CN1580345A - Spunbonded nonwoven fabric and process for making the same - Google Patents
Spunbonded nonwoven fabric and process for making the same Download PDFInfo
- Publication number
- CN1580345A CN1580345A CN200410069643.8A CN200410069643A CN1580345A CN 1580345 A CN1580345 A CN 1580345A CN 200410069643 A CN200410069643 A CN 200410069643A CN 1580345 A CN1580345 A CN 1580345A
- Authority
- CN
- China
- Prior art keywords
- woven material
- viscose non
- low
- component
- melting component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
- D04H3/14—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic yarns or filaments produced by welding
- D04H3/147—Composite yarns or filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/005—Synthetic yarns or filaments
- D04H3/007—Addition polymers
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/005—Synthetic yarns or filaments
- D04H3/009—Condensation or reaction polymers
- D04H3/011—Polyesters
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
- D04H3/14—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic yarns or filaments produced by welding
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Nonwoven Fabrics (AREA)
- Multicomponent Fibers (AREA)
- Treatment Of Fiber Materials (AREA)
Abstract
Spun-bond nonwoven material made of continuous filaments or fibers, whereby the continuous filaments or fibers are multi-component filaments, in particular bi-component filaments, with a low-melting component on the outer surface. The spun-bond nonwoven material is thermally bonded in a calender. The spun-bond nonwoven material has a mass per unit area of more than 40 g/m<2>.
Description
Technical field
The present invention relates to a kind of viscose non-woven material of making by continuous filament yarn or fiber, and the method that is used to make this viscose non-woven material.In scope of the present invention, the yarn or the long filament that have indefinite length on term continuous fibers and the term long filament representation theory, viscose non-woven material is made by it.Between they and staple fibre, should form difference, be shorter than the long filament of mentioning before this in any case described staple fibre is relatively short yarn and average far.Long filament used according to the invention especially is made up of one or more thermoplastics.
Background technology
From practical application, known a large amount of system and method is used for the manufacturing of viscose non-woven material.Known viscose non-woven material, it particularly is made of monofilament, about their mechanical performance also have many have to be achieved, especially about tensile strength and energy storage (maximum strength).This relates in particular to the viscose non-woven material with medium and heavy mass area ratio, described mass area ratio from about 30 to 40g/m
2Because the limited thermal conductivity of plastics that is used, during these had the heat bonding of viscose non-woven material of higher mass area ratio, the energy that is difficult to provide enough was input to the center of described viscose non-woven material.However, during the heat bonding in calender, still attempt to connect in each rag point on the whole thickness of described viscose non-woven material as far as possible the long filament of described viscose non-woven material.This may cause the peripheral region to become fragile, yet it may cause the too early destruction of described nonwoven material under the mechanical stress effect.Adopt for example 17g/m
2Low mass area ratio, adopt for example traditional material and the standard fiber number (1.8-2 DENIER) of polypropylene filament, obtain longitudinal strength up to about 50N/5cm.The mensuration of described longitudinal strength realizes according to the 3rd part of ISO9073 in this example.This respectively with 2.94N/5cm:g/m
2The perhaps certain strength unanimity of N.m2/5cm.g.Yet when mass area ratio rose, described certain strength descended, and drops to less than 2.5, and when described per unit area mass value further rose, it dropped to 2.By using thinner long filament, in fact might improve the certain amount of described strength factor, but can not obtain to surpass 3 strength factor by higher unit plane mass value.
Summary of the invention
In contrast to this, the present invention is based on the intensity that improves viscose non-woven material respectively and the technical problem of tensile strength, described viscose non-woven material has above 50g/m
2Higher mass area ratio.The present invention is further based on such technical problem, and it provides a kind of method that this viscose non-woven material is produced that is used for.
In order to solve this technical problem, the present invention has instructed a kind of viscose non-woven material of being made by continuous filament yarn or fiber, and described thus continuous filament yarn or fiber are multicomponent filaments, specifically bicomponent filament, has at least a low-melting component at outer surface
This is a kind of viscose non-woven material of heat bonding in has less than the calender of 22% embossing/embossed surface thus,
And described thus viscose non-woven material shows one and surpasses 50g/m
2Mass area ratio.
