CN202610045U - Processing system of heavy-metal-contained acid wastewater - Google Patents
Processing system of heavy-metal-contained acid wastewater Download PDFInfo
- Publication number
- CN202610045U CN202610045U CN2012201400991U CN201220140099U CN202610045U CN 202610045 U CN202610045 U CN 202610045U CN 2012201400991 U CN2012201400991 U CN 2012201400991U CN 201220140099 U CN201220140099 U CN 201220140099U CN 202610045 U CN202610045 U CN 202610045U
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- Prior art keywords
- reverse osmosis
- water
- osmosis membrane
- pressure pump
- membrane section
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000002351 wastewater Substances 0.000 title claims abstract description 27
- 239000002253 acid Substances 0.000 title claims abstract description 25
- 238000001223 reverse osmosis Methods 0.000 claims abstract description 132
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 81
- 238000000108 ultra-filtration Methods 0.000 claims abstract description 18
- 238000001914 filtration Methods 0.000 claims abstract description 10
- 238000007781 pre-processing Methods 0.000 claims abstract description 10
- 229920002678 cellulose Polymers 0.000 claims abstract description 9
- 239000001913 cellulose Substances 0.000 claims abstract description 9
- 239000004576 sand Substances 0.000 claims abstract description 6
- 239000012528 membrane Substances 0.000 claims description 78
- 229910001385 heavy metal Inorganic materials 0.000 claims description 24
- 239000000835 fiber Substances 0.000 claims description 8
- 238000004062 sedimentation Methods 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 abstract description 5
- 239000002184 metal Substances 0.000 abstract description 5
- 230000004907 flux Effects 0.000 description 10
- 238000001556 precipitation Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L Calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- 235000015450 Tilia cordata Nutrition 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 230000031018 biological processes and functions Effects 0.000 description 2
- 238000004070 electrodeposition Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 230000004308 accommodation Effects 0.000 description 1
- 230000005591 charge neutralization Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 229910003439 heavy metal oxide Inorganic materials 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 230000002035 prolonged Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 201000002282 venous insufficiency Diseases 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
- 230000003245 working Effects 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
Abstract
The utility model discloses a processing system of heavy-metal-contained acid wastewater. The processing system of the heavy-metal-contained acid wastewater comprises a preprocessing part and a reverse osmosis part, wherein the preprocessing part comprises an initial settling pond, a sand filtering pond, a raw water pond, a cellulose filtering apparatus and an ultrafiltration device which are communicated in sequence; the reverse osmosis part comprises a first pressure pump, a first-stage reverse osmosis apparatus, a second pressure pump and a second-stage reverse osmosis apparatus which are communicated in sequence, concentrated water of the first-stage reverse osmosis apparatus enters the second-stage reverse osmosis apparatus through the second pressure pump, and concentrated water of the second-stage reverse osmosis apparatus flows out from a concentrated water outlet of the second-stage reverse osmosis apparatus; product water of the first-stage reverse osmosis apparatus and the second-stage reverse osmosis apparatus flows out from product water outlets of the first-stage reverse osmosis apparatus and the second-stage reverse osmosis apparatus; and a water outlet of the ultrafiltration device is communicated with a water inlet of the first pressure pump. According to the processing system of the heavy-metal-contained acid wastewater, heave metal is effectively recycled, and meanwhile, the secondary pollution to the environment is avoided; and the operation of the whole processing system is simple, and the investment and operation cost is low.
Description
Technical field
The utility model belongs to the Industrial Wastewater Treatment field, is specifically related to a kind of treatment system of acid waste water containing heavy metal.
Background technology
Acid waste water containing heavy metal is the bigger trade effluent of hazard rating, extensively is present in nonferrous metal mine, Metal smelting, ore dressing and electroplating industry.To the treatment process of acid waste water containing heavy metal, mainly contain lime neutralisation, sulphide precipitation and biological process etc. in the prior art.What wherein lime precipitation was used is the most extensive, but the sediment of processing back generation is more and the dehydration difficulty, and occupation of land is big, stores up the easy secondary dissolving of heavy metal oxide in the process, causes the secondary pollution to water surrounding; The pH value accommodation of sulphide precipitation is big, but the valuable metal in the efficient recovery waste water, but its precipitation agent source is limited, cost an arm and a leg, and the hydrogen sulfide that produces causes atmospheric pollution easily; Though biological process can effectively reclaim valuable metal and be difficult for causing second environmental pollution, its investment and working cost are all higher, and the sulfide precipitation added value that obtains is lower, and still further processing thereby comprehensive cost are higher for the waste water after the processing.
