CN1690331A - Corner threads made of artificial stone - Google Patents

Corner threads made of artificial stone Download PDF

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Publication number
CN1690331A
CN1690331A CN 200410013111 CN200410013111A CN1690331A CN 1690331 A CN1690331 A CN 1690331A CN 200410013111 CN200410013111 CN 200410013111 CN 200410013111 A CN200410013111 A CN 200410013111A CN 1690331 A CN1690331 A CN 1690331A
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China
Prior art keywords
corner stitch
corner
edge
unsaturated polyester
accelerator
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Pending
Application number
CN 200410013111
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Chinese (zh)
Inventor
梁春坚
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梁春坚
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Application filed by 梁春坚 filed Critical 梁春坚
Priority to CN 200410013111 priority Critical patent/CN1690331A/en
Publication of CN1690331A publication Critical patent/CN1690331A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a corner stitch of artificial stone, comprising the body of corner stitch and edging strip (1). The body of corner stitch comprises external corner stitch (2) and inner corner stitch (3), characterized in the fixed connection of edging strip (1) and the body of corner stitch; the components of said body of corner stitch include (percentage by weight): unsaturated polyester resin in 22-77 %, filling material in 28-74 %, hardener in 0.2-1.5 %, accelerant in 0.2-1.5 %, and pigment in 0.1-2 %. The invention has following characteristics and advantages: high level of product, bright surface, various kinds of color, the inner and outer corner stitch can meet the constructive requirement of wall corner, and common sand paper can change the size with finished produce.

