CN1986789B - 用于污染水源修复的固定化酶复合材料及其制备方法 - Google Patents
用于污染水源修复的固定化酶复合材料及其制备方法 Download PDFInfo
- Publication number
- CN1986789B CN1986789B CN200610135342A CN200610135342A CN1986789B CN 1986789 B CN1986789 B CN 1986789B CN 200610135342 A CN200610135342 A CN 200610135342A CN 200610135342 A CN200610135342 A CN 200610135342A CN 1986789 B CN1986789 B CN 1986789B
- Authority
- CN
- China
- Prior art keywords
- enzyme
- immobilized enzyme
- composite immobilized
- composite
- water
- Prior art date
Links
- 239000000463 materials Substances 0.000 title claims abstract description 58
- 108010093096 Immobilized Enzymes Proteins 0.000 title claims abstract description 40
- 239000002131 composite materials Substances 0.000 title claims abstract description 40
- 239000011901 water Substances 0.000 title claims abstract description 32
- 238000000034 methods Methods 0.000 title claims abstract description 14
- 108090000790 Enzymes Proteins 0.000 claims abstract description 34
- 102000004190 Enzymes Human genes 0.000 claims abstract description 34
- 239000000969 carriers Substances 0.000 claims abstract description 15
- 239000010865 sewage Substances 0.000 claims abstract description 12
- 238000002360 preparation methods Methods 0.000 claims abstract description 11
- 239000010881 fly ash Substances 0.000 claims abstract description 9
- 230000000996 additive Effects 0.000 claims abstract description 8
- 239000000654 additives Substances 0.000 claims abstract description 8
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium monoxide Chemical compound data:image/svg+xml;base64,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 data:image/svg+xml;base64,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 [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910000118 calcium oxide Inorganic materials 0.000 claims abstract description 8
- 239000000292 calcium oxide Substances 0.000 claims abstract description 8
- 238000001035 drying Methods 0.000 claims abstract description 5
- 238000005303 weighing Methods 0.000 claims abstract description 4
- 229940088598 Enzyme Drugs 0.000 claims description 33
- 239000000203 mixtures Substances 0.000 claims description 20
- 239000000047 products Substances 0.000 claims description 11
- 239000011449 bricks Substances 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 238000009472 formulation Methods 0.000 claims description 8
- 230000024881 catalytic activity Effects 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 230000002522 swelling Effects 0.000 claims description 7
- 239000002994 raw materials Substances 0.000 claims description 6
- 239000003469 silicate cements Substances 0.000 claims description 6
- 239000002699 waste materials Substances 0.000 claims description 6
- 238000000748 compression moulding Methods 0.000 claims description 5
- 239000000344 soaps Substances 0.000 claims description 5
- 238000007605 air drying Methods 0.000 claims description 4
- 239000002245 particles Substances 0.000 claims description 4
- 230000002378 acidificating Effects 0.000 claims description 3
- 238000007906 compression Methods 0.000 claims description 3
- 230000000704 physical effects Effects 0.000 claims description 3
- 239000004575 stone Substances 0.000 claims description 3
- 101710028359 CELB Proteins 0.000 claims description 2
- 229940106157 CELLULASE Drugs 0.000 claims description 2
- 101710028037 Cellulase Proteins 0.000 claims description 2
- 101710037514 GLU8 Proteins 0.000 claims description 2
- 101710028339 GUNK Proteins 0.000 claims description 2
- 108010029541 Laccase Proteins 0.000 claims description 2
- 101710028126 Os02g0733300 Proteins 0.000 claims description 2
- 229940072417 Peroxidase Drugs 0.000 claims description 2
- 102000003992 Peroxidases Human genes 0.000 claims description 2
- 108090000437 Peroxidases Proteins 0.000 claims description 2
- 101710003441 Phosphoglucomutase Proteins 0.000 claims description 2
- 101710042136 bcsZ Proteins 0.000 claims description 2
- 101710028363 celCCC Proteins 0.000 claims description 2
- 101710028355 celE Proteins 0.000 claims description 2
- 101710028327 celF Proteins 0.000 claims description 2
- 230000000875 corresponding Effects 0.000 claims description 2
- 238000009826 distribution Methods 0.000 claims description 2
- 101710066465 endo-1,6-beta-glucanase Proteins 0.000 claims description 2
- 238000006062 fragmentation reactions Methods 0.000 claims description 2
- 230000003000 nontoxic Effects 0.000 claims description 2
- 231100000252 nontoxic Toxicity 0.000 claims description 2
- 230000002797 proteolythic Effects 0.000 claims description 2
- 239000002351 wastewater Substances 0.000 abstract description 8
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 5
- 238000002156 mixing Methods 0.000 abstract description 2
- 239000011398 Portland cement Substances 0.000 abstract 1
