A kind of combined type ceramic honey comb film filtering element
Technical field
The utility model relates to the membrane separation technique field, relates in particular to a kind of ceramic honeycomb filter membrane element.
Background technology
Compare with other separating technology, it is a kind of simple relatively, low separating technology of power consumption that film separates, and can reclaim and utilize component in the mixture in principle, thereby be widely used in bioengineering, oil, chemical industry, metallurgy, medicine and other fields.Film separates realizes that by membrane module its core is a filter membrane.Compare with organic film, ceramic filter membrane has that chemical stability is good, mechanical strength is big, anti-microbe ability is strong, high temperature resistant, pore-size distribution is narrow, the separative efficiency advantages of higher.Because the rigidity of ceramic material is better, is subjected to preparation technology's restriction simultaneously, the prior art ceramic membrane is mainly based on tubular type and multichannel tubular type at present.Yet because its film density of ceramic membrane of single tube configuration (being the membrane area in the unit volume) is lower, therefore the ceramic membrane of commodity production at present improves film density by increasing duct number (as 7,19,37 passages) mostly.In addition, be further to increase membrane area, ceramic filter element has also adopted the ceramic honey comb structure at present, increases membrane area in the unit volume by the method that increases fenestra road number, reduces channel diameter.
Yet in prior art multichannel/ceramic honey comb pipe configuration, the formed penetrating fluid in duct that is in the center need be through outside the long distance ability discharger, and this has obviously increased the osmotic resistance of film, has reduced permeation flux; And the ceramic honeycomb filter membrane is along with channel diameter and ceramic membrane pore wall thickness reduces, and more the penetrating fluid in multimembrane duct can only infiltrate into outlet by the inner duct of ceramic honey comb supporter, and the transport resistance of penetrating fluid also obviously increases.Be head it off, for the ceramic honey comb film, prior art adopts the method that part fenestra road is transformed into permeate passageway usually, to reduce the path of infiltration water outlet; Perhaps, along cross-wise direction slotted in the part duct, reserve the part fluting, use the method for sintering that the port that penetrates aquaporin is carried out shutoff then as penetrating water out in the port; In addition, also have and central duct do not filmed and as the filtration and infiltration side, and adopt in central hole that a drainage tube is drawn penetrating fluid, method that epoxy sealing is adopted in the gap between centre bore and the drainage tube, to reduce osmotic resistance, improve permeation flux.But prior art ceramic honey comb pipe configuration still exists following technological deficiency:
(1) utilizes the part passage as permeate passageway, can reduce the path of infiltration water outlet, but also reduced the membrane area in the unit volume simultaneously, run counter to the design original intention that increases membrane area by honeycomb configuration.
(2) need carry out post-processed to ceramic membrane, the post-production difficulty is higher for ceramic membrane, has further increased preparation technology's complexity.
(3) for methods such as port fluting or increase drainage tubes, need port be sealed, sealing difficulty is bigger, causes penetrating fluid to mix with feed liquid easily.For example, the port of cross-notching carries out the method for shutoff owing to relate to drying and sintering process, and the difference between plugging material and the ceramic honey comb performance forms hole easily, thereby causes feed liquid pollution infiltration water outlet in filter process easily.
(4) more, the complex process of the preparation section of ceramic honey comb film, the possibility of introducing defective increases, make that the yield rate of zero defect ceramic honey comb film is lower, the ceramic honey comb film of larger volume particularly, increase along with the ceramic membrane sectional area, yield rate also can be lower, thereby further increased originally just than higher ceramic membrane cost.
The utility model content
The purpose of this utility model is to overcome the deficiencies in the prior art, a kind of have higher permeation flux and the simple combined type ceramic honey comb of unit volume membrane area, configuration and preparation technology film filtering element are provided, to effectively reduce osmotic resistance, greatly improve yield rate, the reduction ceramic membrane cost of ceramic honey comb film simultaneously.
The purpose of this utility model is achieved by the following technical programs:
A kind of combined type ceramic honey comb film filtering element that the utility model provides, the filtration duct that comprises the ceramic honey comb supporter and set within it; In addition, also comprise supporting member and securing member; Described ceramic honey comb supporter is a tabular, and its axis of described filtration duct is parallel with the plate face of ceramic honey comb supporter and be arranged side by side in the ceramic honey comb supporter and constitute ceramic honey comb film monomer; Described ceramic honey comb film monomer is more than two or two, and is and stacks at interval combination; Described securing member is arranged on the ceramic honey comb film monomer periphery after the combination; Described supporting member is between the adjacent cell ceramic membrane monomer and between securing member and the ceramic honey comb film monomer, and is arranged on and filters the port, duct.
It is the feed liquid passage that the utility model filters the duct, and each ceramic honey comb film monomer is tabular, makes ceramic membrane have short seepage distance.Gap between the ceramic honey comb film monomer is a permeate passageway, and the hole wall infiltration in duct after, thereby flow out, have higher permeation flux after filtration by the gap between ceramic honey comb film monomer for penetrating fluid.
The utility model also can be taked following further measure: detachable being arranged on of described supporting member filtered the port, duct.Like this, can adjust the width of permeate passageway by the thickness of regulating supporting member according to the size of infiltration capacity; In addition, it is seriously polluted or replace defective ceramic honey comb film monomer to be convenient to disassembly, cleaning.
