CN1629262A - Coal additive - Google Patents
Coal additive Download PDFInfo
- Publication number
- CN1629262A CN1629262A CN 200310107752 CN200310107752A CN1629262A CN 1629262 A CN1629262 A CN 1629262A CN 200310107752 CN200310107752 CN 200310107752 CN 200310107752 A CN200310107752 A CN 200310107752A CN 1629262 A CN1629262 A CN 1629262A
- Authority
- CN
- China
- Prior art keywords
- accounts
- sodium
- coal
- mantoquita
- coal combustion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003245 coal Substances 0.000 title claims abstract description 22
- 239000000654 additive Substances 0.000 title abstract description 5
- 230000000996 additive effect Effects 0.000 title abstract description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 18
- 239000000203 mixture Substances 0.000 claims abstract description 14
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 claims abstract description 12
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910021538 borax Inorganic materials 0.000 claims abstract description 11
- 238000002485 combustion reaction Methods 0.000 claims abstract description 11
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims abstract description 11
- 239000001095 magnesium carbonate Substances 0.000 claims abstract description 11
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims abstract description 11
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 11
- 239000011572 manganese Substances 0.000 claims abstract description 11
- 239000004576 sand Substances 0.000 claims abstract description 11
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 11
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 11
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 9
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000011575 calcium Substances 0.000 claims abstract description 8
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 6
- 235000014380 magnesium carbonate Nutrition 0.000 claims description 10
- 229960001708 magnesium carbonate Drugs 0.000 claims description 10
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 claims description 9
- 235000017550 sodium carbonate Nutrition 0.000 claims description 8
- 235000012204 lemonade/lime carbonate Nutrition 0.000 claims description 6
- 238000009423 ventilation Methods 0.000 claims description 5
- 235000003599 food sweetener Nutrition 0.000 claims description 4
- 239000003765 sweetening agent Substances 0.000 claims description 4
- 230000008961 swelling Effects 0.000 claims description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 2
- 239000002671 adjuvant Substances 0.000 abstract 1
- 238000003915 air pollution Methods 0.000 abstract 1
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 abstract 1
- 230000001007 puffing effect Effects 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- 239000002994 raw material Substances 0.000 description 10
- 230000000694 effects Effects 0.000 description 9
- 238000010298 pulverizing process Methods 0.000 description 5
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 4
- 239000000446 fuel Substances 0.000 description 3
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 229960004643 cupric oxide Drugs 0.000 description 2
- 239000003500 flue dust Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- -1 mantoquita Chemical compound 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 229940001516 sodium nitrate Drugs 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Solid Fuels And Fuel-Associated Substances (AREA)
Abstract
The invention provides a coal additive which comprises 15-25 wt% of combustion adjuvant composing the mixture of nantokite, sodium chlorate and manganese sand, 50-70% of scale remover composing the mixture of borax, sodium chloride and magnesium carbonate, 4-6% of sodium carbonate desulfurizer, and 10-20% of lightweight calcium puffing agent. The invention can improve coal combustion efficiency, save energy and lower air pollution by the fire coal.
Description
(1), affiliated field
What the present invention relates to is a kind of auxiliary agent of fuel.Specifically a kind of additive for fire coal with combustion-supporting, scale removal, reduction pollutant emission.
(2), background technology
Coal is a kind of important fuel, widespread use in many heating boilers and station boiler.Scatter fire of raw coal, not only thermo-efficiency is low, energy consumption is big, production cost is high, and owing to contain a large amount of objectionable impuritiess such as sulphur in the raw coal, can produce a large amount of noxious gas emissions.Because the obnoxious flavour that coal burning discharged has become atmospheric primary pollution source.In order to reduce coal burning to atmospheric pollution, improve the efficiency of combustion of coal, save energy reduces production costs, and some additive for fire coal also occurred seeing year.For example coal-saving agent, coal-fired promotor, ignition dope etc.They mainly are to be ignition dope with permanganate, carbonate, calcium oxide, are dedusting agent with SODIUMNITRATE, mantoquita, magnesiumcarbonate, are sweetening agent with soda ash, calcium oxide.Not only it is combustion-supporting for these additives, dust removing effects has much room for improvement, and does not have descaling function.