- 238000003825 pressing Methods 0.000 abstract 1
- 238000005516 engineering processes Methods 0.000 description 6
- 238000010521 absorption reactions Methods 0.000 description 5
- 238000006243 chemical reactions Methods 0.000 description 4
- 238000010586 diagrams Methods 0.000 description 3
- 239000000706 filtrates Substances 0.000 description 3
- 239000011499 joint compounds Substances 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- SVPXDRXYRYOSEX-UHFFFAOYSA-N Bentoquatam Chemical compound data:image/svg+xml;base64,<?xml version='1.0' encoding='iso-8859-1'?>
<svg version='1.1' baseProfile='full'
              xmlns='http://www.w3.org/2000/svg'
                      xmlns:rdkit='http://www.rdkit.org/xml'
                      xmlns:xlink='http://www.w3.org/1999/xlink'
                  xml:space='preserve'
width='300px' height='300px' viewBox='0 0 300 300'>
<!-- END OF HEADER -->
<rect style='opacity:1.0;fill:#FFFFFF;stroke:none' width='300' height='300' x='0' y='0'> </rect>
<path class='bond-0' d='M 176.347,203.561 L 189.852,203.561' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-0' d='M 189.852,203.561 L 203.357,203.561' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-0' d='M 176.347,191.98 L 189.852,191.98' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-0' d='M 189.852,191.98 L 203.357,191.98' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-1' d='M 235.537,203.561 L 249.042,203.561' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-1' d='M 249.042,203.561 L 262.547,203.561' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-1' d='M 235.537,191.98 L 249.042,191.98' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-1' d='M 249.042,191.98 L 262.547,191.98' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-2' d='M 34.5583,114.826 L 44.1845,120.384' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-2' d='M 44.1845,120.384 L 53.8107,125.942' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-2' d='M 40.3486,104.797 L 49.9748,110.355' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-2' d='M 49.9748,110.355 L 59.601,115.912' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-3' d='M 88.8852,139.506 L 98.5114,145.063' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-3' d='M 98.5114,145.063 L 108.138,150.621' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-4' d='M 137.745,150.621 L 147.371,145.063' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-4' d='M 147.371,145.063 L 156.997,139.506' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-5' d='M 192.072,125.942 L 201.698,120.384' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-5' d='M 201.698,120.384 L 211.324,114.826' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-5' d='M 186.282,115.912 L 195.908,110.355' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-5' d='M 195.908,110.355 L 205.534,104.797' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<text dominant-baseline="central" text-anchor="end" x='129.832' y='200.955' style='font-size:19px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#E84235' ><tspan>H</tspan><tspan style='baseline-shift:sub;font-size:14.25px;'>2</tspan><tspan>O</tspan></text>
<text dominant-baseline="central" text-anchor="end" x='168.627' y='200.665' style='font-size:19px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#E84235' ><tspan>O</tspan></text>
<text dominant-baseline="central" text-anchor="middle" x='219.447' y='200.665' style='font-size:19px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#3B4143' ><tspan>Si</tspan></text>
<text dominant-baseline="central" text-anchor="start" x='270.267' y='200.665' style='font-size:19px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#E84235' ><tspan>O</tspan></text>
<text dominant-baseline="central" text-anchor="end" x='29.733' y='104.16' style='font-size:19px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#E84235' ><tspan>O</tspan></text>
<text dominant-baseline="central" text-anchor="middle" x='72.7955' y='133.112' style='font-size:19px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#3B4143' ><tspan>Al</tspan></text>
<text dominant-baseline="central" text-anchor="middle" x='122.941' y='162.063' style='font-size:19px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#E84235' ><tspan>O</tspan></text>
<text dominant-baseline="central" text-anchor="middle" x='173.087' y='133.112' style='font-size:19px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#3B4143' ><tspan>Al</tspan></text>
<text dominant-baseline="central" text-anchor="start" x='216.15' y='104.16' style='font-size:19px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#E84235' ><tspan>O</tspan></text>
</svg>
 data:image/svg+xml;base64,<?xml version='1.0' encoding='iso-8859-1'?>
<svg version='1.1' baseProfile='full'
              xmlns='http://www.w3.org/2000/svg'
