CN1727310A - Composite plate of microcrystalline glass and porcelain, and production process - Google Patents
Composite plate of microcrystalline glass and porcelain, and production process Download PDFInfo
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- CN1727310A CN1727310A CN 200410050915 CN200410050915A CN1727310A CN 1727310 A CN1727310 A CN 1727310A CN 200410050915 CN200410050915 CN 200410050915 CN 200410050915 A CN200410050915 A CN 200410050915A CN 1727310 A CN1727310 A CN 1727310A
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- ceramic
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- devitrified glass
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Abstract
A composite microcrystalline glass-ceramic plate with high-reflectivity spots on its surface and high decorative effect is composed of a ceramic substrate and a surficial glass layer containing the microcrystalline glass particles with one or more colors and monosilicon particles (0.05-10 Wt%). Its preparing process includes such steps as conventionally preparing ceramic substrate blank, applying the surficial particles mixture to its surface, calcining in roller-way kiln, cutting edges and polishing.
Description
Technical field
The present invention relates to a kind of Microcrystal Glass Glazed Ceramic Composite Plate And Preparation Method.
Background technology
Improvement along with growth in the living standard and living environment, the human consumer more and more comes high to the requirement and the aesthetic conceptions of building and ornament materials, particularly to novel, high-grade and to have the demand of " humane, science and technology, environmental protection " hommization finishing material more and more, promoted the fast development of architectural pottery and building and ornament materials industry effectively, particularly various decoration techniques, technology and gimmick have been applied in the decoration of ceramic, have promoted the development and application of architectural pottery again.Especially various, the thousand strange different expressions metalluster effects of occurring in nature have caused architectural pottery circle personage's extensive concern and consumers in general's favor with its noble quality, novelty, gorgeous characteristic, and insider's exploratory development always expectation can form flash metal luster spot effect in devitrified glass porcelain composite surface.
Summary of the invention
The devitrified glass porcelain composition board that the purpose of this invention is to provide a kind of surface particles shape flash metal luster spot.
Another order of the present invention provides a kind of production technique of devitrified glass porcelain composition board of surface particles shape flash metal luster spot
The object of the present invention is achieved like this, it is made up of bottom and surface layer, the ceramic matrix that bottom is formed for the ceramic tile proportioning, the silicon single crystal particle that is mixed with in by one or two or more kinds color microcrystalline glass particle surface layer, silicon single crystal particulate usage quantity account for (weight percent) 0.05-10% of gross weight.
Silicon single crystal particulate preferred amount ranges of the present invention is (weight percent) 0.1%-0.5%.
(weight percent) 0.2% that silicon single crystal particulate optimum quantum of utilization of the present invention is.
Another object of the present invention is achieved in that its production craft step is as follows:
1), the preparation of bottom: bottom is and does not burn the ceramic tile base substrate, or biscuit ware adobe body, or glaze spraying agglomerating ceramic brick or porcelain brick are standby;
2), 2-60 order silicon single crystal particle and the single look of 2-60 order or two kinds of above devitrified glass particles of color are surface layer by the proportioning uniform mixing;
3), the surface layer that mixes is evenly distributed on the bottom;
4), adopt roller kiln to burn till by ceramic sintering process;
5), cut edge polishing.
The present invention is through experimental study, and devitrified glass particle blended silicon single crystal that filter out and surface layer is used for porcelain first and makes ornamental raw materials.
The present invention has sneaked into silicon single crystal in above-mentioned capstock after, the devitrified glass porcelain composite surface that adopts production technique of the present invention to make has the flash of light speckle granule of metalluster, under light, produce the high light reflectivity spot, has extraordinary decorative effect, for the human consumer provides a kind of luxurious decoration devitrified glass porcelain composition board, be more suitable for beautifying the luxurious decoration of household and large public building.
Embodiment
Embodiment 1
The preparation of ceramic adobe powder: by proportioning weighing (weight percent) black mud 16%, mixed soil 10%, in high hypothermia grait 45%, stone flour 29%, add talcum powder 2%, water 33%, the goal abrading-ball is worn into mud, 250 mesh screen residue 0.5-2.5% are spray dried to white base substrate powder after deironing;
White base substrate powder is through the moulding of SITI3205 swaging machine, through 120 ℃ of temperature, after 2 hours dryings, makes and do not burn the ceramic tile base substrate and directly use;
Select for use qualified silicon single crystal fragmentation to be processed as the 20-30 order, get silicon single crystal particle (weight percent) 0.2% and mix with 8-2 purpose white micro-crystals glass frit particle (weight percent) 99.8%; Adopt material distributing machine of dry method evenly to be layered on the unburned brick base substrate, the sticking edible methyl of the height of spray 250 gram concentration 0.5%, in 1210 ℃ of once-firings, the compound ceramic sheet of white micro-crystals glass surface forms silver gray granular metal flash effect after product polishing, the deburring.
