CN1614108A - Production for wool textile containing regenerating animal azelon - Google Patents

Production for wool textile containing regenerating animal azelon Download PDF

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Publication number
CN1614108A
CN1614108A CN 200410065375 CN200410065375A CN1614108A CN 1614108 A CN1614108 A CN 1614108A CN 200410065375 CN200410065375 CN 200410065375 CN 200410065375 A CN200410065375 A CN 200410065375A CN 1614108 A CN1614108 A CN 1614108A
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China
Prior art keywords
animal protein
wool
regenerated
protein fiber
add
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CN 200410065375
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Chinese (zh)
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CN100422411C (en
Inventor
赵国英
张建良
张新龙
杨自冶
白唯义
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凯诺科技股份有限公司
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Priority to CNB2004100653752A priority Critical patent/CN100422411C/en
Publication of CN1614108A publication Critical patent/CN1614108A/en
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Abstract

A spun wool fabric containing regenerated animal protein fibres is prepared through loosening the regenerated animal protein fibres, slivering, pretreating, dyeing, mixing it with wool sliver, spinning, warp beaming, weaving, trimming and finishing. It has the both styles of wool fabric and silk fabric.

Description

The production method that contains the wool blending fabric of regenerated animal protein fiber
Technical field:
The present invention relates to a kind of production method of wool blending fabric, especially relate to a kind of production method that contains the wool blending fabric of regenerated animal protein fiber.Belong to woolen spinning technical field.
Background technology:
Regenerated animal protein fiber is can not spin azelon and some with some can not to discard albumen be raw material, utilize the Biochemical Engineering technology therefrom leach protein handle via other auxiliary agent, with the wet method regeneration novel protein fiber that spins.This fibre property is good, far below natural protein fiber, has the extremely strong market competitiveness on the price.
Summary of the invention:
The object of the present invention is to provide a kind of production method that contains the wool blending fabric of regenerated animal protein fiber.
The object of the present invention is achieved like this: a kind of production method that contains the wool blending fabric of regenerated animal protein fiber comprises the following steps:
---regenerated animal protein fiber is combed the loose slivering and the pre-treatment of dyeing, make it be suitable for dyeing and after backwashing;
---to regeneration animal protein bar dyeing through the overstain pre-treatment;
---will regenerate animal protein bar and wool silver mixing, produce the blended sliver that mixes;
---blended sliver is spinned, obtain can be used for woven spinning yarn;
---spinning yarn through warping, weave and obtain grey cloth;
---grey cloth promptly obtains wool blending fabric after Sheng Xiu and dyeing and finishing deep processing,
Be characterized in:
When a) regenerated animal protein fiber being dyeed pre-treatment, when the animal protein fibre balling-up, add one deck terylene bar or/and add softener, add the terylene bar, dye uniformity is improved or/and flexibility can effectively prevent filament contraction in the ball the inside;
B) to adopt the dyestuff of dyeing to be that REACTIVE DYES or Lan Nasu, orchid receive unrestrainedness, gram jail plain for regenerated animal protein fiber.Adopt above dyeing temperature low, COLOR FASTNESS satisfies takes requirement, and dyeing is succinctly effective;
C) in regenerated animal protein fiber bar and the wool silver mixing, add mixed type and crude oil 80 ± 10g/kg fiber, contain antistatic additive 0.3~0.5% percentage by weight in mixed type and the crude oil, oil, water ratio are 1: 8~10, deposit after 20~24 hours and descend road production again.Adding mixed type and crude oil are beneficial to the multiple protective to regenerated animal protein fiber and wool fibre, make fiber along sliding, the damage of avoiding the processing of road, back to be brought, and road processing after being more conducive to makes the two evenly mixed, improves yarn matter.The particularly adding of antistatic additive prevents that effectively fiber is owing to static twines, ties and problem etc.Long as the resting period, the wool top moisture regain is reduced, make troubles for back road production, weakened the effect that adds with crude oil.And too short, various fiber conditions do not tend towards stability, and finish and fiber are fully inharmonious, have reduced the effect with crude oil equally.
