CN1521145A - Crystalline glaze with metallic luster for ceramic of building sanitation - Google Patents

Crystalline glaze with metallic luster for ceramic of building sanitation Download PDF

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Publication number
CN1521145A
CN1521145A CNA031180906A CN03118090A CN1521145A CN 1521145 A CN1521145 A CN 1521145A CN A031180906 A CNA031180906 A CN A031180906A CN 03118090 A CN03118090 A CN 03118090A CN 1521145 A CN1521145 A CN 1521145A
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CN
China
Prior art keywords
glaze
ceramic
oxide
crystalline glaze
crystalline
Prior art date
Application number
CNA031180906A
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Chinese (zh)
Inventor
谭红军
Original Assignee
谭红军
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 谭红军 filed Critical 谭红军
Priority to CNA031180906A priority Critical patent/CN1521145A/en
Publication of CN1521145A publication Critical patent/CN1521145A/en

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Abstract

The crystalline glaze with metallic color and luster for building and sanitary ceramic is produced with zinc oxide, silicon oxide or titanium oxide as the crystallizing matter, low temperature fused block and boric acid as flux for forming glaze vitreous body, and the oxide of Cu, Fe, Mn, Ti and other metal as coloring agent, and through common ceramic glaze producing process. It is applied to the surface of building and sanitary ceramic and baked through fast continuous procedure. Adopting special short crystal forming period forms glass ceramic layer with metallic color and luster on the glaze surface and makes the glaze possess decorative metallic color and luster and high mechanical strength similar to glass ceramic. The present invention may be used widely in the surface decoration of various building ceramic products and sanitary ceramic products.

Description

Construction sanitary ceramic metalluster crystalline glaze
The invention belongs to the new enamel of a kind of construction sanitary ceramic decoration.
Generally adopt glassiness color glaze to decorate at present in the construction sanitary ceramic field, these color glaze have with the base substrate cooperation better, in a great variety, lower-price characteristic, but it exists glaze softer, can not form defectives such as metalluster.The crystalline glaze technology is also used in the daily art pottery, and a kind of decoration glaze of star, needle-like or the thick aggregate of floral leaf shape also can not form full overglaze metallic luster but it is just distributing on glaze.Now along with people to improving constantly that the construction sanitary ceramic decorative art requires, each enterprise constantly releases the product of various imitative stone materials, but all still untapped construction sanitary ceramic product that goes out to imitate metalluster.
The objective of the invention is to develop the new glaze of metallic surface glossy construction sanitary ceramic such as a kind of imitative gold and silver, copper.
Technology contents of the present invention mainly is the prescription problem that solves glaze, and according to the graceful crystallization theory of Thailand, the melt crystallization at first will have the one-tenth eutectic substance that is in hypersaturated state, to form nucleus; When next is the melt cooling, must in the crystalline range of this material, be incubated, so that the nucleus growing, and the different choice of holding temperature and soaking time can be controlled brilliant size and the shape of spending again.Imitative metalluster crystalline glaze can produce brilliant flower under certain calcining system, brilliant flower specification comprises large, medium and small, crystallite flower, and brilliant flower Board Lot, distribution density can be controlled by technological measures such as crystal seed ratio, glaze amount, calcining systems.Large, medium and small, brilliant flower is because the light refraction effect of wafer produces reflecting effect, and is painted by metal oxide, forms versicolor gloss.The present invention is exactly a this reflective characteristic of utilizing brilliant flower, develops from prescription to be fit to the crystalline glaze prescription that construction sanitary ceramic becomes the porcelain scope, and wherein zinc oxide, silicon oxide and titanium oxide are the eutectic substance that becomes of above-mentioned glaze; Low temperature melts alkynes, boric acid for forming the Vitrea flux raw material of glaze; Cupric oxide, ferric oxide, manganese oxide, titanium oxide etc. are tinting material, and it is painted that glaze glass and crystalline substance are spent.Because crystallizing layer of the present invention is thicker, crystal grain distributes uniform, is equivalent to form a glass-ceramic layer in billet surface, has improved the physical strength of glaze layer greatly, thereby ornamental brick has been risen to the class level of polished tile.
The object of the present invention is achieved like this: with the one-tenth eutectic substance of crystalline glaze, form Vitrea flux raw material of glaze and metal oxide tinting material and mix by a certain percentage, be made by the preparation method of general pottery with glaze.
Golden gloss crystalline glaze material formula weight percent is formed:
Low temperature frit: 30~75% boric acid: 0.1~3% zinc oxide: 20~35%
Titanium oxide: 1~35% cupric oxide: 0.1~0.5%
Coppery gloss crystalline glaze material formula weight percent is formed:
Low temperature frit: 30~75% boric acid, 0.1~3% zinc oxide: 20~35%
Titanium oxide: 1~35% ferric oxide: 0.5~5% manganese oxide: 0.5~3%
Silvering crystalline glaze material formula weight percent is formed:
Low temperature frit 30~75%, boric acid 0.1~0.3%, zinc oxide 20~35%
Cupric oxide 0.1~2.5%
The low temperature frit that this assembly side uses comprises a kind of of glass, boron frit, lead frit and plumbous boron frit.
Compared with prior art, the present invention has following characteristics:
1, having utilized the reflecting effect of brilliant flower wafer in the crystalline glaze, produced the glaze with metalluster, made that the surface decoration effect of construction sanitary ceramic is abundanter, is a brand-new field.
2, because this crystalline glaze is equivalent to form one deck devitrified glass on base substrate, improves the overglaze physical strength greatly, as imposed on the floor tile, will rise to ornamental brick the class level of polished tile.
Embodiment one: golden gloss crystalline glaze material formula weight percent composition is:
Low temperature frit: 65% boric acid: 2% zinc oxide: 26%
Titanium oxide: 6.6% cupric oxide: 0.4%
Embodiment two: coppery gloss crystalline glaze material formula weight percent composition is:
Low temperature frit: 65% boric acid: 2% zinc oxide: 26%
Titanium oxide: 4% ferric oxide: 1.5% manganese oxide: 1.5%
Embodiment three: silvering crystalline glaze material formula weight percent composition is:
Low temperature frit: 65% boric acid: 2.5% zinc oxide: 31%
Cupric oxide: 1.5%
Above-mentioned glaze preparation technology controlling index is:
1, glaze fineness: 10000-hole sieve surpluss 0.01~1.5%
2, glaze concentration: 15~75%
3, glazing thickness: 0.01~5.0mm
4, glazing mode: drench, soak, spray, get rid of glaze and all can.
Above-mentioned glaze is imposed on when burning till on the floor tile, and its heating curve that burns till roller kiln is:
Normal temperature → 800~1300 ℃ 20~60mim;
800~1300℃→ 600~1220℃ 1~60mim;
At 600~1220 ℃ of soaking time: 5~120mim.

