CN201185207Y - Apparatus for simultaneously humidifying air and hydrogen - Google Patents

Apparatus for simultaneously humidifying air and hydrogen Download PDF

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Publication number
CN201185207Y
CN201185207Y CNU2007200767841U CN200720076784U CN201185207Y CN 201185207 Y CN201185207 Y CN 201185207Y CN U2007200767841 U CNU2007200767841 U CN U2007200767841U CN 200720076784 U CN200720076784 U CN 200720076784U CN 201185207 Y CN201185207 Y CN 201185207Y
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China
Prior art keywords
hydrogen
air
humidification
side end
cooling water
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Expired - Fee Related
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CNU2007200767841U
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Chinese (zh)
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胡里清
章波
李丽
李拯
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Shanghai Shenli Technology Co Ltd
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Shanghai Shen Li High Tech Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Abstract

The utility model relates to a device which simultaneously humidifies air and hydrogen. The device comprises an air humifying reactor, hydrogen humifying reactor, an air side end-plate and a hydrogen side end-plate. The air humifying reactor consists of a plurality of groups of cooling water baffles, humifying diaphragms and air baffles which are overlapped in turn. The hydrogen humifying reactor consists of a plurality of groups of cooling water baffles, humifying diaphragms and hydrogen baffles which are overlapped in turn. Besides, the hydrogen humifying reactor also comprises a clapboard. The air humifying reactor and the hydrogen humifying reactor are respectively arranged on the two sides of the clapboard to form an integrated humifying device of air and hydrogen. Pipelines for air, hydrogen and cooling water to pass in and out are arranged respectively on the air side end-plate and the hydrogen side end-plate. Compared with the prior art, the device of the utility model has the advantages of simple structure, space saving, etc.

Description

The device of a kind of while humidification air and hydrogen
Technical field
The utility model relates to fuel cell, relates in particular to a kind of integrated approach with Proton Exchange Membrane Fuel Cells of interior humidifying device.
Background technology
Electrochemical fuel cell is a kind of device that hydrogen fuel and oxidant can be changed into electric energy and product.The internal core parts of this device are membrane electrode (Membrane Electrode Assembly are called for short MEA), and membrane electrode (MEA) is made up of as carbon paper a proton exchange membrane, two porous conductive materials of film two sides folder.The catalyst that contains the initiation electrochemical reaction of even tiny dispersion on two boundary faces of film and carbon paper is as the metal platinum catalyst.The electronics that the membrane electrode both sides can will take place to generate in the electrochemical reaction process with conductive body is drawn by external circuit, constitutes current circuit.
At the anode tap of membrane electrode, fuel can pass porousness diffusion material (carbon paper) by infiltration, and electrochemical reaction takes place on catalyst surface, lose electronics, form cation, cation can pass proton exchange membrane by migration, arrives the other end cathode terminal of membrane electrode.At the cathode terminal of membrane electrode, contain the gas of oxidant (as oxygen), as air, pass porousness diffusion material (carbon paper), and the generation electrochemical reaction obtains electronics on catalyst surface, forms anion by infiltration.The cation of coming in the anion and the anode tap migration of cathode terminal formation reacts, and forms product.
Adopting hydrogen is fuel, and the air that contains oxygen is in the Proton Exchange Membrane Fuel Cells of oxidant (or pure oxygen is an oxidant), and fuel hydrogen has just produced hydrogen cation (or being proton) in the catalytic electrochemical reaction of anode region.Proton exchange membrane helps the hydrogen cation to move to the cathodic region from the anode region.In addition, proton exchange membrane is separated the air-flow and the oxygen containing air-flow of hydrogen fuel, they can not mixed mutually and produces explosion type reaction.
