CN1500167A - 含有阳离子紫外光吸收剂的织物淋洗组合物 - Google Patents
含有阳离子紫外光吸收剂的织物淋洗组合物 Download PDFInfo
- Publication number
- CN1500167A CN1500167A CNA028074467A CN02807446A CN1500167A CN 1500167 A CN1500167 A CN 1500167A CN A028074467 A CNA028074467 A CN A028074467A CN 02807446 A CN02807446 A CN 02807446A CN 1500167 A CN1500167 A CN 1500167A
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- composition
- alkylidene
- formula
- alkyl
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- 239000004744 fabric Substances 0.000 title claims abstract description 45
- 239000006096 absorbing agent Substances 0.000 title abstract description 4
- 125000002091 cationic group Chemical group 0.000 title 1
- 239000000203 mixture Substances 0.000 claims abstract description 64
- 239000001257 hydrogen Substances 0.000 claims abstract description 19
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000002979 fabric softener Substances 0.000 claims abstract description 8
- 125000004433 nitrogen atom Chemical group N* 0.000 claims abstract description 8
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 4
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims abstract description 4
- ZCILGMFPJBRCNO-UHFFFAOYSA-N 4-phenyl-2H-benzotriazol-5-ol Chemical compound OC1=CC=C2NN=NC2=C1C1=CC=CC=C1 ZCILGMFPJBRCNO-UHFFFAOYSA-N 0.000 claims abstract description 3
- VMRIVYANZGSGRV-UHFFFAOYSA-N 4-phenyl-2h-triazin-5-one Chemical compound OC1=CN=NN=C1C1=CC=CC=C1 VMRIVYANZGSGRV-UHFFFAOYSA-N 0.000 claims abstract description 3
- 150000001449 anionic compounds Chemical class 0.000 claims abstract description 3
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000012965 benzophenone Substances 0.000 claims abstract description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims abstract description 3
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims abstract description 3
- 229910001412 inorganic anion Inorganic materials 0.000 claims abstract description 3
- 150000002891 organic anions Chemical class 0.000 claims abstract description 3
- 125000004430 oxygen atom Chemical group O* 0.000 claims abstract description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 3
- 125000003944 tolyl group Chemical group 0.000 claims abstract description 3
- 238000005406 washing Methods 0.000 claims description 40
- 239000002250 absorbent Substances 0.000 claims description 39
- 230000002745 absorbent Effects 0.000 claims description 37
- -1 4Be hydrogen Chemical class 0.000 claims description 25
- 238000000034 method Methods 0.000 claims description 20
- 239000003760 tallow Substances 0.000 claims description 20
- JZMJDSHXVKJFKW-UHFFFAOYSA-N methyl sulfate Chemical group COS(O)(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-N 0.000 claims description 19
- 239000004753 textile Substances 0.000 claims description 17
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims description 14
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 11