The embossing surface of described calender refers to the active surface zone, and this active surface zone is created in the tie point in the viscose non-woven material or between long filament respectively during heat bonding.In other words, this is the surface that acts directly on the long filament.Usually, described embossed surface is formed by the embossed spots of the embossing cylinder of described calender.A knurling rolls-smooth roll that is used as described calender is to falling into scope of the present invention.Described viscose non-woven material one have at least 10% and the calender of preferred at least 12% embossing face in by heat bonding, this falls into scope of the present invention.
In scope of the present invention, the fiber number value that the long filament that is used has between the 1.8-2.5 DENIER is suitable.Also might use thinner long filament, yet: in principle, therefore, the long filament that is used in the scope of the invention has the fiber number between the 0.8-2.5 DENIER.
Long filament used according to the invention preferably forms the more dystectic component of having of long filament core by a low-melting component that is arranged on described long filament outer surface and one and forms.According to a highly preferred embodiment of the present invention, multicomponent filaments used according to the invention, particularly bicomponent filament show a skin-core structure and described in this article low-melting component and form epitheca.Compare, Min. is the core that a kind of more dystectic component forms described long filament.It falls among the scope of the present invention, and in having the long filament of skin-core structure, the epitheca that described core is formed by described low-melting component surrounds fully.In addition, described core and the epitheca whole length that extends beyond long filament falls into scope of the present invention.
According to a particularly preferred embodiment of the present invention, described low-melting component shows a fusing point than low at least 5 ℃ of the fusing point of described more high melting point component, and preferred low at least 10 ℃, and preferred especially low at least 15 ℃.Suitably, the fusing point of described low-melting component hangs down at least 20 ℃ than the fusing point of described more high melting point component.Preferably, the fusing point of described low-melting component is about 120 ℃ or higher.According to a preferred embodiment of the present invention, described low-melting component is the mixture of polyolefin or polyolefin and their copolymers.According to an embodiment of the invention, described low-melting component is a polyethylene, and described high melting point component is a polypropylene.In this case, polyethylene forms the epitheca of skin-core structure thus, and polypropylene forms the core of described long filament.According to another implementation of the invention, described low-melting component is polypropylene-co-polymer, and its softening point or fusing point are lower than the softening point or the fusing point of virgin pp.According to a back embodiment, described more high melting point component is made up of polypropylene suitably.Also be according to this embodiment, be fit to for the skin-core structure that will form that described thus polypropylene-co-polymer forms described epitheca, described polypropylene forms the core of described long filament.Described polypropylene-co-polymer is polypropylene-polyethylene and ethylene copolymers preferably.This copolymer can be heteroplastic.Also in scope of the present invention, for example for the non-heteroplastic polypropylene-polyethylene and ethylene copolymers that uses, it comprises the polyethylene part of preferred 2-6% weight for it.According to an embodiment of the invention, replace described polypropylene co-polymer, polypropylene terpolymer also can be used as described low-melting component, and preferably this is the terpolymer of a kind of polypropylene-polyethylene-polybutene thus.According to another implementation of the invention, polyethylene or polypropylene might be used as described low-melting component, and polyester is used as described high melting point component.By preferred skin-core structure, described polyethylene or polypropylene form described epitheca respectively, and described polyester forms described core.
Low-melting component in the long filament partly reaches 10-40% weight, and preferably reaches the weight of 15-35%, and this falls into scope of the present invention.In this case, weight percentage data is relevant with whole long filament.Therefore the total amount of described more high melting point component part preferably reaches the weight of 90-60%, and preferably reaches the weight of 85-65%.
Suitable, viscose non-woven material according to the present invention is a kind of like this viscose non-woven material, its in one has less than the calender of 20% embossing face by heat bonding.According to a particularly preferred embodiment of the present invention, described viscose non-woven material shows greater than 60g/m
2Mass area ratio.
In order to solve described technical problem, the present invention has further instructed a kind of method that is used for the manufacturing of viscose non-woven material.