D) percentage by weight of regenerated animal protein fiber and wool is in the finished product wool fabric: regenerated protein 5~40%, wool 60~95%.Be preferably regenerated protein 5~30%, wool 70~95%.The ratio of regenerated protein is too high, and the production difficulty is increased, and easily twines roller, and yarn matter reduces, and is unsuitable for the production of spinning process route, and institute's production kind is easily lost the quality of worsted fabric.Make product not have the exploitation meaning of regenerated animal protein fiber and cross to hang down.
Wherein:
Softener is nonionic and weak cation type organic silicon emulsion, as amido organosilicon.Amido organosilicon is more conducive to it as softener and combines with interfibrous molecule, makes its effect more lasting, obvious.
Mixed type and crude oil are two kinds or multiple composition in fatty acid ester or modified vegetable oil, monoglyceride and the polyglycols.Above-mentioned mixed type and crude oil are to prepare at regenerated animal protein fiber and wool fibre characteristics specially, are more conducive to the protection to wool fibre and regenerated animal protein fiber, are beneficial to production, improve the product total quality.
Antistatic additive is a kind of in the poly-ethanol ether nonionic of phosphate anionic or alkyl amino, polyethylene glycol compound, fatty acid ester, the fatty acid ester nonionic surface active agent or several.Consider regenerated animal protein fiber molecular chain structure and wool fibre design feature, and actual in conjunction with producing, select above-mentioned antistatic additive antistatic behaviour the best for use.
Regenerated animal protein fiber is milk protein fiber or regenerated fibroin fiber, regenerated wool azelon.Above fiber is can't direct fabrics or utilize discarded native protein regeneration system to make to form, and the amino acid that they not only have native protein and are had also have remarkable health care functions, and fiber has the outward appearance of spun silk and takes effect.
Dyestuff is a REACTIVE DYES, and its dyeing recipe is: dyestuff 0.5~18%O, w, f, glauber salt 45~55g/l solution and soda ash 18~22g/l solution, and the bath raio of regenerated animal protein fiber and water is 1: 45~55; Dyeing course is: add dyestuff in the time of 35~60 ℃, divide after 5~10 minutes to add glauber salt several times, each 5~10 minutes at interval; Add glauber salt and add part soda ash after 5~10 minutes, add part soda ash after 5~10 minutes again, be warming up to 65 ℃ ± 5 ℃ by 1~3 ℃/min after 10~20 minutes, be incubated 35~50 minutes, divide during this time and add remaining soda ash several times, be 5~10 minutes its blanking time, puts clear water then and dash clear.
Dyestuff is that orchid receives element or orchid to receive unrestrainedness, gram jail plain, its dyeing recipe is: dyestuff 0.5~18%O, w, f, acetic acid 0.20~0.3%O, w, f, dye leveller A Baige B1.0~2.0%O, w, f and A Baige FFA0.5~1.0g/l solution, and the bath raio of regenerated animal protein fiber and water is 1: 45~55; Dyeing course is: add acetic acid during 35~60 ℃ of water temperatures, add dyestuff after 10~15 minutes, add dyestuff and add dye leveller A Baige B after 5~10 minutes, every again interval added dye leveller A Baige FFA in 5~10 minutes, 1~3 ℃/min is warming up to 100 ℃ then, be incubated 35~55 minutes, put clear water then and dash clear.
The present invention makes regenerated animal protein fiber successful Application on the spinning fabric of hair by regenerated animal protein fiber being combed loose slivering, dyeing processing and the wool blended worsted fabric of producing a kind of new product type.The fabric tool wool fabric of being produced and the dual style of silk fabrics.And because this tencel and human body skin compatibility are good, contain the several amino acids of needed by human body, have the good health care effect, this product has embodied multiple styles such as environmental protection, comfortable, novelty.
