CN202558938U - Anti-corrosion power transmission iron tower angle steel and anti-corrosion power transmission iron tower steel tube - Google Patents
Anti-corrosion power transmission iron tower angle steel and anti-corrosion power transmission iron tower steel tube Download PDFInfo
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- CN202558938U CN202558938U CN2012202231558U CN201220223155U CN202558938U CN 202558938 U CN202558938 U CN 202558938U CN 2012202231558 U CN2012202231558 U CN 2012202231558U CN 201220223155 U CN201220223155 U CN 201220223155U CN 202558938 U CN202558938 U CN 202558938U
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Abstract
本实用新型涉及一种防腐蚀输电铁塔角钢、钢管,在角钢基体的全部外周覆有一层化学镀镍磷涂层;在钢管基体的内表面和外表面分别覆有一层化学镀镍磷涂层,化学镀镍磷涂层厚度在20-50微米。所制备的防腐蚀输电铁塔角钢、钢管表面光亮、致密,且涂层与钢基体结合紧密,从而使得碳钢基体表面通过化学镀Ni-P镀层提高了其耐蚀性。
The utility model relates to an anti-corrosion transmission tower angle steel and a steel pipe, in which a layer of electroless nickel-phosphorus coating is coated on the entire outer periphery of the angle steel base; The thickness of the electroless nickel-phosphorus coating is 20-50 microns. The prepared anti-corrosion transmission tower angle steel and steel pipe have bright and dense surfaces, and the coating is closely combined with the steel substrate, so that the surface of the carbon steel substrate improves its corrosion resistance by electroless Ni-P coating.
Description
技术领域: Technical field:
本实用新型涉及一种防腐蚀输电铁塔角钢、钢管,属于输电防腐蚀技术领域。The utility model relates to an anti-corrosion power transmission iron tower angle steel and a steel pipe, belonging to the technical field of power transmission anti-corrosion.
背景技术: Background technique:
输电铁塔是电力传输重要支撑,近年来电力工业的进步使得输电铁塔的使用量大幅增加,对其承受荷载,防止腐蚀的能力也提出了更高要求。由于钢铁材料在大气环境下容易腐蚀生锈造成构件破坏,因此需采用表面技术制备耐腐蚀涂层来提高构件的耐腐蚀能力,从而达到满足其在大气环境中长时服役的目的。目前输电铁塔的角钢和钢管部件均采用热镀锌的方式生产,经过镀锌的部件在施工现场再进行组装形成最终铁塔。然而热镀锌工艺需要高温条件,工艺过程中产生的锌蒸汽还会给操作人员以及周围环境带来较大危害。从耐蚀机理上讲,这类防护属于牺牲阳极的防护机理,在易于形成电化学腐蚀液的环境中有较好的防腐效果,但是由于目前环境污染及酸雨的加重,在一些特定区域热镀锌角钢和钢管将面临提前失效问题,难以达到满足服役寿命的要求。因此亟需开发出腐蚀性更优的涂层体系。The transmission tower is an important support for power transmission. In recent years, the progress of the power industry has greatly increased the use of transmission towers, and higher requirements have been placed on their ability to withstand loads and prevent corrosion. Since iron and steel materials are easy to corrode and rust in the atmospheric environment and cause component damage, it is necessary to use surface technology to prepare corrosion-resistant coatings to improve the corrosion resistance of components, so as to meet the purpose of long-term service in the atmospheric environment. At present, the angle steel and steel pipe parts of the transmission tower are produced by hot-dip galvanizing, and the galvanized parts are assembled at the construction site to form the final tower. However, the hot-dip galvanizing process requires high temperature conditions, and the zinc vapor generated during the process will also bring great harm to the operators and the surrounding environment. In terms of corrosion resistance mechanism, this type of protection belongs to the protection mechanism of sacrificial anodes, and has a good anti-corrosion effect in environments where electrochemical corrosion solutions are easily formed. Zinc angle steel and steel pipe will face the problem of premature failure, and it is difficult to meet the requirements of service life. Therefore, it is urgent to develop a coating system with better corrosion resistance.
