵和清洗保安过滤器,所述清洗保安过滤器的出水管一路连接所述纳滤膜装置,一路连接所述反渗透膜装置,在连接所述纳滤膜装置和反渗透膜装置的管路上均设有调节阀,所述纳滤膜装置和反渗透膜装置上均设有浓水排放电磁阀。  5. The emergency treatment system according to any one of claims 1 to 4, further comprising a self-cleaning system, said self-cleaning system comprising a cleaning water tank connected in sequence, a third regulating valve, a chemical cleaning pump and cleaning Security filter, the outlet pipe of the cleaning security filter is connected to the nanofiltration membrane device all the way, connected to the reverse osmosis membrane device all the way, and is provided on the pipeline connecting the nanofiltration membrane device and the reverse osmosis membrane device A regulating valve, the nanofiltration membrane device and the reverse osmosis membrane device are provided with concentrated water discharge solenoid valves. the 6.根据权利要求5所述的应急处理系统,其特征在于,所述输水总管上还设有阻垢剂投加装置。  6. The emergency treatment system according to claim 5, characterized in that, the water main pipe is also provided with a scale inhibitor dosing device. the 7.根据权利要求6所述的应急处理系统,其特征在于,所述自清洗过滤器前设有混凝剂投加装置。  7. The emergency treatment system according to claim 6, characterized in that a coagulant dosing device is provided in front of the self-cleaning filter. the
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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102874902A (en) * 2012-10-11 2013-01-16 浙江工商大学 Emergency treatment system and method for drinking water organic contaminant pollution
CN103626316A (en) * 2013-11-28 2014-03-12 深圳职业技术学院 Emergency treatment device for drinking water sources polluted by heavy metals
CN103755079A (en) * 2014-02-21 2014-04-30 河南洁源膜分离科技有限公司 Sewage treatment method for production of refined cotton
CN104211206A (en) * 2014-08-15 2014-12-17 浙江工商大学 Seawater reverse osmosis desalination technology for boats, and apparatus thereof
CN104355441A (en) * 2014-10-24 2015-02-18 杨晓斌 Coal mine wastewater recycling device
CN104445791A (en) * 2014-12-12 2015-03-25 青岛水务集团有限公司科技中心 Water purification and deep treatment device
CN104529035A (en) * 2014-12-24 2015-04-22 北京桑德环境工程有限公司 High-concentration organic wastewater zero-discharge treatment system and method
CN106277437A (en) * 2016-08-18 2017-01-04 成都振中电气有限公司 It is applicable to the water treatment system of remote districts
CN115475521A (en) * 2022-02-28 2022-12-16 青岛海尔施特劳斯水设备有限公司 Filter element and water purification device including the filter element
CN115677075A (en) * 2022-08-29 2023-02-03 湖北祥云(集团)化工股份有限公司 Emergency treatment method for phosphogypsum yard leakage liquid polluted spring water

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102874902B (en) * 2012-10-11 2014-07-09 浙江工商大学 Emergency treatment system and method for drinking water organic contaminant pollution
CN102874902A (en) * 2012-10-11 2013-01-16 浙江工商大学 Emergency treatment system and method for drinking water organic contaminant pollution
CN103626316B (en) * 2013-11-28 2015-08-12 深圳职业技术学院 A kind of for the emergency treatment device by heavy metal contamination drinking water source
CN103626316A (en) * 2013-11-28 2014-03-12 深圳职业技术学院 Emergency treatment device for drinking water sources polluted by heavy metals
CN103755079A (en) * 2014-02-21 2014-04-30 河南洁源膜分离科技有限公司 Sewage treatment method for production of refined cotton
CN103755079B (en) * 2014-02-21 2015-03-04 河南洁源膜分离科技有限公司 Sewage treatment method for production of refined cotton
CN104211206A (en) * 2014-08-15 2014-12-17 浙江工商大学 Seawater reverse osmosis desalination technology for boats, and apparatus thereof
CN104355441A (en) * 2014-10-24 2015-02-18 杨晓斌 Coal mine wastewater recycling device
CN104445791A (en) * 2014-12-12 2015-03-25 青岛水务集团有限公司科技中心 Water purification and deep treatment device
CN104529035A (en) * 2014-12-24 2015-04-22 北京桑德环境工程有限公司 High-concentration organic wastewater zero-discharge treatment system and method
CN106277437A (en) * 2016-08-18 2017-01-04 成都振中电气有限公司 It is applicable to the water treatment system of remote districts
CN115475521A (en) * 2022-02-28 2022-12-16 青岛海尔施特劳斯水设备有限公司 Filter element and water purification device including the filter element
CN115677075A (en) * 2022-08-29 2023-02-03 湖北祥云(集团)化工股份有限公司 Emergency treatment method for phosphogypsum yard leakage liquid polluted spring water

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