CN1908211A - Manufacture method of high-strength powder metallurgy bevel gear and copper seeping agent for the same - Google Patents
Manufacture method of high-strength powder metallurgy bevel gear and copper seeping agent for the same Download PDFInfo
- Publication number
- CN1908211A CN1908211A CN 200610041163 CN200610041163A CN1908211A CN 1908211 A CN1908211 A CN 1908211A CN 200610041163 CN200610041163 CN 200610041163 CN 200610041163 A CN200610041163 A CN 200610041163A CN 1908211 A CN1908211 A CN 1908211A
- Authority
- CN
- China
- Prior art keywords
- powder
- bevel gear
- powder metallurgy
- copper
- sintering
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Powder Metallurgy (AREA)
Abstract
the invention discloses a preparing method of high-strength powder metallurgical bevel gear and cupric cemented agent, which comprises the following steps: allocating through ferric powder; stirring evenly; moulding in the specific model on the powder metallurgical machine; sintering to obtain the high-strength bevel gear. the cupric cemented agent is composed of 3-5% carbonyl ferric powder, 0.7-1% Ni, 3-5% Zn and Cu, which doesn't reduce precision of bevel gear.
Description
One, technical field
The present invention relates to a kind of powdered metal parts manufacturing process, especially relate to a kind of manufacture method of high-strength powder metallurgy bevel gear and be used for the copper seeping agent of this method.
Two, background technology
Conical gear is one of vital part in the light-duty machinery wheel casing, influences complete machine transmission efficiency and work-ing life, to its intensity and accuracy requirement height.Original general employing of conical gear forged pressure/pendulum compression technology production, and technology and equipment are complicated, and material use efficiency is low, and production cost is high.Powder metallurgical technique is widely used in the part manufacturing owing to its technical advantage.For reducing manufacturing cost, domestic manufacturer begins to adopt powder metallurgy process to produce conical gear.Institute's " high precision powder metallurgy gear " project is forged in Tianjin mechanical investigations designing institute casting in 1991, comprise that powder metallurgy makes special-shaped cylindrical gear, conical pinion etc., adopt metal-powder to add other alloy materials, repressed, sintering, shaping, form its density 6.4g/cm through a small amount of machining and surface treatment again
3～6.84g/cm
3, sintering strength 250～350MPa, 8 grades of precision.The application for a patent for invention (application number 200410024924) that name is called " manufacture method of high-strength powder metallurgy bevel gear " has disclosed a kind of conical gear manufacture method, with iron molybdenum prealloy powder is original washing powder, add auxiliary materials such as nickel powder, Graphite Powder 99 and lubricant again, make product density 7.21g/cm through batch mixing, compacting, sintering, quenching step
3The conical gear that the ordinary powder metallurgical technology is produced, finished product density is low, and especially tooth portion density is low causes sintering warpage, causes the accuracy of gear low, and homogeneity of product and interchangeability are poor, are not suitable for producing in batches; And product strength is low, and flank of tooth smooth finish is poor.In powder metallurgical technique, adopt melting infiltration sintering technology, infiltrate in sintered part or the pressed compact hole, density, intensity, elongation, hardness and the impelling strength of powdered metal parts are greatly improved with the metal or alloy fusing back that fusing point is lower.But on the manufacture method of conical gear, Shang Weiyou adopts the report of melting infiltration sintering technology; And iron-based powder metallurgy parts can adopt copper or copper alloy as the infiltration material usually, but the infiltration material generally can leave residue or pit at product surface, influences the precision of conical gear.
The production technology of high-strength powder metallurgy bevel gear is monopolized by companies such as external large-scale powder metallurgy company of minority and Taiwan Bao Laide, and these companies only provide product, not its manufacture method of public publish.Though China's powder metallurgy industry has had development faster by unremitting effort, but aggregate level is compared with international most advanced level and is still had big gap, particularly on the production technology of high-density, high precision, high-strength powder metallurgical part, be restricted, severe service components can't be produced in batches, can only depend on import mostly.
High-strength powder metallurgy bevel gear is mainly used in the power tool, and the quick growth of power tool demand brings the huge market opportunity to high-strength powder metallurgy bevel gear.The import parts price is high, has raised product cost, causes main computer boxes price height, lacks the market competitiveness.And the conical gear that machining process and ordinary powder metallurgical technology are produced, because the influence of product strength and precision can't be mated host performance and the requirement on the life-span.Domestic powder metallurgy industry presses for the production technology of independent development high-strength powder metallurgy bevel gear, realizes the batch process of high-strength powder metallurgy bevel gear, and the substitute products of the import parts of super quality and competitive price are provided.