- 125000004429 atom Chemical group 0.000 claims description 8
- 229910052736 halogen Inorganic materials 0.000 claims description 8
- 150000002367 halogens Chemical class 0.000 claims description 8
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 150000002431 hydrogen Chemical class 0.000 claims description 6
- 229920000742 Cotton Polymers 0.000 claims description 5
- 125000003342 alkenyl group Chemical group 0.000 claims description 5
- 125000001118 alkylidene group Chemical group 0.000 claims description 4
- 238000007046 ethoxylation reaction Methods 0.000 claims description 4
- 150000002191 fatty alcohols Chemical class 0.000 claims description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 150000005846 sugar alcohols Polymers 0.000 claims description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims description 3
- 239000012752 auxiliary agent Substances 0.000 claims description 3
- 239000002585 base Substances 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 150000002460 imidazoles Chemical class 0.000 claims description 3
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 claims description 2
- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical compound CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- 239000004952 Polyamide Substances 0.000 claims description 2
- 229920002125 Sokalan® Polymers 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
- 230000000844 anti-bacterial effect Effects 0.000 claims description 2
- 239000003899 bactericide agent Substances 0.000 claims description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 230000007797 corrosion Effects 0.000 claims description 2
- 238000005260 corrosion Methods 0.000 claims description 2
- OGQYPPBGSLZBEG-UHFFFAOYSA-N dimethyl(dioctadecyl)azanium Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC OGQYPPBGSLZBEG-UHFFFAOYSA-N 0.000 claims description 2
- 239000003995 emulsifying agent Substances 0.000 claims description 2
- 125000005456 glyceride group Chemical group 0.000 claims description 2
- 239000003112 inhibitor Substances 0.000 claims description 2
- XLSZMDLNRCVEIJ-UHFFFAOYSA-N methylimidazole Natural products CC1=CNC=N1 XLSZMDLNRCVEIJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000002480 mineral oil Substances 0.000 claims description 2
- 235000010446 mineral oil Nutrition 0.000 claims description 2
- 239000003605 opacifier Substances 0.000 claims description 2
- 239000004584 polyacrylic acid Substances 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- 235000013599 spices Nutrition 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- 125000006656 (C2-C4) alkenyl group Chemical group 0.000 claims 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 1
- 239000006081 fluorescent whitening agent Substances 0.000 claims 1
- 125000005527 methyl sulfate group Chemical group 0.000 claims 1
- 230000000474 nursing effect Effects 0.000 claims 1
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 210000003491 skin Anatomy 0.000 description 15