In the cathodic region, oxygen obtains electronics on catalyst surface, forms anion, and moves the hydrogen cation reaction of coming, reaction of formation product water with the anode region.In the Proton Exchange Membrane Fuel Cells that adopts hydrogen, air (oxygen), anode reaction and cathode reaction can be expressed in order to following equation:
Anode reaction: H 2→ 2H ++ 2e
Cathode reaction: 1/2O 2+ 2H ++ 2e → H 2O
In typical Proton Exchange Membrane Fuel Cells, membrane electrode (MEA) generally all is placed in the middle of the pole plate of two conductions, and quarter is milled by die casting, punching press or machinery in the surface that every block of flow guiding electrode plate contacts with membrane electrode, and formation is the guiding gutter of one or more at least.These flow guiding electrode plates can be the pole plates of metal material, also can be the pole plates of graphite material.Water conservancy diversion duct on these flow guiding electrode plates and guiding gutter import fuel and oxidant the anode region and the cathodic region on membrane electrode both sides respectively.In the structure of a Proton Exchange Membrane Fuel Cells monocell, only there is a membrane electrode, the membrane electrode both sides are respectively the guide plate of anode fuel and the guide plate of cathode oxidant.These guide plates are both as the current collector motherboard, also as the mechanical support on membrane electrode both sides, guiding gutter on the guide plate acts as a fuel again and enters the passage of anode, cathode surface with oxidant, and as the passage of taking away the water that generates in the fuel cell operation process.
In order to increase the gross power of whole Proton Exchange Membrane Fuel Cells, two or more monocells can be connected into battery pack or be unified into battery pack by the mode that tiles usually by straight folded mode.In straight folded, in-line battery pack, can there be guiding gutter on the two sides of a pole plate, and wherein one side can be used as the anode guide face of a membrane electrode, and another side can be used as the cathode diversion face of another adjacent membranes electrode, and this pole plate is called bipolar plates.A series of monocell connects together by certain way and forms a battery pack.Battery pack tightens together by front end-plate, end plate and pull bar usually and becomes one.
A typical battery stack generally includes: the water conservancy diversion import and the flow-guiding channel of (1) fuel and oxidant gas are distributed to fuel (as hydrogen, methyl alcohol or the hydrogen-rich gas that obtained by methyl alcohol, natural gas, gasoline) and oxidant (mainly being oxygen or air) in the guiding gutter of each anode, cathode plane equably after reforming; (2) import and export and the flow-guiding channel of cooling water (as water) are evenly distributed to cooling water in each battery pack inner cooling channel, the heat absorption that hydrogen in the fuel cell, the exothermic reaction of oxygen electrochemistry are generated and take battery pack out of after dispel the heat; (3) outlet of fuel and oxidant gas and corresponding flow-guiding channel, fuel gas and oxidant gas are when discharging, and portability goes out the liquid that generates in the fuel cell, the water of steam state.Usually, the import and export of all fuel, oxidant, cooling water are all opened on the end plate of fuel battery or on two end plates.
Proton Exchange Membrane Fuel Cells can be used as the dynamical system of delivery vehicles such as all cars, ship, can be used as portable, portable, fixed Blast Furnace Top Gas Recovery Turbine Unit (TRT) again.Core component is a membrane electrode in the Proton Exchange Membrane Fuel Cells, and proton exchange membrane is the core component in the membrane electrode.
Used proton exchange membrane in the membrane electrode of fuel batter with proton exchange film needs the hydrone existence and preserves moisture in the battery operation process at present.Because have only the proton of aquation just can freely pass proton exchange membrane, arrive the electrode cathode end from the electrode anode end and participate in electrochemical reaction, otherwise, when the fuel hydrogen of a large amount of dryings or air when the membrane electrode both sides are flow through, easily the moisture subband in the proton exchange membrane is run, this moment, proton exchange membrane was in than drying regime, and proton can't pass proton exchange membrane, cause the electrode internal resistance sharply to increase, battery performance sharply descends.So, in general need through humidification to fuel cell supplied fuel hydrogen or air, the fuel hydrogen or the relative air humidity that enter fuel cell are improved, in order to avoid make the proton exchange membrane dehydration.
The mode that is applied to the Proton Exchange Membrane Fuel Cells humidification at present mainly contains two classes:
(1) outer humidification: humidification device separates with fuel battery, and at the outside self-existent humidification device of fuel battery.Mainly directly outside this, collide the hydrone that impels the GAS ABSORPTION vaporization with hydrone by fully mixing in the humidifying device by fuel hydrogen gas or air gas.