Three, summary of the invention
The manufacture method that the purpose of this invention is to provide a kind of high-strength powder metallurgy bevel gear under the prerequisite that keeps the product precision, overcomes that ordinary powder metallurgical method finished product density is low, the shortcoming of intensity difference, improves the density and the intensity of product; The non-slag copper seeping agent that uses in a kind of powder metallurgical technique is provided simultaneously, solves and to ooze the copper sintering and leave the defective of residue or pit, realize that no slag oozes the copper sintering at product surface.
The inventive method can realize the industrialized mass production of powder metallurgy bevel gear, and product has high-density, high precision, high-intensity characteristics, and performance reaches external like product advanced level.
The invention discloses a kind of manufacture method of high-strength powder metallurgy bevel gear, briefly, with iron powder through the batching, mix after, press forming in the particular manufacturing craft on powder metallurgy press, ooze the copper sintering through sintering oven, carry out aftertreatment more as requested, make the high strength conical gear.
The technical solution used in the present invention is as follows:
A kind of manufacture method of high-strength powder metallurgy bevel gear, the employing iron powder is a raw material, comprise batching, mix, pressed compact shaping, sintering, post-processing step, it is characterized in that adopting non-slag copper seeping agent to ooze the copper sintering, the weight percent of this copper seeping agent consists of carbonyl iron dust 3～5%, Ni 0.7～1%, and Zn 3～5%, and all the other are Cu.
For realizing the present invention, described iron powder can adopt reduced iron powder, atomized iron powder or the pre-alloyed powder etc. of the existing various standard and the trade mark, require to add alloy element copper, nickel, molybdenum etc. according to part material, carry out proportioning as requested, and add auxiliary materials such as graphite, lubricant.In order to reach requirements such as product strength height, precision height and good stability, more excellent scheme is that to select water-atomized iron powder for use be original washing powder, add ultrafine powder that contains alloying elements such as Cu, Ni, Mo and supper-tiny artificial graphite powder and the lubricant that grinds through gas, segregation-free mixes when carrying out microalloying, to guarantee good composition uniformity and alloying effect.Such as the water-atomized iron powder of selecting the MPIF FD0205 of MPIF material prescription for use, with weight percent be respectively the alloying element of Cu1.5～2%, Ni 1.7～2%, Mo 0.5% and auxiliary material carbon 0.6～0.7%, little wax powder 0.3% mixes with water-atomized iron powder, the superfine graphite powder of carbon wherein for grinding through gas, add in the V-type mixer uniform mixing 15 minutes.This iron powder prescription suppression performance is good, oozes copper on this basis, and it is stable that product has sintered dimensions, intensity height, characteristics such as wear-resistant.
Press forming in batching, the particular manufacturing craft of mixed raw material powder on powder metallurgy press, powder becomes mechanical snap by loose combination, and pressed density is at 6.4g/cm
3～7.0g/cm
3
The present invention adopts and oozes the copper sintering process in order to obtain high-density, high-intensity conical gear.Behind the sintering, powdered metal parts is converted into melts combine by mechanical snap to pressed compact in sintering oven.Sintering is one of the most basic operation of powder metallurgy, to powdered metal parts final physics and mechanical property decisive role.In sintering process, the alloying action between each composition also takes place except that the metallurgical binding that takes place between the powder particle, iron powder pressed compact its intensity and elongation behind oversintering improve significantly.Adopt melting infiltration sintering technology in the powder metallurgical technique, promptly infiltrate in sintered part or the pressed compact hole, density, intensity, elongation, hardness and the impelling strength of powdered metal parts are greatly improved with the lower metal or alloy fusing back of fusing point.
Adopt in the powder metallurgy and ooze process for copper, must make powder metallurgy infiltration material and base material isothermal at high temperature, when isothermal temperature was higher than the fusing point of copper seeping agent, copper seeping agent began to melt and penetrate in the hole of matrix.The existing copper method that oozes adopts ordinary copper or copper alloy as oozing copper product, and after oozing the copper sintering, product surface can leave copper ashes or pit inevitably.The copper ashes that product surface is left or the processing of pit can increase the complicacy of technology, and even more serious is the precision that can influence conical gear.