- 150000001875 compounds Chemical class 0.000 description 14
- 230000004224 protection Effects 0.000 description 7
- 230000005855 radiation Effects 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000006378 damage Effects 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000000975 dye Substances 0.000 description 4
- MOYKHGMNXAOIAT-JGWLITMVSA-N isosorbide dinitrate Chemical compound [O-][N+](=O)O[C@H]1CO[C@@H]2[C@H](O[N+](=O)[O-])CO[C@@H]21 MOYKHGMNXAOIAT-JGWLITMVSA-N 0.000 description 4
- 229960000201 isosorbide dinitrate Drugs 0.000 description 4
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 238000005160 1H NMR spectroscopy Methods 0.000 description 3
- MSXVEPNJUHWQHW-UHFFFAOYSA-N 2-methylbutan-2-ol Chemical compound CCC(C)(C)O MSXVEPNJUHWQHW-UHFFFAOYSA-N 0.000 description 3
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N DMSO Substances CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005562 fading Methods 0.000 description 3
- 239000002657 fibrous material Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 239000003223 protective agent Substances 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- 206010013786 Dry skin Diseases 0.000 description 2
- KLDXJTOLSGUMSJ-JGWLITMVSA-N Isosorbide Chemical compound O[C@@H]1CO[C@@H]2[C@@H](O)CO[C@@H]21 KLDXJTOLSGUMSJ-JGWLITMVSA-N 0.000 description 2
- 206010034972 Photosensitivity reaction Diseases 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 239000002671 adjuvant Substances 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 238000005660 chlorination reaction Methods 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 229960002479 isosorbide Drugs 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- XIUCEANTZSXBQQ-UHFFFAOYSA-N (3-chloro-2-hydroxypropyl)-trimethylazanium Chemical compound C[N+](C)(C)CC(O)CCl XIUCEANTZSXBQQ-UHFFFAOYSA-N 0.000 description 1
- 241001044369 Amphion Species 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 206010015150 Erythema Diseases 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 208000028990 Skin injury Diseases 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical group CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- 206010042496 Sunburn Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- CRMOQBWCUTZBKJ-UHFFFAOYSA-N chloromethyl-methyl-dioctadecylazanium Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(CCl)CCCCCCCCCCCCCCCCCC CRMOQBWCUTZBKJ-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004737 colorimetric analysis Methods 0.000 description 1
- 238000000205 computational method Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 238000004042 decolorization Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 231100000321 erythema Toxicity 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 208000007578 phototoxic dermatitis Diseases 0.000 description 1