The specific embodiment:
Embodiment 1:
1, regenerated protein is a milk protein fiber, and milk protein fiber is combed loose slivering, and every ball weighs 8 ± 1kg, the inner shop of ball 2kg terylene bar during balling-up;
2, milk protein fiber is dyeed, dyeing recipe is gram firm uniformly dyeing material 2% (O, w, f), acetic acid 0.25% (O, w, f), A Baige B1.5% (O, w, f) and A Baige FFA0.5g/l solution, and the bath raio of milk protein fiber and water is 1: 50; Dyeing course is: add acetic acid during 40 ℃ of water temperatures, add dyestuff after 10 minutes, add dyestuff and add auxiliary agent A Baige B after 10 minutes, added A Baige FFA more at interval in 10 minutes, 1 ℃/min is warming up to 100 ℃ then, is incubated 35~55 minutes, puts clear water then and dashes clear.
3, select 1.5D milk protein fiber bar 60kg, 90 for use SAustralia hair 950kg is a raw material.
4, milk protein fiber bar and wool tops were parked after after backwashing 10 hours, both silver mixings afterwards, the blended sliver that production mixes, add the antistatic additive 80g/1kg fiber that mixes by fatty acid ester and fatty acid ester nonionic surface active agent during production, wherein fatty acid esters nonionic surface active agent 0.4% percentage by weight, oil-water ratio is 1: 8, and each road gill box spaces and is 40mm, and the preceding grilling drafting multiple that spins is between 6.75~8.05.
5, blended sliver is spinned, be can be used for woven spinning spun yarn: single yarn tension 〉=210CN, percentage elongation 〉=10%, wool yarn USA (Cv) % value≤21% (64/2~100/2 public yarn);
6, spun yarn is done automatic winding, and long thick, the tufted yarn fault of excision obtains 88/2 and 58/1 public yarn;
7, above-mentioned 88/2 and 58/1 public affairs are propped up yarn blended yarn warping, are woven into grey cloth; Weave cold slurry agent, speed of a motor vehicle 320r/min, powerful 150~170N, weaving efficiency reaches more than 85%;
8, grey cloth is through the dyeing and finishing deep processing, and the crabbing temperature is controlled at 80 ℃, does not do HEAT SETTING, promptly obtaining composition through further dried wet process is milk protein fiber/wool 20/80,88/2 * 58/1 public of yarn count, every meter weight 250g/m, the novel worsted fabric of 2/2 tissue.The every after testing physical index of fabric all reaches FZ/T24008---1998 " the high light and thin type woolen knitwear of combing " high-class product standard.
Embodiment 2:
Regenerated animal protein fiber is a regenerated fibroin fiber, adds the amido organosilicon softener when combing pine;
Dyeing recipe is REACTIVE DYES 2% (O, w, f), glauber salt 50g/l solution and soda ash 20g/l solution, the bath raio of regenerated fibroin fiber and water is 1: 50, dyeing course is: 50 ℃ of water temperatures, add REACTIVE DYES (the beautiful Jia Feikesi ML supper-intelligent REACTIVE DYES that Shanghai ten thousand Dehua worker Co., Ltds produce), average mark adds glauber salt three times after 10 minutes, each 10 minutes at interval; Add glauber salt and add the soda ash of 1/5 deal after 10 minutes, add the soda ash of 1/5 deal at interval after 10 minutes again, heat up by 3 ℃/min after 10 minutes, to 65 ℃ of insulations 35 minutes, period average adds remaining soda ash at twice, and be 10 minutes its blanking time, dashes afterwards to get final product clearly;
Select 1.5D regenerated fibroin bar 360kg for use, 90 SAustralia hair 900kg is a raw material.
All the other are with embodiment 1.
Embodiment 3:
Regenerated animal protein fiber is a regenerated wool egg ribbon, adds nonionic and weak cation type amido organosilicon emulsion softener when combing pine, and layer is auxilliary within the ball adds 2kg terylene bar, and the balling-up Weight control is at 10 ± 1kg;
Dyeing recipe: orchid receives free and easy dyestuff 2% (O, w, f), acetic acid 0.25% (O, w, f), A Baige B1.5% (O, w, f) and A Baige FFA0.5g/l solution, and the bath raio of regenerated wool egg ribbon and water is 1: 50;
Select 2D regenerated wool egg ribbon 460kg for use, 90 SAustralia hair 700kg is a raw material;
All the other are with embodiment 1.

