CN1663983A - Aqueous polyarylethersulphones dispersion liquid and process for preparing same - Google Patents
Aqueous polyarylethersulphones dispersion liquid and process for preparing same Download PDFInfo
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- CN1663983A CN1663983A CN 200510016655 CN200510016655A CN1663983A CN 1663983 A CN1663983 A CN 1663983A CN 200510016655 CN200510016655 CN 200510016655 CN 200510016655 A CN200510016655 A CN 200510016655A CN 1663983 A CN1663983 A CN 1663983A
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- 239000006185 dispersion Substances 0.000 title claims abstract description 40
- 239000007788 liquid Substances 0.000 title claims description 35
- 238000004519 manufacturing process Methods 0.000 title 1
- 239000003960 organic solvent Substances 0.000 claims abstract description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims abstract description 21
- 239000000839 emulsion Substances 0.000 claims abstract description 20
- 229920000642 polymer Polymers 0.000 claims abstract description 10
- 239000011248 coating agent Substances 0.000 claims abstract description 9
- 238000000576 coating method Methods 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims abstract description 9
- 229920001688 coating polymer Polymers 0.000 claims abstract description 4
- 239000011347 resin Substances 0.000 claims abstract description 3
- 229920005989 resin Polymers 0.000 claims abstract description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 45
- 238000002360 preparation method Methods 0.000 claims description 28
- -1 poly arylidene ether sulfone Chemical class 0.000 claims description 25
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 20
- 239000013543 active substance Substances 0.000 claims description 17
- 238000002156 mixing Methods 0.000 claims description 17
- 125000001174 sulfone group Chemical group 0.000 claims description 17
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 16
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 16
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 16
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 15
- 229920000570 polyether Polymers 0.000 claims description 15
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 13
- 229960001701 chloroform Drugs 0.000 claims description 13
- 229920001652 poly(etherketoneketone) Polymers 0.000 claims description 13
- 150000003457 sulfones Chemical class 0.000 claims description 13
- 229920005601 base polymer Polymers 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 10
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 claims description 9
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical group ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- 238000004945 emulsification Methods 0.000 claims description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 3
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 2
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 2
- 125000003700 epoxy group Chemical group 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 239000012046 mixed solvent Substances 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 125000002769 thiazolinyl group Chemical group 0.000 claims description 2
- 238000010792 warming Methods 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims 1
- 239000002904 solvent Substances 0.000 abstract description 12
- 239000000463 material Substances 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 238000011084 recovery Methods 0.000 abstract description 2
- 239000004094 surface-active agent Substances 0.000 abstract description 2
- 229920000110 poly(aryl ether sulfone) Polymers 0.000 abstract 4
- 230000003252 repetitive effect Effects 0.000 abstract 2
- 238000001704 evaporation Methods 0.000 abstract 1
- 239000011259 mixed solution Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000003973 paint Substances 0.000 abstract 1
- 239000004695 Polyether sulfone Substances 0.000 description 33
- 229920006393 polyether sulfone Polymers 0.000 description 33
- 239000000243 solution Substances 0.000 description 22
- 239000007864 aqueous solution Substances 0.000 description 7
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 5
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 4
- 238000009835 boiling Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- 229920000090 poly(aryl ether) Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
Abstract
The invention relates to water-based polyarylether sulfone dispersion and the preparing method, belonging to the high molecular polymer field.The elementary composition is polyarylideneethersulfone with repetitive units or polyarylideneethersulfone with repetitive units and with side group, the dispersion containing surface active agent, the sodium dodecylbenzene sulfonate.The preparing process comprising putting the polyarylether sulfone into the mixed solution of organic solvent and assisting solvent; preparing emulsion, evaporating the organic solvent and getting the water-based polyarylether sulfone dispersion.Prepared product can be used as heat resisting paint or coating polymer, and can combine with fluoro-resin to prepare coating material. The invention enlarges the application area of the polyarylethersulfone, which is a kind of engineering material, and can recovery the organic solvent during the process, adapted for environmental protection.
Description
Technical field
The invention belongs to the high molecular polymer field, particularly be used for the water based polyaryl ether Sulphone dispersible liquid and its preparation method of heat resisting coating or coating polymer.