Description

The man-made stone corner stitch
Affiliated technical field:
The present invention relates to a kind of corner stitch and production technology, especially belong to corner stitch factory formula and the production technology of man-made stone as basal plane.
Background technology:
In recent years, flourish along with house property industry, adnornment industry, building materials industry, people constantly increase the demand of constructional materials, with the unsaturated polyester resin be primary raw material artificial hard stone product in the application in each field more and more widely, this kind material is replacing traditional plank, pottery, stone material and plastics etc.And do not have the man-made stone of sale corner stitch in the market, the corner stitch of being sold is a raw material with polyvinyl chloride (PVC) all, through extrusion modlings such as machine die equipment.Shortcoming is: product specification is low, can't varying sized size after the moulding, and surperficial pattern dullness, easily aging, hollow is fragile and can't repair.
Summary of the invention:
The purpose of this invention is to provide that a kind of designs and varieties are many, intensity good, processing and man-made stone corner stitch and production technology easy to use.Man-made stone corner stitch of the present invention comprises the corner stitch body of main part and the edge-pressing strip of supporting part, and the corner stitch body comprises outer corner stitch body and inside lock line body, it is characterized in that edge-pressing strip and corner stitch body are fixedly connected to form man-made stone corner stitch of the present invention.Described edge-pressing strip adopts T shape edge-pressing strip or class T shape edge-pressing strip or L shaped edge-pressing strip or L like shape edge-pressing strip; Adopt in the prescription of described man-made stone corner stitch:
1, unsaturated polyester resin can adopt any one of artificial marble resin, universal unsaturated polyester, photostability unsaturated polyester, chemical resistance unsaturated polyester, self-extinguishment unsaturated polyester.As the artificial marble resin, the gel of this resin and to solidify be the cross-linking process of long chain type unsaturated polyester ester molecule and unsaturated monomer, this crosslinked be under the effect of curing compound and accelerator, to carry out.This resin can be regulated thick rare with styrene or other thinner.Content is 22～70%, preferred 40%.
2, filler adopts the mixture of graininess or fleut or graininess and fleut, and almost any epipastic mineral all can be used as filler.But we are normally used to be calcium carbonate, aluminium hydroxide, marble dust, quartz powder, glass microballoon, French chalk and artificial imitative stone granulate or particulate.Granularity is between 0.015～80 micron, and content is 28～74%, and preferred 57%.3, accelerator, the organic acid of the transition metal-type of selecting for use (for example cobalt, manganese organic acid (ROO (CoMn))) impels activated curing agent, accelerated decomposition to become free radical with amine (for example dimethylaniline (CH3C6H6NH2)) accelerator easily, quicken the carrying out of cross-linking reaction, content is 0.5～1.5%, preferred 1%.4, select the organic peroxide curing compound for use, organic peroxide can decompose free radical, causes cross-linking reaction, methyl ethyl ketone peroxide for example, and content is 0.5～1.5%, preferred 1%.5, mill base, pigment make product have abundant colors, but must notice that some pigment has acceleration or slows down effect reaction, and content is 0.1～2%, and preferred 0.5%.
The composition and the content of man-made stone corner stitch of the present invention following (percentage by weight):
Unsaturated polyester resin 22～70%;
Filler 28～74%;
Curing compound 0.2～1.5%:
Accelerator 0.2～1.5%;
Pigment 0.1～2%.
Wherein:
1, unsaturated polyester resin adopts a kind of of artificial marble resin, universal unsaturated polyester, photostability unsaturated polyester, chemical resistance unsaturated polyester, self-extinguishment unsaturated polyester, is specially:
(1) universal unsaturated polyester is as adjacent benzene type unsaturated polyester, metaphenylene unsaturated polyester;
(2) photostability unsaturated polyester;
(3) chemical resistance unsaturated polyester is as M-phthalic acid type unsaturated polyester, bisphenol A-type unsaturated polyester, bisphenol-A and terephthalic acid (TPA) blending type unsaturated polyester;
(4) self-extinguishment unsaturated polyester.
2, filler adopts the powder body inorganic material of granularity between 0.015～80 micron, has at least a kind of preferably from calcium carbonate, aluminium hydroxide, marble dust, quartz powder, glass microballoon, French chalk and artificial imitative stone granulate or particulate.
3, accelerator is selected the organic acid and the amine of transition metal class for use, has at least a kind of preferably from cobalt, manganese organic acid (ROO (CoMn)), dimethylaniline (CH3C6H6NH2).
4, curing compound is selected organic peroxide for use, have at least a kind of preferably from ketone peroxide (R-O-OR '), hydroperoxides (R-O-OH), as methyl ethyl ketone peroxide, cyclohexanone peroxide (MEKP).
5, mill base, select for use organic and inorganic mill base all can reach must decorative effect, have a kind of preferred autoxidation titanium (TiO), zinc oxide (ZnO) at least.