(2) interior humidification: interior humidifying device is the part that fuel battery is formed.Fuel battery is divided into two parts, and a part is interior humidification section, and another part is the active active section of battery.Interior humidification section is made of humidification baffler and humidification diaphragm, and the active active section of battery is made of baffler and membrane electrode.The humidification diaphragm often can be carried out the film that hydrone freely exchanges and formed by a kind of, for example E.I.Du Pont Company's trade mark
Figure Y20072007678400061
Amberplex, this film can allow deionized water flow on one side of film, and allow fuel gas or oxidant gas, flow as the another side of air at film, film can be separated fuel gas or air and liquid water molecules, but hydrone can pass freely through film again and enter in fuel gas or the air and go, and reaches the humidifying purpose.
Though above-mentioned method for designing can reach the humidification purpose, but there is following defective: need the outer humidification of humidifying device be set respectively at air and hydrogen usually, and divide be arranged air humidification device and hydrogen humidifying device itself need occupy very large space, and its pipeline that is used etc. also can occupy big quantity space, for fuel cell as engine application when the vehicles such as city bus, car or fork truck, installing space is limited, the auxiliary system volume and weight is excessive, can influence the efficient of fuel battery engines, and waste many materials.
Summary of the invention
The purpose of this utility model is exactly the device that a kind of while humidification air simple in structure, space-saving and hydrogen are provided for the defective that overcomes above-mentioned prior art existence.
The purpose of this utility model can be achieved through the following technical solutions: the device of a kind of while humidification air and hydrogen, this device comprises the air humidification heap, hydrogen humidification heap, the air side end plate, the hydrogen gas side end plate, described air humidification heap is by many groups cooling water baffler, the humidification diaphragm, air baffle superposes successively and assembles, described hydrogen humidification heap is by many groups cooling water baffler, the humidification diaphragm, the hydrogen flow guide plate superposes successively and assembles, it is characterized in that, also comprise dividing plate, described air humidification heap and hydrogen humidification heap are separately positioned on the dividing plate both sides, form air hydrogen integrated form humidifying device, the air inlet and outlet piping, hydrogen inlet and outlet piping or cooling water inlet and outlet piping are separately positioned on air side end plate or the hydrogen gas side end plate.
The two sides of described dividing plate are provided with the cooling water guiding gutter, and the upper and lower or left and right end of dividing plate is provided with the cooling water manhole appendix, air portals and/or hydrogen portals.
Cooling water baffler, humidification diaphragm, the air baffle of described air humidification heap are provided with air ports and cooling water outlet and inlet, many group cooling water bafflers, humidification diaphragm, air baffle stack are provided with and form air access way and cooling water access way, the air intlet pipeline is arranged on air side end plate or the hydrogen gas side end plate, and the air outlet slit pipeline is arranged on hydrogen gas side end plate or the air side end plate.
Also be provided with hydrogen outlet on the cooling water baffler of described air humidification heap, humidification diaphragm, the air baffle, many group cooling water bafflers, humidification diaphragm, air baffle stack are provided with and form the hydrogen outlet passage, described dividing plate is provided with the cooling water manhole appendix and hydrogen portals, the hydrogen inlet pipeline is arranged on the hydrogen gas side end plate, and the hydrogen outlet pipeline is arranged on the air side end plate.
Described hydrogen inlet pipeline is arranged on the air side end plate, and the hydrogen outlet pipeline is arranged on the hydrogen gas side end plate.
Cooling water baffler, humidification diaphragm, the hydrogen flow guide plate of described hydrogen humidification heap is provided with hydrogen and imports and exports and cooling water outlet and inlet, many group cooling water bafflers, humidification diaphragm, the stack of hydrogen flow guide plate are provided with and form hydrogen access way and cooling water access way, the hydrogen inlet pipeline is arranged on air side end plate or the hydrogen gas side end plate, and the hydrogen outlet pipeline is arranged on hydrogen gas side end plate or the air side end plate.
Also be provided with air outlet slit on the cooling water baffler of described hydrogen humidification heap, humidification diaphragm, the hydrogen flow guide plate, many group cooling water bafflers, humidification diaphragm, the stack of hydrogen flow guide plate are provided with the formation air outlet passage, described dividing plate is provided with the cooling water manhole appendix and air portals, the air intlet pipeline is arranged on the air side end plate, and the air outlet slit pipeline is arranged on the hydrogen gas side end plate.
Described air intlet pipeline is arranged on the hydrogen gas side end plate, and the air outlet slit pipeline is arranged on the air side end plate.