Background technology
The prior art close with the present invention is CN1116428, and disclosed is the organic solution or the molten state polyethersulfone of polyethersulfone, and the polyethersulfone micropowder is smooth ball-type, by polyethersulfone organic solution or the preparation of molten state spraying drying.
The micropowder of poly (arylene ether) sulfone itself is known (WO91/00876 is open), the micropowder of poly (arylene ether) sulfone also can be by providing a kind of paste with a kind of liquid processing poly (arylene ether) sulfone, vigorous stirring makes latter's emulsification in water, makes the emulsion drying again and the acquisition micropowder.Mentioned preparation poly (arylene ether) sulfone emulsion (containing organic solvent N, dinethylformamide) in the patent, the content of the poly (arylene ether) sulfone in the emulsion is very low.
Disadvantages of background technology is, owing to be to be dissolved in the organic solvent, and the content of poly (arylene ether) sulfone is very low, is not fully water base, is unfavorable for environment protection.
Summary of the invention
The technical problem to be solved in the present invention is that prepared aqueous polyarylethersulphondispersion dispersion liquid is not contain organic solvent.Can obtain Recovery of Organic Solvent in the preparation.The aqueous polyarylethersulphondispersion dispersion liquid of the environment-friendly type of preparing is suitable for doing coating and uses.
Aqueous polyarylethersulphondispersion dispersion liquid of the present invention is that a class polyether sulphone base polymer is dispersed in the dispersion liquid in the aqueous solution.
The fundamental component that described aqueous polyarylethersulphondispersion dispersion liquid contains is, contains the poly (arylene ether) sulfone of repeating unit or contains the poly arylidene ether sulfone that has side group of repeating unit.
The said structure that contains the poly (arylene ether) sulfone of repeating unit is:
A：-O- -S-
Wherein A be-O-or-S-; Wherein B be I or/and II or/and III.Wherein the relation of A and B is that A is or/and B.
The said poly arylidene ether sulfone that has side group that contains repeating unit, its side group is: carbonyl or carboxylate salt, sulfonic group or sulfonate, amino or hydroxyl or epoxy group(ing) or thiazolinyl or alkyl or alkyl or cyano group etc.
Described aqueous polyarylethersulphondispersion dispersion liquid, its average particulate diameter is: 0.01～10 μ m, the amount of solid content of aqueous polyarylethersulphondispersion dispersion liquid is from 10%～50%.
Contain tensio-active agent Sodium dodecylbenzene sulfonate (DBS) or sodium laurylsulfonate (K12) or Nonyl pheno class (OP series) in the poly (ether ketone ketone) dispersion liquid of the present invention.
The preferred Sodium dodecylbenzene sulfonate of tensio-active agent (DBS) can also contain polyvinylpyrrolidone (PVP).
The preparation of aqueous polyarylethersulphondispersion dispersion liquid of the present invention, used organic solvent is water-fast, and boiling point is lower than water, and suitable solvent comprises: methylene dichloride, trichloromethane, preferably trichloromethane; Solubility promoter is water-soluble and boiling point is lower than water, mainly contains methyl alcohol, ethanol, preferably methyl alcohol; Used tensio-active agent is Sodium dodecylbenzene sulfonate or sodium laurylsulfonate or Nonyl pheno class.
The present invention prepares aqueous polyarylethersulphondispersion dispersion liquid by emulsification-solvent volatile diffusion method, and preparation process has preparation poly (ether ketone ketone) polymers soln, prepares emulsion, boils off organic solvent:
Said preparation poly (ether ketone ketone) polymers soln process is, polyether sulphone is dissolved in the mixing solutions of organic solvent and solubility promoter, and wherein, be 4～30% or littler by the content of mass ratio polyether sulphone base polymer; The content of solubility promoter is 12% or littler in the mixed solvent;
Said preparation emulsion process is, pours in the high speed dispersion device (such as colloidal mill) tensio-active agent is soluble in water earlier, and be 1～12% by the content of mass ratio tensio-active agent; Slowly pour the poly (ether ketone ketone) polymers soln into dispersion again, be prepared into poly (ether ketone ketone) emulsion.