发明内容: Invention content:
本实用新型的目的是为了克服现有技术不足,而提供了一种防腐蚀输电铁塔角钢、钢管,改善输电铁塔表面处理工艺环保性,提高涂层耐腐蚀性能,延长其服役寿命,提高输电铁塔安全可靠性。The purpose of the utility model is to overcome the deficiencies in the prior art, and provide a kind of anti-corrosion transmission tower angle steel and steel pipe, improve the environmental protection of the surface treatment process of the transmission tower, improve the corrosion resistance of the coating, prolong its service life, and improve the quality of the transmission tower. Safety and reliability.
本实用新型采取的技术方案为:The technical scheme that the utility model takes is:
一种防腐蚀输电铁塔角钢、钢管,在角钢基体的全部外周覆有一层化学镀镍磷涂层;在钢管基体的内表面和外表面分别覆有一层化学镀镍磷涂层。An anti-corrosion power transmission tower angle steel and a steel pipe are coated with a layer of electroless nickel-phosphorus coating on the entire outer periphery of the angle steel substrate;
化学镀镍磷涂层厚度在20-50微米,化学镀镍磷涂层中磷的质量含量为6-12%。The thickness of the electroless nickel-phosphorus coating is 20-50 microns, and the mass content of phosphorus in the electroless nickel-phosphorus coating is 6-12%.
所制备的防腐蚀输电铁塔角钢、钢管表面光亮、致密,且涂层与钢基体结合紧密,Q235钢和Ni-P镀层的极化曲线的拟合结果表明,Q235的自腐蚀电位为-1.0182V,自腐蚀电流密度为5.0481E-5A/cm2;Ni-P镀层的自腐蚀电位为-0.41173V,自腐蚀电流密度为8.3611E-6A/cm2。由此可知Ni-P镀层的自腐蚀速度明显低于Q235钢的自腐蚀速度,说明其耐蚀性明显优于Q235钢。从而表明在Q235钢基体表面通过化学镀NiP镀层能够提高基体的耐蚀性。The prepared anti-corrosion transmission tower angle steel and steel pipe have bright and dense surfaces, and the coating is closely combined with the steel substrate. The fitting results of the polarization curves of Q235 steel and Ni-P coating show that the self-corrosion potential of Q235 is -1.0182V , the self-corrosion current density is 5.0481E-5A/cm 2 ; the self-corrosion potential of the Ni-P coating is -0.41173V, and the self-corrosion current density is 8.3611E-6A/cm 2 . It can be seen that the self-corrosion rate of Ni-P coating is significantly lower than that of Q235 steel, indicating that its corrosion resistance is significantly better than that of Q235 steel. This shows that the corrosion resistance of the substrate can be improved by electroless NiP coating on the surface of the Q235 steel substrate.
附图说明 Description of drawings
图1为本实用新型防腐蚀输电铁塔角钢结构图;Fig. 1 is the utility model anti-corrosion power transmission tower angle steel structural diagram;
图2为本实用新型防腐蚀输电铁塔钢管结构图;Fig. 2 is the structural diagram of the utility model anti-corrosion transmission tower steel pipe;
其中,1.角钢基体,2.钢管基体,3.化学镀镍磷涂层。Among them, 1. Angle steel substrate, 2. Steel pipe substrate, 3. Electroless nickel-phosphorous coating.
具体实施方式 Detailed ways
实施例1Example 1
一种防腐蚀输电铁塔角钢,在角钢基体1的全部外周覆有一层化学镀镍磷涂层3。An anti-corrosion electric transmission tower angle steel, in which a layer of electroless nickel-
化学镀镍磷涂层3厚度在20-50微米,化学镀镍磷涂层3中磷的质量含量为6-12%。The thickness of the electroless nickel-phosphorus coating 3 is 20-50 microns, and the mass content of phosphorus in the electroless nickel-
制造工艺过程如下:The manufacturing process is as follows:
(1)采用磨光机去除Q235角钢表面毛刺,并采用砂纸进行打磨去除污物。(1) Use a grinder to remove the burrs on the surface of the Q235 angle steel, and use sandpaper to remove dirt.
(2)采用NaOH(30g/L)对角钢进行碱洗,之后采用33%(v/v)盐酸进行酸洗除锈,5%(v/v)稀硫酸进行弱酸活化,最后利用去离子水对角钢进行冲洗,供镀层沉积使用。(2) Use NaOH (30g/L) to carry out alkali cleaning on the angle steel, then use 33% (v/v) hydrochloric acid to carry out pickling and rust removal, 5% (v/v) dilute sulfuric acid to carry out weak acid activation, and finally use deionized water Rinsing of steel angles for coating deposition.