Claims (10)

1, a kind of production method that contains the wool blending fabric of regenerated animal protein fiber comprises the following steps:
---regenerated animal protein fiber is combed the loose slivering and the pre-treatment of dyeing, make it be suitable for dyeing and after backwashing;
---to regeneration animal protein bar dyeing through the overstain pre-treatment;
---will regenerate animal protein bar and wool silver mixing, produce the blended sliver that mixes;
---blended sliver is spinned, obtain can be used for woven spinning yarn;
---spinning yarn through warping, weave and obtain grey cloth;
---grey cloth promptly obtains wool blending fabric after Sheng Xiu and dyeing and finishing deep processing, it is characterized in that:
When a) regenerated animal protein fiber being dyeed pre-treatment, when the animal protein fibre balling-up, add one deck terylene bar or/and add softener in the ball the inside;
B) to adopt the dyestuff of dyeing to be that REACTIVE DYES or Lan Nasu, orchid receive unrestrainedness, gram jail plain for regenerated animal protein fiber;
C) in regenerated animal protein fiber bar and the wool silver mixing, add mixed type and crude oil 80 ± 10g/kg fiber, contain antistatic additive 0.3~0.5% percentage by weight in mixed type and the crude oil, oil, water ratio are 1: 8~10, deposit after 20~24 hours and descend road production again;
D) percentage by weight of regenerated animal protein fiber and wool is in the finished product wool fabric: regenerated protein 5~40%, wool 60~95%.
2, a kind of production method that contains the wool blending fabric of regenerated animal protein fiber according to claim 1 is characterized in that softener is an amido organosilicon.
3, a kind of production method that contains the wool blending fabric of regenerated animal protein fiber according to claim 1 is characterized in that mixed type and crude oil are two kinds or multiple composition in fatty acid ester, modified vegetable oil, monoglyceride and the polyglycols.
4, a kind of production method that contains the wool blending fabric of regenerated animal protein fiber according to claim 2 is characterized in that mixed type and crude oil are two kinds or multiple composition in fatty acid ester, modified vegetable oil, monoglyceride and the polyglycols.
5, a kind of production method that contains the wool blending fabric of regenerated animal protein fiber according to claim 1 is characterized in that antistatic additive is a kind of in the poly-ethanol ether nonionic of phosphate anionic or alkyl amino, polyethylene glycol compound, fatty acid ester, the fatty acid ester nonionic surface active agent or several.
6, a kind of production method that contains the wool blending fabric of regenerated animal protein fiber according to claim 2 is characterized in that antistatic additive is a kind of in the poly-ethanol ether nonionic of phosphate anionic or alkyl amino, polyethylene glycol compound, fatty acid ester, the fatty acid ester nonionic surface active agent or several.
7, a kind of production method that contains the wool blending fabric of regenerated animal protein fiber according to claim 1 is characterized in that regenerated animal protein fiber is milk protein fiber or regenerated fibroin fiber, regenerated wool azelon.
8, a kind of production method that contains the wool blending fabric of regenerated animal protein fiber according to claim 1, it is characterized in that the percentage by weight of regenerated animal protein fiber and wool is in the finished product wool fabric: regenerated protein 5~30%, wool 70~95%.
9, according to one of them described a kind of production method that contains the wool blending fabric of regenerated animal protein fiber of claim 1~8, it is characterized in that dyestuff is a REACTIVE DYES, its dyeing recipe is: dyestuff 0.5~18%O, w, f, glauber salt 45~55g/l solution and soda ash 18~22g/l solution, and the bath raio of regenerated animal protein fiber and water is 1: 45~55; Dyeing course is: add dyestuff in the time of 35~60 ℃, divide after 5~10 minutes to add glauber salt several times, each 5~10 minutes at interval; Add glauber salt and add part soda ash after 5~10 minutes, add part soda ash after 5~10 minutes again, be warming up to 65 ℃ ± 5 ℃ by 1~3 ℃/min after 10~20 minutes, be incubated 35~50 minutes, divide during this time and add remaining soda ash several times, be 5~10 minutes its blanking time, puts clear water then and dash clear.
10, according to one of them described a kind of production method that contains the wool blending fabric of regenerated animal protein fiber of claim 1~8, it is characterized in that dyestuff is that orchid receives element or orchid to receive unrestrainedness, gram jail plain, its dyeing recipe is: dyestuff 0.5~18%O, w, f, acetic acid 0.20~0.3%O, w, f, dye leveller A Baige B1.0~2.0%O, w, f and A Baige FFA0.5~1.0g/l solution, and the bath raio of regenerated animal protein fiber and water is 1: 45~55; Dyeing course is: add acetic acid during 35~60 ℃ of water temperatures, add dyestuff after 10~15 minutes, add dyestuff and add dye leveller A Baige B after 5~10 minutes, every again interval added dye leveller A Baige FFA in 5~10 minutes, be warming up to 100 ℃ by 1~3 ℃/min then, be incubated 35~55 minutes, put clear water then and dash clear.
CNB2004100653752A 2004-11-29 2004-11-29 Production for wool textile containing regenerating animal azelon CN100422411C (en)