Compared with prior art, the utility model is that air and hydrogen humidification system are integrated into a humidification system with the humidification system of fuel cell, and is simple in structure, pipeline is few, occupy little space, volume weight is little, thereby has improved the gravimetric specific power and the volumetric specific power of fuel battery engines greatly.
Description of drawings
Fig. 1 is the device schematic diagram of the utility model while humidification air and hydrogen;
Fig. 2 is the air baffle schematic diagram of the utility model air humidification heap;
Fig. 3 is the cooling water baffler schematic diagram of the utility model air humidification heap;
Fig. 4 is the schematic diagram of the utility model dividing plate;
Fig. 5 is the hydrogen flow guide plate of the utility model hydrogen humidification heap;
Fig. 6 is the cooling water baffler schematic diagram of the utility model hydrogen humidification heap.
Embodiment
Below in conjunction with the accompanying drawings and the specific embodiments, the utility model is described in further detail.
Embodiment 1
As shown in Figure 1, the integrated humidifying device of air hydrogen of the motorcar engine of 50kw, long 550mm, wide 210mm, high 240mm, this system comprises air humidification heap 1, hydrogen humidification heap 2, air side end plate 14, hydrogen gas side end plate 24, dividing plate 3, described air humidification heap 1 and hydrogen humidification heap 2 are separately positioned on dividing plate 3 both sides, form air hydrogen integrated form humidifying device, the air intlet pipeline 12 that air is piled 1 side from air humidification enters, pile air outlet slit pipeline 13 outflows of 2 sides behind the humidification from the hydrogen humidification, cooling water enters from the cooling water pipeline 11 of air humidification heap side, and the cooling water pipeline 23 of piling 2 sides from the hydrogen humidification flows out, the hydrogen inlet pipeline 21 that hydrogen is piled 2 sides from the hydrogen humidification enters, and piles hydrogen outlet pipeline 22 outflows of 2 sides behind the humidification from the hydrogen humidification.
Shown in Fig. 1~3, above-mentioned air humidification heap 1 is superposeed successively by 20 groups of cooling water bafflers 15 (as shown in Figure 3), 40 16,20 groups of air baffles 17 of humidification diaphragm (as shown in Figure 2) and assembles, this cooling water baffler 15, humidification diaphragm 16, air baffle 17 are provided with air ports 121,122, cooling water outlet and inlet 111,112,20 groups of cooling water bafflers, 40 humidification diaphragms, 20 groups of air baffle stacks form air access way, cooling water access way.
Shown in Fig. 1,5~6, described hydrogen humidification heap is superposeed successively by 10 groups of cooling water bafflers 25 (as shown in Figure 6), 20 26,10 groups of hydrogen flow guide plates 27 of humidification diaphragm (as shown in Figure 5) and assembles, this cooling water baffler 25, humidification diaphragm 26, hydrogen flow guide plate 27 are provided with hydrogen import and export 211,221, cooling water outlet and inlet 231,232, air outlet slit 122,27 stacks of 26,10 groups of hydrogen flow guide plates of 25,20 humidification diaphragms of 10 groups of cooling water bafflers form the hydrogen access way, and cooling water access way, air go out passage.
As shown in Figure 4, aforementioned barriers 3 is provided with air outlet slit 322, cooling water outlet and inlet 311,312, after air enters air humidification and piles 1 humidification from air side end plate 14, pass dividing plate 3 and hydrogen humidification heap 2, flow out from hydrogen gas side end plate 24, cooling water enters air humidification heap 1 from air side end plate 14, pass dividing plate 3 and enter hydrogen humidification heap 2, flow out from hydrogen gas side end plate 24, hydrogen returns from hydrogen gas side end plate 24 and flows out after entering the hydrogen humidification and pile 2 humidifications from hydrogen gas side end plate 24.
