CN1632072A - Combined device for light oil product alkaline extraction-fixed bed catalytic oxidation sweetening - Google Patents
Combined device for light oil product alkaline extraction-fixed bed catalytic oxidation sweetening Download PDFInfo
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- CN1632072A CN1632072A CN 200410096436 CN200410096436A CN1632072A CN 1632072 A CN1632072 A CN 1632072A CN 200410096436 CN200410096436 CN 200410096436 CN 200410096436 A CN200410096436 A CN 200410096436A CN 1632072 A CN1632072 A CN 1632072A
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- catalytic oxidation
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- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 25
- 230000003197 catalytic effect Effects 0.000 title claims abstract description 18
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- 239000007788 liquid Substances 0.000 claims abstract description 60
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 32
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 32
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims abstract description 27
- 238000000605 extraction Methods 0.000 claims abstract description 20
- 238000000034 method Methods 0.000 claims abstract description 19
- 230000008929 regeneration Effects 0.000 claims abstract description 16
- 238000011069 regeneration method Methods 0.000 claims abstract description 16
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 7
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- 238000004140 cleaning Methods 0.000 claims description 15
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- 239000003054 catalyst Substances 0.000 claims description 12
- 238000004062 sedimentation Methods 0.000 claims description 8
- 239000007795 chemical reaction product Substances 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- -1 gac Chemical class 0.000 claims description 2
- 230000008676 import Effects 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 229910052748 manganese Inorganic materials 0.000 claims description 2
- 229920003240 metallophthalocyanine polymer Polymers 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- 229910004298 SiO 2 Inorganic materials 0.000 claims 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 claims 1
- 239000004480 active ingredient Substances 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- 239000004411 aluminium Substances 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 229910052680 mordenite Inorganic materials 0.000 claims 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical class [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims 1
- 239000007789 gas Substances 0.000 abstract description 24
- 230000008569 process Effects 0.000 abstract description 13
- 230000000694 effects Effects 0.000 abstract description 12
- 238000007670 refining Methods 0.000 abstract description 7
- 238000006477 desulfuration reaction Methods 0.000 abstract description 4
- 239000002699 waste material Substances 0.000 abstract description 4
- 230000008901 benefit Effects 0.000 abstract description 3
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- 230000023556 desulfurization Effects 0.000 abstract description 2
- 150000003573 thiols Chemical class 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 58
- 235000011121 sodium hydroxide Nutrition 0.000 description 27
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 11
- 229910052717 sulfur Inorganic materials 0.000 description 8
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- 238000005516 engineering process Methods 0.000 description 7
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
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- MPMSMUBQXQALQI-UHFFFAOYSA-N cobalt phthalocyanine Chemical class [Co+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 MPMSMUBQXQALQI-UHFFFAOYSA-N 0.000 description 2
- 235000009508 confectionery Nutrition 0.000 description 2
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- 239000000945 filler Substances 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
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- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
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- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
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- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
A process for removing thiol from light oil by liquid-liquid alkali extraction and fixed-bed catalytic oxidation. It mainly adopts the mode of combining liquid-liquid alkali extraction and fixed bed catalytic oxidation regeneration process to attain the goal of refining liquefied gas and other light hydrocarbons. The device has simple flow, convenient operation and good mercaptan removal and desulfurization effects. The economic benefit and the environmental protection effect are obvious, and compared with the prior sweetening process, the method can reduce the discharge amount of waste alkali liquor by 80 percent. The invention is suitable for refining liquid hydrocarbons or gaseous hydrocarbons such as domestic and foreign factories and mines, enterprise liquefied gas, oil field natural gas, light hydrocarbons, gasoline, diesel oil and the like, and has wide industrial application prospect.
Description
Technical field
The present invention relates to a kind ofly adopt liquid-liquor alkali extracting and fixed bed catalytic oxidation to combine to carry out the technology of light-end products mercaptan removal.The light-end products here refer to liquefied hydrocarbon or gaseous hydrocarbonss such as refinery's liquefied gas, oil field Sweet natural gas, lighter hydrocarbons and gasoline, diesel oil.This invention is the improvement to oil, chemical enterprise oil purification method, and the mode that it mainly adopts liquid-liquor alkali extracting and fixed bed catalytic oxidation reclaiming process to combine reaches liquefied gas and other light hydrocarbon purified purpose.