Embodiment 2
The preparation of ceramic adobe powder: by proportioning weighing (weight percent) black mud 16%, mixed soil 10%, in high hypothermia grait 45%, stone flour 29%, add talcum powder 2%, water 33%, the goal abrading-ball is worn into mud, 250 mesh screen residue 0.5-2.5% are spray dried to white base substrate powder after deironing;
White base substrate powder is through the moulding of SITI3205 swaging machine, through 120 ℃ of temperature, after 2 hours dryings, makes and do not burn the ceramic tile base substrate and directly use;
Select for use qualified silicon single crystal fragmentation to be processed as the 30-60 order, get silicon single crystal particle (weight percent) 0.05% and mix with 30-60 purpose white micro-crystals glass frit particle (weight percent) 99.95%; Adopt material distributing machine of dry method evenly to be layered on the unburned brick base substrate, the sticking edible methyl of the height of spray 250 gram concentration (weight percent) 0.5%, in 1210 ℃ of once-firings, the compound ceramic sheet of white micro-crystals glass surface forms silver gray granular metal flash effect after product polishing, the deburring.
Embodiment 3
The preparation of ceramic adobe powder: by proportioning weighing (weight percent) black mud 16%, mixed soil 10%, in high hypothermia grait 45%, stone flour 29%, add talcum powder 2%, water 33%, the goal abrading-ball is worn into mud, 250 mesh screen residue 0.5-2.5% are spray dried to white base substrate powder after deironing;
White base substrate powder is through the moulding of SITI3205 swaging machine, through 120 ℃ of temperature, after 2 hours dryings, makes and do not burn the ceramic tile base substrate and directly use;
Select for use qualified silicon single crystal fragmentation to be processed as the 2-12 order, get silicon single crystal particle (weight percent) 10% and mix with 8-2 purpose white micro-crystals glass frit particle (weight percent) 90%; Adopt material distributing machine of dry method evenly to be layered on the unburned brick base substrate, the sticking edible methyl of the height of spray 250 gram concentration 0.5%, in 1210 ℃ of once-firings, the compound ceramic sheet of white micro-crystals glass surface forms silver gray granular metal flash effect after product polishing, the deburring.
Embodiment 4
The preparation of ceramic adobe powder: by proportioning weighing (weight percent) black mud 16%, mixed soil 10%, in high hypothermia grait 45%, stone flour 29%, add talcum powder 2%, water 33%, the goal abrading-ball is worn into mud, 250 mesh screen residue 0.5-2.5% are spray dried to white base substrate powder after deironing;
White base substrate powder is through the moulding of SITI3205 swaging machine, through 120 ℃ of temperature, after 2 hours dryings, makes and do not burn the ceramic tile base substrate and directly use;
Select for use qualified silicon single crystal fragmentation to be processed as the 20-30 order, get silicon single crystal particle (weight percent) 0.1% and mix with 20-40 purpose white micro-crystals glass frit particle (weight percent) 99.9%; Adopt material distributing machine of dry method evenly to be layered on the unburned brick base substrate, the sticking edible methyl of the height of spray 250 gram concentration 0.5%, in 1210 ℃ of once-firings, the compound ceramic sheet of white micro-crystals glass surface forms silver gray granular metal flash effect after product polishing, the deburring.
Embodiment 5
The preparation of ceramic adobe powder: by proportioning weighing (weight percent) black mud 16%, mixed soil 10%, in high hypothermia grait 45%, stone flour 29%, add talcum powder 2%, water 33%, the goal abrading-ball is worn into mud, 250 mesh screen residue 0.5-2.5% are spray dried to white base substrate powder after deironing;
White base substrate powder is through the moulding of SITI3205 swaging machine, and through 120 ℃ of temperature, after 2 hours dryings, making not, the sintering briquette body directly uses;
Select for use qualified silicon single crystal fragmentation to be processed as the 20-30 order, get silicon single crystal particle (weight percent) 1% and mix with 8-2 purpose white micro-crystals glass frit particle (weight percent) 99%; Adopt material distributing machine of dry method evenly to be layered on the unburned brick base substrate, the sticking edible methyl of the height of spray 250 gram concentration 0.5%, in 1210 ℃ of once-firings, the compound ceramic sheet of white micro-crystals glass surface forms silver gray granular metal flash effect after product polishing, the deburring.
