CN1664043A - Sealing adhesive - Google Patents
Sealing adhesive Download PDFInfo
- Publication number
- CN1664043A CN1664043A CN 200510037857 CN200510037857A CN1664043A CN 1664043 A CN1664043 A CN 1664043A CN 200510037857 CN200510037857 CN 200510037857 CN 200510037857 A CN200510037857 A CN 200510037857A CN 1664043 A CN1664043 A CN 1664043A
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- parts
- sbs
- sebs
- ethylene glycol
- sealing adhesive
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Abstract
The invention discloses an edge banding adhesive which comprises (by weight portion) butadiene rubber 268 10-20 parts, SEBS 5-10 parts, SBS 5-15 parts, terpene resin 25-35 parts, modified rosin resin 25-35 parts, toluene 65-90 parts, 50% emulsified rosin 20-30 parts, VAE emulsion 60-100 parts, ethylene glycol 2-3 parts, dibutylphthalate 5-10 parts, 0P-10 1-1.5 parts, water 10-50 parts. Its preparation comprises the steps of dissolving, mixing, charging a predetermined amount of ethylene glycol, dibutylphthalate, OP-10, water and agitating.
Description
Technical field
The present invention relates to a kind of tackiness agent, especially be applicable to the multiple film paper of BOPP, gloss oil paper, gold and silver paperboard, friction glazed paper etc., is a kind of sealing adhesive that the contour grade packaged thing of gift bag, wine box carries out manual adhesive seal.
Background technology
Sealing adhesive in the market, generally adopting SBS is the preparation of main composition because its main composition inherent characteristic, its bonding strength only 5-30 ℃ still can, but in winter below 0 ℃ or summer more than 40 ℃, viscosity is relatively poor relatively, the phenomenon of coming unglued can occur.The quality of this product has not satisfied people's requirement.
Summary of the invention
At the technical problem of above-mentioned existence, purpose to be solved by this invention is, has proposed a kind of both high-and low-temperature resistances that has, again the good sealing adhesive of bonding strength.
Technical scheme of the present invention is achieved in that a kind of sealing adhesive, its effective ingredient, and weight share is as follows:
Isoprene-isobutylene rubber 268 (structural formulas
10-20 part;
SEBS (structural formula
5-10 part;
SBS (structural formula
5-15 part;
(major ingredient is terpine resin
(d-firpene) 25-35 part;
(major ingredient is modified rosin resin
25-35 part;
Toluene (structural formula
65-90 part;
(major ingredient is C to 50% emulsification rosin
19H
29COOH) 20-30 part;
VAE emulsion (structural formula
60-100 part;
Ethylene glycol (structural formula
2-3 part;
Dibutyl phthalate (structural formula
5-10 part;
OP-10 (structural formula
1-1.5 part;
Water (H
2O) 10-50 part.
Its technological operation step is as follows:
The first step: dissolving
With toluene 65-90 part, isoprene-isobutylene rubber 268 is that 10-20 part is mixed earlier and afterwards soaked two days, adds SEBS 5-10 part, SBS 5-15 part, terpine resin 25-35 part, the adding of modified rosin resin 25-35 part again and is with in the high-speed stirring trough, stirs 3 hours abundant dissolvings.
Second step: mix
VAE emulsion 60-100 part is poured in the empty band agitator groove, the first step dissolved mixture is added, adding ethylene glycol 2-3 part, dibutyl phthalate 5-10 part, OP-10 again is 1-1.5 part, water 10-50 part, stirs 3 hours, gets final product discharging.
Above raw material is all buied from Suzhou industrial chemicals supply and marketing company.
In the present invention prescription, isoprene-isobutylene rubber 268 has the tack that improves sealing compound, and that can improve sealing compound again holds viscosity and resistance to elevated temperatures; SEBS has the viscosity of holding that improves sealing compound, can improve the lower temperature resistance of sealing compound again; Other composition has enhancing, tackify, plasticity, and permanent bonding strength.
Embodiment
Embodiment one:
A kind of sealing adhesive, its effective ingredient, weight share is as follows:
Isoprene-isobutylene rubber 268 is 10 parts; SEBS is 5 parts; 5 parts of SBS; Terpine resin is 25 parts; Modified rosin resin is 25 parts; Toluene is 65 parts; 50% emulsification rosin is 20 parts; The VAE emulsion is 60 parts; Ethylene glycol is 2 parts; Dibutyl phthalate is 5 parts; OP-10 is 1 part; Water is 10 parts.
Its technological operation step is as follows:
The first step: dissolving
65 parts of toluene, isoprene-isobutylene rubber 268 are 10 parts mix earlier and afterwards soaks two days, add SEBS again and be 5 parts, 5 parts of SBS, 25 parts of terpine resins, modified rosin resin and add for 25 parts and be with in the high-speed stirring trough, stir 3 hours abundant dissolvings.
Second step: mix
60 parts of VAE emulsions are poured in the empty band agitator groove, add 20 parts of 50% emulsification rosin and stirred 10 minutes, the first step dissolved mixture is added, add 2 parts of ethylene glycol, 5 parts of dibutyl phthalates, OP-10 again and be 10 parts of 1 parts, water, stirred 3 hours, and got final product discharging.