                      xmlns:rdkit='http://www.rdkit.org/xml'
                      xmlns:xlink='http://www.w3.org/1999/xlink'
                  xml:space='preserve'
width='85px' height='85px' viewBox='0 0 85 85'>
<!-- END OF HEADER -->
<rect style='opacity:1.0;fill:#FFFFFF;stroke:none' width='85' height='85' x='0' y='0'> </rect>
<path class='bond-0' d='M 47.8245,57.1755 L 53.2915,57.1755' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-0' d='M 53.2915,57.1755 L 58.7585,57.1755' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-0' d='M 47.8245,53.8943 L 53.2915,53.8943' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-0' d='M 53.2915,53.8943 L 58.7585,53.8943' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-1' d='M 64.5948,57.1755 L 70.0618,57.1755' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-1' d='M 70.0618,57.1755 L 75.5288,57.1755' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-1' d='M 64.5948,53.8943 L 70.0618,53.8943' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-1' d='M 70.0618,53.8943 L 75.5288,53.8943' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-2' d='M 7.65091,31.0869 L 12.0189,33.6088' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-2' d='M 12.0189,33.6088 L 16.387,36.1306' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-2' d='M 9.29151,28.2453 L 13.6595,30.7672' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-2' d='M 13.6595,30.7672 L 18.0275,33.289' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-3' d='M 23.0435,38.0794 L 27.4116,40.6013' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-3' d='M 27.4116,40.6013 L 31.7796,43.1232' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-4' d='M 36.8872,43.1232 L 41.2552,40.6013' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-4' d='M 41.2552,40.6013 L 45.6232,38.0794' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-5' d='M 52.2798,36.1306 L 56.6478,33.6088' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-5' d='M 56.6478,33.6088 L 61.0158,31.0869' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-5' d='M 50.6392,33.289 L 55.0072,30.7672' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-5' d='M 55.0072,30.7672 L 59.3752,28.2453' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<text dominant-baseline="central" text-anchor="end" x='36.2856' y='56.4372' style='font-size:5px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#E84235' ><tspan>H</tspan><tspan style='baseline-shift:sub;font-size:3.75px;'>2</tspan><tspan>O</tspan></text>
<text dominant-baseline="central" text-anchor="end" x='47.2776' y='56.3552' style='font-size:5px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#E84235' ><tspan>O</tspan></text>
<text dominant-baseline="central" text-anchor="middle" x='61.6766' y='56.3552' style='font-size:5px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#3B4143' ><tspan>Si</tspan></text>
<text dominant-baseline="central" text-anchor="start" x='76.0757' y='56.3552' style='font-size:5px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#E84235' ><tspan>O</tspan></text>
<text dominant-baseline="central" text-anchor="end" x='7.92435' y='29.012' style='font-size:5px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#E84235' ><tspan>O</tspan></text>
<text dominant-baseline="central" text-anchor="middle" x='20.1254' y='37.2149' style='font-size:5px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#3B4143' ><tspan>Al</tspan></text>
<text dominant-baseline="central" text-anchor="middle" x='34.3334' y='45.4179' style='font-size:5px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#E84235' ><tspan>O</tspan></text>
<text dominant-baseline="central" text-anchor="middle" x='48.5413' y='37.2149' style='font-size:5px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#3B4143' ><tspan>Al</tspan></text>
<text dominant-baseline="central" text-anchor="start" x='60.7424' y='29.012' style='font-size:5px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#E84235' ><tspan>O</tspan></text>
</svg>
 O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 239000000356 contaminants Substances 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 230000004059 degradation Effects 0.000 description 2
- 238000006731 degradation reactions Methods 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 239000011159 matrix materials Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 101710008526 parA Proteins 0.000 description 2
- 101710003567 redM Proteins 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 101710052251 res Proteins 0.000 description 2
- 101710003881 resD Proteins 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 101710037138 stbA Proteins 0.000 description 2