Manufacture method according to powder metallurgy bevel gear of the present invention adopts a kind of new Cu-Fe-Ni-Zn copper seeping agent, and its weight percent consists of Fe 3～5%, and Ni 0.7～1%, and Zn 3～5%, and all the other are Cu; Iron wherein is carbonyl iron dust.Described Cu-Fe-Ni-Zn non-slag copper seeping agent, good with the wettability of body material, and the Fe in the discord matrix etc. dissolves each other, behind sintering, product surface does not have residual any copper ashes or pit, copper seeping agent all infiltrates in the space of pressed compact matrix, in the density and intensity that improve product, can not reduce the precision of conical gear.The carbonyl iron dust of Tian Jiaing wherein, be when guaranteeing green sintering axially and the radial variations rate approach zero, the tooth portion distortion during with the product sintering drops to minimum, keeps the profile accuracy of conical gear finished product to greatest extent.
Sintering step at first carries out degreasing in 420 ℃～780 ℃ scopes, carry out high temperature then in 1125 ℃～1130 ℃ scopes and ooze the copper sintering.For guaranteeing good infiltration effect, can prolong sintering time.Sintering can carry out under atmosphere such as nitrogen or cracked ammonium.
The conical gear that makes behind the sintering can carry out aftertreatment as required, such as thermal treatment or surface hardening processing etc., to reach the requirement of intensity and hardness, promptly makes the high-strength powder metallurgy bevel gear finished product after the oil immersion.
The invention also discloses a kind of copper seeping agent that is used for the powder metallurgy bevel gear manufacture method, the weight percent of described copper seeping agent consists of carbonyl iron dust 3～5%, and Ni 0.7～1%, and Zn 3～5%, and all the other are Cu.
According to the high-strength powder metallurgy bevel gear of manufacturing of the present invention, adopt efficient no slag to ooze the copper sintering process, it is big to have density, intensity height, the characteristics that profile accuracy is high, product density 〉=7.7g/cm
3, cross-breaking strength is greater than 1200MPa, and 6 grades of precision, performance reach external like product advanced level.Break through existing powder metallurgy and produced the restriction of conical gear, filled up the blank of domestic high-strength powder metallurgy bevel gear production technology.The contrast of its product performance and home and overseas like product sees Table one.
Table one product of the present invention and home and overseas like product performance comparison
| Performance index | Currently available products | External like product | Product of the present invention |
| Density g/cm 3 | 6.95 | 7.7 | 7.70～7.85 |
| Hardness HRB | 85 | 96 | 95～98 |
| Ballistic work J | 12 | 12 | 19～20 |
| Tensile strength MPa | 350 | 540 | 564～580 |
| Cross-breaking strength MPa | 980 | 1250 | 1285～1310 |
| Elongation % | 0.9 | 1.1 | 1.2～1.8 |
| Profile accuracy | 9 grades | 6 grades | 6 grades |
According to non-slag copper seeping agent of the present invention, in powder metallurgical technique, ooze the copper sintering after, product surface does not have the defective of residue or pit, realizes that no slag oozes the copper sintering.
Realize industrialized mass production according to the present invention, one time compacting sintering obtains high-strength powder metallurgy bevel gear, imported product outside fully can subrogate country, be widely used in the fields such as light-duty machinery wheel casing such as power tool, can greatly reduce cost, enhance product performance and work-ing life, have good economic benefit and market outlook.
Describe the present invention below in conjunction with embodiment.Scope of the present invention is not exceeded with embodiment, but is limited by the scope of claim.
Four, embodiment
Embodiment one
Embodiment one makes high-strength powder metallurgy bevel gear by method of the present invention.
Select water-atomized iron powder for use, and prepare burden in following ratio adding alloying element and auxiliary material: by weight percentage, Cu 1.6%, Ni 1.8, Mo 0.5, C 0.7%, little wax powder 0.3, all the other are water-atomized iron powder.Above-mentioned raw materials packed into mix stirring in the V-type mixer, churning time is 15 minutes.After the mixing, press forming in the conical gear particular manufacturing craft on powder metallurgy press, pressed density is at 6.8g/cm
3～6.9g/cm
3
Pressed compact is put into sintering oven, adopt the Cu-Fe-Ni-Zn non-slag copper seeping agent to carry out high temperature and ooze the copper sintering, copper seeping agent contains (weight percent) carbonyl iron dust 3.5%, and Ni 0.9%, and Zn 4.5%, and all the other are Cu.Sintering carries out degreasing earlier in 420 ℃～780 ℃ scopes, carry out high temperature then in 1125 ℃～1130 ℃ scopes and ooze the copper sintering, and sintering time is 50 minutes.