Background technology
The main component of liquefied petroleum gas (LPG) is C
3, C
4Component is widely used as industry, domestic gas; Can also in occupation of huge industrial chemicals market, be used for the Chemicals of production high added value for the olefin component of chemical utilization (mainly being third rare, iso-butylene and 1-butylene) owing to be rich in.Along with the increase of liquefied gas output and market to C
3, C
4The expansion of the Chemicals demand that alkene is made, for increasing overall economic efficiency, most of refineries begin sight is aimed at the utilization of the liquefied gas degree of depth.And to the abundant reasonable use of LPG, matter of utmost importance is exactly the LPG desulfurizing and purifying, and it is to guarantee that LPG carries out the key of deep processing chemical utilization.
Mercaptan has stench and slightly acidic, and reactive behavior is also stronger, metal is produced corrosion and accelerated corrosion under certain condition, and burning can cause environmental pollution.In addition, the C that from liquefied gas, separates
= 3, C
= 4Component is during as industrial chemicals, and mercaptan wherein easily makes the catalyst deactivation in the downstream process.
Because sulfide is to the influence of its use properties and to the pollution of environment in the liquefied gas, the liquefied gas sulphur content has all been set strict standard both at home and abroad.When domestic LPG is used as industry and domestic fuel, require total sulfur content＜343mgm
-3, copper corrosion is necessary＜and 1 grade; If as industrial chemicals, then require tighter.Polypropylene plant requires total sulfur content＜5 * 10 in the raw material propylene
-6, 1-butylene is made industrial chemicals, and then to require total sulfur be 10
-6-5 * 10
-6, the C of IFP (IFP) exploitation
4Selectivity coincides process catalyst requirement feed sulphur content less than 5 * 10
-6
At present, China's refinery's liquid gas sweetening mainly adopts Merox agent alkali extracting-liquid phase catalytic oxidation doctor process.In extraction tower, the reaction of the mercaptan in the liquefied gas and agent alkaline solution (sulfonated phthalocyanine cobalt alkali lye) generate sodium mercaptides and transfer to alkali mutually in; Enter the oxidation regeneration tower with the agent alkali lye after liquefied gas separates, under air effect, the sodium mercaptides in the alkali lye is oxidized to disulphide, realizes removing of mercaptan, while alkali lye, catalyst regeneration, recycle.Liquid gas sweetening technology mainly contains following shortcoming at present: phthalocyanine cobalt class catalyzer is in alkali phase (liquid catalyst) and assembles inactivation easily, cause frequently more catalyst changeout, and the cost of catalyzer quite high (ten thousand yuan/ton of 80-100) makes simultaneously and produces the influence that is subjected to a certain degree; Liquefied gas carries out the mercaptan extracting with the alkali lye that contains catalyzer, and sodium mercaptides easily generates disulphide and is brought in the liquefied gas product after refining under the catalyzer existence condition, reduces and takes off the total sulfur effect, usually can not reach total sulfur content＜10 * 10
-6Requirement, the production in back step is affected; When liquefied gas carried out the mercaptan extracting with the alkali lye that contains catalyzer, extraction efficiency was not high; Device is irregularly discharged the waste lye that contains catalyzer, owing to have stink and color is extremely difficult, environmental protection pressure is big.
Summary of the invention
The associated plant that purpose of the present invention is provided for light oil product alkaline extraction-fixed bed catalytic oxidation sweetening with regard to being to avoid above-mentioned the deficiencies in the prior art part.It mainly is that the method that adopts liquid-liquor alkali extracting and fixed bed catalytic oxidation to combine is carried out mercaptan removal to light-end products, the major technique characteristics of this device are that the reverse contact extraction tower of liquid-liquid, liquid-liquid static mixer, settlement separate jar, the alkali liquor oxidized regenerator column of extracting and the extracting alkali lye disulphide back suction stripper needs according to product are combined, it is the front end that the reverse contact extraction tower of liquid-liquid is arranged on device, its top outlet is connected with liquid-liquid static mixer, and the bottom outlet is connected with the import of the alkali liquor oxidized regenerator column of extracting; The outlet of liquid-liquid static mixer then is connected with settlement separate jar, and settlement separate pot bottom outlet is connected with the alkali liquor oxidized regenerator column of extracting, and its top is provided with products export; Alkali liquor oxidized regenerator column of extracting and extracting alkali lye disulphide back suction stripper then constitute the regeneration system rapidly of extracting alkali lye, but the reverse contact extraction tower of alkali lye rework solution-liquid after its regeneration recycles.Can be in the actually operating according to treating that the purified liquid hydrocarbon product requires to form different technical process.
Description of drawings
Accompanying drawing is process flow sheet of the present invention, wherein:
1----is equipped with inside the reverse contact extraction tower of liquid-liquid of column plate or filler
2----liquid-liquid static mixer;
Settlement separate jar of 3----;
4----is equipped with inside the alkali liquor oxidized regenerator column of extracting of fixed bed catalyst
5----is equipped with inside the extracting alkali lye disulphide back suction stripper of column plate or filler
Embodiment
Come enumeration technical characterstic of the present invention below in conjunction with specific embodiment.