For reducing the transport resistance of penetrating fluid, the filtration duct is directly adjacent with permeate passageway in the utility model ceramic honey comb film monomer, and single duct can be adopted in promptly described filtration duct; Also can adopt double duct and have higher unit volume membrane area.Further, filter wall thickness between duct and the ceramic honey comb supporter outer surface in the described ceramic honey comb film monomer less than other position wall thickness, thereby have shorter seepage distance, the while can be improved the intensity of ceramic honey comb supporter.
It is a rectangle perpendicular to the cross sectional shape that filters the duct axis for ceramic honey comb film monomer described in the utility model, and the ceramic honey comb film filtering element after the combination is cuboid.Perhaps, this cross sectional shape is trapezoidal for containing arc, and the ceramic honey comb film filtering element after the combination is cylinder.
The shape of cross section in filtration described in the utility model duct can be square, rectangle, hexagon or triangle.
The utlity model has following beneficial effect:
(1) has higher permeation flux and unit volume membrane area
The utility model ceramic honey comb film monomer is tabular, and seepage distance is short, and osmotic resistance obviously reduces, and has higher permeation flux.Interval between the ceramic honey comb film monomer is that the width of permeate passageway can be adjusted, therefore can easily adjust permeate passageway according to the size of permeation flux, thereby avoided the reduction of the unit volume membrane area that unnecessary permeate passageway width caused, helped to improve the film density of ceramic membrane.
(2) configuration and preparation technology are simple, have effectively improved the yield rate of ceramic honey comb film
The flat ceramic honey comb film of the utility model monomer, volume is less, and the possibility that single product produces defective obviously reduces.Simultaneously, configuration is simple, by detachable the combining of ceramic honey comb film monomer, be convenient to the seriously polluted ceramic membrane monomer of disassembly, cleaning, and only change the separation infiltration function that defective ceramic membrane monomer can recover the ceramic honey comb membrane module again, scrap and be unlikely to integral body, greatly improved ceramic membrane yield rate, reduced the ceramic membrane cost.
Description of drawings
Below in conjunction with embodiment and accompanying drawing the utility model is described in further detail:
Fig. 1 is the stereogram of one of the utility model embodiment combined type ceramic honey comb film filtering element;
Fig. 2 is a front view embodiment illustrated in fig. 1;
Fig. 3 is the left view of Fig. 1;
Fig. 4 is the local enlarged diagram of middle ceramic honey comb film monomer cross section embodiment illustrated in fig. 1;
Fig. 5 is the two ceramic honey comb film monomer cross-sectional structure schematic diagrames of the utility model embodiment;
Fig. 6 is the stereogram of combined type ceramic honey comb film filtering element embodiment illustrated in fig. 5.
Among the figure: ceramic honey comb film monomer 1, ceramic honey comb supporter 1a filters duct 1b, supporting member 2, securing member 3, permeate passageway 4, wall thickness W1, W2
The specific embodiment
Embodiment one:
Fig. 1~Figure 4 shows that one of embodiment of the utility model combined type ceramic honey comb film filtering element as depicted in figs. 1 and 2, comprises the ceramic honey comb film monomer 1, supporting member 2 and the securing member 3 that are made of ceramic honey comb supporter 1a and filtration duct 1b.
Wherein, ceramic honey comb supporter 1a is a tabular, and it is parallel with the plate face of ceramic honey comb supporter 1a and be arranged side by side in ceramic honey comb supporter 1a and formation ceramic honey comb film monomer 1 to filter its axis of duct 1b.As shown in Figure 3 and Figure 4, ceramic honey comb film monomer 1 its cross sectional shape perpendicular to filtration duct 1b axis is a rectangle.Filter duct 1b and adopt double duct, the shape of cross section in duct is a square, and the wall thickness W1 between filtration duct 1b and the ceramic honey comb supporter 1a outer surface is less than other positions wall thickness W2.
As depicted in figs. 1 and 2, ceramic honey comb film monomer 1 is several, and is and stacks at interval combination and constitute cuboid.Securing member 3 adopts stainless stirrup, and is arranged on the ceramic honey comb film monomer periphery after the combination.It is the silicone rubber pad of 1mm that supporting member 2 adopts thickness, and detachable be arranged between the adjacent cell ceramic membrane monomer 1 and securing member 3 and ceramic honey comb film monomer 1 between port, filtration duct.
It is the feed liquid passage that present embodiment filters duct 1b, and the gap between the ceramic honey comb film monomer 1 is a permeate passageway 4, and after the hole wall infiltration of duct 1b, the gap between ceramic honey comb film monomer 1 is that permeate passageway 4 flows out to penetrating fluid after filtration.According to the size of permeation flux, can adjust gap between the ceramic honey comb film monomer 1 by the supporting member 2 of changing different-thickness, thereby change the width of permeate passageway 4.And, the with serious pollution ceramic membrane monomer of disassembly, cleaning separately, or only change the overall performance that the ceramic membrane monomer that mass defect is arranged can recover the ceramic honey comb membrane module again.
Embodiment two:
Fig. 5 and two of the embodiment that Figure 6 shows that the utility model combined type ceramic honey comb film filtering element, be with embodiment one difference: as shown in Figure 5, ceramic honey comb film monomer 1 its cross sectional shape perpendicular to filtration duct 1b axis is trapezoidal for containing arc, is to stack combination at interval and constitute the cylinder (see figure 6).