A supatex fabric pad is formed by continuous filament yarn thus, and described continuous filament yarn is formed by bicomponent filament especially by multicomponent filaments, and described continuous filament yarn shows as a low-melting component on its outer surface.
Thus the supatex fabric pad in one has less than the calender of 22% embossing face by heat bonding.
And a viscose non-woven material is produced thus, and it has greater than 50g/m
2Mass area ratio.
By means of described calender, tie point produces between long filament.In scope of the present invention, tie point refers to because the long filament zone that the effect of calender is softened, and is formed at the join domain of this place and adjacent filament.In an embodiment of the invention, only be softened in the long filament perimeter about filament cross at tie point, core area is not softened and keeps avoiding softening.If the fusing point difference about described low melting point and high melting point component is bigger, promptly for example by polyolefin as described low-melting component and polyester as described high melting point component, this possibility exists especially.According to an embodiment of the invention, outer surface or the epitheca of only being made by described low-melting component softened or fusing to small part in this case, and the core of being made by described high melting point component keeps avoiding fully softening.This is also among scope of the present invention, that is, outer surface of being made by described low-melting component or epitheca are softened or melt, and has only the surf zone of described core to be softened or melt, and the other maintenance of described core avoids softening basically.Highly preferred embodiment of the present invention is characterized in that described heat bonding is realized by such principle, promptly in the tie point zone or the described more dystectic component at the tie point place avoid softening fully or basically.Basically avoid softening referring to cross section about long filament at the tie point place, preferred high melting point component 75-90% weight keeps avoiding softening.
The present invention is based on such discovery, respectively since according to the present invention the embodiment of viscose non-woven material, the perhaps long filament of viscose non-woven material according to the present invention, energy applications extends into the centre of described nonwoven material during heat bonding, connects described long filament in order to pass described low melting point cladding material.On the other hand, the disadvantageous thermal damage in other long filament zone does not take place.This has caused such situation, and viscose non-woven material according to the present invention is characterised in that surprising high intensity or tensile strength.Might make and have above 50g/m
2The viscose non-woven material of higher mass area ratio value, and more particularly surpass 60g/m
2, it shows so surprising high intensity or tensile strength.Being higher than 3 longitudinal strength coefficient is obtained by these high mass area ratio values.
The specific embodiment
The present invention is explained in more detail according to embodiment hereinafter:
The specific embodiment 1:
A viscose non-woven material is by the bicomponent filament manufacturing, and this long filament shows the fiber number (1.8-2 DENIER) of a standard thus.Described bicomponent filament has a skin-core structure, and the epitheca of a polypropylene core and a polypropylene copolymer specifically, and the fusing point of described epitheca is compared lower with the polypropylene in the core.Described polypropylene copolymer is special-shaped polypropylene-polyethylene and ethylene copolymers.The ratio of core constituent is that the ratio of 80% weight and sheath component is 20% weight.The spunbond non-manufactured materials of making has 60g/m
2Mass area ratio.Heat bonding is finished by an embossing calender according to the present invention.Obtain the longitudinal strength of a 220N/5cm and one 3.6 longitudinal strength coefficient.
The specific embodiment 2:
A viscose non-woven material is by the bicomponent filament manufacturing with standard fiber number.Skin-core structure of described bicomponent filament performance.Core constituent is that polypropylene and sheath component are polyethylene.The ratio of core constituent is that the ratio of 70% weight and sheath component is 30% weight.Described viscose non-woven material has 55g/m
2Mass area ratio.This spunbond non-manufactured materials also by a calender according to the present invention by heat bonding.Obtain the longitudinal strength of a 220N/5cm and one 4 longitudinal strength coefficient.
The specific embodiment 3:
About this embodiment, a fine fibre nonwoven material is by the bicomponent filament manufacturing with 1.1 DENIER fiber numbers equally, and it has a skin-core structure.Core is made up of polypropylene and epitheca is made up of polyethylene.The ratio of core constituent is that the ratio of 70% weight and sheath component is 30% weight.Described fine fibre nonwoven material has 55g/m
2Mass area ratio.After the heat bonding, determining the longitudinal strength of a 280N/5cm and one 5.1 longitudinal strength coefficient according to the present invention by a calender.
