CN1594183A - Multifunctional heat insulating plaster - Google Patents

Multifunctional heat insulating plaster Download PDF

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Publication number
CN1594183A
CN1594183A CN 200410013478 CN200410013478A CN1594183A CN 1594183 A CN1594183 A CN 1594183A CN 200410013478 CN200410013478 CN 200410013478 CN 200410013478 A CN200410013478 A CN 200410013478A CN 1594183 A CN1594183 A CN 1594183A
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Prior art keywords
heat
insulation
fiber
multifunction
preservation mortar
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CN 200410013478
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CN100596292C (en
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张志峰
周强
郝先成
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WUHAN AOJIE TECHNOLOGIES Inc
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Individual
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  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

The invention relates to a multifunctional heat insulating plaster comprising a composite dried powder A and a polystyrene foam granule B, wherein the composite dried powder A comprises cement 50-80%, aluminosilicate glass hollow sphere material 10-40%, air-entrainer 0.005-0.05%, modifier 1-5%, water reducing agent 0.2-1.2%, fabric 0.1-5%, viscosifying agent 0.5-2%, the polystyrene foam granule B is prepared from finished expanded materials or reclaimed discarded polyphenylacetylene boards through slacking.

Description

Multifunction heat-insulation and heat-preservation mortar
One, technical field:
The invention belongs to the material of construction class, be specifically related to a kind of Multifunction heat-insulation and heat-preservation mortar.
Two, background technology:
Highrise buildings and large bay The development of architecture, more and more higher to the requirement of the lightweight of materials for wall and heat preservation and insulation, thereby the wall heat insulation material of mineral such as perlite, gypsum has appearred dosing; Mineral such as a large amount of harmful materials such as asbestos are arranged in the existing lagging material prescription, and heat insulation, the anti-drying shrinkage of material, overall performance such as impervious are poor, water regain is big; Technology, economic problems such as there is the transportation cost height in traditional technology, resting period is short, the field mix metering is inaccurate, construction inconvenience.
About the heat-insulation and heat-preservation material, existing both at home and abroad big quantity research, report, its main contents are as follows:
1, existing heat-insulation and heat-preservation material mainly is made up of agglutination material and light skeletal.Wherein agglutination material mainly adopts cement, flyash etc., and light skeletal is mainly used pearlstone, polystyrene foam particles;
2, existing heat-insulation and heat-preservation material must adopt the secondary or the moulding of plastering more than the secondary because workability is poor in the construction process.
Existing heat-insulation and heat-preservation material lays particular emphasis on integral construction, as intensity, density etc., lacks the consideration of material function, as the application property of material, thermal insulation, dry shrinkage etc.Although and existing heat-insulation and heat-preservation material selection difference, all there are some common problems: big, poor, the water-intake rate height of heat preservation and insulation of unit weight, comprehensive benefit is poor when being used for the non-load bearing wall of buildings; And complex manufacturing, the cost height also exists polyphenyl heat-insulation and heat-preservation combined wall surface fracture, planeness not high, wall hollow drum, cracking problem.
Three, summary of the invention:
The technical problem that the present invention solves provides a kind of Multifunction heat-insulation and heat-preservation mortar, this bed of mortar be have that construction technology is simple, thermal conductivity is low, heat storage coefficient is high, intensity is high, the building non-bearing wall body heat-insulation and heat-preservation material of, environmental protection and energy saving good, advantage such as with low cost from heavy and light, volume stability.