(3), summary of the invention
The object of the present invention is to provide a kind of combustion-supporting, good dedusting effect, have the coal combustion improver of good descaling function.
The object of the present invention is achieved like this: its weight consists of the ignition dope that the mixture by mantoquita, sodium chlorate, manganese sand of 15-25% is formed, the scale remover that the mixture by borax, sodium-chlor, magnesiumcarbonate of 50-70% is formed, the yellow soda ash sweetening agent of 4-6%, the light weight calcium swelling agent of 10-20%.
The present invention can also comprise like this some features: 1, mantoquita accounts for that 2-4%, sodium chlorate account for 8-12%, manganese sand accounts for 5-9% in the ignition dope that accounts for gross weight 15-25%.2, borax accounts for that 7-13%, sodium-chlor account for 40-50%, magnesiumcarbonate accounts for 3-7% in the scale remover that accounts for gross weight 50-70%.3, described mantoquita is a ventilation breather, and described light weight calcium is a lime carbonate.
The present invention is the mixture of multiple material, and each material cooperatively interacts, coordinates, and its major advantage is embodied in: 1, combustion-supporting effect obviously is better than other ignition dope, and can produce combustion-supporting effect rapidly.Mantoquita can resolve into cupric oxide after being heated, heavy metal has the effect of catalyzer, can play anticorrosion heat transfer effect at boiler tube surface attachment layer protecting film simultaneously.Sodium chlorate in the ignition dope is a strong oxidizer, and decomposes can produce active oxygen, can be rapidly and the coal reactive combustion.The Manganse Dioxide that contains in the manganese sand can play the effect that promotes that sodium chlorate is decomposed.2, features high scale-removing effect.General like product only lays particular emphasis on combustion-supporting, and has ignored the function of scale removal.Scale removal can effectively increase heat exchange area, improves heat-transfer effect, and the burnt dirt that facts have proved 1mm thickness may cause the waste of fuel more than 10%.Borax among the present invention can with the reactive metal oxide in the burnt dirt, dirt is come off, simultaneously can play preservative activity again.Be product monitoring result of the present invention below:
| Project | Coal looses | Additivated coal |
| Flue dust average emission concentration (mg/m 3) | ????1583 | ????1040 |
| Flue dust average discharge (kg/h) | ????55.37 | ????17.57 |
| Sulfurous gas average emission concentration (mg/m 3) | ????251.2 | ????207.8 |
| Sulfurous gas average discharge (kg/h) | ????3.20 | ????1.27 |
| Oxynitride average emission concentration (mg/m 3) | ????76.3 | ????51.8 |
| Oxynitride average discharge (kg/h) | ????0.97 | ????0.32 |
| Lingemann blackness (level) | ??????????????????＜1 | |
(4) specific embodiments
For example the present invention is done in more detail below and describes:
1, consists of the ignition dope that the mixture by mantoquita, sodium chlorate, manganese sand of 15-25% is formed by weight, the scale remover that the mixture by borax, sodium-chlor, magnesiumcarbonate of 50-70% is formed, the yellow soda ash sweetening agent of 4-6%, the ratio of the light weight calcium swelling agent of 10-20% is got raw material ready.With each raw material pulverizing, mix and make product.
2, get raw material ready in the ratio of mantoquita 2-4%, sodium chlorate 8-12%, manganese sand 5-9%, borax 7-13%, sodium-chlor 40-50%, magnesiumcarbonate 3-7%, yellow soda ash 4-6%, light weight calcium 10-20%.With each raw material pulverizing, mix and make product.