Unique accompanying drawing has shown the cross section that passes according to bicomponent filament of the present invention, and this bicomponent filament has a skin-core structure.Epitheca 1, its preferred and as at the described core of encirclement fully shown in the specific embodiment, it for example is made up of polyethylene or polypropylene copolymer.The core 2 that is surrounded by epitheca 1 can be made up of polypropylene in the embodiment that illustrates fully.Yet according to another embodiment, this core 2 also can be made up of polyester or other plastics, and it is compared with sheath component has higher softening temperature.
Claims (8)
1. viscose non-woven material of making by continuous filament yarn or fiber, described thus continuous filament yarn is a multicomponent filaments, bicomponent filament particularly, it has low-melting component at outer surface,
This is a kind of viscose non-woven material of heat bonding in has less than the calender on 22% embossing surface thus,
And described thus viscose non-woven material shows above 50g/m
2Mass area ratio.
2. viscose non-woven material as claimed in claim 1 is characterized in that, described multicomponent filaments, particularly bicomponent filament show a skin-core structure, and described thus low-melting component forms epitheca.
3. as a described viscose non-woven material in claim 1 or 2, it is characterized in that described low-melting component shows a fusing point than low at least 5 ℃ of the fusing point of described more high melting point component.
4. as a described viscose non-woven material among the claim 1-3, it is characterized in that described low-melting component is a polyolefin.
5. as a described viscose non-woven material among the claim 1-4, it is characterized in that the ratio of low-melting component described in the long filament reaches 10-40% weight, and preferred 15-35% weight.
6. as a described viscose non-woven material among the claim 1-5, it is characterized in that, this be a kind of in one has less than the calender of 20% embossing face by the viscose non-woven material of heat bonding.
7. as a described viscose non-woven material among the claim 1-5, it is characterized in that described viscose non-woven material has above 60g/m
2Mass area ratio.
8. be used for producing method as the described viscose non-woven material of claim 1-7,
A supatex fabric pad is formed by continuous filament yarn or fiber thus, and described continuous filament yarn or fiber form multicomponent filaments, forms bicomponent filament especially, and described continuous filament yarn or fiber have a low-melting component at outer surface,
Described thus supatex fabric pad in one has less than the calender of 22% embossing face by heat bonding,
And a kind of thus have greater than 50g/m
2The viscose non-woven material of mass area ratio is produced.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP03018108A EP1505187B1 (en) | 2003-08-08 | 2003-08-08 | Spunbonded nonwoven fabric and process for making the same |
| EP03018108.5 | 2003-08-08 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1580345A true CN1580345A (en) | 2005-02-16 |
| CN100336956C CN100336956C (en) | 2007-09-12 |
Family
ID=33547667
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004100696438A Expired - Fee Related CN100336956C (en) | 2003-08-08 | 2004-07-15 | Spunbonded nonwoven fabric and process for making the same |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20050041312A1 (en) |
| EP (1) | EP1505187B1 (en) |
| CN (1) | CN100336956C (en) |
| AT (1) | ATE333528T1 (en) |
| DE (1) | DE50304289D1 (en) |
| DK (1) | DK1505187T3 (en) |
| ES (1) | ES2265079T3 (en) |
| MY (1) | MY140892A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104662217A (en) * | 2012-09-20 | 2015-05-27 | 旭化成纤维株式会社 | Pulling a semiconductor single crystal according to the czochralski method and silica glass crucible suitable therefor |