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Cited By (9)

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CN102363903A (en) * 2011-07-01 2012-02-29 江苏金辰针纺织有限公司 Blended shell fabric and dyeing process thereof
CN101270528B (en) * 2008-04-21 2012-05-16 宁波雅戈尔毛纺织染整有限公司 Method for producing pure wool crease-shedding facing material
CN102864556A (en) * 2012-09-26 2013-01-09 昆山市周市斐煌服饰厂 Wool and rabbit fur coat
CN103147323A (en) * 2013-03-22 2013-06-12 河南工程学院 Method for improving dye fixing rate of double-protein fiber reactive dye
CN103233312A (en) * 2013-03-26 2013-08-07 桐乡市五丰丝织有限责任公司 Silk protein fabric
CN103271471A (en) * 2013-06-13 2013-09-04 太仓协大申泰羊毛衫有限公司 Antistatic, hygroscopic and degradable woolen sweater
CN103526602A (en) * 2013-09-27 2014-01-22 昆山培新服装有限公司 Reactive dye dyeing technology of milk protein fibers
CN104397910A (en) * 2014-12-22 2015-03-11 江苏倪家巷集团精毛纺织有限公司 Preparation method of high-quality wool heavy-twist and anti-wrinkle fabric
CN109653000A (en) * 2017-10-11 2019-04-19 赤峰东黎羊绒设备有限公司 A kind of dyeing recipe and its technique for wool fiber

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101270528B (en) * 2008-04-21 2012-05-16 宁波雅戈尔毛纺织染整有限公司 Method for producing pure wool crease-shedding facing material
CN102363903A (en) * 2011-07-01 2012-02-29 江苏金辰针纺织有限公司 Blended shell fabric and dyeing process thereof
CN102363903B (en) * 2011-07-01 2013-04-17 江苏金辰针纺织有限公司 Blended shell fabric and dying process thereof
CN102864556A (en) * 2012-09-26 2013-01-09 昆山市周市斐煌服饰厂 Wool and rabbit fur coat
CN103147323A (en) * 2013-03-22 2013-06-12 河南工程学院 Method for improving dye fixing rate of double-protein fiber reactive dye
CN103233312A (en) * 2013-03-26 2013-08-07 桐乡市五丰丝织有限责任公司 Silk protein fabric
CN103271471A (en) * 2013-06-13 2013-09-04 太仓协大申泰羊毛衫有限公司 Antistatic, hygroscopic and degradable woolen sweater
CN103526602A (en) * 2013-09-27 2014-01-22 昆山培新服装有限公司 Reactive dye dyeing technology of milk protein fibers
CN104397910A (en) * 2014-12-22 2015-03-11 江苏倪家巷集团精毛纺织有限公司 Preparation method of high-quality wool heavy-twist and anti-wrinkle fabric
CN104397910B (en) * 2014-12-22 2016-04-27 江苏倪家巷集团精毛纺织有限公司 The production method of senior lousiness heavy twist anti-wrinkle fabric
CN109653000A (en) * 2017-10-11 2019-04-19 赤峰东黎羊绒设备有限公司 A kind of dyeing recipe and its technique for wool fiber

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