The utility model content
The purpose of the utility model is to overcome the prior art defective, provides a kind of simple to operate, and is with low cost and can effectively avoid the treatment system of the acid waste water containing heavy metal of secondary pollution.
The technical scheme of the utility model is following:
A kind of treatment system of acid waste water containing heavy metal, it comprises the r-o-part that acid waste water containing heavy metal is carried out pretreated preprocessing part and pretreated acid waste water containing heavy metal is handled, wherein,
Said preprocessing part comprises preliminary sedimentation tank, sand filter, former pond, Mierocrystalline cellulose filtration unit and the ultra-filtration equipment that is communicated with successively;
Said r-o-partly comprises first pressure pump, first step reverse osmosis unit, second pressure pump and second stage reverse osmosis unit; Wherein, said first step reverse osmosis unit has water-in, dense water out and produces water out, and said second stage reverse osmosis unit has water-in, dense water out and produces water out; The water outlet of said first pressure pump is connected with the water-in of said first step reverse osmosis unit; The dense water out of said first step reverse osmosis unit is connected with the water-in of said second pressure pump; The water outlet of said second pressure pump is connected with the water-in of said second stage reverse osmosis unit, and the dense water out of said second stage reverse osmosis unit is connected with follow-up dense water treating equipment; The product water out of the said first step and second stage reverse osmosis unit all is connected with the product pond;
The water outlet of said ultra-filtration equipment is connected with the water-in of said first pressure pump.
In a preferred version of the utility model; Said first step reverse osmosis unit comprises the first reverse osmosis membrane section parallel with one another and the second reverse osmosis membrane section; Said second stage reverse osmosis unit; Comprise the 3rd reverse osmosis membrane section parallel with one another and the 4th reverse osmosis membrane section, the said first, second, third and the 4th reverse osmosis membrane Duan Jun has water-in, dense water out and produces water out; The water outlet of said first pressure pump is connected with the water-in of the said first reverse osmosis membrane section and the second reverse osmosis membrane section; The dense water out of the said first reverse osmosis membrane section and the second reverse osmosis membrane section is connected with the water-in of said second pressure pump; The water outlet of said second pressure pump is connected with the water-in of said the 3rd reverse osmosis membrane section and the 4th reverse osmosis membrane section; The dense water out of said the 3rd reverse osmosis membrane section and the 4th reverse osmosis membrane section is connected with follow-up dense water treating equipment; The product water out of the said first, second, third and the 4th reverse osmosis membrane section all is connected with the product pond, and the reverse osmosis membrane in the above-mentioned first, second, third and the 4th reverse osmosis membrane section all adopts extraordinary industrial reverse osmosis membrane.
In a preferred version of the utility model, the flux of the said first reverse osmosis membrane section is less than the flux of the second reverse osmosis membrane section, greater than the flux of the third and fourth reverse osmosis membrane section; The flow velocity of the said first reverse osmosis membrane section all be lower than said second, third with the flow velocity of the 4th reverse osmosis membrane section.
In a preferred version of the utility model, said Mierocrystalline cellulose filtration unit is the highly effective cellulose filtration unit.
In a preferred version of the utility model, said ultra-filtration equipment is excellent to be the hollow-fibre membrane ultra-filtration equipment.
In a preferred version of the utility model, the security personnel's strainer of also connecting between the said ultra-filtration equipment and first pressure pump.
The beneficial effect of the utility model is:
1, uses reverse osmosis technology acid waste water containing heavy metal is handled, in the efficient recovery heavy metal, avoided second environmental pollution.
2, adopt the preprocessing part of forming successively by preliminary sedimentation tank, sand filter, former pond, highly effective cellulose filtration unit and hollow-fibre membrane ultra-filtration equipment; Farthest acid waste water containing heavy metal has been carried out pre-treatment; Significantly reduce wherein impurity, guaranteed the efficient operation of follow-up r-o-part.