| CN113308802A (en) * | 2021-06-03 | 2021-08-27 | 四川亿耐特新材料有限公司 | Non-woven fabric forming process |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102007011365B4 (en) * | 2007-03-07 | 2009-02-12 | Carl Freudenberg Kg | Position for use in a HEPA filter element and filter element |
| DE102007021374B4 (en) * | 2007-05-04 | 2010-06-17 | Carl Freudenberg Kg | Non-woven fabric cover with low coefficient of friction for feminine hygiene, in particular for tampons, or for medical purposes, as well as its use |
| EP3508459A1 (en) | 2018-01-09 | 2019-07-10 | OCV Intellectual Capital, LLC | Fiber reinforced materials with improved fatigue performance |
| CN113301877A (en) * | 2019-02-15 | 2021-08-24 | 易希提卫生与保健公司 | Absorbent article with embossed surface layer |
| EP3771761B1 (en) * | 2019-07-30 | 2021-05-19 | Reifenhäuser GmbH & Co. KG Maschinenfabrik | Spunbond nonwoven fabric made from endless filaments and device for producing spunbond nonwoven fabric |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4211816A (en) * | 1977-03-11 | 1980-07-08 | Fiber Industries, Inc. | Selfbonded nonwoven fabrics |
| US5336552A (en) * | 1992-08-26 | 1994-08-09 | Kimberly-Clark Corporation | Nonwoven fabric made with multicomponent polymeric strands including a blend of polyolefin and ethylene alkyl acrylate copolymer |
| US5405682A (en) * | 1992-08-26 | 1995-04-11 | Kimberly Clark Corporation | Nonwoven fabric made with multicomponent polymeric strands including a blend of polyolefin and elastomeric thermoplastic material |
| US5662978A (en) * | 1995-09-01 | 1997-09-02 | Kimberly-Clark Worldwide, Inc. | Protective cover fabric including nonwovens |
| EP1177338B1 (en) * | 1999-04-30 | 2005-07-06 | Kimberly-Clark Worldwide, Inc. | Stretchable nonwoven material |
| US20010019931A1 (en) * | 1999-11-29 | 2001-09-06 | Rosaldo Fare | Method for making improved sealability polyolefin fibers, the fibers made thereby and non-woven textile materials including the fibers |
| US20030056883A1 (en) * | 2001-09-26 | 2003-03-27 | Vishal Bansal | Method for making spunbond nonwoven fabric from multiple component filaments |
| US7008888B2 (en) * | 2003-07-24 | 2006-03-07 | E. I. Du Pont De Nemours And Company | Multiple component spunbond web |
-
2003
- 2003-08-08 AT AT03018108T patent/ATE333528T1/en not_active IP Right Cessation
- 2003-08-08 EP EP03018108A patent/EP1505187B1/en not_active Revoked
- 2003-08-08 ES ES03018108T patent/ES2265079T3/en not_active Expired - Lifetime
- 2003-08-08 DE DE50304289T patent/DE50304289D1/en not_active Revoked
- 2003-08-08 DK DK03018108T patent/DK1505187T3/en active
-
2004
- 2004-06-22 MY MYPI20042442A patent/MY140892A/en unknown
- 2004-07-15 CN CNB2004100696438A patent/CN100336956C/en not_active Expired - Fee Related
- 2004-07-30 US US10/912,740 patent/US20050041312A1/en not_active Abandoned
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104662217A (en) * | 2012-09-20 | 2015-05-27 | 旭化成纤维株式会社 | Pulling a semiconductor single crystal according to the czochralski method and silica glass crucible suitable therefor |
| CN113308802A (en) * | 2021-06-03 | 2021-08-27 | 四川亿耐特新材料有限公司 | Non-woven fabric forming process |
Also Published As
| Publication number | Publication date |
|---|---|
| DK1505187T3 (en) | 2006-10-30 |
| EP1505187B1 (en) | 2006-07-19 |
| DE50304289D1 (en) | 2006-08-31 |
| US20050041312A1 (en) | 2005-02-24 |
| CN100336956C (en) | 2007-09-12 |
| EP1505187A1 (en) | 2005-02-09 |
| ES2265079T3 (en) | 2007-02-01 |
| MY140892A (en) | 2010-01-29 |
| ATE333528T1 (en) | 2006-08-15 |
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Address after: Troisdorf, Germany Patentee after: Machine factory of leffinhauser Co.,Ltd. Address before: Troisdorf, Germany Patentee before: Reifenhauser GmbH & Co. Maschinenfabrik |
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Granted publication date: 20070912 |