The said organic solvent that boils off is, poly (ether ketone ketone) emulsion poured in the device (water-bath) that stirring is housed, reclaims, and feeds the pressurized air of trace, and controlled temperature is taken organic solvent out of for 50 ℃～85 ℃.
When feeding pressurized air was taken organic solvent out of, organic solvent can obtain reclaiming with usual method.
The mixing solutions of dissolving polyether sulphone base polymer is solvent trichloromethane or methylene dichloride, and solubility promoter is methyl alcohol or ethanol.Preferably organic solvent mixes with solubility promoter methyl alcohol mutually with trichloromethane.The adding of methyl alcohol plays hydrotropy.The add-on of methyl alcohol can not be excessive.If the amount of the solubility promoter (particular methanol) that adds is too much, just do not have the effect of hydrotropy, condense easily on the contrary and precipitate, be difficult for the dissolving of polyether sulphone base polymer.
In the mixing solutions that is dissolved with the polyether sulphone base polymer, the content of preferred polyether sulphone base polymer is 10～30% (mass ratioes) or littler.If the content of polyether sulphone base polymer surpasses 30%, the easy caking because viscosity is excessive is difficult for disperseing.
Tensio-active agent polyvinylpyrrolidone (PVP) or the polyvinyl alcohol (PVA) or the polyoxyethylene glycol (PEG) that in organic solvent, can contain non-ionic type, preferred surfactants is polyvinylpyrrolidone (PVP), and the consumption of the tensio-active agent of non-ionic type occupies 0～5% of machine solvent by mass ratio; The tensio-active agent that is dissolved in the water is Sodium dodecylbenzene sulfonate (DBS) or sodium laurylsulfonate (K12) or Nonyl pheno class (OP series), and preferred water-soluble tensio-active agent is Sodium dodecylbenzene sulfonate (DBS).
Boiling off the organic solvent process, the removal temperature range of organic solvent is controlled at 50 ℃～85 ℃ scopes.Can, continue again to be warming up to 64～65 ℃, till not having organic solvent after 2～3 hour time at 50～55 ℃ of constant temperature earlier; Be warmed up to 75～85 ℃ again, constant temperature 0.5～1 hour stops heating, discharging.When removing organic solvent, stirring velocity is slow.
The dispersing apparatus of aqueous polyarylethersulphondispersion dispersion liquid preparation can use various high speed pulverization, dispersing apparatus to include: colloidal mill, sand mill, homogenizer etc.Preferably disperse with colloidal mill.
The particle of aqueous polyarylethersulphondispersion dispersion liquid measures particle diameter≤8 μ m. by SEM (or laser particle analyser), and the pattern of particle is a spheric, has aperture.
This aqueous polyarylethersulphondispersion dispersion liquid can be made heat resisting coating or coating polymer usefulness, and can make up with fluoro-resin, prepares various coating.For example, preparation non-stick pan coating mixes aqueous polyarylethersulphondispersion dispersion liquid with ptfe emulsion and other additive, just can prepare non-stick pan coating.
Aqueous polyarylethersulphondispersion dispersion liquid has enlarged the range of application of poly (ether ketone ketone) polymer engineering material, has avoided the pollution of solvent-borne type polyether sulphone emulsion to environment, adapts to environmental protection requirement.
Embodiment
Embodiment 1
Trichloromethane 240ml and methyl alcohol 30ml thorough mixing, 4g is dissolved in the above-mentioned solution with polyvinylpyrrolidone (PVP), polyethersulfone 140g is dissolved in above-mentioned mixing solutions is mixed with polyethersulfone solution.
The 8g Sodium dodecylbenzene sulfonate is dissolved in the 280ml deionized water; Sodium dodecyl benzene sulfonate aqueous solution is poured in the colloidal mill, again polyethersulfone solution is slowly added in the colloidal mill, disperse, make the polyethersulfone emulsion.