Promptly make finished product after the conical gear oil immersion behind the sintering.
Embodiment two to four is for realizing the specific examples of non-slag copper seeping agent.
Embodiment two
The alloy of copper seeping agent for making as following weight percent, wherein carbonyl iron dust 3%, nickel 0.7%, zinc 3%, all the other are copper.
Embodiment three
The alloy of copper seeping agent for making as following weight percent, wherein carbonyl iron dust 5%, nickel 1%, zinc 5%, all the other are copper.
Embodiment four
The alloy of copper seeping agent for making as following weight percent, wherein carbonyl iron dust 4%, nickel 0.8, zinc 4%, all the other are copper.
Claims (7)
1. the manufacture method of a high-strength powder metallurgy bevel gear, the employing iron powder is a raw material, comprise batching, mix, pressed compact shaping, sintering, post-processing step, it is characterized in that adopting copper seeping agent to ooze the copper sintering, the weight percent of this copper seeping agent consists of carbonyl iron dust 3～5%, Ni 0.7～1%, and Zn 3～5%, and all the other are Cu.
2. the manufacture method of high-strength powder metallurgy bevel gear according to claim 1 is characterized in that described iron powder is a water-atomized iron powder, adds powder and the Graphite Powder 99 and the lubricant of Cu, Ni and/or Mo element.
3. the manufacture method of high-strength powder metallurgy bevel gear according to claim 2, it is characterized in that in the described water-atomized iron powder that the interpolation weight percent is metallic element and 0.6～0.7% Graphite Powder 99 and the 0.3% little wax powder of 1.5～2%Cu, 1.7～2%Ni and 0.5%Mo.
4. the manufacture method of high-strength powder metallurgy bevel gear according to claim 1, it is characterized in that pressed compact is shaped after, pressed density is at 6.4g/cm
3～7.0g/cm
3
5. the manufacture method of high-strength powder metallurgy bevel gear according to claim 1 is characterized in that sintering step at first carries out degreasing in 420 ℃～780 ℃ scopes, carry out high temperature sintering then in 1125 ℃～1130 ℃ scopes.
6. the manufacture method of high-strength powder metallurgy bevel gear according to claim 5 is characterized in that sintering step carries out under nitrogen or cracked ammonium atmosphere.
7. copper seeping agent of implementing the described method of claim 1, the weight percent of described copper seeping agent consists of carbonyl iron dust 3～5%, and Ni 0.7～1%, and Zn 3～5%, and all the other are Cu.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200610041163XA CN100441711C (en) | 2006-08-09 | 2006-08-09 | Manufacture method of high-strength powder metallurgy bevel gear and copper seeping agent for the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200610041163XA CN100441711C (en) | 2006-08-09 | 2006-08-09 | Manufacture method of high-strength powder metallurgy bevel gear and copper seeping agent for the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1908211A true CN1908211A (en) | 2007-02-07 |
| CN100441711C CN100441711C (en) | 2008-12-10 |
Family
ID=37699440
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB200610041163XA Expired - Fee Related CN100441711C (en) | 2006-08-09 | 2006-08-09 | Manufacture method of high-strength powder metallurgy bevel gear and copper seeping agent for the same |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100441711C (en) |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101269416B (en) * | 2008-05-09 | 2010-06-02 | 徐信国 | Powder metallurgy member for piston supporting base of power cylinder and method for manufacturing same |
| CN102672186A (en) * | 2012-06-07 | 2012-09-19 | 太仓市锦立得粉末冶金有限公司 | Manufacturing process for gear ring in powder metallurgy |
| CN102672179A (en) * | 2012-06-07 | 2012-09-19 | 太仓市锦立得粉末冶金有限公司 | Production technique of powder metallurgy product |