- 231100000018 phototoxicity Toxicity 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000037307 sensitive skin Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 231100000075 skin burn Toxicity 0.000 description 1
- 230000037394 skin elasticity Effects 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000000967 suction filtration Methods 0.000 description 1
- 230000008833 sun damage Effects 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2072—Aldehydes-ketones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
- C08K5/19—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3472—Five-membered rings
- C08K5/3475—Five-membered rings condensed with carbocyclic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34928—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C11D3/0015—Softening compositions liquid
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C11D3/42—Brightening agents ; Blueing agents
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/352—Heterocyclic compounds having five-membered heterocyclic rings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
- D06M13/358—Triazines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/467—Compounds containing quaternary nitrogen atoms derived from polyamines
-
- D—TEXTILES; PAPER
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Abstract
公开了一种织物淋洗组合物,包含a)0.1-10wt%式(1)的UV吸收剂,其中U是UV吸收剂的一个基团,选自羟苯基苯并三唑、羟苯基三嗪和二苯甲酮,A是直接键、C1-C6亚烷基,或式(1a)的基团,Y是直接键,或基团-CO-、-COO-、-OOC-、-CO-N(R′)-、-(R′)N-CO-、-SO2-N(R′)-、-(R′)N-SO2-;下列各式的基团(1b)、(1c)、(1d)或(1e),B是直接键、C2-C6亚烷基或C2-C6偏亚烷基,它可被OH取代,且可被-O-或被1个或2个N+X-(R′)2-隔开,或是式(1g)、(1h)的基团,或基团(2)是1个饱和或不饱和的单核或三核的含氮杂环基团,含1-4个N原子作为环原子,其中至少1个是季铵化的;R1、R2和R3各自独立地是氢、C1-C8烷基或被1个-COOR″基团或被3个OH基团取代的C1-C8烷基,被1个或多个-O-基团隔开的C2-C8羟烷基,-(C1-C8)亚烷基-COO-、-(C1-C8)偏亚烷基-COO-、-(C2-C8)偏亚烷基-SO3-,这些基团中每1个都被1个OH取代,C3-C5链烯基,C5-C7环烷基,苯基,甲苯基,苄基,或缩水甘油基,或者R1与R2以及适当时与R3并与其所连接的N+原子一起形成1个N-杂环基,它可含有1-3个N原子或1个O原子作为环原子;R′是氢、C1-C4烷基或C2-C3羟烷基;R″是氢或C1-C4烷基;X-如果不存在于R1、R2或R3中,则是1个无色有机或无机阴离子;B°是-(CH2)m-或下列基团之一(3)、(4)或(5),m和r各自独立地是2或3;p是1-6;n是1-4;g是0或1;其条件是:A、Y和B不同时为直接键;b)占组合物总重量5-25wt%的织物柔软剂;和c)水。
Description
本发明涉及含有紫外光(UV)吸收剂的织物淋洗组合物,并涉及用该组合物处理纺织品的方法。该方法能赋予如此处理后的纺织纤维材料以优异的防UV系数(UPF)值和其它所需性能。
人们已经知道,波长280-400nm的光辐射能使表皮鞣化(tanning)。也知道,波长280-320nm(称为UV-B辐射)的射线会引起红斑和皮肤灼伤,从而抑制皮肤鞣化。
已知波长320-400nm的辐射会诱发皮肤鞣化,但也会使皮肤损伤,尤其对长期暴露于太阳光下的敏感皮肤。这种损伤的例子包括皮肤弹性的丧失和外观起皱,促进红斑反应发作和诱发光毒性或光过敏反应。
防止皮肤由于过分暴露于太阳光而造成的损伤的任何有效方法显然必须包括在太阳光的UV-A和UV-B部分到达皮肤表面之前将其吸收的措施。
传统上,保护暴露的人体皮肤不受太阳光UV部分的潜在损害是通过在皮肤上直接施涂含UV吸收剂的制剂而实现的。
希望防止阳光损伤提高皮肤保护水平的一个方面是考虑在皮肤的直接保护之上或超过这种保护的额外保护措施。例如,考虑用衣服覆盖皮肤,从而使其不直接暴露于阳光的保护措施。
大多数天然和合成纺织材料对太阳光的UV部分都是至少部分地可透过的。因此,光穿衣服并不能对衣服下面的皮肤提供足够的保护来防止UV辐射造成的损伤。虽然染深色和/或有紧密编织结构的衣服对其下面的皮肤可以提供合理水平的保护作用,但是从个人穿着的舒适观点看这样的衣服在炎热的季节是实际的。
因此,需要对衣服下面的皮肤提供保护防止UV辐射,包括不染色或仅染浅色调的重量轻的夏装。依染料性质不同,即使在染了某种暗色调的衣服下面的皮肤也可能还需要防止UV辐射。
这种夏装的定重(单位面积的重量)通常小于200g/m2,其防阳光的保护系数等级在1.5~20之间,视制造这种衣服的纤维的种类而定。
阳光防护剂或防护物(防晒露或衣服)的UPF等级可定义为覆盖了阳光防护剂或防护物的平均个人在对阳光的平均暴露下遭受阳光灼伤所需时间的倍数。例如,如果在标准暴露条件下,平均个人通常在30分钟后会遭受太阳灼伤,则UPF等级为5的阳光防护剂或防护物的防护时间会从30分钟延长到2小时30分钟。对于生活在尤其炎热气候地区的人们而言,平均太阳灼伤时间短,例如对于平均中等皮肤的个人而言在一天中的最热时间里,平均灼伤时间只有15分钟,因此对于重量轻的衣服而言,希望其UPF等级约为20。