In the actual process operation,, mainly be the associated plant of implementing this dose of product alkaline extraction-fixed bed catalytic oxidation mercaptan removal by following several modes according to the refining requirement of liquid towards hydrocarbon.
1. through the liquid hydrocarbon of alkali cleaning (liquid alkali cleaning or solid alkali cleaning) or not alkali cleaning, the reverse contact extraction tower of feed liquor-liquid carries out the mercaptan extracting, and the liquid hydrocarbon behind the mercaptan removal directly advances the slurry tank sedimentation, and the liquid hydrocarbon after sedimentation removes the treatment unit in back step etc. again.
2. through the liquid hydrocarbon of alkali cleaning (liquid alkali cleaning or solid alkali cleaning) or not alkali cleaning, directly pass through liquid-liquid static mixer, enter settlement separate jar then, the liquid hydrocarbon after sedimentation removes the treatment unit in back step etc. again.
3. through the liquid hydrocarbon of alkali cleaning (liquid alkali cleaning or solid alkali cleaning) or not alkali cleaning, the reverse contact extraction tower of elder generation's feed liquor-liquid carries out the mercaptan extracting, liquid hydrocarbon passes through liquid-liquid static mixer more then, and the liquid hydrocarbon after settlement separate jar of sedimentation removes the treatment unit in back step etc.Liquid hydrocarbon is further mercaptan removal through the purpose of static mixer, is to provide enough assurances for reaching the liquid hydrocarbon mercaptan removal refining effect after the whole device dilatation.
4. the alkali lye of drawing from extraction tower or slurry tank removes fixed bed oxidizing tower oxidation regeneration, and the alkali lye after the regeneration is introduced the back suction stripper again and carried out back suction with lighter hydrocarbons and carry disulphide (whether needing the back suction stripper to decide on the production needs) in the alkali lye.Alkali lye after oxidation regeneration or back suction are carried recycles.
In the actual motion operation,, be the oxidation regeneration of realizing extracting alkali lye in the mode of fixed bed catalyst catalyzing oxidized regeneration from the reverse contact extraction tower of liquid-liquid or settlement separate jar of extracting alkali lye of drawing.Used agent alkali comprises neat liquid sodium hydroxide, contain the catalyst activity component be in the metallo phthalocyanines such as Co, Fe, Mn, V, Ni, Cu one or more liquid caustic soda, contain extracting solubility promoter alcohols, quaternary ammonium salt, quaternary ammonium bases, contain one or more liquid caustic soda such as oxygen nonionic surfactants, alcamines, urea.The concentration of liquid caustic soda is 5-15 (m) %, and the catalyst activity concentration of component is 5-300 μ g/g, and the content of various extracting solubility promoters is 0.5-10 (m) %.
The invention effect
Compared with prior art, the present invention has following outstanding advantage:
1, uses the alkali lye that does not contain catalyzer to carry out extracting in the liquefied gas mercaptan extracting stage, can improve the mercaptan extraction efficiency; Can prevent that mercaptan is oxidized to disulphide, improve desulfurization depth;
2, at oxidation stage, make the alkali lye that contains sodium mercaptides pass through the fixed bed catalyst bed with air, can improve efficient and alkali liquid regeneration efficient that sodium mercaptides is oxidized to disulphide;
3, with the reverse contact extraction tower of liquid-liquid and liquid-liquid static mixer two portions associating, can improve mercaptan removal, desulfuration purification effect.Because this two portions equipment can serial operation, be equivalent to two step continuous treatings, compare with an original one-step refining, to improve mercaptan removal, the desulfuration purification effect is highly beneficial;
4, pay attention to removing of micro-disulphide in the circulation alkali liquor, kept extractant itself totally; Do not cause disulphide wherein to return the liquefied gas that depollutes again, can reduce total sulfur content.
5, active high, the long service life of fixed bed catalyst is easy to operate.Compare with liquefied gas agent alkali extracting-liquid phase catalytic oxidation doctor process, this technology can reduce the waste lye quantity discharged, can obviously alleviate site operation personnel's labour intensity;
6, the technology mercaptan removal is effective, generally makes mercaptan sulfur below 10 μ g/g.Device takes off the total sulfur effect, can reach sulphur content standard-required in the liquefied gas.
If transform on original device, projected investment is ten thousand yuans of 100-200.Adopt the process cost of present technique liquefied refinery gas can not increase, but can reduce the spent lye treatment expense, improve refining effect than prior art.