- 239000000126 substances Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- 230000035621 Permeability Rate Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N al2o3 Chemical compound data:image/svg+xml;base64,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 data:image/svg+xml;base64,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 [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000004566 building materials Substances 0.000 description 1
- 239000003054 catalysts Substances 0.000 description 1
- 238000010382 chemical cross-linking Methods 0.000 description 1
- 239000003431 cross linking reagents Substances 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound data:image/svg+xml;base64,<?xml version='1.0' encoding='iso-8859-1'?>
<svg version='1.1' baseProfile='full'
              xmlns='http://www.w3.org/2000/svg'
                      xmlns:rdkit='http://www.rdkit.org/xml'
                      xmlns:xlink='http://www.w3.org/1999/xlink'
                  xml:space='preserve'
width='300px' height='300px' viewBox='0 0 300 300'>
<!-- END OF HEADER -->
<rect style='opacity:1.0;fill:#FFFFFF;stroke:none' width='300' height='300' x='0' y='0'> </rect>
<path class='bond-0' d='M 96.2309,217.422 L 113.079,217.422' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-0' d='M 113.079,217.422 L 129.927,217.422' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-0' d='M 96.2309,202.974 L 113.079,202.974' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-0' d='M 113.079,202.974 L 129.927,202.974' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-1' d='M 170.073,217.422 L 186.921,217.422' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-1' d='M 186.921,217.422 L 203.769,217.422' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-1' d='M 170.073,202.974 L 186.921,202.974' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-1' d='M 186.921,202.974 L 203.769,202.974' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-2' d='M 39.7375,106.721 L 51.7467,113.654' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-2' d='M 51.7467,113.654 L 63.7559,120.588' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-2' d='M 46.9613,94.2089 L 58.9705,101.142' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-2' d='M 58.9705,101.142 L 70.9797,108.076' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-3' d='M 107.513,137.51 L 119.522,144.443' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-3' d='M 119.522,144.443 L 131.532,151.377' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-4' d='M 168.468,151.377 L 180.478,144.443' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-4' d='M 180.478,144.443 L 192.487,137.51' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-5' d='M 236.244,120.588 L 248.253,113.654' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-5' d='M 248.253,113.654 L 260.262,106.721' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-5' d='M 229.02,108.076 L 241.03,101.142' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-5' d='M 241.03,101.142 L 253.039,94.2089' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<text dominant-baseline="central" text-anchor="end" x='86.5993' y='213.81' style='font-size:24px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#E84235' ><tspan>O</tspan></text>
<text dominant-baseline="central" text-anchor="middle" x='150' y='213.81' style='font-size:24px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#3B4143' ><tspan>Si</tspan></text>
<text dominant-baseline="central" text-anchor="start" x='213.401' y='213.81' style='font-size:24px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#E84235' ><tspan>O</tspan></text>
<text dominant-baseline="central" text-anchor="end" x='33.7177' y='93.414' style='font-size:24px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#E84235' ><tspan>O</tspan></text>
<text dominant-baseline="central" text-anchor="middle" x='87.4405' y='129.533' style='font-size:24px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#3B4143' ><tspan>Al</tspan></text>
<text dominant-baseline="central" text-anchor="middle" x='150' y='165.651' style='font-size:24px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#E84235' ><tspan>O</tspan></text>
<text dominant-baseline="central" text-anchor="middle" x='212.559' y='129.533' style='font-size:24px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#3B4143' ><tspan>Al</tspan></text>
<text dominant-baseline="central" text-anchor="start" x='266.282' y='93.414' style='font-size:24px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#E84235' ><tspan>O</tspan></text>
</svg>
 data:image/svg+xml;base64,<?xml version='1.0' encoding='iso-8859-1'?>
<svg version='1.1' baseProfile='full'
              xmlns='http://www.w3.org/2000/svg'
                      xmlns:rdkit='http://www.rdkit.org/xml'
                      xmlns:xlink='http://www.w3.org/1999/xlink'
                  xml:space='preserve'
width='85px' height='85px' viewBox='0 0 85 85'>