3, r-o-partly comprises the first step reverse osmosis unit that is parallel with first and second reverse osmosis membrane section and is parallel with the second stage reverse osmosis unit of the 3rd and the 4th reverse osmosis membrane section; First step reverse osmosis unit and the series connection of second stage reverse osmosis unit; And the flux of the first reverse osmosis membrane section is less than the flux of the second reverse osmosis membrane section, greater than the flux of the third and fourth reverse osmosis membrane section; The flow velocity of the first reverse osmosis membrane section all be lower than said second, third with the flow velocity of the 4th reverse osmosis membrane section, such design has effectively alleviated the infringement of foulings such as calcium sulfate, permanent white to reverse osmosis membrane, has prolonged the work-ing life of reverse osmosis membrane.
4, the entire treatment system operation is simple, and investment and working cost are cheap.
Description of drawings
Fig. 1 is a synoptic diagram of handling the reverse osmosis system of acid waste water containing heavy metal in the utility model.
Embodiment
Below combine accompanying drawing the utility model is further explained and to be described through embodiment.
Liquid communication situation in the utility model is shown in arrow in the accompanying drawing.
As shown in Figure 1, the treatment system of a kind of acid waste water containing heavy metal of the utility model, it comprises the r-o-part 2 that acid waste water containing heavy metal is carried out pretreated preprocessing part 1 and pretreated acid waste water containing heavy metal is handled, wherein,
Said preprocessing part comprises preliminary sedimentation tank 11, sand filter 12, former pond 13, highly effective cellulose filtration unit 14 and the hollow-fibre membrane ultra-filtration equipment 15 that is communicated with successively, and wherein highly effective cellulose filtration unit 14 all adopts the two pattern settings of a usefulness fully with hollow-fibre membrane ultra-filtration equipment 15.
Said r-o-partly comprises first pressure pump 21, first step reverse osmosis unit 22, second pressure pump 23 and second stage reverse osmosis unit 24; The water outlet of said first pressure pump 21 is connected with the water-in of said first reverse osmosis unit 22; The dense water out of said first reverse osmosis unit 22 is connected with the water-in of said second stage reverse osmosis unit 24 through said second pressure pump 23, and the dense water B of said second stage reverse osmosis unit 24 flows out the back from its dense water out and gets into dense pond or get into the electrodeposition recovery that extraction plant carries out heavy metal; The product water A of the said first step and second stage reverse osmosis unit 22,23 flows out the back from each self-produced water out and directly gets into the product pond, recycles;
Said r-o-partly comprises first pressure pump 21, first step reverse osmosis unit 22, second pressure pump 23 and second stage reverse osmosis unit 24; Wherein, said first step reverse osmosis unit 22 has water-in, dense water out and produces water out, and said second stage reverse osmosis unit 24 has water-in, dense water out and produces water out; The water outlet of said first pressure pump 21 is connected with the water-in of said first step reverse osmosis unit 22; The dense water out of said first step reverse osmosis unit 22 is connected with the water-in of said second pressure pump 23; The water outlet of said second pressure pump 23 is connected with the water-in of said second stage reverse osmosis unit 24; The dense water out of said second stage reverse osmosis unit 24 is connected with follow-up dense water treating equipment, and dense water B flows out the back from this dense water out and gets into the dense water treatment procedure in downstream; The product water out of the said first step and second stage reverse osmosis unit (22,24) all is connected with the product pond, and product water A flows out directly entering product pond, back from producing water out, recycles;
Said preprocessing part 1 is connected with the water-in of said first pressure pump 21 with the water outlet of said r-o-part 2 through said hollow-fibre membrane ultra-filtration equipment 15, the security personnel's strainer 3 of also connecting between the said hollow-fibre membrane ultra-filtration equipment 15 and first pressure pump 21.