This device flow process is simple, easy to operate, and mercaptan removal, sweetening effectiveness are good.Economic benefit and environment protecting are obvious.If with year treatment capacity be that 500,000 tons catalytic cracking liquefied gas deodorization device calculates, compare with present doctor process, can reduce waste lye quantity discharged 1/2nd.In environmental requirement strict more today, this technology has the unrivaled environment protection significance of other deodorizing technology.Therefore, the present invention is suitable for the treating process of liquefied hydrocarbons such as domestic and international factories and miness, enterprise's liquefied gas, oil field Sweet natural gas, lighter hydrocarbons and gasoline, diesel oil or gaseous hydrocarbons, has wide prospect in industrial application.
Claims (6)
1. the associated plant that is used for light oil product alkaline extraction-fixed bed catalytic oxidation sweetening, it is that the method that adopts liquid-liquor alkali extracting and fixed bed catalytic oxidation to combine is carried out mercaptan removal to light-end products, it is characterized in that this device is with the reverse contact extraction tower of liquid-liquid, liquid-liquid static mixer, settlement separate jar, alkali liquor oxidized regenerator column of extracting and extracting alkali lye disulphide back suction stripper combine according to the needs of product, it is the front end that the reverse contact extraction tower of liquid-liquid is arranged on device, its top outlet is connected with liquid-liquid static mixer, and the bottom outlet is connected with the import of the alkali liquor oxidized regenerator column of extracting; The outlet of liquid-liquid static mixer then is connected with settlement separate jar, and settlement separate pot bottom outlet is connected with the alkali liquor oxidized regenerator column of extracting, and its top is provided with products export; Alkali liquor oxidized regenerator column of extracting and extracting alkali lye disulphide back suction stripper then constitute the regeneration system rapidly of extracting alkali lye, but the reverse contact extraction tower of alkali lye rework solution-liquid after its regeneration recycles.
2. the associated plant that is used for light oil product alkaline extraction-fixed bed catalytic oxidation sweetening according to claim 1, it is characterized in that the catalyzer in the alkali liquor oxidized regenerator column of extracting is that active ingredient is metallo phthalocyanines such as Co, Fe, Mn, V, Ni, Cu, carrier is γ-Al
2O
3, η-Al
2O
3, SiO
2, each molecular sieve analog, gac, activated carbon fiber, mordenite, low aluminium and high aluminum silicate fixed bed catalyst.
3. the associated plant that is used for light oil product alkaline extraction-fixed bed catalytic oxidation sweetening according to claim 1, it is characterized in that liquid hydrocarbon through alkali cleaning, the reverse contact extraction tower of feed liquor-liquid carries out the mercaptan extracting, liquid hydrocarbon behind the mercaptan removal directly advances the slurry tank sedimentation, and the liquid hydrocarbon after sedimentation removes the back treatment unit in step again.
4. the associated plant that is used for light oil product alkaline extraction-fixed bed catalytic oxidation sweetening according to claim 1, it is characterized in that liquid hydrocarbon through alkali cleaning, directly through liquid-liquid static mixer, enter settlement separate jar then, the liquid hydrocarbon after sedimentation removes the back treatment unit in step again.
5. the associated plant that is used for light oil product alkaline extraction-fixed bed catalytic oxidation sweetening according to claim 1, it is characterized in that liquid hydrocarbon through alkali cleaning, the reverse contact extraction tower of elder generation's feed liquor-liquid carries out the mercaptan extracting, liquid hydrocarbon passes through liquid-liquid static mixer more then, and the liquid hydrocarbon after settlement separate jar of sedimentation removes the back treatment unit in step again.