<!-- END OF HEADER -->
<rect style='opacity:1.0;fill:#FFFFFF;stroke:none' width='85' height='85' x='0' y='0'> </rect>
<path class='bond-0' d='M 24.7187,61.1028 L 31.5391,61.1028' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-0' d='M 31.5391,61.1028 L 38.3595,61.1028' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-0' d='M 24.7187,57.0093 L 31.5391,57.0093' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-0' d='M 31.5391,57.0093 L 38.3595,57.0093' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-1' d='M 45.6405,61.1028 L 52.4609,61.1028' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-1' d='M 52.4609,61.1028 L 59.2813,61.1028' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-1' d='M 45.6405,57.0093 L 52.4609,57.0093' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-1' d='M 52.4609,57.0093 L 59.2813,57.0093' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-2' d='M 8.71224,28.5559 L 14.1616,31.702' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-2' d='M 14.1616,31.702 L 19.6109,34.8482' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-2' d='M 10.759,25.0108 L 16.2083,28.157' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-2' d='M 16.2083,28.157 L 21.6576,31.3032' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-3' d='M 27.9153,37.2794 L 33.3647,40.4256' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-3' d='M 33.3647,40.4256 L 38.814,43.5718' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-4' d='M 45.186,43.5718 L 50.6353,40.4256' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-4' d='M 50.6353,40.4256 L 56.0847,37.2794' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-5' d='M 64.3891,34.8482 L 69.8384,31.702' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-5' d='M 69.8384,31.702 L 75.2878,28.5559' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-5' d='M 62.3424,31.3032 L 67.7917,28.157' style='fill:none;fill-rule:evenodd;stroke:#3B4143;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<path class='bond-5' d='M 67.7917,28.157 L 73.241,25.0108' style='fill:none;fill-rule:evenodd;stroke:#E84235;stroke-width:2px;stroke-linecap:butt;stroke-linejoin:miter;stroke-opacity:1' />
<text dominant-baseline="central" text-anchor="end" x='24.0365' y='60.0794' style='font-size:6px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#E84235' ><tspan>O</tspan></text>
<text dominant-baseline="central" text-anchor="middle" x='42' y='60.0794' style='font-size:6px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#3B4143' ><tspan>Si</tspan></text>
<text dominant-baseline="central" text-anchor="start" x='59.9635' y='60.0794' style='font-size:6px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#E84235' ><tspan>O</tspan></text>
<text dominant-baseline="central" text-anchor="end" x='9.05336' y='25.9673' style='font-size:6px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#E84235' ><tspan>O</tspan></text>
<text dominant-baseline="central" text-anchor="middle" x='24.2748' y='36.2009' style='font-size:6px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#3B4143' ><tspan>Al</tspan></text>
<text dominant-baseline="central" text-anchor="middle" x='42' y='46.4346' style='font-size:6px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#E84235' ><tspan>O</tspan></text>
<text dominant-baseline="central" text-anchor="middle" x='59.7252' y='36.2009' style='font-size:6px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#3B4143' ><tspan>Al</tspan></text>
<text dominant-baseline="central" text-anchor="start" x='74.9466' y='25.9673' style='font-size:6px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#E84235' ><tspan>O</tspan></text>
</svg>
 O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 230000002255 enzymatic Effects 0.000 description 1
- 238000006911 enzymatic reactions Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000011521 glasses Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- 235000021190 leftovers Nutrition 0.000 description 1
- 239000007788 liquids Substances 0.000 description 1
- 239000010893 paper wastes Substances 0.000 description 1
- 229920000642 polymers Polymers 0.000 description 1
- 239000002243 precursors Substances 0.000 description 1
- 230000002335 preservative Effects 0.000 description 1
- 239000003755 preservative agents Substances 0.000 description 1