为了用于实现提高纺织纤维材料的UPF值的方法(通常称为“UV剪切”处理法),选择适当的UVA时除了考虑其UPF值外,还必须考虑下述事实,即被处理的纺织纤维材料必须满足广大地区的性能标准,例如耐洗性、耐光性和抗撕裂性。
对世界各地的消费者而言,另一个主要问题是染色织物在穿着期间和干燥过程中由于太阳光的作用而褪色(所谓的“光褪色”)的问题。因此敏感的织物除了在热带区域以外,在温度下和高纬度地区也会发生严重褪色。织物的光褪色是消费者特别关心的一个问题,因为暴露区与未暴露区之间的对比特别明显。
令人惊奇的是,已经发现在织物淋洗组合物中使用特定的UV吸收剂可使UPF提高,且可同时有效防止所述织物的光褪色。
因此,本发明提供一种稳定的浓缩织物淋洗组合物,该组合物包含
a)0.1-10wt%,优选0.1-5wt%式(1)的UV吸收剂:
其中U是UV吸收剂的一个基团,选自羟苯基苯并三唑、羟苯基三嗪和二苯甲酮;
A是直接键、C1-C6亚烷基,C1-C6偏亚烷基或式(1a)的基团
Y是直接键,或基团-CO-、-COO-、-OOC-、-CO-N(R′)-、-(R′)N-CO-、-SO2-N(R′)-、-(R′)N-SO2-;下列各式的基团:
B是直接键、C2-C6亚烷基或C2-C6偏亚烷基,它可被OH取代,且可被-O-或被1个或2个N+X-(R′)2-隔开,或是式(1g)或(1h)的基团
或基团
是1个饱和或不饱和的单核或三核的含氮杂环基团,含1-4个N原子作为环原子,其中至少1个是季铵化的;
R1、R2和R3各自独立地是氢、C1-C8烷基或被1个-COOR″基团或被1-3个OH基团取代的C1-C8烷基,被1个或多个-O-基团隔开的C2-C8羟烷基,-(C1-C8)亚烷基-COO-、-(C1-C8)偏亚烷基-COO-、-(C2-C8)偏亚烷基-SO3 -,这些基团中每1个都被1个OH取代,C3-C5链烯基,C5-C7环烷基,苯基,甲苯基,苄基,或缩水甘油基,或者R1与R2以及适当时与R3并与其所连接的N+原子一起形成1个N-杂环基,它可含有1-3个N原子或1个O原子作为环原子;
R′是氢、C1-C4烷基或C2-C3羟烷基;
R″是氢或C1-C4烷基;
X-如果不存在于R1、R2或R3中,则是1个无色有机或无机阴离子;
B°是-(CH2)m-;或下列基团之一:
m和r各自独立地是2或3;
p是1-6;
n是1-4;
g是0或1;
其条件是:A、Y和B不同时为直接键;
b)占组合物总重量5-25wt%的织物柔软剂;和
c)水。
本发明优选涉及使用一种组合物,其中式(1)中的U对应于下式的UV吸收剂基团:
其中
R4是氢、C1-C4烷基、C1-C4烷氧基,或卤素;
n是0-3。
最优选的是用下式(2a)的UV吸收剂作为组分(a):
其中
B是C2-C6亚烷基或被OH取代且可被-O-或被1个-N+X-(R′)2-隔开的C2-C6亚烷基;最优选
R1、R2、R3、R′、X和n的定义与式(1)中定义的相同,R4的定义与式(2)中定义的相同。
优选的是U对应于下式的UV吸收剂基团:
其中
R5、R6、R7、R8、R9和R10各自独立地是氢;C1-C18烷基;C5-C7环烷基;卤素;或下式(3a1)的基团:
其中R1、R2、R3、A、B、X、Y和g如式(1)中所定义。
最优选,该UV吸收剂对应于下式:
其中
Y是基团-CO-、-COO-、-OOC-、-CO-N(R′)-、-(R′)N-CO-、-SO2-N(R′)-、-(R′)N-SO2-;
B是C2-C6亚烷基或C2-C6偏亚烷基,它可被OH取代,且可被-O-或被1个或2个N+X-(R′)2-隔开;或
基团
是1个饱和或不饱和的单核或三核的含氮杂环基团,含1-4个N原子作为环原子,其中至少1个是季铵化的;
R1、R2、R3、R′和X如式(1)中所定义;和
R5、R6、R7、R8、R9和R10如式(3a)或(3b)中所定义。
最优选的是式(3a1)的UV吸收剂,其中
Y是-CO-、-COO-、-OOC-、-CO-N(R′)-或-(R′)N-CO-;
B是被OH取代的C2-C6亚烷基;
R7是氢或C1-C6烷基;
R5、R6、R8、R9和R10各自独立地是氢或C1-C6烷基;和
R1、R2、R3和R′如式(1)中所定义。
进一步优选的是式(3b1)的UV吸收剂:
其中
Y是基团-CO-、-COO-、-OOC-、-CO-N(R′)-、-(R′)N-CO-、-SO2-N(R′)-、-(R′)N-SO2-;
B是C2-C6亚烷基或C2-C6偏亚烷基,它可被OH取代,且可被-O-或被1个或2个N+X-(R′)2-隔开;和
R1、R2、R3、R′和X如式(1)中所定义;和
R5、R6、R7、R8、R9和R10如式(3a)或(3b)中所定义。
此外,U优选对应于下式的一种UV吸收剂基团:
其中
R11、R12、R13和R14独立地是氢、卤素、OH、C1-C6烷基;或C1-C6烷氧基或通式为-O-CH2-CH(OH)CH2X的基团;和
X是-SO3H或其碱金属盐。
组分(a)的优选UV吸收剂对应于下式
其中
B是C2-C6亚烷基或C2-C6偏亚烷基,被OH取代,且可被-O-隔开;和
R1、R2和R3如式(1)中所定义;和
R11、R12、R13和R14如式(4)中所定义。
可用于本发明的阳离子UV吸收剂可列举如下:
本发明组合物中所用的UV吸收剂很容易吸收UV光,尤其300-400nm范围内的UV光,并通过化学中间反应将所吸收的能量转化成没有影响的稳定的化合物或转化成非干扰性形式的能量。当然,UV吸收剂必须能与淋洗周期的织物柔软剂组合物相容。
优选,所用的UV吸收剂在淋洗周期的织物柔软剂处理过程中能被吸收在洗过的纺织品上。
适用于本发明的织物柔软剂(组分(b))选自下列各类化合物:
(i)阳离子季铵盐。这种阳离子季铵盐的反离子可以是卤根,如氯根或溴根,甲基硫酸根或文献中众所周知的其它阴离子。优选该反离子是甲基硫酸根或任何烷基硫酸根或任何卤根,对本发明的在干燥机中加入纺织品而言,甲基硫酸根是最优选的。
阳离子季铵盐的例子包括,但不限于:
1.含有至少2个C8-C30,优选C12-C22烷基链或链烯基链的丙烯酸类季铵盐,例如甲基硫酸二牛脂基二甲基铵、甲基硫酸二(氢化牛脂基)二甲基铵、二硬脂基二甲基铵的甲基硫酸盐或氯化物,和甲基硫酸二椰油基二甲基铵等。尤其优选的是该织物柔软化合物是一种含有通过至少1个酯键连接到分子中的2个C12-C18烷基或链烯基基团的化合物的水溶性季铵材料。更优选的是,该季铵材料有2个酯键存在。尤其优选的用于本发明的酯连接的季铵材料可用下式表示:
其中
各个R15基团独立地选自C1-C4烷基、羟烷基或C2~C4链烯基;
各个R16基团独立地选自C8-C28烷基或C8-C28链烯基基团;以及
e是0~5的整数。
第二类优选的季铵材料可用下式表示:
其中R15、R16和e的定义如式(12)中所述。