Technical scheme of the present invention: a kind of Multifunction heat-insulation and heat-preservation mortar, its component and weight content are: polystyrene foam particles B1 part, composite dry powder material A8~13 parts, 6~15 parts in water; Wherein the component of composite dry powder material A and weight content are: cement 50~80%, sial glass hollow ball material 10~40%, water reducer 0.2~1.2%, air entrapment agent 0.005~0.05%, properties-correcting agent 1~5%, fiber 0.1~5%, tackifier 0.5~2%.The preparation method: composite dry powder material A, polystyrene foam particles B mix respectively and quota packing in advance, deliver to the working-yard and are mixed in proportion, and stir to add water.Described polystyrene foam particles B globulate is irregularly shaped with other, and particle diameter is 2~5mm, and unit weight is 10~100kg/m 3Described sial glass hollow ball material, its specific surface area is 400~5000m 2/ kg, spheroid particle diameter are 0.5 μ m~60 μ m, and the content of silicon oxide is more than 50%.Described water reducer is a naphthalene series high-efficiency water-reducing agent.Described fiber is one or more compound in modified polypropylene fiber, alkali resistant glass fiber, nylon fiber, the animal and plant fiber.Described air entrapment agent is a colophonium pyrolytic polymer class air entrapment agent.Described properties-correcting agent is Mierocrystalline cellulose or cellulosic derivative.Described tackifier are vinyl acetate between to for plastic class tackifier.
Cement is as inorganic coagulation material, and p-poly-phenyl vinyl foam particle plays package action, also is simultaneously the intensity source of whole material.Polystyrene foam particles plays the heat-insulation and heat-preservation effect simultaneously as light skeletal.Sial glass hollow ball material is as lagging material and supplementary cementitious material; This compound contains a large amount of glass spheres, significantly improves construction working owing to " ball effect ".Add a large amount of fibers in this material, made material form reticulated structure, stronger fracture toughness property has been arranged, strengthened the tension effect.Air entrapment agent plays water conservation, bleed effect, makes lagging material produce even bubble, can strengthen heat insulation effect, has increased the workability of material simultaneously; The dried porosity of holding one's breath of this heat-insulation and heat-preservation mortar layer reaches 70~90%, has very strong heat insulation and preservation effect.The adding of properties-correcting agent had both increased the workability of material, improved the extent of hydration of cement again, increased the later strength of material.
Beneficial effect of the present invention: 1, the optimization design of the proportioning of p-poly-phenyl vinyl foam particulate grating and it and gelling material, make the various performance index such as density, thermal conductivity, heat storage coefficient, shrinking percentage and intensity of this material all obtain optimization, each performance index sees Table 1.
The report of table 1 building heat insulation material tests
Sequence number Test item Measure unit Measured result
????1 Do apparent density ????Kg/cm 3 ????200~226
????2 Thermal conductivity ????W/m·k ???0.057~0.059
????3 Heat storage coefficient ????W/m 2·k ????1.30~1.75
????4 Pressure is cut cohesive strength ??????MPa ????0.06~0.07
????5 Compressive strength (normal temperature 28d) ??????MPa ????0.26~0.30
????6 Tensile strength ??????MPa ????0.15~0.18
????7 Linear shrinkage ??????% ????0.05~0.08
????8 Coefficient of softening ????0.70~0.82
2, added this material of sial glass hollow ball material, it and polystyrene foam particles all belong to light porous material, have played the heat-insulation and heat-preservation effect; In addition, " ball effect " improved workability, the globality of material, and once construction reaches more than the 4cm, and does not need the secondary levelling, has significantly improved operating efficiency.
3, because 1~5% bubble has been introduced in the existence of air entrapment agent, cut off heat transfer channel, both reached the effect of heat-insulation and heat-preservation, also reached effect of water keeping, improved the hydrated cementitious degree, strengthened the intensity of material layer.
4, main raw material of the present invention is a waste polystyrene foam, and it is that waste product utilizes renewable resource, has reduced white pollution again, so this plaster material is good environmentfriendly products, has also saved resource significantly.
5, the present invention adopts dry mash pre-mixing dry mixing technology and polyphenyl foam particle packing technology, the on-the-spot water that only need add in proportion stirs and can construct, and has solved techno-economic questions such as the production stirring phase is long in the traditional technology, transportation cost is high, resting period is short, the field mix metering is inaccurate, construction inconvenience.
Technology mechanism:
(1), heat-insulation and heat-preservation mechanism:
The uniform miniature closed pore bubble that 1, some amount is arranged in the lagging material: because still air is good heat-insulation and heat-preservation material, thermal conductivity λ g=0.026w/ (mk) in the time of static 0 ℃, thermal conductivity than present various heat-insulation and heat-preservation materials is all little, so still air is best heat-insulation and heat-preservation material.2, adopt unicellular structure: in order to eliminate the convective heat exchange of gas in the hole, adopt miniature pore can reduce radiation heat transfer between the hole wall, thereby further improve the heat preservation and insulation of solid-state material.3, adopt polystyrene foam: because the heat preservation and insulation of polystyrene foam is good, its thermal conductivity is less: λ g=0.041W/ (mk).In this heat-insulation and heat-preservation material, add some amount polystyrene spherical particle, improved heat preservation and insulation.
(2), the low-grade fever bridge cuts off effect:
Gelling material such as cement bond together polystyrene foam particles as the agglutination material of polystyrene foam particles.1, because capillary effect, introduced ten thousand/ modification air entrapment agent, thereby produced 1~5% bubble to 5/10000ths, " partition " heat transfer channel, make inner heat be not easy to scatter and disappear, the heat of outside is difficult to enter into the inside again, plays good insulation and heat-blocking action.2, a large amount of microbubbles are contained in sial glass hollow ball material inside, and some is the aggregate of a plurality of microballons then, has the pore of " natural ", plays good heat insulation and preservation effect.
Embodiment:
Embodiment 1:
A kind of Multifunction heat-insulation and heat-preservation mortar, its component and weight content are: polystyrene foam particles B1 part, composite dry powder material A9 part, 8 parts in water; Wherein the component of composite dry powder material A and weight content are: cement 52%, sial glass hollow ball material 40%, water reducer 0.6%, air entrapment agent 0.03%, properties-correcting agent 5%, fiber 0.47%, tackifier 1.9%.The preparation method: composite dry powder material A, polystyrene foam particles B mix respectively and quota packing in advance, deliver to the working-yard and are mixed in proportion, and stir to add water and can use.Used polystyrene foam particles B globulate is irregularly shaped with other, and particle diameter is 2~5mm, and unit weight is 18.6kg/m 3, sial glass hollow ball material is Wuhan Iron and Steel Plant production, its specific surface area is 4235m 2/ kg, spheroid particle diameter are 0.5 μ m~60 μ m, and the content of silicon oxide is more than 50%, and water reducer is the FDN-1 high efficiency water reducing agent, and fiber is a modified polypropylene fiber, and air entrapment agent is commercially available lime extract, and properties-correcting agent is methylcellulose gum, and tackifier are vinyl acetate between to for plastic.
Embodiment 2:
A kind of Multifunction heat-insulation and heat-preservation mortar, its component and weight content are: polystyrene foam particles B1 part, composite dry powder material A13 part, 14 parts in water; Wherein the component of composite dry powder material A and weight content are: cement 69%, sial glass hollow ball material 24.15%, water reducer 1.1%, air entrapment agent 0.05%, properties-correcting agent 3%, fiber 2%, tackifier 0.7%.The preparation method: composite dry powder material A, polystyrene foam particles B mix respectively and quota packing in advance, deliver to the working-yard and are mixed in proportion, and stir to add water and can use.Used polystyrene foam particles B globulate is irregularly shaped with other, and particle diameter is 2~5mm, and unit weight is 20.3kg/m 3, sial glass hollow ball material is Wuhan Iron and Steel Plant production, its specific surface area is 4320m 2/ kg, spheroid particle diameter are 0.5 μ m~60 μ m, and the content of silicon oxide is more than 50%, the high efficiency water reducing agent that water reducer is produced for the Tianjin giant dragon, fiber is alkaline-resisting short glass fiber, air entrapment agent is commercially available mortar king, properties-correcting agent is carboxymethyl cellulose, and tackifier are vinyl acetate between to for plastic.
Embodiment 3:
A kind of Multifunction heat-insulation and heat-preservation mortar, its component and weight content are: polystyrene foam particles B1 part, composite dry powder material A9 part, 8 parts in water; Wherein the component of composite dry powder material A and weight content are: cement 60%, sial glass hollow ball material 29%, water reducer 1.2%, air entrapment agent 0.03%, properties-correcting agent 5%, fiber 3.77%, tackifier 1%.The preparation method: composite dry powder material A, polystyrene foam particles B mix respectively and quota packing in advance, deliver to the working-yard and are mixed in proportion, and stir to add water and can use.Used polystyrene foam particles B globulate is irregularly shaped with other, and particle diameter is 2~5mm, and unit weight is 19.1kg/m 3, sial glass hollow ball material is Wuhan Iron and Steel Plant production, its specific surface area is 4231m 2/ kg, spheroid particle diameter are 0.5 μ m~60 μ m, and the content of silicon oxide is more than 50%, and naphthalene series high-efficiency water-reducing agent is available from the great source of Wuhan Iron and Steel Plant, and fiber is a nylon fiber, and air entrapment agent is commercially available lime extract, and properties-correcting agent is carboxymethyl cellulose, and tackifier are vinyl acetate between to for plastic.

Claims (8)

1, a kind of Multifunction heat-insulation and heat-preservation mortar, it is characterized in that: its component and weight content are: polystyrene foam particles B1 part, 8~13 parts of composite dry powder material A, 6~15 parts in water; Wherein the component of composite dry powder material A and weight content are: cement 50~80%, sial glass hollow ball material 10~40%, water reducer 0.2~1.2%, air entrapment agent 0.005~0.05%, properties-correcting agent 1~5%, fiber 0.1~5%, tackifier 0.5~2%; The preparation method: composite dry powder material A, polystyrene foam particles B mix respectively and quota packing in advance, can directly mix in proportion at the construction field (site), add water and stir.
2, according to the described a kind of Multifunction heat-insulation and heat-preservation mortar of claim 1, it is characterized in that: described polystyrene foam particles B globulate is irregularly shaped with other, and particle diameter is 2~5mm, and unit weight is 10~100kg/m 3
3, according to the described a kind of Multifunction heat-insulation and heat-preservation mortar of claim 1, it is characterized in that: described sial glass hollow ball material, its specific surface area is 400~5000m 2/ kg, spheroid particle diameter are 0.5 μ m~60 μ m, and the content of silicon oxide is more than 50%.
4, according to the described a kind of Multifunction heat-insulation and heat-preservation mortar of claim 1, it is characterized in that: described water reducer is a naphthalene series high-efficiency water-reducing agent.
5, according to the described a kind of Multifunction heat-insulation and heat-preservation mortar of claim 1, it is characterized in that: described fiber is one or more compound in modified polypropylene fiber, alkali resistant glass fiber, nylon fiber, the animal and plant fiber.
6, according to the described a kind of Multifunction heat-insulation and heat-preservation mortar of claim 1, it is characterized in that: described air entrapment agent is a colophonium pyrolytic polymer class air entrapment agent.
7, according to the described a kind of Multifunction heat-insulation and heat-preservation mortar of claim 1, it is characterized in that: described properties-correcting agent is Mierocrystalline cellulose or cellulosic derivative.
8, according to the described a kind of Multifunction heat-insulation and heat-preservation mortar of claim 1, it is characterized in that: described tackifier are vinyl acetate between to for plastic class tackifier.
CN200410013478A 2004-07-16 2004-07-16 Multifunctional heat insulating plaster Expired - Fee Related CN100596292C (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102173677A (en) * 2010-11-29 2011-09-07 杨长文 Inflaming retarding building heat insulation material and production method thereof
CN103410245A (en) * 2013-08-07 2013-11-27 苏州市世好建材新技术工程有限公司 External thermal-insulating wall
CN103641390A (en) * 2013-11-08 2014-03-19 许炜 Compound bubble mortar for lightweight concrete
CN104446236A (en) * 2014-11-11 2015-03-25 黄美忠 Light environment-friendly heat-preservation mortar
CN105254241A (en) * 2015-07-21 2016-01-20 上海城建物资有限公司 Method for improving anti-penetrability of recycled concrete
AT524706A1 (en) * 2021-02-10 2022-08-15 Egon Doeberl Thermally insulating filling material

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102173677A (en) * 2010-11-29 2011-09-07 杨长文 Inflaming retarding building heat insulation material and production method thereof
CN103410245A (en) * 2013-08-07 2013-11-27 苏州市世好建材新技术工程有限公司 External thermal-insulating wall
CN103641390A (en) * 2013-11-08 2014-03-19 许炜 Compound bubble mortar for lightweight concrete
CN104446236A (en) * 2014-11-11 2015-03-25 黄美忠 Light environment-friendly heat-preservation mortar
CN105254241A (en) * 2015-07-21 2016-01-20 上海城建物资有限公司 Method for improving anti-penetrability of recycled concrete
AT524706A1 (en) * 2021-02-10 2022-08-15 Egon Doeberl Thermally insulating filling material
AT524706B1 (en) * 2021-02-10 2022-10-15 Egon Doeberl Thermally insulating filling material

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