Embodiment two:
A kind of sealing adhesive, its effective ingredient, weight share is as follows:
Isoprene-isobutylene rubber 268 is 20 parts; SEBS is 10 parts; 15 parts of SBS; Terpine resin is 35 parts; Modified rosin resin is 35 parts; Toluene is 90 parts; 50% emulsification rosin is 30 parts; The VAE emulsion is 100 parts; Ethylene glycol is 3 parts; Dibutyl phthalate is 10 parts; OP-10 is 1.5 parts; Water is 50 parts.
Its technological operation step is as follows:
The first step: dissolving
With 90 parts of toluene, isoprene-isobutylene rubber 268 is to soak two days after 20 parts of mixing, adds SEBS again and is 10 parts, SBS and be 15 parts, 35 parts of terpine resins, modified rosin resin and add in the band high-speed stirring trough for 35 parts, stirs and fully dissolves in 3 hours.
Second step: mix
100 parts of VAE emulsions are poured in the empty band agitator groove, add 30 parts of 50% emulsification rosin and stirred 10 minutes, the first step dissolved mixture is added, add 3 parts of ethylene glycol, 10 parts of dibutyl phthalates, OP-10 again and be 50 parts of 1.5 parts, water, stirred 3 hours, and got final product discharging.
Embodiment three:
A kind of sealing adhesive, its effective ingredient, weight share is as follows:
Isoprene-isobutylene rubber 268 is 10 parts; SEBS is 5 parts; SBS is 7 parts; Terpine resin is 29 parts; Modified rosin resin is 29 parts; Toluene is 70 parts; 50% emulsification rosin is 20 parts; The VAE emulsion is 64 parts; Ethylene glycol is 2 parts; Dibutyl phthalate is 5 parts; OP-10 is 1 part; Water is 10 parts.
Its technological operation step is as follows:
The first step: dissolving
With 70 parts of toluene, isoprene-isobutylene rubber 268 is to soak two days behind 10 parts, 5 parts of mixing of SEBS, adds SBS again and is 7 parts, 29 parts of terpine resins, modified rosin resin and add in the band high-speed stirring trough for 29 parts, stirs and fully dissolves in 3 hours.
Second step: mix
64 parts of VAE emulsions are poured in the empty band agitator groove, add 20 parts of 50% emulsification rosin and stirred 10 minutes, the first step dissolved mixture is added, add 2 parts of ethylene glycol, 5 parts of dibutyl phthalates, OP-10 again and be 10 parts of 1 parts, water, stirred 3 hours, and got final product discharging.
It below is the comparison sheet of like product and product of the present invention
| -15C is with down to the above qualification rate of 50C | |
| The market like product | About 85% |
| Product of the present invention | More than 99% |
Claims (3)
1. sealing adhesive is characterized in that: this effective ingredient, and weight share is as follows: isoprene-isobutylene rubber 268 is 10-20 part; SEBS is 5-10 part; SBS is 5-15 part; Terpine resin is 25-35 part; Modified rosin resin is 25-35 part; Toluene is 65-90 part; 50% emulsification rosin is 20-30 part; The VAE emulsion is 60-100 part; Ethylene glycol is 2-3 part; Dibutyl phthalate is 5-10 part; OP-10 is 1-1.5 part; Water is 10-50 part.
2. sealing adhesive according to claim 1 is characterized in that: this effective ingredient, and weight share is as follows:
Isoprene-isobutylene rubber 268 is 10 parts; SEBS is 5 parts; SBS is 7 parts; Terpine resin is 29 parts;
Modified rosin resin is 29 parts; Toluene is 70 parts; Emulsification rosin (50%) is 20 parts; The VAE emulsion is 64 parts; Ethylene glycol is 2 parts; Dibutyl phthalate is 5 parts; OP-10 is 1 part; Water is 10 parts.
