Linear magnetic field sensor and preparation method thereof
Technical field
The present invention relates to a kind of senser element and preparation method thereof, relate in particular to a kind of digital magnetic field sensor that has tunnel junction resistance element or giant magnetoresistance element and preparation method thereof.
Background technology
One of them technical barrier that must overcome is how to make output signal become linear dependence with external magnetic field in linear magnetic sensor, present most popular linear magnetic field sensor is the Hall magnetic field sensor, promptly based on Hall effect, the intrinsic characteristic of its material property is exactly that output signal and external magnetic field are linear, but the Hall magnetic field sensor is very little to the output signal of low-intensity magnetic field, so generally be used for the big magnetic field of perception 100 to 1000 oersted (Oe) scopes, another kind of MR magnetic field sensor is based on anisotropic magneto-resistive effect (AMR), caused the sensitive element changes in resistance by the external magnetic field of sensing, cause the variation of corresponding curtage.The bridge-type magnetic sensor of being made by AMR is as the magnetic field below the about 50Oe of perception.
In magnetoresistance effect, observed the more significant magnetic resistance of another kind, tunnel junction magneto-resistor (TMR) and giant magnetoresistance (GMR).Be characterized in having at least two ferromagnetic metal layers to be separated by a non-ferromagnetic metal level or oxide layer.TMG and GMR multilayer film have multiple structure, its physics root all is to originate from the electronic spin dependent scattering, since giant magnetoresistance and tunnel junction magneto-resistor phenomenon are found, because its high sensitivity to low-intensity magnetic field, be subjected to the extensive attention of business circles, except the important application aspect computer magnetic head and the MARM (non-volatile magnetic storage), also be penetrated into gradually some to other among the application than low-intensity magnetic field induction, as position transducer, galvanometer, compass or the like.
In giant magnetoresistance and tunnel junction magneto-resistor low-intensity magnetic field being responded to the sensitiveest structure is exactly so-called Spin Valve (spin valve), its design feature is that two very little ferromagnetic layers that are not coupled or are coupled are separated by a non-magnetic metal layer or oxide layer, one of them ferromagnetic layer is lived by another inverse ferric magnetosphere pinning, be pinning layer, another ferromagnetic layer can freely rotate with external magnetic field, is free layer.When the effect of the magnetization direction outside magnetic field of free layer down with the magnetization direction of pinning layer by parallel during to antiparallel, the size of resistance is with regard to ascending variation.Just can know the size of external magnetic field by the resistance variations of measuring the Spin Valve multilayer film.So just cause a Spin Valve magnetic sensor.But because the non-linear relation of its signal domain output external magnetic field, so can not be directly used in the making of linear transducer, in order to make it have linear relationship with external magnetic field, the general structure that adopts common bridge-type AMR magnetic sensor, the United States Patent (USP) of IBM has shown similar a kind of basic Spin Valve magnetic sensor for No. 5206590.One of several at least ferromagnetic layers are cobalt or cobalt-base alloy in a kind of sensor that No. the 5159513rd, the United States Patent (USP) of IBM shows, and free layer and pinning layer are vertical mutually when zero externally-applied magnetic field.This is that wherein the magnetization of pinning layer is parallel to signal field by the Spin Valve magnetic sensor of line style response and wide dynamic range.The United States Patent (USP) 5341261 of IBM has proposed a kind of Spin Valve magnetic sensor, and itself and nonmagnetic layer adjacent have a cobalt thin layer to increase magneto-resistor.People such as Heim are at " Spin Valve magnetic Design of Sensor and manufacturing " (IEEETransactions on Magnetics 30 316-321 1994) literary composition.Daughton etc. are at " being applied to low GMR material " (IEEE Transactions on Magnetics, 29 2705-2710) suggestion uses the GMR element to make magnetic sensor in bridge circuit in, and the patent of this design proposal is finally obtained by IBM Corporation.It has utilized being better than the AMR sensor of spin-valve sensor and has improved the performance of magnetic sensor.The sensor that adopts the GMR element to make has improved 5 times than the sensitivity of AMR member sensor device.However, in order to make output signal and external magnetic field linear, the direction of two its pinning layers in 4 spin valve elements in the bridge-type magnetic sensor of design such as Daughton must be opposite with the top bundle layer direction of two other spin valve elements, in order to reach this purpose, the employing that has on manufacture craft is provided with electric current magnetic bias method, the employing that has is provided with permanent magnet magnetic bias method, the employing secondary sedimentation that also has, these preparation technologies are comparatively complicated, increased the manufacture difficulty of sensor, main is that consistency of product is difficult to be guaranteed.