The composition and the preferred content of man-made stone corner stitch of the present invention following (percentage by weight):
Unsaturated polyester resin 40%;
Filler 57%;
Curing compound 1%;
Accelerator 1%;
Pigment 1%.
The production technology of man-made stone corner stitch of the present invention has four kinds, and is specific as follows:
(1) normal temperature cure: unsaturated polyester resin, filler, accelerator, pigment are mixed, add curing compound and stir evenly again; Pour in the mould, the wedge pressure edge strip, normal temperature and pressure solidifies bonding, the demoulding, and dried man-made stone curved surfaces pastes hinge, packing.
(2) vacuumize heating cure: unsaturated polyester resin, filler, accelerator, pigment are mixed, add curing compound and stir evenly again; Pour in the mould, the wedge pressure edge strip is placed on vacuum P then and is generally 1 * 10 4Pa～3 * 10 4It is bonding to vacuumize curing in the vacuum tank between the Pa, and heating-up temperature is generally between 40 ℃～80 ℃.The purpose that vacuumizes and heat is to improve curing rate.The demoulding, dried man-made stone curved surfaces paste hinge, packing.
(3) each unsaturated polyester resin, filler, accelerator, the pigment with formulation content mixes, and adds curing compound and stirs evenly; Pour in the mould, normal temperature and pressure curing is bonding, the demoulding becomes the corner stitch body, and the corner stitch body is bonded into product with edge-pressing strip again.
(4) each unsaturated polyester resin, filler, accelerator, the pigment with formulation content mixes, and adds curing compound and stirs evenly; Pour in the mould, be placed on then to vacuumize in the vacuum tank and solidify bondingly, heating-up temperature is that the demoulding becomes the corner stitch body between 40 ℃～80 ℃, then the right-angle side fluting of corner stitch body with the edge-pressing strip embedded groove in and the gluing product that is tightened to.
The soft mode that above-mentioned mould can be made with silica gel.
Above-mentioned gelling, hardening time mainly are subjected to the influence of accelerator and curing compound addition, and the addition of accelerator and curing compound changes with the variation of environment temperature, humidity, pressure.
Matching used edge-pressing strip can adopt the edge-pressing strip of the various moulding that materials such as aluminium alloys, hard PVC, glass fiber reinforced plastic make.
Compare with the corner stitch of selling on the existing market, the present invention has following characteristics and advantage: owing to adopting man-made stone and being solid, thereby product specification height, surface-brightening, designs and varieties are many, inside and outside corner stitch all can satisfy the construction requirement in various corners, then just can reach with common sand paper if want varying sized behind the finished product.Damage, scratch are repaired easily, fire protection flame retarding, anti-aging, shock resistance, nontoxic, "dead" environmental protection.Have simple in structure, intensity good, manufacturing process is simple, characteristics such as easy to use.
Description of drawings:
Fig. 1 is the perspective view of outer corner stitch of the present invention.
Fig. 2 is the perspective view of inside lock line of the present invention.
Fig. 3 is the corner stitch body that the present invention produced and the structural representation of the bonding formed outer corner stitch of edge-pressing strip.
Fig. 4 for the right-angle side of the corner stitch body that the present invention produced fluting with in the edge-pressing strip embedded groove and the structural representation of gluing fastening formed outer corner stitch.
Fig. 5 is a process flow diagram of the present invention.
The specific embodiment:
The present invention is described in detail below in conjunction with accompanying drawing:
The structure of product is as follows:
As Fig. 1, Fig. 2, Fig. 3 and shown in Figure 4, the present invention includes corner stitch body and edge-pressing strip 1, the corner stitch body comprises outer corner stitch body 2 and inside lock line body 3, the fan type that the outer corner cross sectional shape of outer corner stitch body is circular-arc or oval arcuation, the inside lock of inside lock line body is generally circular arc or the elliptic arc that caves in, design feature is that the part of edge-pressing strip 1 is fixedlyed connected with the corner stitch body, and it is to embed in the corner stitch body that the edge-pressing strip 1 of fixedlying connected with the corner stitch body has an end, that end that embeds in the corner stitch body is fixedlyed connected with the corner stitch body, and the concrete man-made stone corner stitch product structure that forms is seen Fig. 1, Fig. 2.The dual-side of corner stitch body is generally vertical each other; Corner stitch body of the present invention is a man-made stone, generally forms with the filled curing of unsaturated polyester resin.Described edge-pressing strip shape can be various, general L shaped edge-pressing strip or L like shape edge-pressing strip or T shape edge-pressing strip or the class T shape edge-pressing strip of adopting, the built-in end shape of edge-pressing strip