Pour the polyethersulfone emulsion that contains organic solvent of preparation into 1000 milliliters of there-necked flasks that whipping appts, condensing works are housed, in water-bath, heat, temperature controlling range 55 ℃ 3 hours 65 ℃ 3 hours till not having solvent to steam, be warmed up to 85 ℃ again, 30 minutes.Stop to stir stopping to heat and obtain water base polyethersulfone dispersion liquid.
Embodiment 2
Trichloromethane 240ml and methyl alcohol 20ml thorough mixing are dissolved in above-mentioned mixing solutions with polyethersulfone 90g, make polyethersulfone solution.
The 8g Sodium dodecylbenzene sulfonate is dissolved in the 280ml deionized water.. sodium dodecyl benzene sulfonate aqueous solution is poured in the colloidal mill, again polyethersulfone solution is slowly added in the colloidal mill, disperse, make the polyethersulfone emulsion.
Pour the polyethersulfone emulsion that contains organic solvent of preparation into 1000 milliliters of there-necked flasks that whipping appts, condensing works are housed, in water-bath, heat, temperature controlling range 55 ℃ 3 hours 65 ℃ 3 hours till not having solvent to steam, be warmed up to 85 ℃ again, 30 minutes.Stop to stir stopping to heat and obtain water base polyethersulfone dispersion liquid.
Embodiment 3
Trichloromethane 240ml and methyl alcohol 10ml thorough mixing are dissolved in above-mentioned mixing solutions with polyethersulfone 90g.
The 6g Sodium dodecylbenzene sulfonate is dissolved in the 280ml deionized water.Sodium dodecyl benzene sulfonate aqueous solution is poured in the colloidal mill, again polyethersulfone solution is slowly added in the colloidal mill, disperse.
Pour the polyethersulfone emulsion that contains organic solvent of preparation into 1000 milliliters of there-necked flasks that whipping appts, condensing works are housed, in water-bath, heat, temperature controlling range 55 ℃ 2 hours, 65 ℃ 3 hours till not having solvent to steam, be warmed up to 80 ℃ again, 30 minutes.Stop to stir, stop heating and obtain water base polyethersulfone dispersion liquid.
Embodiment 4
Trichloromethane 240ml and methyl alcohol 15ml thorough mixing are dissolved in above-mentioned mixing solutions with polyethersulfone 60g.
The 4g Sodium dodecylbenzene sulfonate is dissolved in the 280ml deionized water.The above-mentioned aqueous solution is poured in the colloidal mill, again polyethersulfone solution is slowly added in the colloidal mill, disperse.
Pour the polyethersulfone emulsion that contains organic solvent of preparation into 1000 milliliters of there-necked flasks that whipping appts, condensing works are housed, in water-bath, heat, temperature controlling range 55 ℃ 2 hours 65 ℃ 3 hours till not having solvent to steam, be warmed up to 85 ℃ again, 30 minutes.Stop to stir, stop heating and obtain water base polyethersulfone dispersion liquid.
Embodiment 5
Trichloromethane 240ml and methyl alcohol 20ml thorough mixing, 4g is dissolved in above-mentioned mixing solutions with polyvinylpyrrolidone (PVP), and dissolving back fully is being dissolved in above-mentioned mixing solutions with polyethersulfone 90g.
The 8g Sodium dodecylbenzene sulfonate is dissolved in the 280ml deionized water.Sodium dodecyl benzene sulfonate aqueous solution is poured in the colloidal mill, again polyethersulfone solution is slowly added in the colloidal mill, disperse.
Pour the polyethersulfone emulsion that contains organic solvent of preparation into 1000 milliliters of there-necked flasks that whipping appts, condensing works are housed, in water-bath, heat, temperature controlling range 55 ℃ 2 hours 65 ℃ 3 hours till not having solvent to steam, be warmed up to 85 ℃ again, 30 minutes.Stop to stir, heating obtains water base polyethersulfone dispersion liquid.
Embodiment 6
Trichloromethane 240ml, 4g is dissolved in the above-mentioned solution with polyvinylpyrrolidone (PVP), and dissolving back fully is being dissolved in above-mentioned mixing solutions with polyethersulfone 90g.