Summary of the invention
In order to overcome this difficulty, the invention provides a kind of linear magnetic field sensor method for making, the direction that can realize two its pinning layers in 4 spin valve elements in the bridge-type magnetic sensor in primary depositing is opposite with the pinning layer direction of two other spin valve elements, realizes the linear response of sensor to external magnetic field.
Further, the present invention also provides a kind of linear magnetic field sensor that adopts this method for making to obtain.
For achieving the above object, a kind of linear magnetic field sensor method for making provided by the invention: original position is changed mask in main sputtering chamber when the deposition nonmagnetic layer, promptly when deposition, utilize mask to block the sputter of nonmagnetic layer on the 1st, 3 spin valve elements or the 2nd, 4 spin valve elements, cause the thinner thickness of nonmagnetic layer on the 1st, 3 spin valve elements or the 2nd, 4 spin valve elements or thicker, and then take away mask, remaining spin valve elements material in the sputter.
Further, described spin valve elements is tunnel junction element or GMR element.
A kind of linear magnetic field sensor provided by the invention, comprise: sheet base and formed 4 spin valve elements on described base, wherein, 1st, 3 spin valve elements structures are just the same, 2nd, 4 spin valve elements are just the same, 1st, 3 spin valve elements are than the thinner thickness of the nonmagnetic layer of the 2nd, 4 spin valve elements or thicker, and the pinning layer of described spin valve elements adopts synthetic pinning form, and described synthetic pinning form is inverse ferric magnetosphere/ferromagnetic layer/nonmagnetic layer/ferromagnetic layer.
Further, described spin valve elements is tunnel junction element or GMR element.
The invention has the beneficial effects as follows: the direction that can realize two its pinning layers in 4 spin valve elements in the bridge-type magnetic sensor in primary depositing is opposite with the top bundle layer direction of two other spin valve elements, realize the linear response of sensor to external magnetic field, promptly do not need to be provided with electric current magnetic bias method, permanent magnet magnetic bias method also need not be set, simplify preparation technology greatly, can improve consistency of product effectively.
Description of drawings
Fig. 1 is the sensor synoptic diagram with different-thickness nonmagnetic layer.
Fig. 2 mask method preparation technology synoptic diagram.
Specific embodiment
As shown in Figure 2, tie lines magnetic field sensor method for making: original position is changed mask in main sputtering chamber when the deposition nonmagnetic layer, promptly when deposition, utilize mask to block the sputter of nonmagnetic layer on the 1st, 3 tunnel junctions 1,3, cause the thinner thickness of nonmagnetic layer on the 1st, 3 tunnel junctions 1,3, and then take away mask, remaining tunnel junction material in the sputter.
As shown in Figure 1, adopt the prepared sensor of said method to comprise: formed 4 tunnel junctions on sheet base and the described base with different-thickness nonmagnetic layer, wherein the 1st, 3 tunnel junctions 1,3 are just the same, 2nd, 4 tunnel junctions 2,4 are just the same, 1st, the thinner thickness of the nonmagnetic layer of 3 tunnel junctions, 1,3 to the 2,4 tunnel junctions 2,4, the pinning layer of tunnel junction 1,2,3,4 adopts synthetic pinning form, be inverse ferric magnetosphere/ferromagnetic layer/nonmagnetic layer/ferromagnetic layer, for example: IrMn/Co/Ru/Co.In the layer coupling of material, the phenomenon of Fa Xianing is that some ferromagnetic materials are (as Fe already, Co, Ni) and their some alloys with the nonmagnetic layer of centre (as Cu, Ru, Cr etc.) layer coupling of generation vibration, promptly the variation in thickness along with nonmagnetic layer has the variation of ferromagnetic coupling to antiferromagnetic coupling, we just can make the 1st in top 4 tunnel junctions by changing nonmagnetic layer thickness in the synthetic pinning layer like this, 3 tunnel junctions 1,3 are ferromagnetic coupling, the 2nd, 4 tunnel junctions 2,4 are antiferromagnetic coupling, so just can realize in the bridge type magnetic sensor of forming by these 4 sensors that the direction of two its pinning layers in 4 spin valve elements is opposite with the pinning layer direction of two other spin valve elements, reaches the linear output of sensor with external magnetic field.
The present invention equally also is applicable to giant magnetoresistance (GMR) element.