Claims (4)

1, a kind of construction sanitary ceramic metalluster crystalline glaze is characterized in that: the basic percentage composition part and the proportioning of this crystallization glaze are:
Raw material: proportioning (wt%)
Low temperature frit: 30~75%
Boric acid: 0.1~3%
Zinc oxide: 20~35%
2, construction sanitary ceramic according to claim 1 metalluster crystalline glaze is characterized in that: being golden glossy crystalline glaze is to have added 1~35% titanium oxide and 0.1~0.5% cupric oxide in its basic proportioning.
3, construction sanitary ceramic according to claim 1 metalluster crystalline glaze is characterized in that: being coppery glossy crystalline glaze is to have added 1~35% titanium oxide, 0.5~5% ferric oxide and 0.5~3% manganese oxide in its basic proportioning.
4, construction sanitary ceramic according to claim 1 metalluster crystalline glaze is characterized in that: be silvery crystalline glaze and be add 0.1~2.5% cupric oxide in its basic proportioning.
CNA031180906A 2003-02-14 2003-02-14 Crystalline glaze with metallic luster for ceramic of building sanitation CN1521145A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNA031180906A CN1521145A (en) 2003-02-14 2003-02-14 Crystalline glaze with metallic luster for ceramic of building sanitation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNA031180906A CN1521145A (en) 2003-02-14 2003-02-14 Crystalline glaze with metallic luster for ceramic of building sanitation

Publications (1)

Publication Number Publication Date
CN1521145A true CN1521145A (en) 2004-08-18

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CN (1) CN1521145A (en)

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1321094C (en) * 2005-12-23 2007-06-13 胡武强 Ceramic glaze material and method for burning ceramic glaze
CN100410197C (en) * 2007-02-02 2008-08-13 南安协进建材有限公司 Method for producing metal enamel
CN100455549C (en) * 2007-06-14 2009-01-28 湖南华联瓷业股份有限公司 Medium and high temperature sintered coarse crystalline Fe-Ti glaze and its prepn process
CN101880178A (en) * 2010-07-13 2010-11-10 广东道氏标准制釉股份有限公司 Ceramic glazed tile with gold metal effect and preparation method thereof
CN101935233A (en) * 2010-09-28 2011-01-05 广东道氏标准制釉股份有限公司 Low-temperature glaze with silver white metal luster and preparation method thereof
CN102249739A (en) * 2011-05-26 2011-11-23 山西高陶瓷业有限责任公司 Preparation method of carbon-golden metallic luster crystalline glaze
CN102701792A (en) * 2012-06-19 2012-10-03 卡罗比亚釉料(昆山)有限公司 Black glaze for preparing ceramic
CN102795839A (en) * 2012-08-22 2012-11-28 陈永定 Method for manufacturing red clay flambe-glazed pottery product
CN103992695A (en) * 2014-05-21 2014-08-20 佛山远牧数码科技有限公司 Ceramic printing ink with crystallizing effect, and preparation and application methods thereof
CN104193411A (en) * 2014-08-05 2014-12-10 广东道氏技术股份有限公司 Crystalline glaze for sanitary ceramic sanitary ware and preparation process thereof
CN105152685A (en) * 2015-10-19 2015-12-16 福建省德化县华茂陶瓷有限公司 Matte metal glaze, matte metal glaze ceramic product prepared from same and preparation method of matte metal glaze ceramic product
CN105565907A (en) * 2015-12-23 2016-05-11 蒙娜丽莎集团股份有限公司 Production method of flambe crystal pattern seeding color-fixing ceramic tile
CN106430967A (en) * 2016-08-31 2017-02-22 广东金意陶陶瓷有限公司 Dyeing-assistant fancy glaze capable of promoting pigment color development and ceramic tile prepared from same
CN106565281A (en) * 2016-11-14 2017-04-19 蒙娜丽莎集团股份有限公司 Fully-polished-glaze ceramic tile with metal particles and metallic luster and manufacturing method thereof
CN106626935A (en) * 2016-09-30 2017-05-10 詹良富 High-temperature preparing method of metallic color effect embosses capable of overlaying gold and metallic color effect embosses
CN106747660A (en) * 2015-11-20 2017-05-31 广东顺祥陶瓷有限公司 A kind of zinc boron fritted glaze high
CN108715517A (en) * 2018-08-30 2018-10-30 佛山市荣冠玻璃建材有限公司 Potlery tile low temperature is burnt joss sticks Bin golden metallic luster glaze and preparation method slowly