| CN102744400A (en) * | 2012-06-21 | 2012-10-24 | 芜湖禾丰离合器有限公司 | Automobile transmission gear based on copper aluminum steel sintering by powder metallurgy technology and manufacture method of automobile transmission gear |
| CN102756122A (en) * | 2012-06-21 | 2012-10-31 | 芜湖禾丰离合器有限公司 | Powder-metallurgy automobile transmission gear and manufacturing method thereof |
| CN102777568A (en) * | 2012-08-02 | 2012-11-14 | 韶关市富洋粉末冶金有限公司 | High-performance powder metallurgy cam and transmission gear and producing method thereof |
| CN102909373A (en) * | 2012-09-15 | 2013-02-06 | 安徽省怀远县尚冠模具科技有限公司 | Method for preparing mould punching ejector rod |
| CN103071799A (en) * | 2013-01-22 | 2013-05-01 | 山东信义粉末冶金有限公司 | Method for producing surface-densified powder metallurgic gear |
| CN104439251A (en) * | 2014-10-24 | 2015-03-25 | 苏州莱特复合材料有限公司 | Copper infiltration agent for powder metallurgy |
| CN105478782A (en) * | 2015-11-25 | 2016-04-13 | 芜湖市鸿坤汽车零部件有限公司 | Preparation method of automobile frame crossbeam through powder metallurgy |
| CN105478778A (en) * | 2015-11-25 | 2016-04-13 | 芜湖市鸿坤汽车零部件有限公司 | Method for preparing automobile anti-collision beam bypowder metallurgy process |
| CN105555440A (en) * | 2013-09-26 | 2016-05-04 | 杰富意钢铁株式会社 | Alloy steel powder for powder metallurgy and method of producing iron-based sintered body |
| CN105945289A (en) * | 2016-06-03 | 2016-09-21 | 江苏保捷锻压有限公司 | Powder forging technology for main speed reduction gear for automobile manual transmission |
| US10265766B2 (en) | 2013-06-07 | 2019-04-23 | Jfe Steel Corporation | Alloy steel powder for powder metallurgy and method of producing iron-based sintered body |
| CN109868422A (en) * | 2019-03-14 | 2019-06-11 | 有研粉末新材料（北京）有限公司 | A kind of powder metallurgy firm gear and preparation method thereof |
| CN110923502A (en) * | 2019-12-20 | 2020-03-27 | 佛山科学技术学院 | Wear-resistant corrosion-resistant copper-based alloy and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85100669A (en) * | 1985-04-01 | 1986-07-16 | 冶金部钢铁研究总院 | The reparation technology of superfine iron carbonyl powder |
| CN1704189A (en) * | 2004-06-04 | 2005-12-07 | 上海汽车股份有限公司 | Manufacturing method of high-strength sintered umbrella gear |
-
2006
- 2006-08-09 CN CNB200610041163XA patent/CN100441711C/en not_active Expired - Fee Related
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101269416B (en) * | 2008-05-09 | 2010-06-02 | 徐信国 | Powder metallurgy member for piston supporting base of power cylinder and method for manufacturing same |
| CN102672186A (en) * | 2012-06-07 | 2012-09-19 | 太仓市锦立得粉末冶金有限公司 | Manufacturing process for gear ring in powder metallurgy |
| CN102672179A (en) * | 2012-06-07 | 2012-09-19 | 太仓市锦立得粉末冶金有限公司 | Production technique of powder metallurgy product |
| CN102756122B (en) * | 2012-06-21 | 2014-04-02 | 芜湖禾丰离合器有限公司 | Powder-metallurgy automobile transmission gear and manufacturing method thereof |
| CN102744400A (en) * | 2012-06-21 | 2012-10-24 | 芜湖禾丰离合器有限公司 | Automobile transmission gear based on copper aluminum steel sintering by powder metallurgy technology and manufacture method of automobile transmission gear |
| CN102744400B (en) * | 2012-06-21 | 2014-04-30 | 芜湖禾丰离合器有限公司 | Automobile transmission gear based on copper aluminum steel sintering by powder metallurgy technology and manufacture method of automobile transmission gear |
| CN102756122A (en) * | 2012-06-21 | 2012-10-31 | 芜湖禾丰离合器有限公司 | Powder-metallurgy automobile transmission gear and manufacturing method thereof |
| CN102777568A (en) * | 2012-08-02 | 2012-11-14 | 韶关市富洋粉末冶金有限公司 | High-performance powder metallurgy cam and transmission gear and producing method thereof |
| CN102777568B (en) * | 2012-08-02 | 2015-05-13 | 韶关市富洋粉末冶金有限公司 | High-performance valve ventilation transmission gear and producing method thereof |
| CN102909373A (en) * | 2012-09-15 | 2013-02-06 | 安徽省怀远县尚冠模具科技有限公司 | Method for preparing mould punching ejector rod |
| CN103071799A (en) * | 2013-01-22 | 2013-05-01 | 山东信义粉末冶金有限公司 | Method for producing surface-densified powder metallurgic gear |
