CN1837414A - Addictive for tin-electroplating solution of tin methane sulphonate series - Google Patents
Addictive for tin-electroplating solution of tin methane sulphonate series Download PDFInfo
- Publication number
- CN1837414A CN1837414A CN 200510033691 CN200510033691A CN1837414A CN 1837414 A CN1837414 A CN 1837414A CN 200510033691 CN200510033691 CN 200510033691 CN 200510033691 A CN200510033691 A CN 200510033691A CN 1837414 A CN1837414 A CN 1837414A
- Authority
- CN
- China
- Prior art keywords
- additive
- tin
- active agent
- surface active
- nonionic surface
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000009713 electroplating Methods 0.000 title claims abstract description 20
- AICMYQIGFPHNCY-UHFFFAOYSA-J methanesulfonate;tin(4+) Chemical class [Sn+4].CS([O-])(=O)=O.CS([O-])(=O)=O.CS([O-])(=O)=O.CS([O-])(=O)=O AICMYQIGFPHNCY-UHFFFAOYSA-J 0.000 title claims description 12
- 239000000654 additive Substances 0.000 claims abstract description 68
- 230000000996 additive effect Effects 0.000 claims abstract description 66
- -1 tin methanesulfonic sulfate series Chemical class 0.000 claims abstract description 19
- 150000001875 compounds Chemical class 0.000 claims abstract description 14
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 20
- 239000004094 surface-active agent Substances 0.000 claims description 19
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 12
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical group OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 10
- 229960003237 betaine Drugs 0.000 claims description 10
- DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical group CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 claims description 7
- 239000002280 amphoteric surfactant Substances 0.000 claims description 6
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 claims description 6
- 229960003742 phenol Drugs 0.000 claims description 5
- DFPAKSUCGFBDDF-UHFFFAOYSA-N Nicotinamide Chemical compound NC(=O)C1=CC=CN=C1 DFPAKSUCGFBDDF-UHFFFAOYSA-N 0.000 claims description 4
- 229960003966 nicotinamide Drugs 0.000 claims description 4
- 235000005152 nicotinamide Nutrition 0.000 claims description 4
- 239000011570 nicotinamide Substances 0.000 claims description 4
- ZYWVUGXNGJVBAL-UHFFFAOYSA-N propan-1-amine;sulfuric acid Chemical compound CCCN.OS(O)(=O)=O ZYWVUGXNGJVBAL-UHFFFAOYSA-N 0.000 claims description 4
- AIHQPHWZLSEGNR-UHFFFAOYSA-N C(CCCCCCCCCCC)CN(C(C(=O)O)(C)C)C Chemical compound C(CCCCCCCCCCC)CN(C(C(=O)O)(C)C)C AIHQPHWZLSEGNR-UHFFFAOYSA-N 0.000 claims description 3
- KGWDUNBJIMUFAP-KVVVOXFISA-N Ethanolamine Oleate Chemical compound NCCO.CCCCCCCC\C=C/CCCCCCCC(O)=O KGWDUNBJIMUFAP-KVVVOXFISA-N 0.000 claims description 3
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 3
- 150000002170 ethers Chemical class 0.000 claims description 3
- 229960004418 trolamine Drugs 0.000 claims description 3
- WUGQZFFCHPXWKQ-UHFFFAOYSA-N Propanolamine Chemical compound NCCCO WUGQZFFCHPXWKQ-UHFFFAOYSA-N 0.000 claims description 2
- 150000001413 amino acids Chemical class 0.000 claims description 2
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical class C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 claims 1
- 229940043237 diethanolamine Drugs 0.000 claims 1
- 238000007747 plating Methods 0.000 abstract description 23
- 239000011248 coating agent Substances 0.000 abstract description 20
- 238000000576 coating method Methods 0.000 abstract description 20
- 230000000694 effects Effects 0.000 abstract description 14
- 239000002563 ionic surfactant Substances 0.000 abstract 1
- 239000002736 nonionic surfactant Substances 0.000 abstract 1
- 239000003053 toxin Substances 0.000 abstract 1
- 231100000765 toxin Toxicity 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 28
- 230000035882 stress Effects 0.000 description 18
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 13
- 239000000243 solution Substances 0.000 description 10
- 238000002474 experimental method Methods 0.000 description 9
- 239000007788 liquid Substances 0.000 description 8