Said first step reverse osmosis unit 22 comprises the first reverse osmosis membrane section 221 parallel with one another and the second reverse osmosis membrane section 222; Said second stage reverse osmosis unit 24 comprises the 3rd reverse osmosis membrane section 241 parallel with one another and the 4th reverse osmosis membrane section 242.Said first, second, third nuclear the 4th reverse osmosis membrane section (221,222,241 and 242) all has water-in, dense water out and produces water out; The water outlet of said first pressure pump 21 is connected with the water-in of the said first reverse osmosis membrane section 221 and the second reverse osmosis membrane section 222; The dense water out of the said first reverse osmosis membrane section 221 and the second reverse osmosis membrane section 222 is connected with the water-in of said second pressure pump 23; The water outlet of said second pressure pump 23 is connected with the water-in of said the 3rd reverse osmosis membrane section 241 and the 4th reverse osmosis membrane section 242; The dense water out of said the 3rd reverse osmosis membrane section 241 and the 4th reverse osmosis membrane section 242 is connected with follow-up dense water treating equipment; The product water out of the said first, second, third and the 4th reverse osmosis membrane section (221,222,241 and 242) all is connected with the product pond, and the reverse osmosis membrane in the above-mentioned first, second, third and the 4th reverse osmosis membrane section (221,222,241 and 242) all adopts extraordinary industrial reverse osmosis membrane.
The flux of the said first reverse osmosis membrane section 221 is less than the flux of the second reverse osmosis membrane section 222, greater than the flux of the third and fourth reverse osmosis membrane section 241,242; The flow velocity of the said first reverse osmosis membrane section 221 all be lower than said second, third with the flow velocity of the 4th reverse osmosis membrane section 222,241,242.Be that said reverse osmosis system 2 adopts one-level four-part form mode to arrange; Wherein, The first reverse osmosis membrane section 221 adopts big flux, low flow velocity to relate to; The second reverse osmosis membrane section 222 adopts high-throughput, big flow velocity to relate to, and third and fourth (241 and 242) reverse osmosis membrane section adopts small throughput, big flow velocity design.
In the operational process; The acid waste water containing heavy metal of required processing is successively after but preliminary sedimentation tank 11, sand filter 12, former pond 13, highly effective cellulose filtration unit 14, hollow-fibre membrane ultra-filtration equipment 15 and security personnel's strainer 3 are removed hypostasis, swimmer, suspended substance, colloid, fine silt, larger molecular organics and bacterium; Get into first step reverse osmosis unit 23 through first pressure pump 21; Gained produces water and directly gets into the product pond; Recycle, the dense water of gained is through second pressure pump, 22 entering second stage reverse osmosis units 24, and the product water of second stage reverse osmosis unit 24 also is directly to get into to produce the pond; Recycle, dense pond stores or the entering extraction plant carries out the electrodeposition recovery of heavy metal and its dense water that produces gets into.
The above; Be merely the preferred embodiment of the utility model; So can not limit the scope that the utility model is implemented according to this, the equivalence of promptly doing according to the utility model claim and description changes and modifies, and all should still belong in the scope that the utility model contains.
Claims (4)
1. the treatment system of an acid waste water containing heavy metal, it is characterized in that: it comprises the r-o-part that acid waste water containing heavy metal is carried out pretreated preprocessing part and pretreated acid waste water containing heavy metal is handled, wherein,
Said preprocessing part comprises preliminary sedimentation tank, sand filter, former pond, Mierocrystalline cellulose filtration unit and the ultra-filtration equipment that is communicated with successively;
Said r-o-partly comprises first pressure pump, first step reverse osmosis unit, second pressure pump and second stage reverse osmosis unit; Wherein, said first step reverse osmosis unit has water-in, dense water out and produces water out, and said second stage reverse osmosis unit has water-in, dense water out and produces water out; The water outlet of said first pressure pump is connected with the water-in of said first step reverse osmosis unit; The dense water out of said first step reverse osmosis unit is connected with the water-in of said second pressure pump; The water outlet of said second pressure pump is connected with the water-in of said second stage reverse osmosis unit, and the dense water out of said second stage reverse osmosis unit is connected with follow-up dense water treating equipment; The product water out of the said first step and second stage reverse osmosis unit all is connected with the product pond;
The water outlet of said ultra-filtration equipment is connected with the water-in of said first pressure pump.