20 groups of cooling water bafflers, 40 humidification diaphragms, 20 groups of air baffles of above-mentioned air humidification heap superpose successively, the fluid inlet and outlet stack forms the air access way on each plate, the cooling water access way, on each plate of hydrogen humidification heap, also be provided with air outlet slit simultaneously, thereby on hydrogen humidification heap, form air outlet passage, therefore air enters the humidification system humidification from the air humidification heap, flow out from the air outlet passage of hydrogen humidification heap, the humidification of air is finished at the air humidification heap, only is process at hydrogen humidification heap.The hydrogen import and export are the air intlet on the air baffle of air humidification heap to be divided into two form on the hydrogen flow guide plate of hydrogen humidification heap, and hydrogen returns from the outflow of hydrogen humidification heap behind hydrogen humidification heap humidification.Do not advance or export so do not establish hydrogen on the dividing plate, hydrogen and air are separated humidification heap humidification separately, the while heaps two humidifications become together again, when reaching the humidification effect, has saved the space.
Above-mentioned air also can flow into from hydrogen gas side end plate 24, passes the air outlet passage of hydrogen humidification heap 2 and the air on the dividing plate successively and portals and 322 enter air humidification heap 1 and carry out humidification, flows out from air side end plate 14 again.
Embodiment 2
Referring to Fig. 1~Fig. 6, the air of the city bus fuel battery engines of 100kw and hydrogen is the device of humidification simultaneously, long 600mm, wide 400mm, high 300mm, this system comprises air humidification heap, hydrogen humidification heap, air side end plate, hydrogen gas side end plate, dividing plate, the two sides of this dividing plate are provided with the cooling water guiding gutter, the dividing plate upper and lower end is provided with the cooling water manhole appendix and hydrogen portals, hydrogen passes the hydrogen outlet passage outflow of dividing plate from the air humidification heap after entering hydrogen humidification heap humidification from the hydrogen gas side end plate; Perhaps hydrogen flows into from the air side end plate, passes the hydrogen outlet passage of air humidification heap and dividing plate and enters hydrogen humidification heap and carry out humidification, flows out from the hydrogen gas side end plate again.
Air returns from the air side end plate and flows out after entering air humidification heap humidification from the air side end plate, and cooling water enters humidification system from the air side end plate and flows out from the hydrogen gas side end plate.Described air humidification heap is superposeed successively by 40 groups of cooling water bafflers, 80 humidification diaphragms, 40 groups of air baffles, described hydrogen humidification heap is superposeed successively and is assembled by 40 groups of cooling water bafflers, 80 humidification diaphragms, 40 groups of hydrogen flow guide plates, and other are with embodiment 1.
Embodiment 3
Referring to Fig. 1~Fig. 6, a kind of humidifying device of fork truck fuel battery engines, long 300mm, wide 250mm, high 250mm, this system comprises air humidification heap, hydrogen humidification heap, air side end plate, hydrogen gas side end plate, dividing plate, the two sides of this dividing plate are provided with the cooling water guiding gutter, the left and right end of dividing plate is provided with the cooling water manhole appendix, and hydrogen returns from the hydrogen gas side end plate and flows out after entering hydrogen humidification heap humidification from the hydrogen gas side end plate.Air returns from the air side end plate and flows out after entering air humidification heap humidification from the air side end plate.Cooling water enters humidification system from the hydrogen gas side end plate and flows out from the air side end plate, described air humidification heap is superposeed successively by 10 groups of cooling water bafflers, 20 humidification diaphragms, 10 groups of air baffles, described hydrogen humidification heap is superposeed successively and is assembled by 20 groups of cooling water bafflers, 40 humidification diaphragms, 20 groups of hydrogen flow guide plates, and other are with embodiment 1.
Embodiment 4
Referring to Fig. 1~Fig. 6, a kind of humidifying device of fuel battery engines, this system comprises air humidification heap, hydrogen humidification heap, air side end plate, hydrogen gas side end plate, dividing plate, the two sides of this dividing plate are provided with the cooling water guiding gutter, the left and right end of dividing plate is provided with the cooling water manhole appendix, air portals and hydrogen portals, hydrogen passes dividing plate and air humidification heap and flows out from the air side end plate after entering hydrogen humidification heap humidification from the hydrogen gas side end plate.Air passes dividing plate and hydrogen humidification heap and flows out from the hydrogen gas side end plate after entering air humidification heap humidification from the air side end plate.Cooling water enters humidification system from the air side end plate and flows out from the hydrogen gas side end plate, and other are with embodiment 1.
This humidification system also can be used on other fuel cell systems.