- 239000003792 electrolyte Substances 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000013543 active substance Substances 0.000 description 3
- 238000005282 brightening Methods 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000000866 electrolytic etching Methods 0.000 description 2
- 230000008676 import Effects 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 241001347978 Major minor Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- MIKQOJIIXOGNEO-UHFFFAOYSA-N [Sn].N(CCO)CCO Chemical compound [Sn].N(CCO)CCO MIKQOJIIXOGNEO-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical group CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 1
- 230000006355 external stress Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- HPOIYBGFFZRZKK-UHFFFAOYSA-N lead;methanesulfonic acid Chemical compound [Pb].CS(O)(=O)=O HPOIYBGFFZRZKK-UHFFFAOYSA-N 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- PGGZKNHTKRUCJS-UHFFFAOYSA-N methanesulfonic acid;tin Chemical compound [Sn].CS(O)(=O)=O PGGZKNHTKRUCJS-UHFFFAOYSA-N 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 231100000241 scar Toxicity 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000005476 soldering Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Abstract
Description
The test sequence number | Nonionic surface active agent (g/L) | Nitrogenous compound (g/L) | Amphoterics (g/L) | Thickness (um) |
01 | 6 | 8 | 10 | 3.72 |
02 | 15 | 45 | 10 | 2.96 |
03 | 25 | 25 | 50 | 3.47 |
04 | 35 | 16 | 50 | 3.91 |
05 | 25 | 35 | 10 | 3.24 |
06 | 45 | 35 | 30 | 4.54 |
07 | 35 | 35 | 20 | 4.37 |
08 | 45 | 45 | 40 | 4.68 |
Additive | Can allow strength of current scope (A) | Can allow current density range (A/dm 2) | Electroplating time (min) | Current efficiency (%) | Sedimentation velocity (um/h) |
Import | 0-42 | 0-1.2 | 90 | 40-50 | 10 |
Domestic | 0-55 | 0-1.2 | 60 | 40-50 | 10 |
The present invention | 0-70 | 0-2 | 30 | 70-80 | 20 |
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN200510033691A CN100595342C (en) | 2005-03-24 | 2005-03-24 | Addictive for tin-electroplating solution of tin methane sulphonate series |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN200510033691A CN100595342C (en) | 2005-03-24 | 2005-03-24 | Addictive for tin-electroplating solution of tin methane sulphonate series |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1837414A true CN1837414A (en) | 2006-09-27 |
CN100595342C CN100595342C (en) | 2010-03-24 |
Family
ID=37014919
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN200510033691A Active CN100595342C (en) | 2005-03-24 | 2005-03-24 | Addictive for tin-electroplating solution of tin methane sulphonate series |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN100595342C (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101922026A (en) * | 2010-08-18 | 2010-12-22 | 济南德锡科技有限公司 | Methanesulfonic acid-based matte pure tin electroplating solution and additive thereof |
CN102660760A (en) * | 2010-10-22 | 2012-09-12 | 罗门哈斯电子材料有限公司 | Tin plating solution |
CN102953096A (en) * | 2011-08-17 | 2013-03-06 | 上海申和热磁电子有限公司 | Additive for weak acid methanesulfonic acid dark tin solution |
CN104593835A (en) * | 2015-02-04 | 2015-05-06 | 广东羚光新材料股份有限公司 | Neutral tin plating solution used in electroplating terminal electrodes of chip component |
CN105316711A (en) * | 2014-07-31 | 2016-02-10 | Apct株式会社 | Tin-based electroplating solution for solder bumps including perfluoroalkyl surfactant |
CN110106535A (en) * | 2019-06-10 | 2019-08-09 | 广东比格莱科技有限公司 | A kind of tin plating additive of neutrality |
CN113430592A (en) * | 2021-06-30 | 2021-09-24 | 广东德浩化工新材料有限公司 | Neutral tin plating stabilizer and preparation method thereof |
-
2005
- 2005-03-24 CN CN200510033691A patent/CN100595342C/en active Active
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101922026A (en) * | 2010-08-18 | 2010-12-22 | 济南德锡科技有限公司 | Methanesulfonic acid-based matte pure tin electroplating solution and additive thereof |
CN101922026B (en) * | 2010-08-18 | 2012-02-01 | 济南德锡科技有限公司 | Methanesulfonic acid-based matte pure tin electroplating solution and additive thereof |