| US10265766B2 (en) | 2013-06-07 | 2019-04-23 | Jfe Steel Corporation | Alloy steel powder for powder metallurgy and method of producing iron-based sintered body |
| CN105555440A (en) * | 2013-09-26 | 2016-05-04 | 杰富意钢铁株式会社 | Alloy steel powder for powder metallurgy and method of producing iron-based sintered body |
| CN104439251A (en) * | 2014-10-24 | 2015-03-25 | 苏州莱特复合材料有限公司 | Copper infiltration agent for powder metallurgy |
| CN105478778A (en) * | 2015-11-25 | 2016-04-13 | 芜湖市鸿坤汽车零部件有限公司 | Method for preparing automobile anti-collision beam bypowder metallurgy process |
| CN105478782A (en) * | 2015-11-25 | 2016-04-13 | 芜湖市鸿坤汽车零部件有限公司 | Preparation method of automobile frame crossbeam through powder metallurgy |
| CN105945289A (en) * | 2016-06-03 | 2016-09-21 | 江苏保捷锻压有限公司 | Powder forging technology for main speed reduction gear for automobile manual transmission |
| CN109868422A (en) * | 2019-03-14 | 2019-06-11 | 有研粉末新材料（北京）有限公司 | A kind of powder metallurgy firm gear and preparation method thereof |
| CN110923502A (en) * | 2019-12-20 | 2020-03-27 | 佛山科学技术学院 | Wear-resistant corrosion-resistant copper-based alloy and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100441711C (en) | 2008-12-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100441711C (en) | Manufacture method of high-strength powder metallurgy bevel gear and copper seeping agent for the same | |
| CN104028765B (en) | Production method of powder metallurgy part with mounting through hole | |
| CN100462165C (en) | Manufacture method and die for powder metallurgy inside spin ratchet wheel | |
| CN101850423B (en) | High strength self-lubricating iron-copper powder composite material and preparation method thereof | |
| CN101905411B (en) | Method for manufacturing coupler for distributor of automobile engine | |
| CN103981436A (en) | Metal powder injection molded high-strength martensite aged steel and preparation method thereof | |
| CN105950983A (en) | Production method of powder metallurgy gear | |
| CN104368816A (en) | Method for manufacturing iron-based powder metallurgy components | |
| CN102921941A (en) | Piston rod of damper and preparation method of piston rod | |
| CN103480850A (en) | Powder metallurgy preparing method for heavy truck gearbox synchronizer gear hub | |
| CN102773482B (en) | Method for manufacturing butterfly valve rod by powder metallurgy | |
| CN105200322A (en) | High-strength automobile part powder metallurgy component and preparation method thereof | |
| CN105665716A (en) | Powder metallurgy spiral bevel gear and preparation method and application thereof | |
| CN102029386B (en) | High-hardness powder metallurgy low-alloy steel | |
| CN101590524A (en) | The material prescription of high-strength powder metallurgy valve guide pipe | |
| US9005519B2 (en) | Powder metallurgical material, production method and application thereof | |
| CN1021206C (en) | Technique for iron-based and iron-copper bi-metal products | |
| CN104372234A (en) | High-wear-resistance titanium-copper nickel-silicon alloy composite material and preparation method thereof | |
| CN105886879A (en) | Shaft sleeve material and preparation method | |
| CN103602898A (en) | Novel powder metallurgy automobile-transmission gearshift-mechanism base and preparation method thereof | |
| CN106270489A (en) | The material prescription of a kind of high-strength powder metallurgical part and processing technology | |
| JP6528899B2 (en) | Method of manufacturing mixed powder and sintered body for powder metallurgy | |
| CN111074166A (en) | Molybdenum-containing high-strength powder metallurgy composite material and preparation method thereof | |
| CN110508820B (en) | High-permeability copper infiltrated powder and manufacturing method thereof | |
| CN102672176A (en) | High-abrasion-resistance powder metallurgical spherical hinge for excavating machine and manufacture method of spherical hinge |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20081210 Termination date: 20100809 |