also can adopt various, generally can be made into shapes such as I font cross section structure, dove-tail form cross section structure, arc bend hook cross section structure, ball-shaped cross section structure.During making, generally be to inject man-made stone forming mixture material in the moulding form of corner stitch body or inside lock line body outside, then curing molding in the man-made stone forming mixture material in the built-in end of the edge-pressing strip embedding mould, form the outer corner stitch of man-made stone or the inside lock line of its built-in end that is embedded with edge-pressing strip, see Fig. 1, Fig. 2.Also can directly be bonded into outer corner stitch product to the outer corner stitch body 2 that solidify to form with edge-pressing strip 1, see Fig. 3.Also can see Fig. 4 the right-angle side of the outer corner stitch body 2 that solidify to form fluting 4 with in edge-pressing strip 1 embedded groove 4 and gluingly be tightened to outer corner stitch product.
The prescription of product and manufacturing process embodiment are as follows:
Below one of the manufacturing process of each embodiment two kinds of methods adopting normal temperature cure or vacuumize heating cure produce.The artificial marble resin that unsaturated polyester resin adopts Jiangsu FuLing Chemical Industry Co., Ltd to produce, model is gorgeous board-191,885 resins.Filler can adopt the aluminium hydroxide of granularity between 0.015～80 micron that aluminium powder factory in continent produces in the Huojia County, Henan.Accelerator is adopted the T-8A of composite material Co., Ltd of China and Sweden.The curing compound of present embodiment all adopts the methyl ethyl ketone peroxide of composite material Co., Ltd of China and Sweden.The mill base pigment that example is used uses production lemon yellow of composite material Co., Ltd of China and Sweden, forms: 3PbCrO4,2PbSO4, Al (OH) 3, Al (PO4) 3.
Embodiment 1
With 35 kilograms of artificial marble resins (gorgeous board-885), 62.6 kilograms in aluminum hydroxide particle powder, 0.6 kilogram of T-8A accelerator, 1.2 kilograms of mixing of lemon yellow pigment, add the methyl ethyl ketone peroxide curing compound and stir evenly again for 0.6 kilogram; Pour in the soft mode that silica gel makes, put into the plastics edge-pressing strip, normal temperature and pressure solidifies bonding 10 minutes, the demoulding, and the curved surfaces of dry back man-made stone pastes hinge, packing.
Embodiment 2
With 40 kilograms of artificial marble resins (gorgeous board-885), 57 kilograms in aluminum hydroxide particle powder, 1 kilogram of T-8A accelerator, 1 kilogram of mixing of lemon yellow pigment, add the methyl ethyl ketone peroxide curing compound and stir evenly again for 1 kilogram; Pour in the soft mode that silica gel makes, put into the plastics edge-pressing strip, normal temperature and pressure solidifies bonding 10 minutes, the demoulding, and the curved surfaces of dry back man-made stone pastes hinge, packing.
Embodiment 3
With 45 kilograms of artificial marble resins (gorgeous board-191), 52.7 kilograms in aluminum hydroxide particle powder, 0.9 kilogram of T-8A accelerator, 0.5 kilogram of mixing of lemon yellow pigment, add the methyl ethyl ketone peroxide curing compound and stir evenly again for 0.9 kilogram; Pour in the soft mode that silica gel makes, put into the plastics edge-pressing strip, normal temperature and pressure solidifies bonding 10 minutes, the demoulding, and the curved surfaces of dry back man-made stone pastes hinge, packing.
Embodiment 4
With 30 kilograms of artificial marble resins (gorgeous board-191), 67.8 kilograms in aluminum hydroxide particle powder, 0.6 kilogram of T-8A accelerator, 1 kilogram of mixing of lemon yellow pigment, add the methyl ethyl ketone peroxide curing compound and stir evenly again for 0.6 kilogram; Pour in the soft mode that silica gel makes, put into the plastics edge-pressing strip, normal temperature and pressure solidifies bonding 10 minutes, the demoulding, and the curved surfaces of dry back man-made stone pastes hinge, packing.
Embodiment 5
With 45 kilograms of artificial marble resins (gorgeous board-191), 52.8 kilograms in aluminum hydroxide particle powder, 0.4 kilogram of T-8A accelerator, 1.2 kilograms of mixing of lemon yellow pigment, add the methyl ethyl ketone peroxide curing compound and stir evenly again for 0.6 kilogram; Pour in the soft mode that silica gel makes, put into the plastics edge-pressing strip, being placed on vacuum P then is 3 * 10 4Vacuumize in the vacuum tank of Pa and solidified bonding 3 minutes, the oven dry of heating, heating-up temperature is between 50 ℃.The demoulding, dry back wood-based plate curved surfaces paste hinge, packing.
Embodiment 6
With 25 kilograms of artificial marble resins (gorgeous board-885), 72.8 kilograms in aluminum hydroxide particle powder, 0.5 kilogram of T-8A accelerator, 1.2 kilograms of mixing of lemon yellow pigment, add the methyl ethyl ketone peroxide curing compound and stir evenly again for 0.5 kilogram; Pour in the soft mode that silica gel makes, put into the plastics edge-pressing strip, being placed on vacuum P then is 3 * 10 4Vacuumize in the vacuum tank of Pa and solidified bonding 3 minutes, the oven dry of heating, heating-up temperature is between 70 ℃.The demoulding, dry back wood-based plate curved surfaces paste hinge, packing.