(3)角钢置于镀液中进行化学镀,镀液成分为:硫酸镍25g∕L,次磷酸钠25g∕L,乙酸钠14g∕L,柠檬酸6g∕L,PH值为4,温度为80℃,化学镀时间为4h。(3) The angle steel is placed in the plating solution for electroless plating. The composition of the plating solution is: nickel sulfate 25g/L, sodium hypophosphite 25g/L, sodium acetate 14g/L, citric acid 6g/L, pH value is 4, and the temperature is 80°C, the electroless plating time is 4h.
实施例2Example 2
一种防腐蚀输电铁塔钢管,在钢管基体2的内表面和外表面分别覆有一层化学镀镍磷涂层3。An anti-corrosion electric transmission tower steel pipe, the inner surface and the outer surface of the
化学镀镍磷涂层3厚度在20-50微米,化学镀镍磷涂层3中磷的质量含量为6-12%。The thickness of the electroless nickel-phosphorus coating 3 is 20-50 microns, and the mass content of phosphorus in the electroless nickel-
制造工艺过程如下:The manufacturing process is as follows:
(1)采用磨光机去除Q345钢管表面毛刺,并采用砂纸进行打磨去除污物。(1) Use a grinder to remove the burrs on the surface of the Q345 steel pipe, and use sandpaper to polish to remove dirt.
(2)采用NaOH(30g/L)对角钢进行碱洗,之后采用33%(v/v)盐酸进行酸洗除锈,5%(v/v)稀硫酸进行弱酸活化,最后利用去离子水对角钢进行冲洗,供镀层沉积使用。(2) Use NaOH (30g/L) to carry out alkali cleaning on the angle steel, then use 33% (v/v) hydrochloric acid to carry out pickling and rust removal, 5% (v/v) dilute sulfuric acid to carry out weak acid activation, and finally use deionized water Rinsing of steel angles for coating deposition.
(3)钢管置于镀液中进行化学镀,镀液成分为:硫酸镍25g∕L,次磷酸钠25g∕L,乙酸钠14g∕L,柠檬酸6g∕L,PH值为5,温度为90℃,化学镀时间为4h。(3) The steel pipe is placed in the plating solution for electroless plating. The composition of the plating solution is: nickel sulfate 25g/L, sodium hypophosphite 25g/L, sodium acetate 14g/L, citric acid 6g/L, pH value is 5, and the temperature is 90°C, electroless plating time is 4h.
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| CN2012202231558U CN202558938U (en) | 2012-05-17 | 2012-05-17 | Anti-corrosion power transmission iron tower angle steel and anti-corrosion power transmission iron tower steel tube |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103042367A (en) * | 2013-01-28 | 2013-04-17 | 新兴铸管股份有限公司 | Production method of metallurgical composite channel steel |
| CN105465491A (en) * | 2015-12-14 | 2016-04-06 | 徐州徐工液压件有限公司 | High-precision antiseptic wear-resisting oil tube and manufacturing method thereof |
-
2012
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103042367A (en) * | 2013-01-28 | 2013-04-17 | 新兴铸管股份有限公司 | Production method of metallurgical composite channel steel |
| CN103042367B (en) * | 2013-01-28 | 2015-03-25 | 新兴铸管股份有限公司 | Production method of metallurgical composite channel steel |
| CN105465491A (en) * | 2015-12-14 | 2016-04-06 | 徐州徐工液压件有限公司 | High-precision antiseptic wear-resisting oil tube and manufacturing method thereof |
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Legal Events
| Date | Code | Title | Description |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: STATE GRID CORPORATION OF CHINA Effective date: 20121107 |
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| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20121107 Address after: 250002 Ji'nan City Central District, Shandong, No. 2 South Road, No. 500 Patentee after: Shandong Research Inst. of Electric Power Patentee after: State Grid Corporation of China Address before: 250002 Ji'nan City Central District, Shandong, No. 2 South Road, No. 500 Patentee before: Shandong Research Inst. of Electric Power |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20121128 Termination date: 20190517 |