The 8g Sodium dodecylbenzene sulfonate is dissolved in the 280ml deionized water.Sodium dodecyl benzene sulfonate aqueous solution is poured in the colloidal mill, again polyethersulfone solution is slowly added in the colloidal mill, disperse.
Pour the polyethersulfone emulsion that contains organic solvent of preparation into 1000 milliliters of there-necked flasks that whipping appts, condensing works are housed, in water-bath, heat, temperature controlling range 55 ℃ 2 hours 65 ℃ 3 hours till not having solvent to steam, be warmed up to 85 ℃ again, 30 minutes.Stop to stir, heating obtains water base polyethersulfone dispersion liquid.
Embodiment 7
With any poly (arylene ether) sulfone or have polyethersulfone in the poly arylidene ether sulfone alternate embodiment 1～6 of side group, can make corresponding aqueous-based dispersions.
Embodiment 8
Make the solvent of polyether sulphone base polymer with the trichloromethane in the methylene dichloride alternate embodiment 1～6, perhaps make the solubility promoter of polyether sulphone base polymer with the methyl alcohol in the hexanol alternate embodiment 1～6, the effect of products obtained therefrom and embodiment 1～6 are basic identical.
The preparation of embodiment 9 aqueous polyarylethersulphondispersion dispersion liquids
Make tensio-active agent with the polyvinylpyrrolidone (PVP) in polyvinyl alcohol (PVA) or polyoxyethylene glycol (PEG) alternate embodiment 1,5,6, perhaps use the Sodium dodecylbenzene sulfonate (DBS) in sodium laurylsulfonate (K12) or Nonyl pheno class (OP series) alternate embodiment 1～6 to make tensio-active agent, the effect of products obtained therefrom and embodiment 1～6 are basic identical.
Claims (7)
1, a kind of aqueous polyarylethersulphondispersion dispersion liquid is characterized in that, fundamental component is the poly arylidene ether sulfone that has side group that contains the poly (arylene ether) sulfone of repeating unit or contain repeating unit,
The said structure that contains the poly (arylene ether) sulfone of repeating unit is:
A：-O- -S-
B：
Wherein A be-O-or-S-; Wherein B be I or/and II or/and III; Wherein the relation of A and B is that A is or/and B;
The said poly arylidene ether sulfone that has side group that contains repeating unit, its side group is: carbonyl or carboxylate salt or sulfonic group or salt, amino or hydroxyl or epoxy group(ing) or thiazolinyl or alkyl or alkyl or cyano group;
Contain tensio-active agent Sodium dodecylbenzene sulfonate or sodium laurylsulfonate or Nonyl pheno class in the aqueous polyarylethersulphondispersion dispersion liquid.
According to the described aqueous polyarylethersulphondispersion dispersion liquid of claim 1, it is characterized in that 2, said tensio-active agent is a Sodium dodecylbenzene sulfonate, also contain polyvinylpyrrolidone.
According to claim 1 or 2 described aqueous polyarylethersulphondispersion dispersion liquids, it is characterized in that 3, its average particulate diameter of described aqueous polyarylethersulphondispersion dispersion liquid is: 0.01～10 μ m, the content of solid part is from 5～50%.
4, a kind of preparation method of aqueous polyarylethersulphondispersion dispersion liquid is characterized in that, said polyether sulphone base polymer is the poly arylidene ether sulfone that has side group that contains the poly (arylene ether) sulfone of repeating unit or contain repeating unit; Used organic solvent is methylene dichloride or trichloromethane; Solubility promoter is methyl alcohol or ethanol; Used tensio-active agent Sodium dodecylbenzene sulfonate or sodium laurylsulfonate or Nonyl pheno class; Preparation process has preparation poly (ether ketone ketone) polymers soln, prepares emulsion, boils off organic solvent:
Said preparation poly (ether ketone ketone) polymers soln process is, polyether sulphone is dissolved in the mixing solutions of organic solvent and solubility promoter, and wherein, be 4～30% by the content of mass ratio polyether sulphone base polymer; The content of solubility promoter is 12% or littler in the mixed solvent;
Said preparation emulsion process is, pours in the high speed dispersion device tensio-active agent is soluble in water earlier, and be 2～12% by the content of mass ratio tensio-active agent; Slowly pour the poly (ether ketone ketone) polymers soln into dispersion again, be prepared into poly (ether ketone ketone) emulsion;
The said organic solvent that boils off is, poly (ether ketone ketone) emulsion poured in the device that stirring is housed, reclaims, and feeds the pressurized air of trace, and controlled temperature is taken organic solvent out of for 50 ℃～85 ℃.