Claims (8)

1, the device of a kind of while humidification air and hydrogen, this device comprises the air humidification heap, hydrogen humidification heap, the air side end plate, the hydrogen gas side end plate, described air humidification heap is by many groups cooling water baffler, the humidification diaphragm, air baffle superposes successively and assembles, described hydrogen humidification heap is by many groups cooling water baffler, the humidification diaphragm, the hydrogen flow guide plate superposes successively and assembles, it is characterized in that, also comprise dividing plate, described air humidification heap and hydrogen humidification heap are separately positioned on the dividing plate both sides, form air hydrogen integrated form humidifying device, the air inlet and outlet piping, hydrogen inlet and outlet piping or cooling water inlet and outlet piping are separately positioned on air side end plate or the hydrogen gas side end plate.
2. the device of a kind of while humidification air according to claim 1 and hydrogen is characterized in that the two sides of described dividing plate are provided with the cooling water guiding gutter, and the upper and lower or left and right end of dividing plate is provided with the cooling water manhole appendix, air portals and/or hydrogen portals.
3. the device of a kind of while humidification air according to claim 1 and hydrogen, it is characterized in that, cooling water baffler, humidification diaphragm, the air baffle of described air humidification heap are provided with air ports and cooling water outlet and inlet, many group cooling water bafflers, humidification diaphragm, air baffle stack are provided with and form air access way and cooling water access way, the air intlet pipeline is arranged on air side end plate or the hydrogen gas side end plate, and the air outlet slit pipeline is arranged on hydrogen gas side end plate or the air side end plate.
4. the device of a kind of while humidification air according to claim 3 and hydrogen, it is characterized in that, also be provided with hydrogen outlet on the cooling water baffler of described air humidification heap, humidification diaphragm, the air baffle, many group cooling water bafflers, humidification diaphragm, air baffle stack are provided with and form the hydrogen outlet passage, described dividing plate is provided with the cooling water manhole appendix and hydrogen portals, the hydrogen inlet pipeline is arranged on the hydrogen gas side end plate, and the hydrogen outlet pipeline is arranged on the air side end plate.
5. the device of a kind of while humidification air according to claim 4 and hydrogen is characterized in that described hydrogen inlet pipeline is arranged on the air side end plate, and the hydrogen outlet pipeline is arranged on the hydrogen gas side end plate.
6. the device of a kind of while humidification air according to claim 1 and hydrogen, it is characterized in that, cooling water baffler, humidification diaphragm, the hydrogen flow guide plate of described hydrogen humidification heap is provided with hydrogen and imports and exports and cooling water outlet and inlet, many group cooling water bafflers, humidification diaphragm, the stack of hydrogen flow guide plate are provided with and form hydrogen access way and cooling water access way, the hydrogen inlet pipeline is arranged on air side end plate or the hydrogen gas side end plate, and the hydrogen outlet pipeline is arranged on hydrogen gas side end plate or the air side end plate.
7. the device of a kind of while humidification air according to claim 6 and hydrogen, it is characterized in that, also be provided with air outlet slit on the cooling water baffler of described hydrogen humidification heap, humidification diaphragm, the hydrogen flow guide plate, many group cooling water bafflers, humidification diaphragm, the stack of hydrogen flow guide plate are provided with the formation air outlet passage, described dividing plate is provided with the cooling water manhole appendix and air portals, the air intlet pipeline is arranged on the air side end plate, and the air outlet slit pipeline is arranged on the hydrogen gas side end plate.
8. the device of a kind of while humidification air according to claim 7 and hydrogen is characterized in that described air intlet pipeline is arranged on the hydrogen gas side end plate, and the air outlet slit pipeline is arranged on the air side end plate.
CNU2007200767841U 2007-10-30 2007-10-30 Apparatus for simultaneously humidifying air and hydrogen Expired - Fee Related CN201185207Y (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102201588A (en) * 2010-11-02 2011-09-28 北京万瑞讯通科技有限公司 Device and method for treating tail gas of fuel cell

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102201588A (en) * 2010-11-02 2011-09-28 北京万瑞讯通科技有限公司 Device and method for treating tail gas of fuel cell
CN102201588B (en) * 2010-11-02 2013-07-17 北京万瑞讯通科技有限公司 Device and method for treating tail gas of fuel cell

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