2.咪唑鎓盐型的环状季铵盐,例如甲基硫酸二(氢化牛脂基)二甲基咪唑鎓和甲基硫酸1-亚乙基-双(2-牛脂基-1-甲基)咪唑鎓等。
3.二酰氨基季铵盐,例如甲基硫酸甲基-双(氢化牛脂酰氨基乙基)-2-羟基乙基铵和甲基硫酸甲基双(牛脂酰氨基乙基)-2-羟基丙基铵等。
4.可生物降解季铵盐,例如甲基硫酸N,N-二(牛脂酰氧乙基)-N,N-二甲基铵和甲基硫酸N,N-二(牛脂酰氧丙基)-N,N-二甲基铵。可生物降解季铵盐可参见例如美国专利4,137,180、4,767,547和4,789,491,该专利并入本文作为参考。
优选的可生物降解季铵盐包括可生物降解阳离子二酯化合物,如美国专利4,137,180中所述,该专利并入本文作为参考。
(ii)含至少1个,优选2个C8-C30,优选C12-C22烷基链的脂肪族叔胺。其例子包括位阻牛脂基-二甲基胺和环胺,例如1-(氢化牛脂基)酰氨基乙基-2-(氢化牛脂基)咪唑啉。可用于本发明组合物的环胺可参见美国专利4,806,255,该专利并入本文作为参考。
(iii)含8-30个碳原子并每个分子中有1个羧基的羧酸。烷基部分有8-30个,优选12-22个碳原子。烷基部分可以是直链或支化的,饱和或不饱和的,其中以直链饱和烷基为优选。硬脂酸是用于本发明组合物的一种优选的脂肪酸。这些羧酸的例子是工业级的硬脂酸和棕榈酸及其混合物,它们可以含有少量的其它酸。
(iv)多元醇的酯类,例如脱水山梨醇酯或硬脂酸甘油酯。脱水山梨醇酯是山梨醇或异山梨醇与诸如硬脂酸之类的脂肪酸的缩合产物。优选的脱水山梨醇酯是一烷基酯。常见的脱水山梨醇酯的例子是SPAN 60(ICI公司),它是脱水山梨醇和异山梨醇的硬脂酸酯的混合物。
(v)脂肪醇、乙氧基化脂肪醇、烷基酚、乙氧基化烷基酚、乙氧基化脂肪胺、乙氧基化单甘油酯和乙氧基化二甘油酯。
(vi)矿物油和多元醇如聚乙二醇。
这些柔软剂更明确地公开在美国专利4,134,838中,其公开内容并入本文作为参考。可用于本发明的优选的织物柔软剂是无环的季铵盐。甲基硫酸二(氢化)牛脂基二甲基铵是本发明干燥机中的纺织品(dryer articles)中最广泛使用的。也可以使用上述织物柔软剂的混合物。
此外,按照本发明的组合物还可以含有少量比例的一种或多种助剂。助剂的例子包括乳化剂、香料、着色染料、遮光剂、萤光增白剂、杀菌剂、非离子表面活性剂、抗胶凝剂如碱金属的亚硝酸盐或硝酸盐,尤其硝酸钠,以及腐蚀抑制剂如硅酸钠。
这些任选助剂各自的含量优选为该组合物重量的0.05-5wt%。
特别优选的任选助剂是阳离子、两性离子或阴离子萤光增白剂,如EP-A-0,659,877,第9页~第15页第56行中所公开的那些。本发明也提供一种提高纺织品的UPF值的方法,包括对事先洗过的纺织品施加一种织物淋洗组合物,包含:
a)占组合物总重量0.1-10wt%,优选0.1-5wt%的式(1)的UV吸收剂;
b)占组合物总重量5-25wt%,尤其10-20wt%的织物护理组分;和
c)水。
本发明的方法和组合物除了对皮肤提供保护之外,还可延长按照本发明方法处理的纺织品的使用寿命,因为本发明的方法能保持织物的撕裂强度和/或耐光性或减轻由于阳光作用造成的褪色。
因此,本发明还提供一种减轻织物由于阳光的作用而造成的褪色的方法,包括对事先洗过的纺织品施加一种织物淋洗组合物,包含:
a)占组合物总重量0.1-10wt%,优选0.1-5wt%的式(1)的UV吸收剂;
b)占组合物总重量5-25wt%,尤其10-20wt%的织物护理组分;和
c)水。
本发明的组合物在织物上沉积约0.5mg/g织物~约5mg/g织物的式(1)UV吸收剂,从而减轻织物的阳光褪色作用。
按照本发明方法处理的纺织品可由多种类型的纤维组成,例如毛、聚酰胺、棉花、聚酯、聚丙烯酸类纤维、丝或其任何混纺织物。
在典型洗衣过程的淋洗周期中用本发明的组合物反复处理织物可以得到较高的沉积水平,对防止织物阳光褪色更有效。
下面的实施例进一步说明本发明。
实施例1:式(5)化合物的制备:
反应方案:
100g式(5a)化合物悬浮于650ml叔戊醇中。然后加入17.3g粉状氢氧化钾,通过间接加热使反应混合物温热至80℃,然后在80℃搅拌1小时。在5分钟内滴加77g氯化3-氯-2-羟基丙基三甲基铵,在80℃搅拌。30分钟后发生自发结晶,形成黄色悬浮体。反应混合物间接冷却至60℃,然后通过预热的抽吸过滤漏斗过滤。
得到620ml黄色透明的滤液。抽吸的滤饼用50ml丙酮洗涤4次,先经风干后在70℃进行真空干燥。得到148g灰棕色粉末。
1H-NMR d6-DMSO,ppm:
13.36s,1H | 8.47d,1H | 8.03d,2H | 7.28m,4H | 6.73d,1H | 6.62s,1H |
6.11d,1H | 4.50m,1H | 4.09m,2H | 3.56m,2H | 3.21s,9H | 2.70s,3H |
2.40s,3H |
实施例2:式(6)化合物的制备:
反应方案:
按照实施例1的方法进行制备,所不同的是用化合物(6a)作为起始化合物,用环己醇作为溶剂。
1H-NMR in d6-DMSO,ppm:
13.36s,1H | 7.89d,4H | 7.78d,1H | 7.45t,2H | 7.29t,4H | 6.18d,1H |
3.17s,9H | 5.980s,1H | 4.32s,1H | 3.66m,2H | 3.40m,2H |
实施例3:式(14)化合物的制备:
反应方案:
按照实施例1的方法进行制备,所不同的是用氯化(3-氯-2-羟基丙基)十二烷基二甲基铵作为反应物,2-甲基-2-丁醇作为溶剂。
1H-NMR in d6-DMSO,ppm
13.35s,1H | 8.46d,1H | 8.02d,2H | 7.26m,4H | 6.71d,1H | 6.62s,1H |
6.15s,1H | 4.48m,1H | 4.11m,2H | 3.52t,2H | 3.41t,2H | 3.17s,6H |
2.7s,6H | 2.40s,6H | 1.71m,2H | 1.22m,18H | 0.81t,3H |
实施例4:UPF的改善
采用下列条件将5g漂白棉布(织造的)在Linitest中进行洗涤/淋洗:
主洗:
洗涤剂剂量:4g/l EE 77(含磷酸盐的标准洗涤剂,不含萤光增
白剂和漂白剂)
浴比(Liquor ratio):1∶20
时间:15分钟
温度:25℃
用自来水淋洗30秒钟后甩干。
淋洗浴:
柔软剂剂量:1.66g/l浓缩酯季铵(Esterquat)或5g/l稀释的DSDMAC
浴比:1∶40
时间:15分钟
温度:25℃
该织物在60℃甩干;1和3个洗涤周期。
表1:柔软剂配方 | ||
酯季铵配方 | DSDMAC配方 | |
甲基硫酸二(棕榈羧乙基)-羟乙基甲基铵(RewoquatWE 38 DPG) | 15%有效成分 | -- |
氯化二硬脂基二甲基铵(Arquad 2 HT-75) | 5%有效成分 | |