- 239000000376 reactants Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound data:image/svg+xml;base64,PD94bWwgdmVyc2lvbj0nMS4wJyBlbmNvZGluZz0naXNvLTg4NTktMSc/Pgo8c3ZnIHZlcnNpb249JzEuMScgYmFzZVByb2ZpbGU9J2Z1bGwnCiAgICAgICAgICAgICAgeG1sbnM9J2h0dHA6Ly93d3cudzMub3JnLzIwMDAvc3ZnJwogICAgICAgICAgICAgICAgICAgICAgeG1sbnM6cmRraXQ9J2h0dHA6Ly93d3cucmRraXQub3JnL3htbCcKICAgICAgICAgICAgICAgICAgICAgIHhtbG5zOnhsaW5rPSdodHRwOi8vd3d3LnczLm9yZy8xOTk5L3hsaW5rJwogICAgICAgICAgICAgICAgICB4bWw6c3BhY2U9J3ByZXNlcnZlJwp3aWR0aD0nMzAwcHgnIGhlaWdodD0nMzAwcHgnIHZpZXdCb3g9JzAgMCAzMDAgMzAwJz4KPCEtLSBFTkQgT0YgSEVBREVSIC0tPgo8cmVjdCBzdHlsZT0nb3BhY2l0eToxLjA7ZmlsbDojRkZGRkZGO3N0cm9rZTpub25lJyB3aWR0aD0nMzAwJyBoZWlnaHQ9JzMwMCcgeD0nMCcgeT0nMCc+IDwvcmVjdD4KPHBhdGggY2xhc3M9J2JvbmQtMCcgZD0nTSA2MS4xMzY2LDE2MS45MzkgTCA4OC45ODEzLDE2MS45MzknIHN0eWxlPSdmaWxsOm5vbmU7ZmlsbC1ydWxlOmV2ZW5vZGQ7c3Ryb2tlOiNFODQyMzU7c3Ryb2tlLXdpZHRoOjNweDtzdHJva2UtbGluZWNhcDpidXR0O3N0cm9rZS1saW5lam9pbjptaXRlcjtzdHJva2Utb3BhY2l0eToxJyAvPgo8cGF0aCBjbGFzcz0nYm9uZC0wJyBkPSdNIDg4Ljk4MTMsMTYxLjkzOSBMIDExNi44MjYsMTYxLjkzOScgc3R5bGU9J2ZpbGw6bm9uZTtmaWxsLXJ1bGU6ZXZlbm9kZDtzdHJva2U6IzNCNDE0MztzdHJva2Utd2lkdGg6M3B4O3N0cm9rZS1saW5lY2FwOmJ1dHQ7c3Ryb2tlLWxpbmVqb2luOm1pdGVyO3N0cm9rZS1vcGFjaXR5OjEnIC8+CjxwYXRoIGNsYXNzPSdib25kLTAnIGQ9J00gNjEuMTM2NiwxMzguMDYxIEwgODguOTgxMywxMzguMDYxJyBzdHlsZT0nZmlsbDpub25lO2ZpbGwtcnVsZTpldmVub2RkO3N0cm9rZTojRTg0MjM1O3N0cm9rZS13aWR0aDozcHg7c3Ryb2tlLWxpbmVjYXA6YnV0dDtzdHJva2UtbGluZWpvaW46bWl0ZXI7c3Ryb2tlLW9wYWNpdHk6MScgLz4KPHBhdGggY2xhc3M9J2JvbmQtMCcgZD0nTSA4OC45ODEzLDEzOC4wNjEgTCAxMTYuODI2LDEzOC4wNjEnIHN0eWxlPSdmaWxsOm5vbmU7ZmlsbC1ydWxlOmV2ZW5vZGQ7c3Ryb2tlOiMzQjQxNDM7c3Ryb2tlLXdpZHRoOjNweDtzdHJva2UtbGluZWNhcDpidXR0O3N0cm9rZS1saW5lam9pbjptaXRlcjtzdHJva2Utb3BhY2l0eToxJyAvPgo8cGF0aCBjbGFzcz0nYm9uZC0xJyBkPSdNIDE4My4xNzQsMTYxLjkzOSBMIDIxMS4wMTksMTYxLjkzOScgc3R5bGU9J2ZpbGw6bm9uZTtmaWxsLXJ1bGU6ZXZlbm9kZDtzdHJva2U6IzNCNDE0MztzdHJva2Utd2lkdGg6M3B4O3N0cm9rZS1saW5lY2FwOmJ1dHQ7c3Ryb2tlLWxpbmVqb2luOm1pdGVyO3N0cm9rZS1vcGFjaXR5OjEnIC8+CjxwYXRoIGNsYXNzPSdib25kLTEnIGQ9J00gMjExLjAxOSwxNjEuOTM5IEwgMjM4Ljg2MywxNjEuOTM5JyBzdHlsZT0nZmlsbDpub25lO2ZpbGwtcnVsZTpldmVub2RkO3N0cm9rZTojRTg0MjM1O3N0cm9rZS13aWR0aDozcHg7c3Ryb2tlLWxpbmVjYXA6YnV0dDtzdHJva2UtbGluZWpvaW46bWl0ZXI7c3Ryb2tlLW9wYWNpdHk6MScgLz4KPHBhdGggY2xhc3M9J2JvbmQtMScgZD0nTSAxODMuMTc0LDEzOC4wNjEgTCAyMTEuMDE5LDEzOC4wNjEnIHN0eWxlPSdmaWxsOm5vbmU7ZmlsbC1ydWxlOmV2ZW5vZGQ7c3Ryb2tlOiMzQjQxNDM7c3Ryb2tlLXdpZHRoOjNweDtzdHJva2UtbGluZWNhcDpidXR0O3N0cm9rZS1saW5lam9pbjptaXRlcjtzdHJva2Utb3BhY2l0eToxJyAvPgo8cGF0aCBjbGFzcz0nYm9uZC0xJyBkPSdNIDIxMS4wMTksMTM4LjA2MSBMIDIzOC44NjMsMTM4LjA2MScgc3R5bGU9J2ZpbGw6bm9uZTtmaWxsLXJ1bGU6ZXZlbm9kZDtzdHJva2U6I0U4NDIzNTtzdHJva2Utd2lkdGg6M3B4O3N0cm9rZS1saW5lY2FwOmJ1dHQ7c3Ryb2tlLWxpbmVqb2luOm1pdGVyO3N0cm9rZS1vcGFjaXR5OjEnIC8+Cjx0ZXh0IGRvbWluYW50LWJhc2VsaW5lPSJjZW50cmFsIiB0ZXh0LWFuY2hvcj0iZW5kIiB4PSc0NS4yMTg1JyB5PScxNTUuOTY5JyBzdHlsZT0nZm9udC1zaXplOjM5cHg7Zm9udC1zdHlsZTpub3JtYWw7Zm9udC13ZWlnaHQ6bm9ybWFsO2ZpbGwtb3BhY2l0eToxO3N0cm9rZTpub25lO2ZvbnQtZmFtaWx5OnNhbnMtc2VyaWY7ZmlsbDojRTg0MjM1JyA+PHRzcGFuPk88L3RzcGFuPjwvdGV4dD4KPHRleHQgZG9taW5hbnQtYmFzZWxpbmU9ImNlbnRyYWwiIHRleHQtYW5jaG9yPSJtaWRkbGUiIHg9JzE1MCcgeT0nMTU1Ljk2OScgc3R5bGU9J2ZvbnQtc2l6ZTozOXB4O2ZvbnQtc3R5bGU6bm9ybWFsO2ZvbnQtd2VpZ2h0Om5vcm1hbDtmaWxsLW9wYWNpdHk6MTtzdHJva2U6bm9uZTtmb250LWZhbWlseTpzYW5zLXNlcmlmO2ZpbGw6IzNCNDE0MycgPjx0c3Bhbj5TaTwvdHNwYW4+PC90ZXh0Pgo8dGV4dCBkb21pbmFudC1iYXNlbGluZT0iY2VudHJhbCIgdGV4dC1hbmNob3I9InN0YXJ0IiB4PScyNTQuNzgyJyB5PScxNTUuOTY5JyBzdHlsZT0nZm9udC1zaXplOjM5cHg7Zm9udC1zdHlsZTpub3JtYWw7Zm9udC13ZWlnaHQ6bm9ybWFsO2ZpbGwtb3BhY2l0eToxO3N0cm9rZTpub25lO2ZvbnQtZmFtaWx5OnNhbnMtc2VyaWY7ZmlsbDojRTg0MjM1JyA+PHRzcGFuPk88L3RzcGFuPjwvdGV4dD4KPC9zdmc+Cg== data:image/svg+xml;base64,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 O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000007787 solids Substances 0.000 description 1
- 239000007858 starting materials Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000000576 supplementary Effects 0.000 description 1
- 239000000725 suspensions Substances 0.000 description 1
- HNBDQABBWNOTRU-UHFFFAOYSA-N thalline Chemical compound data:image/svg+xml;base64,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 data:image/svg+xml;base64,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 C1=CC=[Tl]C=C1 HNBDQABBWNOTRU-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Abstract
本发明提供一种用于污染水源修复的固定化酶复合材料及其制备方法，其原料配方重量配比为：无机载体60～70％，粉煤灰8～20％、生物酶制剂3～15％、氧化钙膨胀剂0.5～0.7％、硅酸盐水泥8～20％、添加剂0.5～2％；制备步骤为；按照各原料组分的重量配比称取各组分，将无机载体材料破碎，按照重量配比加入各组分；混合搅拌物料，静置硝化；压制成型，干燥即得固定化酶复合材料。本发明生产方法简单，造价低，效果好，该材料可广泛应用于污废水处理工程，是一种经济实用，前景广阔的新型环保材料，具有综合交叉学科集成创新的特点，对环保领域水处理工程技术带来崭新的突破。
Description
用于污染水源修复的固定化酶复合材料及其制备方法
技术领域
[0001] 本发明属于环境、生物、材料工程交叉技术相结合的领域，属于用免烧结技术制备
固定化酶复合材料的方法，具体涉及一种用于污染水源修复的固定化酶复合材料产品及其 制备方法。
背景技术
[0002] 固定化酶作为一种生物催化剂应用于污水处理，已经有相当长的历史，长期以来， 由于受酶的品种与价格的制约，酶在环保工程实践上的研究与应用一直处于滞后的状况。 目前，酶制剂应用于环境工程水处理方面已经出现的主要有三种形式。其一，在污废水中直 接投加酶制剂。其二，用高分子滤料装置在池体反应器中，让酶吸附，促进菌酶生长进行酶 促反应。其三，将酶或游离酶与载体结合，通过吸附、交联、共价结合、包埋等方法，将酶固定 在载体上。这些方法都存在着很大的缺陷。上述的第一种方法由于直接添加酶制剂，污水 处理成本过大，很难得到实际应用（目前国外的酶制剂厂家进入中国环保市场主要用于这 方法），用户难以接受，从而影响到酶与酶技术在环保领域的推广（当然还有其它方面的因 素的影响）。其第二种方法，虽然通过滤料，使酶一定数量上得到了吸附，物理性质上得到了 一些改变，但酶的使用周期短。（如酶促生物滤料，难以从根本上解决酶使用成本过高的问
题）。第三种方法将酶（或游离酶）与载体相结合，通过目前常用的吸附、交联、共价结合、 包埋等一种或两种以上结合方法来制备固定化酶，也存在于诸多的缺陷。这些方法大多需