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1321094C (en) * 2005-12-23 2007-06-13 胡武强 Ceramic glaze material and method for burning ceramic glaze
CN100410197C (en) * 2007-02-02 2008-08-13 南安协进建材有限公司 Method for producing metal enamel
CN100455549C (en) * 2007-06-14 2009-01-28 湖南华联瓷业股份有限公司 Medium and high temperature sintered coarse crystalline Fe-Ti glaze and its prepn process
CN101880178B (en) * 2010-07-13 2012-03-28 广东道氏技术股份有限公司 Ceramic glazed tile with gold metal effect and preparation method thereof
CN101880178A (en) * 2010-07-13 2010-11-10 广东道氏标准制釉股份有限公司 Ceramic glazed tile with gold metal effect and preparation method thereof
CN101935233A (en) * 2010-09-28 2011-01-05 广东道氏标准制釉股份有限公司 Low-temperature glaze with silver white metal luster and preparation method thereof
CN101935233B (en) * 2010-09-28 2011-07-27 广东道氏标准制釉股份有限公司 Low-temperature glaze with silver white metal luster and preparation method thereof
CN102249739B (en) * 2011-05-26 2013-01-16 山西高陶瓷业有限责任公司 Preparation method of carbon-golden metallic luster crystalline glaze
CN102249739A (en) * 2011-05-26 2011-11-23 山西高陶瓷业有限责任公司 Preparation method of carbon-golden metallic luster crystalline glaze
CN102701792A (en) * 2012-06-19 2012-10-03 卡罗比亚釉料(昆山)有限公司 Black glaze for preparing ceramic
CN102701792B (en) * 2012-06-19 2014-02-05 卡罗比亚釉料(昆山)有限公司 Black glaze for preparing ceramic
CN102795839A (en) * 2012-08-22 2012-11-28 陈永定 Method for manufacturing red clay flambe-glazed pottery product
CN102795839B (en) * 2012-08-22 2014-03-05 陈永定 Method for manufacturing red clay flambe-glazed pottery product
CN103992695A (en) * 2014-05-21 2014-08-20 佛山远牧数码科技有限公司 Ceramic printing ink with crystallizing effect, and preparation and application methods thereof
CN104193411A (en) * 2014-08-05 2014-12-10 广东道氏技术股份有限公司 Crystalline glaze for sanitary ceramic sanitary ware and preparation process thereof
CN105152685A (en) * 2015-10-19 2015-12-16 福建省德化县华茂陶瓷有限公司 Matte metal glaze, matte metal glaze ceramic product prepared from same and preparation method of matte metal glaze ceramic product
CN106747660A (en) * 2015-11-20 2017-05-31 广东顺祥陶瓷有限公司 A kind of zinc boron fritted glaze high
CN105565907A (en) * 2015-12-23 2016-05-11 蒙娜丽莎集团股份有限公司 Production method of flambe crystal pattern seeding color-fixing ceramic tile
CN106430967A (en) * 2016-08-31 2017-02-22 广东金意陶陶瓷有限公司 Dyeing-assistant fancy glaze capable of promoting pigment color development and ceramic tile prepared from same
CN106626935A (en) * 2016-09-30 2017-05-10 詹良富 High-temperature preparing method of metallic color effect embosses capable of overlaying gold and metallic color effect embosses
CN106565281A (en) * 2016-11-14 2017-04-19 蒙娜丽莎集团股份有限公司 Fully-polished-glaze ceramic tile with metal particles and metallic luster and manufacturing method thereof
CN106565281B (en) * 2016-11-14 2019-09-06 蒙娜丽莎集团股份有限公司 A kind of full throwing glaze Ceramic Tiles and preparation method thereof with metallic particles and gloss
CN108715517A (en) * 2018-08-30 2018-10-30 佛山市荣冠玻璃建材有限公司 Potlery tile low temperature is burnt joss sticks Bin golden metallic luster glaze and preparation method slowly

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