平均含6EO单元的C12-C13脂肪醇乙氧基化物(Dobanol23-6,5) | -- | 0.5% |
MgCl2 | 0.1% | -- |
UV-吸收剂 | 2.4% | 0.8% |
水 | 加至100% | 加至100% |
用装有Ulbricht杯的双光栅分光光度计测量透过织物的UV光,从而确定经柔软剂处理过的干燥织物的UPF值。UPF值的计算方法按B.L.Diffey和J.Robson在J.Soc.Cosm.Chem.
40(1989),第130-131页中所述方法进行。
结果列于表2:
表2: | ||||
通式的化合物 | 不含UV吸收剂的柔软剂配方 | 含有式(8)UV吸收剂的柔软剂配方 | 含有式(7)UV吸收剂的柔软剂配方 | 含有式(5)UV吸收剂的柔软剂配方 |
DSDMAC配方 | ||||
第1洗涤/淋洗 | 3 | 13 | 12 | 10 |
第3洗涤/淋洗 | 3 | 31 | 21 | 20 |
酯季铵配方 | ||||
第1洗涤/淋洗 | 3 | 11 | 8 | 11 |
第3洗涤/淋洗 | 3 | 17 | 15 | 17 |
表2的结果清楚地表明用本发明的淋洗组合物处理过的棉织物的UPF值得到改善。
实施例2:光褪色的抑制
采用下列条件将下列6种不同颜色的棉布在Linitest中分别进行洗涤和淋洗。
A:活性黑005,B:活性红226,C:活性蓝013,D:活性红264,E:活性红228,F:活性红002
主洗:
洗涤剂剂量:4g/l ECE 77
浴比:1∶20
时间:15分钟
温度:25℃
该织物用自来水淋洗30秒钟,然后甩干。
淋洗浴:
柔软剂剂量:4g/l DSDMAC配方
浴比:1∶20
时间:15分钟
温度:25℃
该织物在60℃甩干,然后在下列条件下在一台ATLAS Weather-O-Meter Ci 65 A气候老化机中进行辐照试验:
滤光器:Boro/Boro
辐照灯:3.5KW
织物上的辐照量:0.22W/m2
干球温度:29.3℃
湿球温度:21.9℃
湿球下降:7.3℃
相对湿度:43%
时间:7小时
10个洗涤/淋洗/辐照周期
表3:柔软剂配方 | |
DSDMAC配方 | |
氯化二硬脂基二甲基铵(Arquad 2 HT-75) | -- |
平均含6EO单元的C12-C13脂肪醇乙氧基化物(Dobanol 23-6,5) | 0.5% |
UV-吸收剂 | 0.4%式(5)化合物 |
水 | 加至100% |
CIE颜色测定评估
CIE色系评估以L*、a*和b*坐标表示的织物样品的颜色,这些坐标值是由分光光度计读数确定的(L*、a*、b*详见Colorimetry,2nd Edition,CIE Publication no.15.2,published by Bureau,Central de la CIE,paris 1982)。
ΔE值由下式定义:
ΔE={(Lf *-Li *)2+(af *-ai *)2+(bf *-bi *)2}1/2
式中下标i和f分别指用经辐照或不经辐照的样品所测得的值。
经洗涤/不用UV吸收剂的淋洗/辐照的染色织物(参照物=不辐照)和经洗涤/用UV吸收剂的淋洗/辐照的染色织物的CIE颜色测定结果如下:
表4: | ||
ΔE1(周期 | ||
不用式(5)化合物 | 用式(5)化合物 | |
A: | 9.1 | 8.0 |
B: | 17.2 | 16.6 |
C: | 6.5 | 5.9 |
D: | 14.6 | 12.6 |
E: | 14.2 | 12.3 |
F: | 6.9 | 6.3 |
表4中的结果表明:按照本发明的方法处理的染色织物显示出显著的光褪色抑制作用。
Claims (23)
1.一种织物淋洗组合物,包含
a)0.1-10wt%式(1)的UV吸收剂:
其中U是UV吸收剂的一个基团,选自羟苯基苯并三唑、羟苯基三嗪和二苯甲酮;
A是直接键、C1-C6亚烷基,C1-C6偏亚烷基或式(1a)的基团
Y是直接键,或基团-CO-、-COO-、-OOC-、-CO-N(R′)-、-(R′)N-CO-、-SO2-N(R′)-、-(R′)N-SO2-;下列各式的基团:
B是直接键、C2-C6亚烷基或C2-C6偏亚烷基,它可被OH取代,且可被-O-或被1个或2个N+X-(R′)2-隔开,或是式(1g)或(1h)的基团
或基团
R1、R2和R3各自独立地是氢、C1-C8烷基或被1个-COOR″基团或被1-3个OH基团取代的C1-C8烷基,被1个或多个-O-基团隔开的C2-C8羟烷基,-(C1-C8)亚烷基-COO-、-(C1-C8)偏亚烷基-COO-、-(C2-C8)偏亚烷基-SO3 -,这些基团中每1个都被1个OH取代,C3-C5链烯基,C5-C7环烷基,苯基,甲苯基,苄基,或缩水甘油基,或者R1与R2以及适当时与R3并与其所连接的N+原子一起形成1个N-杂环基,它可含有1-3个N原子或1个O原子作为环原子;
R′是氢、C1-C4烷基或C2-C3羟烷基;
R″是氢或C1-C4烷基;
X-如果不存在于R1、R2或R3中,则是1个无色有机或无机阴离子;
B°是-(CH2)m-;或下列基团之一:
m和r各自独立地是2或3;
p是1-6;
n是1-4;
g是0或1;
其条件是:A、Y和B不同时为直接键;
b)占组合物总重量5-25wt%的织物柔软剂;和
c)水。
3.按照权利要求1或2的组合物,其中所述UV吸收剂对应于下式
其中
B是C2-C6亚烷基或被OH取代且可被-O-或被1个-N+X-(R′)2-隔开的C2-C6亚烷基;
R1、R2、R3、R′、X和n如权利要求1所定义;和
R4如权利要求2所定义。
7.按照权利要求6的组合物,其中
Y是-CO-、-COO-、-OOC-、-CO-N(R′)-或-(R′)N-CO-;
B是被OH取代的C2-C6亚烷基;
R7是氢或C1-C6烷基;
R5、R6、R8、R9和R10各自独立地是氢或C1-C6烷基;和
R1、R2、R3和R′如权利要求1所定义。
8.按照权利要求5的组合物,其中组分(a)的UV吸收剂对应于下式
其中
Y是基团-CO-、-COO-、-OOC-、-CO-N(R′)-、-(R′)N-CO-、-SO2-N(R′)-、-(R′)N-SO2-;
B是C2-C6亚烷基或C2-C6偏亚烷基,它可被OH取代,且可被-O-或被1个或2个N+X-(R′)2-隔开;和
R1、R2、R3、R′和X如权利要求1中所定义;和
R5、R6、R7、R8、R9和R10如权利要求5中所定义。
11.按照前述权利要求中任何一项的组合物,其中所述织物护理成分选自阳离子季铵盐、含有至少1个C8-C30烷基链的脂肪族叔胺、含8-30个碳原子且每个分子中有1个羧基的羧酸、多元醇的酯类、脂肪醇、乙氧基化脂肪醇、烷基酚、乙氧基化烷基酚、乙氧基化脂肪胺、乙氧基化单甘油酯和乙氧基化二甘油酯、矿物油和多元醇。
12.按照权利要求11的组合物,其中阳离子季铵盐织物柔软剂选自含有至少2个C8-C30烷基链或链烯基链的丙烯酸类季铵盐、环状季铵盐、二酰氨基季铵盐和生物可降解季铵盐。