3. sealing adhesive according to claim 1 and 2, it is characterized in that: on the basis of the main adhesives of SBS conduct, add described isoprene-isobutylene rubber 268 and described SEBS to improve the high-and low-temperature resistance performance of sealing compound, it is not being come unglued more than-15 ℃ and 50 ℃, improve the qualification rate of product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100378571A CN1296449C (en) | 2005-02-25 | 2005-02-25 | Sealing adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100378571A CN1296449C (en) | 2005-02-25 | 2005-02-25 | Sealing adhesive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1664043A true CN1664043A (en) | 2005-09-07 |
| CN1296449C CN1296449C (en) | 2007-01-24 |
Family
ID=35035360
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100378571A Expired - Fee Related CN1296449C (en) | 2005-02-25 | 2005-02-25 | Sealing adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1296449C (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101824288A (en) * | 2010-04-23 | 2010-09-08 | 中国建筑材料科学研究总院苏州防水研究院 | Butyl rubber composition and method for producing butyl rubber adhesive tape by using same |
| CN101058704B (en) * | 2007-05-29 | 2011-06-22 | 林润强 | Multifunctional aqueous adhesive and preparation method thereof |
| CN105315930A (en) * | 2014-06-11 | 2016-02-10 | 中国石油化工股份有限公司 | Styrene-type thermoplastic elastomer laminating adhesive emulsion and preparation method thereof |
| CN107722880A (en) * | 2017-09-26 | 2018-02-23 | 康菲胶粘剂技术（广东）有限公司 | A kind of low temperature resistant lagging glue |
| CN108410399A (en) * | 2018-03-28 | 2018-08-17 | 如皋市嘉好热熔胶有限公司 | A kind of left and right waist patch special glue and preparation method thereof |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4716183A (en) * | 1985-11-22 | 1987-12-29 | Raychem Corp. | Styrene-diene block copolymer compositions |
| JPS62192441A (en) * | 1986-02-20 | 1987-08-24 | Yokohama Rubber Co Ltd:The | Hot melt composition for use in molding |
| FR2620458A1 (en) * | 1987-09-10 | 1989-03-17 | Nat Starch Chem Sa | THERMOREACTIVABLE ADHESIVES HAVING INSTANTANEOUS INSTANTANEOUS TIGHTENING PURPOSE, PREDICTED FOR BONDING ELASTIC ELEMENTS |
| JPH04110381A (en) * | 1990-08-30 | 1992-04-10 | Sekisui Chem Co Ltd | Hot-melt gasket composition |
| US6214935B1 (en) * | 1998-07-15 | 2001-04-10 | Avery Dennison Corporation | Intermediate softening point resin-based hot melt PSAs |
| JP4406785B2 (en) * | 2002-10-22 | 2010-02-03 | 株式会社スリーボンド | Adhesive composition |
-
2005
- 2005-02-25 CN CNB2005100378571A patent/CN1296449C/en not_active Expired - Fee Related
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101058704B (en) * | 2007-05-29 | 2011-06-22 | 林润强 | Multifunctional aqueous adhesive and preparation method thereof |
| CN101824288A (en) * | 2010-04-23 | 2010-09-08 | 中国建筑材料科学研究总院苏州防水研究院 | Butyl rubber composition and method for producing butyl rubber adhesive tape by using same |
| CN105315930A (en) * | 2014-06-11 | 2016-02-10 | 中国石油化工股份有限公司 | Styrene-type thermoplastic elastomer laminating adhesive emulsion and preparation method thereof |
| CN105315930B (en) * | 2014-06-11 | 2018-08-24 | 中国石油化工股份有限公司 | A kind of styrene analog thermoplastic elastomer laminating adhesive latex solution and preparation method thereof |
| CN107722880A (en) * | 2017-09-26 | 2018-02-23 | 康菲胶粘剂技术（广东）有限公司 | A kind of low temperature resistant lagging glue |
| CN108410399A (en) * | 2018-03-28 | 2018-08-17 | 如皋市嘉好热熔胶有限公司 | A kind of left and right waist patch special glue and preparation method thereof |
| CN108410399B (en) * | 2018-03-28 | 2019-10-11 | 江苏嘉好热熔胶股份有限公司 | A kind of left and right waist patch special glue and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1296449C (en) | 2007-01-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Shanghai Donghe Adhesive Co., Ltd. Assignor: Suzhou Congling Adhesives Co., Ltd. Contract fulfillment period: 2007.2.1 to 2012.2.1 contract change Contract record no.: 2008310000226 Denomination of invention: Sealing adhesive Granted publication date: 20070124 License type: Exclusive license Record date: 20081119 |
|
| LIC | Patent licence contract for exploitation submitted for record |
Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2007.2.1 TO 2012.2.1; CHANGE OF CONTRACT Name of requester: SHANGHAI DONGHE ADHESIVE CO., LTD. Effective date: 20081119 |
|
| ASS | Succession or assignment of patent right |
Owner name: SUZHOU ADHESIVE FACTORY CO., LTD. Free format text: FORMER OWNER: SUZHOU CITY CONGLING ADHESIVES CO., LTD. Effective date: 20120327 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20120327 Address after: 215144 spring and Autumn Road, Pan Yang Industrial Zone, Suzhou, Xiangcheng District, Jiangsu Patentee after: Suzhou Adhesive Factory Co., Ltd. Address before: 215144 Jinfeng Industrial Park, Lingfeng village, North Town, Suzhou, Jiangsu, Xiangcheng District Patentee before: Suzhou Congling Adhesives Co., Ltd. |
|
| ASS | Succession or assignment of patent right |
Owner name: SUZHOU CITY CONGLING ADHESIVES CO., LTD. Free format text: FORMER OWNER: SUZHOU ADHESIVE FACTORY CO., LTD. Effective date: 20130814 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20130814 Address after: 215144, Lingfeng Town, North Qiao Town, Suzhou, Jiangsu, Xiangcheng District Patentee after: Suzhou Congling Adhesives Co., Ltd. Address before: 215144 spring and Autumn Road, Pan Yang Industrial Zone, Suzhou, Xiangcheng District, Jiangsu Patentee before: Suzhou Adhesive Factory Co., Ltd. |
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| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20070124 Termination date: 20140225 |