3, get raw material ready in the ratio of ventilation breather 2-4%, sodium chlorate 8-12%, manganese sand 5-9%, borax 7-13%, sodium-chlor 40-50%, magnesiumcarbonate 3-7%, yellow soda ash 4-6%, lime carbonate 10-20%.With each raw material pulverizing, mix and make product.
4, get raw material ready in the ratio of cupric oxide 2-4%, sodium chlorate 8-12%, manganese sand 5-9%, borax 7-13%, sodium-chlor 40-50%, magnesiumcarbonate 3-7%, yellow soda ash 4-6%, lime carbonate 10-20%.With each raw material pulverizing, mix and make product.
5, get raw material ready in the ratio of ventilation breather 3%, sodium chlorate 10%, manganese sand 7%, borax 10%, sodium-chlor 45%, magnesiumcarbonate 5%, yellow soda ash 5%, lime carbonate 15%.With each raw material pulverizing, mix and make product.
Claims (5)
1, a kind of coal combustion improver, it is characterized in that: its weight consists of the ignition dope that the mixture by mantoquita, sodium chlorate, manganese sand of 15-25% is formed, the scale remover that the mixture by borax, sodium-chlor, magnesiumcarbonate of 50-70% is formed, the yellow soda ash sweetening agent of 4-6%, the light weight calcium swelling agent of 10-20%.
2, coal combustion improver according to claim 1 is characterized in that: mantoquita accounts for that 2-4%, sodium chlorate account for 8-12%, manganese sand accounts for 5-9% in the ignition dope that accounts for gross weight 15-25%.
3, coal combustion improver according to claim 1 and 2 is characterized in that: borax accounts for that 7-13%, sodium-chlor account for 40-50%, magnesiumcarbonate accounts for 3-7% in the scale remover that accounts for gross weight 50-70%.
4, coal combustion improver according to claim 1 and 2 is characterized in that: described mantoquita is a ventilation breather, and described light weight calcium is a lime carbonate.
5, coal combustion improver according to claim 3 is characterized in that: described mantoquita is a ventilation breather, and described light weight calcium is a lime carbonate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200310107752 CN1247751C (en) | 2003-12-17 | 2003-12-17 | Coal additive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200310107752 CN1247751C (en) | 2003-12-17 | 2003-12-17 | Coal additive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1629262A true CN1629262A (en) | 2005-06-22 |
| CN1247751C CN1247751C (en) | 2006-03-29 |
Family
ID=34843016
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200310107752 Expired - Fee Related CN1247751C (en) | 2003-12-17 | 2003-12-17 | Coal additive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1247751C (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1332000C (en) * | 2006-01-12 | 2007-08-15 | 张新明 | Desulfate agent for fuel coal and preparation process thereof |
| CN101649240A (en) * | 2009-06-12 | 2010-02-17 | 袁锁营 | Multifunctional coal-fired energy-saving additive |
| CN120059817A (en) * | 2025-02-26 | 2025-05-30 | 陕西久泰腾飞化工材料有限公司 | Coal-saving desulfurization decoking catalyst for boiler and application method thereof |
-
2003
- 2003-12-17 CN CN 200310107752 patent/CN1247751C/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1332000C (en) * | 2006-01-12 | 2007-08-15 | 张新明 | Desulfate agent for fuel coal and preparation process thereof |
| CN101649240A (en) * | 2009-06-12 | 2010-02-17 | 袁锁营 | Multifunctional coal-fired energy-saving additive |
| CN101649240B (en) * | 2009-06-12 | 2013-12-18 | 袁锁营 | Multifunctional coal-fired energy-saving additive |
| CN120059817A (en) * | 2025-02-26 | 2025-05-30 | 陕西久泰腾飞化工材料有限公司 | Coal-saving desulfurization decoking catalyst for boiler and application method thereof |
| CN120059817B (en) * | 2025-02-26 | 2025-08-26 | 陕西久泰腾飞化工材料有限公司 | A coal-saving, desulfurizing and decoking catalyst for boilers and its application method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1247751C (en) | 2006-03-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |