CN1583809A - 偏氟乙烯聚合物及其制备方法 - Google Patents
偏氟乙烯聚合物及其制备方法 Download PDFInfo
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- CN1583809A CN1583809A CN 200410025005 CN200410025005A CN1583809A CN 1583809 A CN1583809 A CN 1583809A CN 200410025005 CN200410025005 CN 200410025005 CN 200410025005 A CN200410025005 A CN 200410025005A CN 1583809 A CN1583809 A CN 1583809A
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- vinylidene
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- 238000000034 method Methods 0.000 title claims description 25
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 title claims description 24
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 30
- 238000007334 copolymerization reaction Methods 0.000 claims abstract description 15
- 150000003254 radicals Chemical class 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000003999 initiator Substances 0.000 claims description 48
- -1 vinyl compound Chemical class 0.000 claims description 38
- 238000009826 distribution Methods 0.000 claims description 32
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 27
- 239000000178 monomer Substances 0.000 claims description 26
- 239000006185 dispersion Substances 0.000 claims description 19
- CHBCHAGCVIMDKI-UHFFFAOYSA-N [F].C=C Chemical group [F].C=C CHBCHAGCVIMDKI-UHFFFAOYSA-N 0.000 claims description 18
- 229920000573 polyethylene Polymers 0.000 claims description 18
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims description 17
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical group CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 claims description 17
- 239000012986 chain transfer agent Substances 0.000 claims description 16
- 230000009466 transformation Effects 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 14
- 229920002554 vinyl polymer Polymers 0.000 claims description 13
- 229910052731 fluorine Inorganic materials 0.000 claims description 11
- BEQKKZICTDFVMG-UHFFFAOYSA-N 1,2,3,4,6-pentaoxepane-5,7-dione Chemical compound O=C1OOOOC(=O)O1 BEQKKZICTDFVMG-UHFFFAOYSA-N 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 238000005502 peroxidation Methods 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 9
- 125000003709 fluoroalkyl group Chemical group 0.000 claims description 8
- 229920001519 homopolymer Polymers 0.000 claims description 8
- 238000002844 melting Methods 0.000 claims description 8
- 230000008018 melting Effects 0.000 claims description 8
- 230000002902 bimodal effect Effects 0.000 claims description 7
- 125000001153 fluoro group Chemical group F* 0.000 claims description 7
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 6
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 6
- 125000004428 fluoroalkoxy group Chemical group 0.000 claims description 6
- BLTXWCKMNMYXEA-UHFFFAOYSA-N 1,1,2-trifluoro-2-(trifluoromethoxy)ethene Chemical compound FC(F)=C(F)OC(F)(F)F BLTXWCKMNMYXEA-UHFFFAOYSA-N 0.000 claims description 5
- 229920001577 copolymer Polymers 0.000 claims description 5
- WUMVZXWBOFOYAW-UHFFFAOYSA-N 1,2,3,3,4,4,4-heptafluoro-1-(1,2,3,3,4,4,4-heptafluorobut-1-enoxy)but-1-ene Chemical compound FC(F)(F)C(F)(F)C(F)=C(F)OC(F)=C(F)C(F)(F)C(F)(F)F WUMVZXWBOFOYAW-UHFFFAOYSA-N 0.000 claims description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical group CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical group ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 4
- 150000002632 lipids Chemical class 0.000 claims description 4
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 claims description 4
- GDOPTJXRTPNYNR-UHFFFAOYSA-N methylcyclopentane Chemical group CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 claims description 4
- 150000004978 peroxycarbonates Chemical class 0.000 claims description 4
- FJAUCWNKOXKMHB-UHFFFAOYSA-N 2-tert-butylperoxyethanol Chemical group CC(C)(C)OOCCO FJAUCWNKOXKMHB-UHFFFAOYSA-N 0.000 claims description 3
- 239000004721 Polyphenylene oxide Chemical class 0.000 claims description 3
- 150000001298 alcohols Chemical group 0.000 claims description 3
- 150000001993 dienes Chemical class 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical group FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- 150000002576 ketones Chemical class 0.000 claims description 3
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 3
- 150000002978 peroxides Chemical class 0.000 claims description 3
- IUGYQRQAERSCNH-UHFFFAOYSA-N pivalic acid Chemical compound CC(C)(C)C(O)=O IUGYQRQAERSCNH-UHFFFAOYSA-N 0.000 claims description 3
- 229920000570 polyether Chemical class 0.000 claims description 3
- BWJUFXUULUEGMA-UHFFFAOYSA-N propan-2-yl propan-2-yloxycarbonyloxy carbonate Chemical compound CC(C)OC(=O)OOC(=O)OC(C)C BWJUFXUULUEGMA-UHFFFAOYSA-N 0.000 claims description 3
- 239000004094 surface-active agent Substances 0.000 claims description 3
- VXHFNALHLRWIIU-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropanoate Chemical compound CC(C)(C)OC(=O)C(C)(C)C VXHFNALHLRWIIU-UHFFFAOYSA-N 0.000 claims description 3
- OHMHBGPWCHTMQE-UHFFFAOYSA-N 2,2-dichloro-1,1,1-trifluoroethane Chemical compound FC(F)(F)C(Cl)Cl OHMHBGPWCHTMQE-UHFFFAOYSA-N 0.000 claims description 2
- LTMRRSWNXVJMBA-UHFFFAOYSA-L 2,2-diethylpropanedioate Chemical compound CCC(CC)(C([O-])=O)C([O-])=O LTMRRSWNXVJMBA-UHFFFAOYSA-L 0.000 claims description 2
- VOPWNXZWBYDODV-UHFFFAOYSA-N Chlorodifluoromethane Chemical compound FC(F)Cl VOPWNXZWBYDODV-UHFFFAOYSA-N 0.000 claims description 2
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 claims description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims description 2
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 claims description 2
- 229910001413 alkali metal ion Chemical group 0.000 claims description 2
- 229920002678 cellulose Polymers 0.000 claims description 2
- 239000001913 cellulose Substances 0.000 claims description 2
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 claims description 2
- 235000019404 dichlorodifluoromethane Nutrition 0.000 claims description 2
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical group [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 claims description 2
- CXHHBNMLPJOKQD-UHFFFAOYSA-M methyl carbonate Chemical compound COC([O-])=O CXHHBNMLPJOKQD-UHFFFAOYSA-M 0.000 claims description 2
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 claims description 2
- BZPCMSSQHRAJCC-UHFFFAOYSA-N 1,2,3,3,4,4,5,5,5-nonafluoro-1-(1,2,3,3,4,4,5,5,5-nonafluoropent-1-enoxy)pent-1-ene Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)=C(F)OC(F)=C(F)C(F)(F)C(F)(F)C(F)(F)F BZPCMSSQHRAJCC-UHFFFAOYSA-N 0.000 claims 2
- 229920000642 polymer Polymers 0.000 abstract description 7
- 238000012546 transfer Methods 0.000 abstract description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 abstract 4
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 49
- 239000000126 substance Substances 0.000 description 14
- 239000002904 solvent Substances 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 7
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 238000012545 processing Methods 0.000 description 5
- 239000011737 fluorine Substances 0.000 description 4
- 239000013543 active substance Substances 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- NUHSROFQTUXZQQ-UHFFFAOYSA-N isopentenyl diphosphate Chemical compound CC(=C)CCO[P@](O)(=O)OP(O)(O)=O NUHSROFQTUXZQQ-UHFFFAOYSA-N 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 238000001542 size-exclusion chromatography Methods 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- KHXKESCWFMPTFT-UHFFFAOYSA-N 1,1,1,2,2,3,3-heptafluoro-3-(1,2,2-trifluoroethenoxy)propane Chemical compound FC(F)=C(F)OC(F)(F)C(F)(F)C(F)(F)F KHXKESCWFMPTFT-UHFFFAOYSA-N 0.000 description 1
- MIZLGWKEZAPEFJ-UHFFFAOYSA-N 1,1,2-trifluoroethene Chemical group FC=C(F)F MIZLGWKEZAPEFJ-UHFFFAOYSA-N 0.000 description 1
- 125000004776 1-fluoroethyl group Chemical group [H]C([H])([H])C([H])(F)* 0.000 description 1
- 125000004777 2-fluoroethyl group Chemical group [H]C([H])(F)C([H])([H])* 0.000 description 1
- ZRNSSRODJSSVEJ-UHFFFAOYSA-N 2-methylpentacosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCC(C)C ZRNSSRODJSSVEJ-UHFFFAOYSA-N 0.000 description 1
- FDMFUZHCIRHGRG-UHFFFAOYSA-N 3,3,3-trifluoroprop-1-ene Chemical compound FC(F)(F)C=C FDMFUZHCIRHGRG-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical compound FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 125000004786 difluoromethoxy group Chemical group [H]C(F)(F)O* 0.000 description 1
- 125000001028 difluoromethyl group Chemical group [H]C(F)(F)* 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000005621 ferroelectricity Effects 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 239000004811 fluoropolymer Substances 0.000 description 1
- 125000005816 fluoropropyl group Chemical group [H]C([H])(F)C([H])([H])C([H])([H])* 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N monofluoromethane Natural products FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000005009 perfluoropropyl group Chemical group FC(C(C(F)(F)F)(F)F)(F)* 0.000 description 1
- 238000010094 polymer processing Methods 0.000 description 1
- 230000005616 pyroelectricity Effects 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000006276 transfer reaction Methods 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
实施例 | 重均分子量(万克/摩尔) | 分子量分布系数 | MFR(克/10分钟) | 熔融焓(焦耳/克) | 溶液外观 |
实施例1 | 136.5 | 5.3 | 0.9 | 35.4 | 澄清透明 |
实施例2 | 102.5 | 11.6 | 16.2 | 37.9 | 澄清透明 |
实施例3 | 78.3 | 11.5 | 19.1 | 35.2 | 澄清透明 |
实施例4 | 87.1 | 9.7 | 7.4 | 42.3 | 澄清透明 |
实施例5 | 72.9 | 3.7 | 1.9 | 44.5 | 澄清透明 |
实施例6 | 60.1 | 2.9 | 1.8 | 44.2 | 澄清透明 |
实施例7 | 64.4 | 5.1 | 4.5 | 36.7 | 澄清透明 |
实施例8 | 130.3 | 10.7 | 14.6 | 25.1 | 澄清透明 |
实施例9 | 80.4 | 8.5 | 5.3 | 16.2 | 澄清透明 |
实施例10 | 65.0 | 3.1 | 1.1 | 18.3 | 澄清透明 |
比较例1 | 78.1 | 20.5 | 18.7 | 41.5 | 澄清透明 |
比较例2 | 147.7 | 4.3 | 0.3 | 49.4 | 澄清透明 |
Claims (14)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN 200410025005 CN1257921C (zh) | 2004-06-09 | 2004-06-09 | 偏氟乙烯聚合物及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN 200410025005 CN1257921C (zh) | 2004-06-09 | 2004-06-09 | 偏氟乙烯聚合物及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1583809A true CN1583809A (zh) | 2005-02-23 |
CN1257921C CN1257921C (zh) | 2006-05-31 |
Family
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Application Number | Title | Priority Date | Filing Date |
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CN 200410025005 Expired - Lifetime CN1257921C (zh) | 2004-06-09 | 2004-06-09 | 偏氟乙烯聚合物及其制备方法 |
Country Status (1)
Country | Link |
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CN (1) | CN1257921C (zh) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101195669B (zh) * | 2006-12-04 | 2011-11-16 | 上海三爱富新材料股份有限公司 | 一种偏氟乙烯聚合物的制备方法 |
CN102585077A (zh) * | 2011-12-16 | 2012-07-18 | 中昊晨光化工研究院 | 三氟氯乙烯改性聚偏氟乙烯的制备方法 |
CN102634150A (zh) * | 2012-03-31 | 2012-08-15 | 苏州新区特氟龙塑料制品厂 | 一种防黏聚偏二氟乙烯的配方 |
CN103601827A (zh) * | 2013-12-02 | 2014-02-26 | 内蒙古三爱富万豪氟化工有限公司 | 偏氟乙烯聚合物及其制备方法 |
CN104151754A (zh) * | 2014-08-15 | 2014-11-19 | 上海三爱富新材料股份有限公司 | 高流动性乙烯-四氟乙烯共聚物组合物及其制备方法 |
CN104592431A (zh) * | 2014-12-29 | 2015-05-06 | 东莞市长安东阳光铝业研发有限公司 | 一种宽分布聚偏氟乙烯的制备方法 |
CN107406529A (zh) * | 2015-03-16 | 2017-11-28 | 阿科玛股份有限公司 | 改性的氟聚合物 |
CN107778412A (zh) * | 2016-08-30 | 2018-03-09 | 中昊晨光化工研究院有限公司 | 一种水性含氟分散液及其制备方法和应用 |
CN108503738A (zh) * | 2018-04-16 | 2018-09-07 | 中国海洋石油集团有限公司 | 一种聚偏氟乙烯树脂及其制备方法与应用 |
CN110183562A (zh) * | 2019-05-30 | 2019-08-30 | 浙江孚诺林化工新材料有限公司 | 一种用于锂离子动力电池黏结剂的偏氟乙烯聚合物及其制备方法和用途 |
WO2024138977A1 (zh) * | 2022-12-29 | 2024-07-04 | 上海华谊三爱富新材料有限公司 | 杂化乳液及其制备方法 |
-
2004
- 2004-06-09 CN CN 200410025005 patent/CN1257921C/zh not_active Expired - Lifetime
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101195669B (zh) * | 2006-12-04 | 2011-11-16 | 上海三爱富新材料股份有限公司 | 一种偏氟乙烯聚合物的制备方法 |
CN102585077A (zh) * | 2011-12-16 | 2012-07-18 | 中昊晨光化工研究院 | 三氟氯乙烯改性聚偏氟乙烯的制备方法 |
CN102585077B (zh) * | 2011-12-16 | 2013-11-06 | 中昊晨光化工研究院 | 三氟氯乙烯改性聚偏氟乙烯的制备方法 |
CN102634150A (zh) * | 2012-03-31 | 2012-08-15 | 苏州新区特氟龙塑料制品厂 | 一种防黏聚偏二氟乙烯的配方 |
CN103601827A (zh) * | 2013-12-02 | 2014-02-26 | 内蒙古三爱富万豪氟化工有限公司 | 偏氟乙烯聚合物及其制备方法 |
CN103601827B (zh) * | 2013-12-02 | 2016-04-27 | 内蒙古三爱富万豪氟化工有限公司 | 偏氟乙烯聚合物及其制备方法 |
CN104151754A (zh) * | 2014-08-15 | 2014-11-19 | 上海三爱富新材料股份有限公司 | 高流动性乙烯-四氟乙烯共聚物组合物及其制备方法 |
CN104592431A (zh) * | 2014-12-29 | 2015-05-06 | 东莞市长安东阳光铝业研发有限公司 | 一种宽分布聚偏氟乙烯的制备方法 |
CN107406529A (zh) * | 2015-03-16 | 2017-11-28 | 阿科玛股份有限公司 | 改性的氟聚合物 |
CN107406529B (zh) * | 2015-03-16 | 2020-06-19 | 阿科玛股份有限公司 | 改性的氟聚合物 |
CN107778412A (zh) * | 2016-08-30 | 2018-03-09 | 中昊晨光化工研究院有限公司 | 一种水性含氟分散液及其制备方法和应用 |
CN107778412B (zh) * | 2016-08-30 | 2019-08-06 | 中昊晨光化工研究院有限公司 | 一种水性含氟分散液及其制备方法和应用 |
CN108503738A (zh) * | 2018-04-16 | 2018-09-07 | 中国海洋石油集团有限公司 | 一种聚偏氟乙烯树脂及其制备方法与应用 |
CN108503738B (zh) * | 2018-04-16 | 2020-06-26 | 中国海洋石油集团有限公司 | 一种聚偏氟乙烯树脂及其制备方法与应用 |
CN110183562A (zh) * | 2019-05-30 | 2019-08-30 | 浙江孚诺林化工新材料有限公司 | 一种用于锂离子动力电池黏结剂的偏氟乙烯聚合物及其制备方法和用途 |
WO2024138977A1 (zh) * | 2022-12-29 | 2024-07-04 | 上海华谊三爱富新材料有限公司 | 杂化乳液及其制备方法 |
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