According to the preparation method of the described aqueous polyarylethersulphondispersion dispersion liquid of claim 4, it is characterized in that 5, in the said preparation poly (ether ketone ketone) polymers soln process, mixing solutions is that the organic solvent trichloromethane mixes mutually with solubility promoter methyl alcohol; Contain tensio-active agent polyvinylpyrrolidone or polyvinyl alcohol or polyoxyethylene glycol in the solution.
6, according to the preparation method of claim 4 or 5 described aqueous polyarylethersulphondispersion dispersion liquids, it is characterized in that said removal organic solvent process is earlier at 50～55 ℃ of constant temperature after 2～3 hour time, continue again to be warming up to 64～65 ℃, till not having organic solvent; Be warmed up to 75～85 ℃ again, constant temperature 0.5～1 hour.
7, a kind of application of aqueous polyarylethersulphondispersion dispersion liquid is characterized in that, said polyether sulphone base polymer is, contains the poly (arylene ether) sulfone of repeating unit or contains the poly arylidene ether sulfone that has side group of repeating unit; Make heat resisting coating or coating polymer usefulness, or make up, preparation coating with fluoro-resin.
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| CNB2005100166559A CN1302047C (en) | 2005-03-25 | 2005-03-25 | Aqueous polyarylethersulphones dispersion liquid and process for preparing same |
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| CNB2005100166559A CN1302047C (en) | 2005-03-25 | 2005-03-25 | Aqueous polyarylethersulphones dispersion liquid and process for preparing same |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101831177A (en) * | 2010-05-05 | 2010-09-15 | 吉林大学 | Formula and production process of water dispersible poly(ether ketone ketone) emulsion |
| CN103881118A (en) * | 2014-04-06 | 2014-06-25 | 吉林大学 | Preparation method of redispersible polyether sulphone micro powder |
| CN105153439A (en) * | 2015-07-21 | 2015-12-16 | 吉林大学 | Preparation method for water-based dispersion liquid of polyarylether polymers |
| CN108314962A (en) * | 2018-02-07 | 2018-07-24 | 吉林大学 | The polyether sulphone of cyano-containing/Polyethersulfone Coating composition and preparation method thereof and coating processes |
| CN110776642A (en) * | 2018-07-30 | 2020-02-11 | 天津大学 | Blend, blend film, preparation method of blend film and application of blend film in super capacitor |
| CN113354834A (en) * | 2021-07-26 | 2021-09-07 | 浙江鹏孚隆新材料有限公司 | Heat-resistant hydrolysis-resistant engineering plastic dispersion liquid, and preparation method and application thereof |
| CN114805811A (en) * | 2022-05-31 | 2022-07-29 | 浙江鹏孚隆新材料有限公司 | Polyarylether resin containing carboxyl side group, synthesis method and application of polyarylether resin in coating |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4945154A (en) * | 1989-07-07 | 1990-07-31 | Hexcel Corporation | Densified polyethersulfone |
| BR9405783A (en) * | 1993-01-08 | 1995-12-19 | Basf Ag | Micropowder process for obtaining micropowders that contain polyarylene ether-sulfones or ketones as an essential component |
| CN1162460C (en) * | 2001-08-14 | 2004-08-18 | 上海交通大学 | Polyester sulphone with lateral carboxylate group and its prepn |
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2005
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| CN114805811A (en) * | 2022-05-31 | 2022-07-29 | 浙江鹏孚隆新材料有限公司 | Polyarylether resin containing carboxyl side group, synthesis method and application of polyarylether resin in coating |
| CN114805811B (en) * | 2022-05-31 | 2023-08-25 | 浙江鹏孚隆新材料有限公司 | Polyarylether resin containing carboxyl side group, synthesis method and application thereof in coating aspect |
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