CN102660760A (en) * | 2010-10-22 | 2012-09-12 | 罗门哈斯电子材料有限公司 | Tin plating solution |
CN102660760B (en) * | 2010-10-22 | 2015-09-23 | 罗门哈斯电子材料有限公司 | Tin plating electrolyte |
CN102953096A (en) * | 2011-08-17 | 2013-03-06 | 上海申和热磁电子有限公司 | Additive for weak acid methanesulfonic acid dark tin solution |
CN105316711A (en) * | 2014-07-31 | 2016-02-10 | Apct株式会社 | Tin-based electroplating solution for solder bumps including perfluoroalkyl surfactant |
CN105316711B (en) * | 2014-07-31 | 2018-01-05 | Apct株式会社 | Solder bump comprising perfluoralkyl surfactant tin alloy electric plating liquid |
CN104593835A (en) * | 2015-02-04 | 2015-05-06 | 广东羚光新材料股份有限公司 | Neutral tin plating solution used in electroplating terminal electrodes of chip component |
CN110106535A (en) * | 2019-06-10 | 2019-08-09 | 广东比格莱科技有限公司 | A kind of tin plating additive of neutrality |
CN113430592A (en) * | 2021-06-30 | 2021-09-24 | 广东德浩化工新材料有限公司 | Neutral tin plating stabilizer and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
CN100595342C (en) | 2010-03-24 |
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Legal Events
Date | Code | Title | Description |
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
ASS | Succession or assignment of patent right |
Owner name: GUANGDONG FENGHUA HIGH SCIENCE & TECHNOLOGY GROUP Free format text: FORMER OWNER: GUANGDONG FENGHUA HIGH SCIENCE + TECHNOLOGY GROUP CO., LTD. Effective date: 20070105 |
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C41 | Transfer of patent application or patent right or utility model | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20070105 Address after: 18 Fenghua Electronics City, Fenghua Road, Guangdong, Zhaoqing 526020, China Applicant after: Guangdong Fenghua High New Science & Technology Group Co., Ltd. Co-applicant after: Guangdong Fenghua Advanced Technology (Holding) Co., Ltd. Address before: 18 Fenghua Electronics City, Fenghua Road, Guangdong, Zhaoqing 526020, China Applicant before: Guangdong Fenghua High New Science & Technology Group Co., Ltd. |
|
ASS | Succession or assignment of patent right |
Owner name: ZHAOQING CITY LINGGUANG PHOTOELECTRON CHEMICAL MA Free format text: FORMER OWNER: GUANGDONG FENGHUA HIGH SCIENCE + TECHNOLOGY GROUP CO., LTD.; APPLICANT Effective date: 20080919 |
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C41 | Transfer of patent application or patent right or utility model | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20080919 Address after: Taihe Road, Zhaoqing, Guangdong Province, China: 526020 Applicant after: Zhaoqing Lingguang Electronic Chemical Material Technology Co., Ltd. Address before: Fenghua City, Fenghua Road, Fenghua City, Guangdong Province, Zhaoqing 18, China: 526020 Applicant before: Guangdong Fenghua High Tech Group Co., Ltd. Co-applicant before: Guangdong Fenghua Advanced Technology (Holding) Co., Ltd. |
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C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C56 | Change in the name or address of the patentee |
Owner name: GUANGDONG LINGGUANG NEW MATERIAL CO., LTD. Free format text: FORMER NAME: ZHAOQING LINGGUANG ELECTRONIC CHEMICAL MATERIAL TECHNOLOGY CO., LTD. |
|
CP03 | Change of name, title or address |
Address after: 526020 three Rong port industrial processing zone, Duanzhou District, Guangdong, Zhaoqing Patentee after: Guangdong Lingguang New Material Co., Ltd. Address before: 526020 Taihe Road, Guangdong, Zhaoqing Patentee before: Zhaoqing Lingguang Electronic Chemical Material Technology Co., Ltd. |
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TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20210616 Address after: 526108 Room 301, 3 / F, building 1, Lehua Road, phase II, Jindu industrial agglomeration base, Jindu Town, Gaoyao District, Zhaoqing City, Guangdong Province Patentee after: Zhaoqing Lingguang new material technology development Co.,Ltd. Address before: 526020 sanronggang industrial processing zone, Duanzhou District, Zhaoqing City, Guangdong Province Patentee before: GUANGDONG LINGGUANG NEW MATERIAL Co.,Ltd. |