要对载体进行表面化学处理以后，进行物理结合法或化学交联剂交联的方式，生产成本高， 固定化方法复杂，酶的损失大，酶活力较低，酶的使用周期短。 一直未能适用于水环境处理 工程的实践应用，且这些方法仍处于实验性阶段，目前仍未见过工程应用方面成功的报道。
发明内容
[0003] 本发明目的是针对上述问题，提供一种用于污染水源修复的固定化酶复合材料及 其制备方法，该方法制备产品的生产工艺简单，材料易得，可利用工业下脚材料与建筑垃圾 制得本产品，成本低，酶活稳定，使用寿命长，可再生循环使用。
[0004] 本发明固定化酶复合材料的原料各组分的重量配比为：无机载体60〜70%，粉煤 灰10〜20%、生物酶制剂3〜15%、氧化*丐膨胀剂0. 5〜0. 7%、硅酸盐水泥10〜20%、添 加剂0. 5〜2% ;所述的生物酶制剂是漆酶、纤维素酶、酯酶、蛋白酶、木聚糖酶或过氧化物 酶中的一种或几种；所述的添加剂为松香皂、辅助添加剂或结合剂中的一种或几种；其制 备方法为：将各原料组分按重量配比称重计量、物料分选、混合搅拌、静置硝化、挤压成型、 筛分检测、干燥或自然风干即得成品。 [0005] 本发明具有如下显著优点：
[0006] 1)本产品置于固定床式生物反应器时，不需经任何化学处理，床层阻力小，几何比 表面积大，固定化酶复合材料中的酶分子与微孔中的产生的菌体能共存并增殖，而不易脱 落，不仅适用于小规模的生活污水，有机工业废水的处理，而且适用于大面积的江河污染水源的修复与再生。
[0007] 2)固定化酶复合材料中选用的各酶种，经过提纯，复配处理，酶活性高、效果好。
[0008] 3)利用建筑垃圾及粉煤灰等下脚料，作为载体的原材料，原料易得，价格便宜，变
废为宝，与酶的结合固定化效果好，酶活稳定，使本发明制得的产品具有质量稳定、产量高，
成本低、工业化生产便利等优点，并提供了一种崭新的固定化酶的方法。
[0009] 4)整个制备工艺在常温下进行，有效地解决了酶制剂对温度，pH条件耐受力差的
问题，大大稳定了制作工艺。
[0010] 5)创造性地将建筑材料工业生产上应用的免烧结技术与免烧砖机作为本发明中 成型与干燥的工艺，解决了酶的固定化及过程受温度干扰的问题，且生产工艺稳定，工业化 生产效率高，单次成型周期为30〜60秒。
[0011] 6)本发明制备的材料，可装置在酶反应器中根据处理对象及污染物的特性，进行 单级或者多级处理，工艺简单灵活，运行可靠安全。
[0012] 7)本发明生产制备的固定化酶复合材料（材料与产品）酶活性保存期长，不易吸 潮变质，便于使用和贮藏。
附图说明
[0013] 图1为平流式净水反应池示意图，其中，1为固定化酶复合材料；2为污水，3为净 化水。
[0014] 图2为升流式净水反应池示意图，其中，1为固定化酶复合材料；2为排水处，3为 排气处，4为污泥区，5为循环水，6为污泥，7为污泥悬浮区，8为污泥区，9为进水处。 [0015] 图3为混流式净水反应池示意图，其中，1为固定化酶复合材料；2为进水处，3为 出水处。
具体实施方式
[0016] 按照各原料组分的重量配比称取各组分；酶制剂的选用：根据处理对象污染物的 特性，精选酶制剂进行提纯和复配；将无机载体材料破碎，破碎的粒径在3〜5mm范围内，以 增加免烧结强度，按照重量配比加入各组分：无机载体60〜70%、粉煤灰10〜20%、生物 酶制剂3〜15%、氧化钙膨胀剂0. 5〜0. 7%、硅酸盐水泥10〜20%、添加剂0. 5〜2% ; 混合搅拌物料，搅拌速度在10〜20转/分钟，搅拌时间在30〜60分钟；静置硝化；在常温 状态下，将混合后的半成品物料静置1〜2个小时，其含水率控制在20〜25%;通过免烧砖 机或者预先制作的成型摸具将物料压制成型，干燥或者自然风干，即得固定化酶复合材料。 [0017] 其中，无机载体是陶瓷粒、建筑垃圾、浮石、多孔玻璃、活性炭、酸性白土、高岭石、 氧化铝、硅藻土或膨润土中的一种或几种。 [0018] 生物酶制剂为液状、粉状或颗粒状。 [0019] 结合剂为膨润土或木质素。
[0020] 免烧砖机，其工作原理与机型采用国内厂家生产的机型，根据生产规模的大小配 套砖机或采用自制木结构或钢架等成型模具。
[0021] 用该方法制备的固定化酶复合材料由检测得知：该种固定化酶复合材料具有一 定几何形状并含有50 %以上的正态分布微孔，青灰色或淡黄色，无毒无害无气味，酶活力> 2000u/mg，抗压强度在1. 5〜1. 8Mpa，浸泡在水中不易崩解，具有空隙率在10〜30%、 透水性0. 5〜1. 5mm/S， pH值显中性或弱酸性，物理性质稳定，崩解度在标况下浸泡在水中 10〜30年不脱落、不粉状。
[0022] 该种固定化酶复合材料用于污水修复中的固定化床式，根据反应器的特性制成不 同规格与形状，其横截面与固定化床式形成相应的几何型形状，微孔结构与外型尺寸根据 处理对象的水质与水量等特性以及酶制剂的生物特性来设计与制备。 [0023] 实施例1
[0024] 按上述具体实施方式进行，固定化酶复合材料的原料配方重量为：建筑垃圾（粒 径3〜5mm) 70 % 、粉煤灰20 % 、松香皂0. 5 % 、氧化钙膨胀剂0. 5 % ，酶液9 % (酶活力 2000u/ml)，加适量水，混合搅拌物料，搅拌速度在10〜20转/分钟，搅拌时间在30〜60 分钟；静置硝化；再混合拌搅均匀，使泥料的含水率为22%，常温下静置1〜2个小时，送入 免烧砖机压制成型，自然风干，制得该产品。机型为：P-HST30，免烧砖机。 [0025] 将上述固定化酶复合材料用于印染废水处理时，首先将这种固定化酶复合材料 (外径为36 X 24 X 12cm的块状物体材料）填充于池体生物反应器内，采用平流式反应器，废 水在反应器里停留时间为30分钟，采用单级处理得到的各项污染物降解结果如下： [0026] 印染废水：进水水质：C0Dcrl500mg/L， B0D5300mg/L，色度500，水温50 。C ， SS 300mg/L， pH值8. 2。出水水质：CODcr500mg/L， BOD5100mg/L，色度50， SS 100mg/L， pH值 7. 2。
[0027] 实施例2
[0028] 按上述具体实施方式进行，固定化酶复合材料的原料配方重量为：陶瓷粒（粒径 3〜5mm)60X、硅酸盐水泥10%、粉煤灰20%、松香皂0. 5%、氧化钙膨胀剂0. 5%、酶制剂 (固体状）9 % (酶活力2000u/mg)，加适量水，混合搅拌物料，搅拌速度在10〜20转/分 钟，搅拌时间在30〜60分钟；静置硝化；再混合拌搅均匀，使泥料含水率25% ，测得泥料pH 值为6. 5，常温下静置2〜3小时。选用型号为GQC-302型的免烧砖机压制成型，经温度为 40 °C干燥机干燥，制得该产品。
[0029] 将上述固定化酶复合材料充填于升流式的生物反应器内，（反应器前段辅助物化 处理）处理造纸废水。反应器里停留时间为60分钟，采用单级处理得到的各项污染物降解 结果如下：
[0(K30] 造纸废水（洗桨水）：进水水质：CODcrl500mg/L，BOD5300mg/L，SS 1000mg/L，pH值 8.2。处理后出水水质：C0Dcr400mg/L， BOD5100mg/L， SS 100mg/L， pH值7. 0。 [0031] 实施例3
[0032] 按上述具体实施方式进行，固定化酶复合材料的原料配方重量为：浮石65%、硅 酸盐水泥18 % 、粉煤灰8 % 、松香皂0. 4 % 、氧化钙膨胀剂0. 4 % 、酶制剂8. 2 % (酶活力 2000u/ml)，经混合搅拌均匀配料后加水适量，调整泥料含水率在26 % ，测得物体浸泡水的 pH值为6. 0，搅拌速度在10〜20转/分钟，搅拌时间在30〜60分钟；静置硝化；再混合 拌搅均匀，常温下静置3个小时后，送入免烧砖机，压制成型，即制得外观形状为方形的固 定化酶复合材料。该材料，色呈弱灰色，无气味，间接测得酶活力^ 18000u/kg，抗压强度 6mpa，空隙率在20% ，透水率0. 9mm/S.
[0033] 将上述的固定化酶复合材料，填充于混流式生物反应器中，用于生活污水处理，得出的处理的效果：生活污水：进水水质：C0Dcr400mg/L， BOD5250mg/L， SS 300mg/L， NH3_N 50mg/L，pH值6. 5。处理后的水质如下；CODcrlOOmg/L， BOD560mg/L， SS 70mg/L，NH3_N 15mg/ L，pH值6. 9。
[0034] 本发明的固定化酶复合材料，主要用于污染水源的修复与再生，它通过固定床式 的生物反应器装置对污废水进行处理，该固定化酶复合材料具有床层阻力小，几何比表面 积大，载体可再生处理，生产方法简单，造价低，效果好等特点.该材料可广泛应用于污废 水处理工程，是一种经济实用，前景广阔的新型环保材料，具有综合交叉学科集成创新的特 点，对环保领域水处理工程技术带来崭新的突破。
Claims (4)
- 一种用于污染水源修复的固定化酶复合材料，其特征在于：固定化酶复合材料的原料各组分的重量配比为：无机载体60～70％，粉煤灰10～20％、生物酶制剂3～15％、氧化钙膨胀剂0.5～0.7％、硅酸盐水泥10～20％、添加剂0.5～2％；所述的生物酶制剂是漆酶、纤维素酶、酯酶、蛋白酶、木聚糖酶或过氧化物酶中的一种或几种；所述的添加剂为松香皂，所述的无机载体是陶瓷粒、建筑垃圾或浮石；所述固定化酶复合材料的制备方法的步骤为：a)按照各原料组分的重量配比称取各组分；b)酶制剂的选用：根据处理对象污染物的特性，精选酶制剂进行提纯和复配；c)将无机载体材料破碎，破碎的粒径在3～5mm范围内，以增加免烧结强度，按照重量配比加入各组分：无机载体60～70％、粉煤灰10～20％、生物酶制剂3～15％、氧化钙膨胀剂0.5～0.7％、硅酸盐水泥10～20％、添加剂0.5～2％；d)混合搅拌物料，搅拌速度在10～20转/分钟，搅拌时间在30～60分钟；e)静置硝化，在常温状态下，将混合后的半成品物料静置1～2个小时，其含水率控制在20～25％；f)通过免烧砖机或者预先制作的成型模具将物料压制成型，干燥或者自然风干，即得固定化酶复合材料。
- 2. 根据权利要求1所述的用于污染水源修复的固定化酶复合材料，其特征在于：所述的生物酶制剂为液状、粉状或颗粒状。
- 3. 根据权利要求1所述的用于污水修复的固定化酶复合材料，其特征在于：所述的 固定化酶复合材料由检测得知：该种固定化酶复合材料具有一定几何形状并含有50%以上的正态分布微孔，青灰色或淡黄色，无毒无害无气味，酶活力> 2000u/mg，抗压强度在 1. 5〜1. 8Mpa，浸泡在水中不易崩解，具有空隙率10〜30%、透水性0. 5〜1. 5mm/S，pH值 显中性或弱酸性，物理性质稳定，崩解度为在标况下浸泡在水中10〜30年不脱落、不粉状。
- 4. 根据权利要求1所述的用于污水修复的固定化酶复合材料，其特征在于：所述的固 定化酶复合材料的用途是：用于污水修复中的固定化床式，根据反应器的特性制成不同规 格与形状，其横截面与固定化床式形成相应的几何型形状，微孔结构与外型尺寸根据处理 对象的水质与水量特性以及酶制剂的生物特性来设计与制备。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200610135342A CN1986789B (zh) | 2006-12-20 | 2006-12-20 | 用于污染水源修复的固定化酶复合材料及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200610135342A CN1986789B (zh) | 2006-12-20 | 2006-12-20 | 用于污染水源修复的固定化酶复合材料及其制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1986789A CN1986789A (zh) | 2007-06-27 |