Claims (5)

1, a kind of man-made stone corner stitch comprises corner stitch body and edge-pressing strip (1), and the corner stitch body comprises outer corner stitch body (2) and inside lock line body (3), it is characterized in that edge-pressing strip (1) fixedlys connected with the corner stitch body; Described corner stitch body is formed and content following (percentage by weight):
Unsaturated polyester resin 22～70%;
Filler 28～74%;
Curing compound 0.2～1.5%;
Accelerator 0.2～1.5%;
Pigment 0.1～2%.
2, the production technology of the described man-made stone corner stitch of claim 1 is characterized in that each unsaturated polyester resin, filler, accelerator, the pigment of formulation content are mixed, and adds curing compound and stirs evenly; Pour in the mould, the wedge pressure edge strip, normal temperature and pressure curing is bonding, the demoulding becomes product.
3, the production technology of the described man-made stone corner stitch of claim 1 is characterized in that each unsaturated polyester resin, filler, accelerator, the pigment of formulation content are mixed, and adds curing compound and stirs evenly; Pour in the mould, the wedge pressure edge strip is placed on then to vacuumize in the vacuum tank and solidifies bondingly, is heating and curing, and the demoulding becomes product.
4, the production technology of the described man-made stone corner stitch of claim 1 is characterized in that each unsaturated polyester resin, filler, accelerator, the pigment of formulation content are mixed, and adds curing compound and stirs evenly; Pour in the mould, normal temperature and pressure solidifies, the demoulding becomes the corner stitch body, and the corner stitch body is bonded into product with edge-pressing strip again.
5, the production technology of the described man-made stone corner stitch of claim 1 is characterized in that each unsaturated polyester resin, filler, accelerator, the pigment of formulation content are mixed, and adds curing compound and stirs evenly; Pour in the mould, be placed on then to vacuumize in the vacuum tank and solidify bondingly, be heating and curing, the demoulding becomes the corner stitch body, then the right-angle side fluting of corner stitch body with the edge-pressing strip embedded groove in and the gluing product that is tightened to.
CN 200410013111 2004-04-25 2004-04-25 Corner threads made of artificial stone Pending CN1690331A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 200410013111 CN1690331A (en) 2004-04-25 2004-04-25 Corner threads made of artificial stone

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Application Number Priority Date Filing Date Title
CN 200410013111 CN1690331A (en) 2004-04-25 2004-04-25 Corner threads made of artificial stone

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100463798C (en) * 2006-01-23 2009-02-25 邓伟 Artificial stone composite platform and method for manufacturing same
CN103709699A (en) * 2014-01-15 2014-04-09 上海澳金玻璃钢制品有限公司 Lightweight mold closing material for independent acrylic bathtub
CN103819135A (en) * 2013-12-31 2014-05-28 武汉武新新型建材有限公司 Artificial stone and production process thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100463798C (en) * 2006-01-23 2009-02-25 邓伟 Artificial stone composite platform and method for manufacturing same
CN103819135A (en) * 2013-12-31 2014-05-28 武汉武新新型建材有限公司 Artificial stone and production process thereof
CN103819135B (en) * 2013-12-31 2016-09-21 武汉武新新型建材有限公司 A kind of artificial stone and production technology thereof
CN103709699A (en) * 2014-01-15 2014-04-09 上海澳金玻璃钢制品有限公司 Lightweight mold closing material for independent acrylic bathtub

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