Embodiment 6
The preparation of ceramic adobe powder: by proportioning weighing (weight percent) black mud 20%, mixed soil 6%, in high hypothermia grait 55%, stone flour 19%, add talcum powder 4%, water 33%, the goal abrading-ball is worn into mud, 250 mesh screen residue 0.5-2.5% are spray dried to white base substrate powder after deironing;
White base substrate powder is through the moulding of SITI5200 swaging machine, through 100 ℃ of temperature, and 1 hour dry back 150 meters roller kiln, 1000 ℃ are burnt till, and make the biscuiting base substrate and use;
The light grey glass ceramics frit particle of 10-30 purpose (weight percent) 98% mixes with 2-12 order silicon single crystal particle (weight percent) 2%, adopt material distributing machine of dry method to be layered on the plain adobe body of unglazed, the sticking edible methyl of the height of spray 300 gram concentration 0.5%, 1150 ℃ of twice firings in roller kiln, the product polishing, the compound ceramic sheet of grey devitrified glass surface forms silver gray granular metal flash effect after the deburring.
Embodiment 7
The preparation of ceramic adobe powder: by proportioning weighing (weight percent) black mud 20%, mixed soil 10%, in high hypothermia grait 40%, stone flour 30%, add talcum powder 3%, 510B colorant 1% and pr-yellow material 3%, water 33%, the goal abrading-ball is worn into mud, and 250 mesh screen residue 0.5-2.5% are spraying drying yellowly base substrate powder after deironing;
Yellow base substrate powder through 100 ℃ of temperature, after 1 hour drying, is sprayed the thick ceramic glaze of 0.5mm through the moulding of SACMI4600 swaging machine, advances 150 meters roller kiln, and 1210 ℃ are burnt till, and makes water-intake rate and is lower than 0.5% ceramic body use;
White micro-crystals glass frit and yellow glass ceramics frit and grey glass ceramics frit are pressed 60: 10: 30 mixed, three kinds of color microcrystalline glass frits of blended (weight percent) 99.5% and 8-20 order silicon single crystal particle (weight percent) 0.5% are mixed, adopt the dry method material distributing machine for the first time behind cloth 5mm on the above base substrate, process printing machine just black toner dry method is imprinted on the material of institute's cloth, pass through the above compound of the dry method material distributing machine second substandard cloth 4mm again, the sticking edible methyl of the height of spray 400 gram concentration (weight percent) 0.5%, under 1120 ℃ of temperature in roller way kiln twice firing, the product polishing, the compound ceramic sheet of black glass ceramic surface forms silver gray granular metal flash effect after the deburring.
Claims (8)
1, a kind of devitrified glass porcelain composition board, it is made up of bottom and surface layer, the ceramic matrix that bottom is formed for the ceramic tile proportioning, it is characterized in that: the silicon single crystal particle that is mixed with in by one or two or more kinds color crystallite frit particle surface layer, silicon single crystal particulate usage quantity accounts for the 0.05%-10% of gross weight.
2, devitrified glass porcelain composition board according to claim 1, it is characterized in that: the weight percent of described silicon single crystal particle usage quantity is 0.1%-0.5%.
3, devitrified glass porcelain composition board according to claim 1, it is characterized in that: the weight percent of described silicon single crystal particle usage quantity is 0.2%
4, devitrified glass porcelain composition board according to claim 1, it is characterized in that: described silicon single crystal silicon grain is the 2-60 order; One or two or more kinds color crystallite frit particle is the 2-60 order.
5, according to the production technique of claim 1 or 2 or 3 or 4 described devitrified glass porcelain composition boards, it is characterized in that:
1), bottom promptly do not burn the ceramic tile base substrate, or biscuit ware adobe body, or the ceramic brick of spray bristol glaze or the preparation of porcelain brick;
2), 2-60 order silicon single crystal and the single look of 2-60 order or two kinds of above devitrified glass particles of color are mixed into surface layer;
3), the surface layer that mixes is evenly distributed on the bottom;
4), adopt roller kiln to burn till by ceramic sintering process;
5), cut edge polishing.