6. the associated plant that is used for light oil product alkaline extraction-fixed bed catalytic oxidation sweetening according to claim 1, it is characterized in that removing the alkali liquor oxidized regenerator column oxidation regeneration of extracting from the reverse contact extraction tower of liquid-liquid or settlement separate jar of alkali lye of drawing, alkali lye after the regeneration is introduced extracting alkali lye disulphide back suction stripper again and is carried out back suction with lighter hydrocarbons and carry disulphide in the alkali lye, and the alkali lye after oxidation regeneration or back suction are carried can be recycled.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410096436 CN1283760C (en) | 2004-12-01 | 2004-12-01 | Combined device for light oil product alkaline extraction-fixed bed catalytic oxidation sweetening |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410096436 CN1283760C (en) | 2004-12-01 | 2004-12-01 | Combined device for light oil product alkaline extraction-fixed bed catalytic oxidation sweetening |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1632072A true CN1632072A (en) | 2005-06-29 |
| CN1283760C CN1283760C (en) | 2006-11-08 |
Family
ID=34847861
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410096436 Expired - Fee Related CN1283760C (en) | 2004-12-01 | 2004-12-01 | Combined device for light oil product alkaline extraction-fixed bed catalytic oxidation sweetening |
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|---|---|
| CN (1) | CN1283760C (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100460483C (en) * | 2005-12-27 | 2009-02-11 | 中国石油化工股份有限公司 | Method and device for lye extraction desulfurization |
| CN100462146C (en) * | 2006-11-07 | 2009-02-18 | 北京三聚环保新材料股份有限公司 | Method for preparing catalyst for converting mercaptan in gasoline |
| CN100462145C (en) * | 2006-11-07 | 2009-02-18 | 北京三聚环保新材料股份有限公司 | Method for preparing catalyst for converting mercaptan in liquefied gas |
| CN101705108B (en) * | 2009-12-11 | 2012-09-05 | 郝天臻 | Liquid hydrocarbon mercaptan removal technique capable of deeply removing total sulfur |
| CN103087761A (en) * | 2013-02-06 | 2013-05-08 | 山东寿光鲁清石化有限公司 | Gasoline sweetening device |
| CN103911177A (en) * | 2014-03-07 | 2014-07-09 | 武汉纺织大学 | Deep desulfurization method for saturated liquid hydrocarbon |
| CN106978207A (en) * | 2016-01-15 | 2017-07-25 | 中国石油化工股份有限公司 | A kind of method of sulfur-bearing lighter hydrocarbons deep desulfuration |
| CN110857402A (en) * | 2018-08-22 | 2020-03-03 | 中国石油化工股份有限公司 | Combined processing technology of catalytic cracking gasoline |
| CN112824500A (en) * | 2019-11-20 | 2021-05-21 | 中国石化工程建设有限公司 | Method and system for removing hydrogen sulfide in liquid hydrocarbon by amine |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101319150B (en) * | 2007-06-07 | 2010-09-15 | 中国石油化工股份有限公司 | Hot-soda washing desulfurization method |
-
2004
- 2004-12-01 CN CN 200410096436 patent/CN1283760C/en not_active Expired - Fee Related
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100460483C (en) * | 2005-12-27 | 2009-02-11 | 中国石油化工股份有限公司 | Method and device for lye extraction desulfurization |
| CN100462146C (en) * | 2006-11-07 | 2009-02-18 | 北京三聚环保新材料股份有限公司 | Method for preparing catalyst for converting mercaptan in gasoline |
| CN100462145C (en) * | 2006-11-07 | 2009-02-18 | 北京三聚环保新材料股份有限公司 | Method for preparing catalyst for converting mercaptan in liquefied gas |
| CN101705108B (en) * | 2009-12-11 | 2012-09-05 | 郝天臻 | Liquid hydrocarbon mercaptan removal technique capable of deeply removing total sulfur |
| CN103087761B (en) * | 2013-02-06 | 2014-12-03 | 山东寿光鲁清石化有限公司 | Gasoline sweetening device |
| CN103087761A (en) * | 2013-02-06 | 2013-05-08 | 山东寿光鲁清石化有限公司 | Gasoline sweetening device |
| CN103911177A (en) * | 2014-03-07 | 2014-07-09 | 武汉纺织大学 | Deep desulfurization method for saturated liquid hydrocarbon |
| CN103911177B (en) * | 2014-03-07 | 2015-11-18 | 湖北华邦化学有限公司 | A kind of saturated liquid hydrocarbon deep desulfurization method |
| CN106978207A (en) * | 2016-01-15 | 2017-07-25 | 中国石油化工股份有限公司 | A kind of method of sulfur-bearing lighter hydrocarbons deep desulfuration |
| CN106978207B (en) * | 2016-01-15 | 2019-02-01 | 中国石油化工股份有限公司 | A kind of method of sulfur-bearing lighter hydrocarbons deep desulfuration |
| CN110857402A (en) * | 2018-08-22 | 2020-03-03 | 中国石油化工股份有限公司 | Combined processing technology of catalytic cracking gasoline |
| CN110857402B (en) * | 2018-08-22 | 2023-06-06 | 中国石油化工股份有限公司 | Combined processing technology of catalytic cracking gasoline |
| CN112824500A (en) * | 2019-11-20 | 2021-05-21 | 中国石化工程建设有限公司 | Method and system for removing hydrogen sulfide in liquid hydrocarbon by amine |
| CN112824500B (en) * | 2019-11-20 | 2022-11-01 | 中国石化工程建设有限公司 | Method and system for removing hydrogen sulfide in liquid hydrocarbon by amine |
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