2. the treatment system of a kind of acid waste water containing heavy metal as claimed in claim 1; It is characterized in that: said first step reverse osmosis unit comprises the first reverse osmosis membrane section parallel with one another and the second reverse osmosis membrane section; Said second stage reverse osmosis unit; Comprise the 3rd reverse osmosis membrane section parallel with one another and the 4th reverse osmosis membrane section, the said first, second, third and the 4th reverse osmosis membrane Duan Jun has water-in, dense water out and produces water out; The water outlet of said first pressure pump is connected with the water-in of the said first reverse osmosis membrane section and the second reverse osmosis membrane section; The dense water out of the said first reverse osmosis membrane section and the second reverse osmosis membrane section is connected with the water-in of said second pressure pump; The water outlet of said second pressure pump is connected with the water-in of said the 3rd reverse osmosis membrane section and the 4th reverse osmosis membrane section; The dense water out of said the 3rd reverse osmosis membrane section and the 4th reverse osmosis membrane section is connected with follow-up dense water treating equipment, and the product water out of the said first, second, third and the 4th reverse osmosis membrane section all is connected with the product pond.
3. the treatment system of a kind of acid waste water containing heavy metal as claimed in claim 1 is characterized in that said ultra-filtration equipment is the hollow-fibre membrane ultra-filtration equipment.
4. like the treatment system of the described a kind of acid waste water containing heavy metal of arbitrary claim in the claim 1 to 3, it is characterized in that: the security personnel's strainer of also connecting between the said ultra-filtration equipment and first pressure pump.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012201400991U CN202610045U (en) | 2012-04-05 | 2012-04-05 | Processing system of heavy-metal-contained acid wastewater |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012201400991U CN202610045U (en) | 2012-04-05 | 2012-04-05 | Processing system of heavy-metal-contained acid wastewater |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN202610045U true CN202610045U (en) | 2012-12-19 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012201400991U Expired - Lifetime CN202610045U (en) | 2012-04-05 | 2012-04-05 | Processing system of heavy-metal-contained acid wastewater |
Country Status (1)
| Country | Link |
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| CN (1) | CN202610045U (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105731682A (en) * | 2014-12-11 | 2016-07-06 | 苏州澄江环境科技有限公司 | System and method for treating acetic acid-containing wastewater |
| CN105948351A (en) * | 2016-05-16 | 2016-09-21 | 神华集团有限责任公司 | Water treatment system and method |
| CN109320012A (en) * | 2018-10-26 | 2019-02-12 | 首创爱华(天津)市政环境工程有限公司 | A kind of municipal sewage system and method |
-
2012
- 2012-04-05 CN CN2012201400991U patent/CN202610045U/en not_active Expired - Lifetime
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105731682A (en) * | 2014-12-11 | 2016-07-06 | 苏州澄江环境科技有限公司 | System and method for treating acetic acid-containing wastewater |
| CN105948351A (en) * | 2016-05-16 | 2016-09-21 | 神华集团有限责任公司 | Water treatment system and method |
| CN109320012A (en) * | 2018-10-26 | 2019-02-12 | 首创爱华(天津)市政环境工程有限公司 | A kind of municipal sewage system and method |
| CN109320012B (en) * | 2018-10-26 | 2021-11-09 | 首创爱华(天津)市政环境工程有限公司 | Municipal sewage treatment system and method |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C53 | Correction of patent of invention or patent application | ||
| CB03 | Change of inventor or designer information |
Inventor after: Huang Huaiguo Inventor after: Chen Jiahong Inventor after: Zhang Qing Inventor after: Ji Changqing Inventor after: Lin Guoqin Inventor after: Chen Qibin Inventor after: Qiu Yaoxing Inventor before: Huang Huaiguo Inventor before: Zhang Qing Inventor before: Ji Changqing Inventor before: Lin Guoqin Inventor before: Chen Qibin Inventor before: Qiu Yaoxing |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: HUANG HUAIGUO ZHANG QING JI CHANGQING LIN GUOQIN CHEN QIBIN QIU YAOXING TO: HUANG HUAIGUO CHEN JIAHONG ZHANG QING JI CHANGQING LIN GUOQIN CHEN QIBIN QIU YAOXING |
|
| CX01 | Expiry of patent term | ||
| CX01 | Expiry of patent term |
Granted publication date: 20121219 |