15.按照权利要求13的组合物,其中所述无环季铵盐是甲基硫酸二(棕榈羧酸乙基)羟乙基甲基铵。
16.按照权利要求12的组合物,其中所述无环季铵盐选自甲基硫酸二牛脂基二甲基铵、甲基硫酸二(氢化牛脂基)二甲基铵、二硬脂基二甲基铵的甲基硫酸盐或氯化物,和甲基硫酸二椰油基二甲基铵。
17.按照权利要求11或12的组合物,其中所述环状季铵盐选自甲基硫酸二(氢化牛脂基)二甲基咪唑鎓和甲基硫酸1-亚乙基-双(2-牛脂基-1-甲基)咪唑鎓。
18.按照权利要求11或12的组合物,其中所述二酰氨基季铵盐选自甲基硫酸甲基-双(氢化牛脂酰氨基乙基)-2-羟基乙基铵和甲基硫酸甲基双(牛脂酰氨基乙基)-2-羟基丙基铵。
19.按照权利要求11或1 2的组合物,其中所述可生物降解季铵盐选自甲基硫酸N,N-二(牛脂酰氧乙基)-N,N-二甲基铵和甲基硫酸N,N-二(牛脂酰氧丙基)-N,N-二甲基铵。
20.按照前述权利要求中任何一项的组合物,该组合物还含有选自下列的助剂:乳化剂、香料、着色染料、遮光剂、荧光增白剂、杀菌剂、非离子表面活性剂、抗胶凝剂和腐蚀抑制剂。
21.一种提高纺织品的UPF值的方法,该方法包括对事先洗过的纺织品施加一种织物淋洗组合物,包含:
a)占组合物总重量0.1-10wt%的式(1)的UV吸收剂;
b)占组合物总重量5-25wt%的织物护理组分;和
c)水。
22.一种减轻织物因阳光而褪色的方法,该方法包括对事先洗过的纺织品施加一种织物淋洗组合物,包含:
a)占组合物总重量0.1-10wt%的式(1)的UV吸收剂;
b)占组合物总重量5-25wt%,尤其10-20wt%的织物护理组分;和
c)水。
23.按照权利要求21或22的方法,其中所述纺织品由毛、聚酰胺、棉花、聚酯、聚丙烯酸类纤维、丝或其任何混纺织物构成。
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CN107916569A (zh) * | 2017-11-29 | 2018-04-17 | 无锡昊瑜节能环保设备有限公司 | 一种环保型防紫外回潮针织布的制备方法 |
CN111749012A (zh) * | 2020-05-21 | 2020-10-09 | 苏州浩迈纺织股份有限公司 | 水性乳液抗紫外线整理剂及其制备方法 |
CN112608467A (zh) * | 2020-12-13 | 2021-04-06 | 东北石油大学 | 一种阳离子型油污清洗剂的制备方法 |
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CN106543098B (zh) * | 2016-12-07 | 2018-10-19 | 常州大学 | 一种多功能型紫外线吸收剂的制备方法及其应用 |
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GB1567947A (en) * | 1976-07-02 | 1980-05-21 | Unilever Ltd | Esters of quaternised amino-alcohols for treating fabrics |
GB2188653A (en) * | 1986-04-02 | 1987-10-07 | Procter & Gamble | Biodegradable fabric softeners |
US4789491A (en) * | 1987-08-07 | 1988-12-06 | The Procter & Gamble Company | Method for preparing biodegradable fabric softening compositions |
EP0357545A3 (de) * | 1988-07-21 | 1990-03-21 | Ciba-Geigy Ag | Kationische Verbindungen, deren Herstellung und deren Anwendung zur fotochemischen Stabilisierung basisch anfärbbarer Polyamid-, Polyacrylnitril-und Polyesterfasermaterialien |
US5096781A (en) * | 1988-12-19 | 1992-03-17 | Ciba-Geigy Corporation | Water-soluble compounds as light stabilizers |
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WO1998030663A2 (en) * | 1997-01-10 | 1998-07-16 | Unilever Plc | Fabric treatment compositions |
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CN107916569A (zh) * | 2017-11-29 | 2018-04-17 | 无锡昊瑜节能环保设备有限公司 | 一种环保型防紫外回潮针织布的制备方法 |
CN111749012A (zh) * | 2020-05-21 | 2020-10-09 | 苏州浩迈纺织股份有限公司 | 水性乳液抗紫外线整理剂及其制备方法 |
CN111749012B (zh) * | 2020-05-21 | 2022-09-16 | 苏州浩迈纺织股份有限公司 | 水性乳液抗紫外线整理剂及其制备方法 |
CN112608467A (zh) * | 2020-12-13 | 2021-04-06 | 东北石油大学 | 一种阳离子型油污清洗剂的制备方法 |
CN112608467B (zh) * | 2020-12-13 | 2022-09-30 | 东北石油大学 | 一种阳离子型油污清洗剂的制备方法 |
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WO2002088455A1 (en) | 2002-11-07 |
KR20040019283A (ko) | 2004-03-05 |
BR0208400A (pt) | 2004-03-30 |
EP1373629A1 (en) | 2004-01-02 |
CA2433763A1 (en) | 2002-11-07 |
JP2004526882A (ja) | 2004-09-02 |
US20040103482A1 (en) | 2004-06-03 |
MXPA03006314A (es) | 2003-10-06 |
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