6, devitrified glass porcelain composition board according to claim 1, it is characterized in that: bottom does not promptly burn the ceramic tile base substrate, or biscuiting polishing porcelain brick base substrate, or spray bristol glaze agglomerating ceramic brick, or the proportioning raw materials of ceramic brick is (weight percent): black mud 15-20%, mixed soil 5-10%, in high hypothermia grait 30-60%, stone flour 5-30%, add talcum powder 0-8%, one or two or more kinds ceramic pigment 1-10%, water 25-40%.
7, the production technique of devitrified glass porcelain composition board according to claim 6, it is characterized in that: bottom does not promptly burn the ceramic tile base substrate, or biscuit ware adobe body, or the preparation method of spray bristol glaze agglomerating porcelain brick or porcelain brick: 1), by proportioning get raw material black mud, mixed soil, in high hypothermia grait, stone flour, add talcum powder, one or two or more kinds ceramic pigment, water, ball milling and become mud, 250 mesh screen residues (weight percent) 0.5-2.5%, it is standby to be spray dried to one or more color base substrate powders after deironing; 2), the base substrate powder is through press-molding, after drying, make and do not burn the ceramic tile base substrate; Or advance kiln and burn till biscuit ware adobe body through 600-1250 ℃; Or spray the glaze of one deck 0.1-1mm, through 1160-1250 ℃ of glaze spraying porcelain brick or porcelain brick of burning till.
8, the production technique of devitrified glass porcelain composition board according to claim 5 is characterized in that: it is to adopt dry method once or secondary to four time cloth that capstock is evenly distributed on the bottom, sprays the high sticking edible methyl of concentration 0-20% of 0-10%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410050915 CN1291944C (en) | 2004-07-30 | 2004-07-30 | Composite plate of microcrystalline glass and porcelain, and production process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410050915 CN1291944C (en) | 2004-07-30 | 2004-07-30 | Composite plate of microcrystalline glass and porcelain, and production process |
Publications (2)
| Publication Number | Publication Date |
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| CN1727310A true CN1727310A (en) | 2006-02-01 |
| CN1291944C CN1291944C (en) | 2006-12-27 |
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| CN 200410050915 Active CN1291944C (en) | 2004-07-30 | 2004-07-30 | Composite plate of microcrystalline glass and porcelain, and production process |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100400472C (en) * | 2006-07-10 | 2008-07-09 | 中国地质大学（武汉） | Process for preparing microcrystal glass-ceramic compounded plate |
| CN101941830A (en) * | 2010-09-01 | 2011-01-12 | 佛山红狮陶瓷有限公司 | Method for manufacturing sintered tile with spot effect |
| CN102690130A (en) * | 2012-06-11 | 2012-09-26 | 佛山瑭虹釉料科技有限公司 | Manufacturing method of microcrystal imitation stone tile |
| CN102765129A (en) * | 2012-07-05 | 2012-11-07 | 广东东鹏控股股份有限公司 | Method and device for recycling fusion cakes of polished crystal tiles |
| CN104743881A (en) * | 2015-02-06 | 2015-07-01 | 佛山石湾鹰牌陶瓷有限公司 | Microcrystal ceramic composite board as well as blank and preparation method of microcrystal ceramic composite board |
| CN106187323A (en) * | 2015-05-04 | 2016-12-07 | 杭州诺贝尔陶瓷有限公司 | A kind of Imitation Rock Porcelain Tiles with three-dimensional decorative effect and production method thereof |
| CN108793953A (en) * | 2018-06-29 | 2018-11-13 | 河源市东源鹰牌陶瓷有限公司 | Low clay glazed tile green body of a kind of low temperature fast firing and preparation method thereof |
| CN112408800A (en) * | 2020-11-25 | 2021-02-26 | 江西璞晶新材料股份有限公司 | Method for preparing marble-like colored microcrystalline glass by using ceramic pigment |
| CN114478025A (en) * | 2022-03-09 | 2022-05-13 | 王云娟 | Method for decorating ceramic by using crystalline silicon |