| CN1986789B true CN1986789B (zh) | 2010-05-12 |
Family
ID=38183733
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200610135342A CN1986789B (zh) | 2006-12-20 | 2006-12-20 | 用于污染水源修复的固定化酶复合材料及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1986789B (zh) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102583880B (zh) * | 2012-02-08 | 2013-07-24 | 广州市环境保护工程设计院有限公司 | 一种抗生素制药废水的处理工艺 |
| CN103882001A (zh) * | 2012-12-21 | 2014-06-25 | 中国科学院大连化学物理研究所 | 琼脂包埋法固定化污泥中产氢微生物的改性方法 |
| CN103146675B (zh) * | 2013-03-06 | 2014-07-30 | 昆明理工大学 | 以赤石脂为载体的固定化脂肪酶的制备方法 |
| CN103834621A (zh) * | 2013-12-30 | 2014-06-04 | 贵州大学 | 一种生产漆酶的方法 |
| CN103951035B (zh) * | 2014-05-17 | 2015-09-23 | 李品 | 一种水域治理用颗粒材料及其制备和使用方法 |
| CN105668804A (zh) * | 2014-11-20 | 2016-06-15 | 海南大学 | 一种海绵状高效印染废水生物处理材料及其制备工艺 |
| CN105622028B (zh) * | 2015-12-25 | 2018-02-23 | 中国石油大学(华东) | 一种有机—无机复合多孔污水处理材料及其制备方法 |
| CN105858787B (zh) * | 2016-04-27 | 2019-06-07 | 中国科学院南京地理与湖泊研究所 | 一种除磷填料X-Phos基质及其制备方法 |
| CN106396128B (zh) * | 2016-09-23 | 2019-07-26 | 华南师范大学 | 一种用于黑臭河涌水体富氧生物修复的催化剂及其制备方法 |
| CN107012138B (zh) * | 2017-05-03 | 2020-04-10 | 福州晨翔环保工程有限公司 | 硅/碳基复合固定化酶环保材料及其制备方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1778912A (zh) * | 2004-11-23 | 2006-05-31 | 孙祥章 | 在多孔陶瓷上固定化环保用酶的方法 |
-
2006
- 2006-12-20 CN CN200610135342A patent/CN1986789B/zh not_active IP Right Cessation
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1778912A (zh) * | 2004-11-23 | 2006-05-31 | 孙祥章 | 在多孔陶瓷上固定化环保用酶的方法 |
Non-Patent Citations (3)
| Title |
|---|
| JP特开平11-292654A 1999.10.26 |
| 罗开昆，彭红，龚跃法.漆酶的固定化及其在废水处理中的应用.工业水处理25 5.2005,25(5),14-17. |
| 罗开昆,彭红,龚跃法.漆酶的固定化及其在废水处理中的应用.工业水处理25 5.2005,25(5),14-17. * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1986789A (zh) | 2007-06-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Ahmad et al. | Sustainable management of water treatment sludge through 3 ‘R’concept | |
| CN101746941B (zh) | 一种城市污水厂脱水污泥生物干化处理方法 | |
| CN1150975C (zh) | 一种用于废水处理球型多孔轻质陶粒及其制造方法 | |
| CN103387371B (zh) | 一种城市污泥固化/稳定化的复合固化剂及其应用 | |
| Wu et al. | Preparation of ceramic filler from reusing sewage sludge and application in biological aerated filter for soy protein secondary wastewater treatment | |
| JP2018513096A (ja) | 防塵および建築材製造のための組成物および方法 | |
| Han et al. | Effect of sludge-fly ash ceramic particles (SFCP) on synthetic wastewater treatment in an A/O combined biological aerated filter | |
| CN101597131B (zh) | 一种垃圾渗滤液的处理方法及处理装置 | |
| EP0430232B1 (en) | Ash and paper treatment | |
| CN100488903C (zh) | 城市污水厂污泥的固化处理方法 | |
| US3232865A (en) | Method of purifying waste water | |
| Kumar et al. | Recovery of value added products from rice husk ash to explore an economic way for recycle and reuse of agricultural waste | |
| CN1297508C (zh) | 利用污泥与煤矸石生产建筑材料的方法 | |
| CN101585714B (zh) | 一种完全利用生物污泥和淤泥制作陶粒的方法 | |
| CN102206073B (zh) | 一种淤泥免烧砖及其生产方法 | |
| CN104193127B (zh) | 一种废水生物处理后剩余污泥的处理方法 | |
| CN104828928B (zh) | 一种脱氮除磷生物滤池滤料的制备方法 | |
| CN1922117A (zh) | 基于污泥及污泥废弃物的建筑材料 | |
| KR100759833B1 (ko) | 생물학적 하수 및 폐수 처리를 위한 활성 물질, 상기 활성물질을 내재한 미생물 담체 및 그 제조 방법 | |
| CN101935195B (zh) | 一种具有碱缓释功能的多孔除磷陶粒及其制备方法 | |
| KR101273444B1 (ko) | 미생물과 제올라이트를 이용한 수질 정화용 시멘트 벽돌 및 이의 제조방법 | |
| CN103880253B (zh) | 一种垃圾渗滤液的深度处理方法及芬顿反应塔 | |
| CN101148346A (zh) | 一种用城市污水厂污泥制备陶粒的方法 | |
| WO2016058437A1 (zh) | 一种污泥深度脱水的处理方法 | |
| CN101306849B (zh) | 一种改性粉煤灰沸石用于造纸废水处理的方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| C06 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| C10 | Entry into substantive examination | ||
| GR01 | Patent grant | ||
| C14 | Grant of patent or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20160307 Address after: 210038 Jiangsu Province, Nanjing economic and Technological Development Zone No. 12 Chong Xing Ke Lu base room 213 Patentee after: Jiangsu morning environmental Polytron Technologies Inc Address before: 350002, Fujian Province, 611 Industrial Road, Fuzhou province hi tech Innovation Park, the main building 6 Patentee before: Fuzhou Chenxiang Environmental Protection Engineering Co., Ltd. Effective date of registration: 20160307 Address after: 210038 Jiangsu Province, Nanjing economic and Technological Development Zone No. 12 Chong Xing Ke Lu base room 213 Patentee after: Jiangsu morning environmental Polytron Technologies Inc Address before: 350002, Fujian Province, 611 Industrial Road, Fuzhou province hi tech Innovation Park, the main building 6 Patentee before: Fuzhou Chenxiang Environmental Protection Engineering Co., Ltd. |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20100512 Termination date: 20181220 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |