CN202849583U - Cleaning device for tinning plate after tinning - Google Patents

Cleaning device for tinning plate after tinning Download PDF

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CN202849583U
CN202849583U CN201220438757.5U CN201220438757U CN202849583U CN 202849583 U CN202849583 U CN 202849583U CN 201220438757 U CN201220438757 U CN 201220438757U CN 202849583 U CN202849583 U CN 202849583U
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counter
flow vat
flow
vat
flow trough
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CN201220438757.5U
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黄邦霖
晏人芸
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Baoshan Iron and Steel Co Ltd
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Baoshan Iron and Steel Co Ltd
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Abstract

The utility model relates to a cleaning device for tinning plate after tinning. The cleaning device comprises a primary counter-flow trough which is connected with an intermediate counter-flow trough and a final counter-flow trough sequentially, wherein the primary counter-flow trough, the intermediate counter-flow trough and the final counter-flow trough are provided with tinning plate conveying devices; and the outer sides at the bottom of the primary counter-flow trough, the intermediate counter-flow trough and the final counter-flow trough are respectively connected with first valves through pipelines. The cleaning device is characterized in that the outer sides at the bottom of the primary counter-flow trough, the intermediate counter-flow trough and the final counter-flow trough are also respectively connected with one sides of second valves, the other sides of the second valves are connected with pumps and a spraying frame sequentially, and the spray frame is provided with first nozzles which are arranged above the primary counter-flow trough, the intermediate counter-flow trough and the final counter-flow trough. The cleaning capacity of the cleaning device provided by the utility model is improved, and residual plating solution entrained by the surface of a tinning plate coil from a plating tank can be completely recycled to prevent the generation of tin sludge in the device.

Description

A kind of device for cleaning after the tin plate plating
Technical field
The utility model relates to a kind of device, particularly, relates to a kind of device for cleaning after the tin plate plating.
Background technology
Now, most PSA(sulfocarbolic acids) the tin plating electrolyte system is all used the solubility promoter of rare plating bath before as the soft heat operation.The benefit of bringing like this is that solubility promoter and electroplate liquid are the same material, can not produce interference phenomenon.It is few that whole treating processes takies number of times.But poisonous and hazardous sulfocarbolic acid can be brought in the hardening waste water, thereby increases the processing costs of waste water.And the MSA(methylsulphonic acid) solubility promoter of tin plating electrolyte is the environmental protection solution of special exploitation because and plating bath be not same system, must be with residual the cleaning up of plate plated surface tin liquor before applying solubility promoter.For the tin plating electrolyte system of MSA, the pollution that is subject to methylsulfonic acid when solubility promoter reaches 0.8g/l when above, and blue mist layer can appear in the plate face after the soft heat, and therefore, it is vital that the plate face before fluxing cleans.In order to prevent blue mist layer, find in the plating system based on MSA, need to reach and be higher than 95% cleaning efficiency.Whole treating processes takies often.In order to reach the purpose that cleans up, the equipment that needs is also many.
Now, the plating after-treatment system of MSA tin plating electrolyte forms (see figure 1) by three grooves of three stage countercurrent rinsings.Countercurrent rinsing is to reach best cleaning efficiency with minimum water loss, and the pure water that cleans usefulness is that the 3rd groove fills into continuously from last step.The rinse efficiency of every one-level can reach 60%, and level two can realize 86% rinse efficiency, and three-level system can reach 94% rinse efficiency.Therefore, three stage countercurrent rinsings can only meet the demands substantially, and can not guarantee the zero defect operation.It is very low to increase 1 counter-flow vat cost effectiveness again, improve, only in addition perfect on the specific design of three stage countercurrent rinse-systems.
Patent documentation CN101230480 " electroplating reverse-flow rinsing process " discloses the reverse-flow rinsing process that a kind of electroplating parts is used, workpiece carries out rinsing successively from elementary counter-flow vat to final stage counter-flow vat electroplate out groove in bath trough after, tap water enters from the final stage counter-flow vat after ion exchange treatment, then successively to the upper level counter-flow vat stage by stage step by step guide groove fill into, the rinse water of overflowing from elementary counter-flow vat enters hold tank recovery storage again, workpiece is after the rinsing of a certain stage countercurrent groove goes out groove, use again from the rinse water of next stage counter-flow vat and carry out atomizing spray, spray time is controlled at 4-15 second, and the atomizing nozzle pressure-controlling is at 0.04-0.1MPa.Although this patent documentation for be single workpiece, the principle of its countercurrent rinsing has similar part with the present extensively purging method at the zinc-plated coiled material of the high-speed and continuous operation of usefulness.
Additive in the MSA tin plating electrolyte has superpower and adsorptive power metallic tin, therefore, tin plate in the production from plating tank out after, it has plated the solution additive of having carried excess in the remained on surface plating bath of tin secretly, can automatically not run away without washing away of external force.Only to cross in rinse tank be the purpose that does not reach cleaning to the high-speed motion by tin plate.Solution is with large hitting power tin plate sheet surface to be washed away.Patent documentation CN101230480 " electroplating reverse-flow rinsing process " is although also proposed workpiece after the rinsing of a certain stage countercurrent groove goes out groove, use again the method for carrying out atomizing spray from the rinse water of next stage counter-flow vat, but the method for atomizing spray can not be accomplished large hitting power, this is to be the rinse water of next stage because this patent uses, if increasing hitting power, the flow that certainly will will add giant, so just mean that the amount that enters the rare plating bath that reclaims container for storing liquid recovery storage is inevitable very large, rare plating bath of hold tank recovery storage will overflow the groove tank at short notice, make the recovery operation be forced to stop.Use simultaneously the rinse water from the next stage counter-flow vat to enter the method that atomizing nozzle enters into upper level again by pump, can produce a control difficult problem.If three stage countercurrent rinsings just have two pumps, it is very difficult that the flow of these two pumps is consistent, if do not add control, may make a lot of that the water of certain one-level trough reduces, and causes product quality problem.
The utility model content
For solving the problem of above-mentioned existence, the purpose of this utility model is to provide a kind of device for cleaning after the tin plate plating, improve the cleansing power of existing apparatus, accomplish to zinc-plated coiled sheet from plating tank out the residual plating bath carried secretly of its surface and avoid in device, producing tin mud near 100% recovery.
For achieving the above object, the utility model adopts following technical scheme:
A kind of device for cleaning after the tin plate plating, described device comprises elementary counter-flow vat, described elementary counter-flow vat is connected with the final stage counter-flow vat with intermediate counter-flow vat and is connected, be provided with the tin plate transport unit on described elementary counter-flow vat, intermediate counter-flow vat and the final stage counter-flow vat, described elementary counter-flow vat, intermediate counter-flow vat and final stage counter-flow vat bottom outside are connected pipeline and are connected with the first valve respectively, it is characterized in that:
Described elementary counter-flow vat, intermediate counter-flow vat and final stage counter-flow vat bottom outside also are connected with the second valve one side respectively, described the second valve opposite side and pump be connected framed bent and be connected successively, be provided with the first nozzle on the described spray framed bent, described the first nozzle is arranged at elementary counter-flow vat, intermediate counter-flow vat and final stage counter-flow vat top.
According to a kind of device for cleaning after the tin plate plating provided by the utility model, employing be that described the first nozzle is arranged at elementary counter-flow vat, intermediate counter-flow vat and ingress, final stage counter-flow vat top.
According to a kind of device for cleaning after the tin plate plating provided by the utility model, what adopt is, exit, described final stage counter-flow vat top is provided with the spray framed bent, described spray framed bent is connected with under meter, the 3rd valve and pure water storing unit successively by pipeline, is provided with second nozzle on the described spray framed bent.
According to a kind of device for cleaning after the tin plate plating provided by the utility model, employing be that an end of described the first valve is connected with the recovery container for storing liquid by pipeline.
According to a kind of device for cleaning after the tin plate plating provided by the utility model, employing be, described elementary counter-flow vat inside front is provided with drainage trough, described drainage trough is connected with the recovery container for storing liquid by pipeline.
The beneficial effects of the utility model are:
1), adopt the tin plate of rinse water spray in corresponding levels motion at the corresponding levels, make rinse water form a closed circuit self-circulation system, have nothing to do to the water yield of the previous stage overflow water yield with spray like this;
2), spray equipment is installed in the entrance of counter-flow vat, the tin plate that enters this groove is cleaned, can make has a concentration difference between the residual plating bath of spray water and tin plate sheet surface, can improve cleaning performance like this;
3), the in the end outlet of one-level counter-flow vat is equipped with spray equipment, uses pure pure water, this water yield is exactly step by step forward overflow and finally enter the amount that reclaims container for storing liquid, thereby can save water resources.
Description of drawings
Fig. 1 is the structural representation that is used for the rear device that cleans of tin plate plating in the prior art.
Fig. 2 is the structural representation of a kind of device for cleaning after the tin plate plating provided by the utility model.
Among the figure, 1, elementary counter-flow vat, 2, intermediate counter-flow vat, 3, the final stage counter-flow vat, 4, tin plate transport unit, the 5, first valve, the 6, second valve, 7, pump, 8, the spray framed bent, 9, the pure water storing unit, 10, the 3rd valve, 11, under meter, the 12, first nozzle, 13, second nozzle, 14, pipeline, 15, reclaim container for storing liquid, 16, drainage trough, 17, tin plate, 18, vaporizer.
Embodiment
Below in conjunction with accompanying drawing a kind of device for cleaning after the tin plate plating provided by the utility model is further explained explanation.
The mode of connection of a kind of device for cleaning after the tin plate plating that provides is as follows:
As shown in Figure 2, described device comprises elementary counter-flow vat 1, described elementary counter-flow vat 1 is connected with the final stage counter-flow vat with intermediate counter-flow vat 2 and is connected successively, described elementary counter-flow vat 1, be provided with tin plate transport unit 4 on middle rank counter-flow vat 2 and the final stage counter-flow vat 3, described elementary counter-flow vat 1, middle rank counter-flow vat 2 is connected bottom outside and is connected with the first valve 5 respectively by pipeline 14 with the final stage counter-flow vat, described elementary counter-flow vat 1, middle rank counter-flow vat 2 is connected bottom outside and also is connected with the second valve 6 one sides respectively with the final stage counter-flow vat, described the second valve 6 opposite sides and pump 7 be connected framed bent 8 and be connected successively, be provided with the first nozzle 12 on the described spray framed bent 8, described the first nozzle 12 is arranged at elementary counter-flow vat 1, middle rank counter-flow vat 2 and final stage counter-flow vat 3 tops, described the first nozzle 12 is arranged at elementary counter-flow vat 1, middle rank counter-flow vat 2 and ingress, final stage counter-flow vat 3 top, exit, described final stage counter-flow vat 3 top is provided with spray framed bent 8, described spray framed bent 8 is by pipeline 14 and under meter 11, the 3rd valve 10 and pure water storing unit 9 connect successively, be provided with second nozzle 13 on the described spray framed bent 8, one end of described the first valve 5 is connected with recovery container for storing liquid 15 by pipeline 14, described elementary counter-flow vat 1 inside front is provided with drainage trough 16, and described drainage trough 16 is connected with recovery container for storing liquid 15 by pipeline 14.Shown in drainage trough 16 both sides height have difference, its role is to a low side spillwag chute towards strip steel at entry, thereby the preferential overflow of the recovery liquid of high density reclaimed.
In the prior art, adopt the method for atomizing spray that tin plate is cleaned, but the method for atomizing spray can not be accomplished large hitting power to tin plate, this be because its application be the rinse water of the counter-flow vat of next stage, if the increasing hitting power, certainly will will add the flow of giant, so just mean enter reclaim the amount that container for storing liquid reclaims rare plating bath of storing must be very large, rare plating bath of hold tank recovery storage will overflow the groove tank at short notice, make the recovery operation be forced to stop.Use simultaneously the rinse water from the next stage counter-flow vat to enter the method that atomizing nozzle enters into upper level again by pump, can produce a control difficult problem.If three stage countercurrent rinsings just have two pumps, it is very difficult that the flow of these two pumps is consistent, if do not add control, may make a lot of that the water of certain one-level trough reduces, and causes product quality problem.
In order to solve this a pair of contradiction between large flow and the recovery, what the utility model adopted is with the tin plate of rinse water spray in corresponding levels motion at the corresponding levels, make rinse water form a closed circuit self-circulation system, namely realize by the second valve 6 and pump 7, if not having the rinse water overflow of next stage comes, rinse water at the corresponding levels is can not increase or reduce, and so just can simplify a problem as overflowing to the amount that reclaims in the container for storing liquid is exactly the amount that the last step overflow is come.
If a groove is only with a cover spray equipment, general design all is to spray the outlet that is installed in counter-flow vat with cleaning, and the tin plate that is about to leave is cleaned.A feature of the present utility model is the entrance that spray equipment is installed in counter-flow vat, and the tin plate that enters this groove is cleaned.The reason of doing like this is that the utility model is that if also be mounted in outlet, the concentration of plating bath almost equates with the plating bath residual concentration that contains by the tin plate sheet surface after the rinsing at the corresponding levels in the rinse water with rinse water spray at the corresponding levels.But to hang down an order of magnitude the plating bath residual concentration that the concentration of plating bath contains for the tin plate sheet surface that enters entrance at the corresponding levels from upper level in the rinse water.Therefore, spray equipment riding position of the present utility model can make between spray water and the residual plating bath of tin plate sheet surface a concentration difference, can improve cleaning performance like this.
Another one feature of the present utility model is, the in the end outlet of one-level counter-flow vat is equipped with spray equipment, its use be pure pure water, because have the spray of powerful hitting power cleans through first three groups, the residual plating bath of tin plate sheet surface comprises that additive has all dropped to extremely low level, the spray that therefore exports at last, and it is so unimportant that hitting power has seemed, so can spray by the minimum water yield, as long as this water yield is not more than the maximum value that reclaims steam output.Because this water yield is exactly step by step forward overflow and finally enter the amount that reclaims container for storing liquid.
Embodiment
The utility model is in the plating aftertreatment of existing MSA tin plating electrolyte, obtain implementing (see figure 2) in the system that three grooves of i.e. three stage countercurrent rinsings form, the method that provides by the utility model, install the washing unit that a cover comprises pump 7 and spray framed bent 8 additional for each counter-flow vat, spray framed bent 8 is installed in the entrance of each counter-flow vat, the first nozzle 12 is provided by the model of the large surging force of can providing of larger caliber, and the suction port of pump 7 is connected on bottom land, can form so a closed circuit self-circulation system.The newly-increased cover spray framed bent 8 of the in the end outlet of one-level, second nozzle 13 is selected the more small-bore model that can control flow, and the access of pure water can utilize original pipeline and original under meter to control the ability that the amount of cleaning pure water is no more than vaporizer.
Improved recovering effect is very obvious, and the original concentration of work plating bath is as follows:
Sn 2+ 15±3g/l
Additive 25 ± 5ml/l
Wide variation have occured in the bath concentration that reclaims in the reservoir tank before and after transforming, and see the following form
Figure GDA00002077025000071
The recovery of additive surpasses 2 times of aimed concn, has proved that the additive of tin plate sheet surface excess absorption has been cleaned really.Divalent tin ion has also been accomplished normal recovery.Rinse water in three counter-flow vats remains the state of cleaning, has guaranteed the surface quality of product, has reduced the loss of tin mud.

Claims (5)

1. one kind is used for the rear device that cleans of tin plate plating, described device comprises elementary counter-flow vat (1), described elementary counter-flow vat (1) is connected 3 with intermediate counter-flow vat (2) with the final stage counter-flow vat) be connected successively, be provided with tin plate transport unit (4) on described elementary counter-flow vat (1), intermediate counter-flow vat (2) and the final stage counter-flow vat (3), described elementary counter-flow vat (1), intermediate counter-flow vat (2) are connected 3 with the final stage counter-flow vat) bottom outside is connected with the first valve (5) respectively by pipeline (14), it is characterized in that:
Described elementary counter-flow vat (1), intermediate counter-flow vat (2) are connected 3 with the final stage counter-flow vat) bottom outside also is connected with the second valve (6) one sides respectively, described the second valve (6) opposite side and pump (7) be connected framed bent (8) and be connected successively, be provided with the first nozzle (12) on the described spray framed bent (8), described the first nozzle (12) is arranged at elementary counter-flow vat (1), intermediate counter-flow vat (2) and final stage counter-flow vat (3) top.
2. a kind of device for cleaning after the tin plate plating according to claim 1 is characterized in that described the first nozzle (12) is arranged at elementary counter-flow vat (1), intermediate counter-flow vat (2) and ingress, final stage counter-flow vat (3) top.
3. according to claim 1 a kind of for the rear device that cleans of tin plate plating, it is characterized in that exit, described final stage counter-flow vat (3) top is provided with spray framed bent (8), described spray framed bent (8) is connected with under meter (11), the 3rd valve (10) and pure water storing unit (9) successively by pipeline (14), is provided with second nozzle (13) on the described spray framed bent (8).
4. a kind of device for cleaning after the tin plate plating according to claim 1 is characterized in that an end of described the first valve (5) is connected with recovery container for storing liquid (15) by pipeline (14).
5. according to claim 1 a kind of for the rear device that cleans of tin plate plating, it is characterized in that described elementary counter-flow vat (1) inside front is provided with drainage trough (16), described drainage trough (16) is connected with recovery container for storing liquid (15) by pipeline (14).
CN201220438757.5U 2012-08-30 2012-08-30 Cleaning device for tinning plate after tinning Expired - Lifetime CN202849583U (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2018118183A (en) * 2017-01-23 2018-08-02 光治郎 大川 Cleaning device of object to be cleaned
CN109721201A (en) * 2019-03-05 2019-05-07 天津市富仁板带有限公司 Water process environmental protecting device for the cleaning of tin plating plate
CN110965114A (en) * 2018-09-29 2020-04-07 上海梅山钢铁股份有限公司 Recovery device and method for tin methane sulfonate electroplating solution
CN112481671A (en) * 2019-09-12 2021-03-12 上海梅山钢铁股份有限公司 Reflow pretreatment device and method for low-tin-layer electrotinning steel plate

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2018118183A (en) * 2017-01-23 2018-08-02 光治郎 大川 Cleaning device of object to be cleaned
CN110965114A (en) * 2018-09-29 2020-04-07 上海梅山钢铁股份有限公司 Recovery device and method for tin methane sulfonate electroplating solution
CN110965114B (en) * 2018-09-29 2021-12-14 上海梅山钢铁股份有限公司 Recovery device and method for tin methane sulfonate electroplating solution
CN109721201A (en) * 2019-03-05 2019-05-07 天津市富仁板带有限公司 Water process environmental protecting device for the cleaning of tin plating plate
CN112481671A (en) * 2019-09-12 2021-03-12 上海梅山钢铁股份有限公司 Reflow pretreatment device and method for low-tin-layer electrotinning steel plate
CN112481671B (en) * 2019-09-12 2024-05-10 上海梅山钢铁股份有限公司 Reflow pretreatment device and method for low-tin-layer electroplated tin plate

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