| CN114890777A (en) * | 2022-06-15 | 2022-08-12 | 佛山市三水天宇陶瓷颜料有限公司 | Dry granules with metal luster for blank, preparation process and preparation process of ceramic tile |
-
2004
- 2004-07-30 CN CN 200410050915 patent/CN1291944C/en active Active
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100400472C (en) * | 2006-07-10 | 2008-07-09 | 中国地质大学（武汉） | Process for preparing microcrystal glass-ceramic compounded plate |
| CN101941830A (en) * | 2010-09-01 | 2011-01-12 | 佛山红狮陶瓷有限公司 | Method for manufacturing sintered tile with spot effect |
| CN102690130A (en) * | 2012-06-11 | 2012-09-26 | 佛山瑭虹釉料科技有限公司 | Manufacturing method of microcrystal imitation stone tile |
| CN102765129A (en) * | 2012-07-05 | 2012-11-07 | 广东东鹏控股股份有限公司 | Method and device for recycling fusion cakes of polished crystal tiles |
| CN104743881B (en) * | 2015-02-06 | 2017-07-28 | 佛山石湾鹰牌陶瓷有限公司 | A kind of micro-crystalline ceramic composite plate, its blank and preparation method |
| CN104743881A (en) * | 2015-02-06 | 2015-07-01 | 佛山石湾鹰牌陶瓷有限公司 | Microcrystal ceramic composite board as well as blank and preparation method of microcrystal ceramic composite board |
| CN106187323A (en) * | 2015-05-04 | 2016-12-07 | 杭州诺贝尔陶瓷有限公司 | A kind of Imitation Rock Porcelain Tiles with three-dimensional decorative effect and production method thereof |
| CN106187323B (en) * | 2015-05-04 | 2019-01-25 | 杭州诺贝尔陶瓷有限公司 | A kind of Imitation Rock Porcelain Tiles and its production method with three-dimensional decorative effect |
| CN108793953A (en) * | 2018-06-29 | 2018-11-13 | 河源市东源鹰牌陶瓷有限公司 | Low clay glazed tile green body of a kind of low temperature fast firing and preparation method thereof |
| CN108793953B (en) * | 2018-06-29 | 2021-09-17 | 河源市东源鹰牌陶瓷有限公司 | Low-clay glazed brick blank capable of being quickly fired at low temperature and preparation method thereof |
| CN112408800A (en) * | 2020-11-25 | 2021-02-26 | 江西璞晶新材料股份有限公司 | Method for preparing marble-like colored microcrystalline glass by using ceramic pigment |
| CN114478025A (en) * | 2022-03-09 | 2022-05-13 | 王云娟 | Method for decorating ceramic by using crystalline silicon |
| CN114890777A (en) * | 2022-06-15 | 2022-08-12 | 佛山市三水天宇陶瓷颜料有限公司 | Dry granules with metal luster for blank, preparation process and preparation process of ceramic tile |
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| Publication number | Publication date |
|---|---|
| CN1291944C (en) | 2006-12-27 |
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| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Foshan Jia Jun Ceramics Co., Ltd. Assignor: Ye Rongsong|Chen Yaoqiang Contract fulfillment period: 2008.3.12 to 2018.3.12 contract change Contract record no.: 2008990000050 Denomination of invention: Composite plate of microcrystalline glass and porcelain, and production process Granted publication date: 20061227 License type: Exclusive license Record date: 2008.3.20 |
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Free format text: EXCLUSIVE LICENCE; TIME LIMIT OF IMPLEMENTING CONTACT: 2008.3.12 TO 2018.3.12 Name of requester: JIAJUN CERAMICS CO., LTD., FUSHAN CITY Effective date: 20080320 |
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Free format text: FORMER OWNER: CHEN YAOQIANG Owner name: GUANGDONG JIAJUN CERAMICS CO., LTD. Free format text: FORMER OWNER: YE RONGSONG Effective date: 20110822 |
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Free format text: CORRECT: ADDRESS; FROM: 528222 FOSHAN, GUANGDONG PROVINCE TO: 529471 JIANGMEN, GUANGDONG PROVINCE |
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| TR01 | Transfer of patent right |
Effective date of registration: 20110822 Address after: 529471, Guangdong, Enping province Shahu Town Po Bridge New Building Materials Industry Park No. 10 Patentee after: Guangdong Jiajun Ceramics Co., Ltd. Address before: 528222, Guangdong, Foshan Province Nanhai District town of Five Star Industrial Zone Jia Jun Ceramic Co., Ltd. Co-patentee before: Chen Yaoqiang Patentee before: Ye Rongsong |