CN1465646A - Environment protective lignin flame redardant adhesive agent - Google Patents
Environment protective lignin flame redardant adhesive agent Download PDFInfo
- Publication number
- CN1465646A CN1465646A CNA021121745A CN02112174A CN1465646A CN 1465646 A CN1465646 A CN 1465646A CN A021121745 A CNA021121745 A CN A021121745A CN 02112174 A CN02112174 A CN 02112174A CN 1465646 A CN1465646 A CN 1465646A
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- Prior art keywords
- adhesive agent
- environment protective
- flame redardant
- water
- lignin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to a kind of environment-protecting lignin five-resisting adhesive formed from lignin mucilage, adhesion promoter, fire-resisting agent, filling material and water. Said invention is characterized by that its adhesive composition is composed of (wt%) 30%-40% of lignin, 2%-5% of polvinyl alcohol, 4%-8% of polyamine phosphate, 2%-8% of starch, 1%-2% of dipentene and the rest is water. Said adhesive can be used for fibre plate and veneer board, and does not produce the harmful substances of formaldehyde, etc.
Description
Technical field
The present invention relates to a kind of tackiness agent, particularly a kind of environment protective lignin flame redardant adhesive agent.
Background technology
Widely used fiberboard in building materials at present, aerodux in the clamping plate is with phenol, formaldehyde is raw material, along with fiberboard in people's house decoration, a large amount of uses of clamping plate, from fiberboard, free formaldehyde can be distributed to indoor in the clamping plate, and phenol, formaldehyde is harmful and possible carcinogenic to HUMAN HEALTH when manufacturing tackiness agent, because fiberboard, the free formaldehyde volatilization cycle in the clamping plate is extremely long, re-use after making its volatilization after can't be before use, therefore press for a kind of phenol that do not contain, the environment-friendly type tackiness agent of formaldehyde composition is used for fiberboard, the making of clamping plate.
Summary of the invention
The objective of the invention is to solve in the prior art that the aerodux in widely used fiberboard, the clamping plate contains a large amount of formaldehyde in the building materials, the formaldehyde volatilization cycle in fiberboard, the clamping plate is extremely long, re-use after can't making its volatilization before use, after the free formaldehyde emission was extremely indoor, human body sucked the problem of meeting insalubrity for a long time.The present invention designs environment protective lignin flame redardant adhesive agent, it is characterized in that: by xylogen mucus, tackifier, fire retardant, stopping composition and water are formed, it is characterized in that: constitute xylogen 30% by following constituent and weight percent---40%, polyvinyl alcohol 2%---5%, polyphosphoric acid amine 4%---8%, starch 2%---8%, kautschin 1%---2%, surplus is a water.Advantage of the present invention is to use the tackiness agent in fiberboard, clamping plate need not contain the toxic substance industrial chemicals to come synthetic resin binder, thereby can not produce objectionable impurities such as formaldehyde, the health of protection human body.Below in conjunction with embodiment the present invention is elaborated,
Embodiment is got 40 kilograms in xylogen, add 37 kilograms in water and under 80 ℃ condition, put into the reactor dilution, put into 5 kilograms of polyvinyl alcohol again, 8 kilograms of polyphosphoric acid amine, 8 kilograms of starch, 2 kilograms of kautschins, mixing and stirring, can in preparation, add a little sodium hydroxide and regulate pH value,---in 25% the ratio adding fiberboard substrate, at 180 ℃---hot-forming after 5 minutes under 220 ℃ the condition, temperature is below 180 ℃ with 15% with above-mentioned tackiness agent, the thermofixation reaction of xylogen is insufficient, and temperature can make xylogen worsen more than 220 ℃.Also above-mentioned tackiness agent can be directly used in the bonding hot-forming making of wooden splint, and the polyphosphoric acid amine in the tackiness agent there is fire-retardant effect.
Claims (2)
1, environment protective lignin flame redardant adhesive agent is characterized in that: by xylogen mucus, and tackifier, fire retardant, stopping composition and water are formed,
2, by the described environment protective lignin flame redardant adhesive agent of claim 1, it is characterized in that: constitute xylogen 30% by following constituent and weight percent---40%,
Polyvinyl alcohol 2%---5%,
Polyphosphoric acid amine 4%---8%,
Starch 2%---8%,
Kautschin 1%---2%
Surplus is a water.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNA021121745A CN1465646A (en) | 2002-06-21 | 2002-06-21 | Environment protective lignin flame redardant adhesive agent |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNA021121745A CN1465646A (en) | 2002-06-21 | 2002-06-21 | Environment protective lignin flame redardant adhesive agent |
Publications (1)
Publication Number | Publication Date |
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CN1465646A true CN1465646A (en) | 2004-01-07 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CNA021121745A Pending CN1465646A (en) | 2002-06-21 | 2002-06-21 | Environment protective lignin flame redardant adhesive agent |
Country Status (1)
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CN (1) | CN1465646A (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101879739A (en) * | 2010-06-24 | 2010-11-10 | 郭明辉 | Manufacturing method for environmental-friendly fire-retardant fiber board |
CN102268145A (en) * | 2011-08-22 | 2011-12-07 | 东北林业大学 | Starch-lignin membrane and preparation method thereof |
CN102876260A (en) * | 2012-09-27 | 2013-01-16 | 上海群乐船舶附件启东有限公司 | Environment-friendly adhesive |
CN104293287A (en) * | 2014-11-12 | 2015-01-21 | 广西南宁绿园北林木业有限公司 | Lignin damp-proof fiberboard adhesive and producing method thereof |
CN104293288A (en) * | 2014-11-12 | 2015-01-21 | 广西南宁绿园北林木业有限公司 | Lignin thermostable fiberboard adhesive and producing method thereof |
CN105419653A (en) * | 2015-11-18 | 2016-03-23 | 广德县常丰竹木业制品有限公司 | Flame-retardant adhesive for bamboo wood and preparation method thereof |
CN108501478A (en) * | 2018-05-25 | 2018-09-07 | 南京林业大学 | A kind of compound laminated veneer lumber of high intensity eucalyptus poplar and its manufacturing method |
CN111793454A (en) * | 2020-08-17 | 2020-10-20 | 广西龙酉商贸有限公司 | Green non-formaldehyde wood adhesive and preparation method thereof |
-
2002
- 2002-06-21 CN CNA021121745A patent/CN1465646A/en active Pending
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101879739A (en) * | 2010-06-24 | 2010-11-10 | 郭明辉 | Manufacturing method for environmental-friendly fire-retardant fiber board |
CN102268145A (en) * | 2011-08-22 | 2011-12-07 | 东北林业大学 | Starch-lignin membrane and preparation method thereof |
CN102268145B (en) * | 2011-08-22 | 2012-11-21 | 东北林业大学 | Starch-lignin membrane and preparation method thereof |
CN102876260A (en) * | 2012-09-27 | 2013-01-16 | 上海群乐船舶附件启东有限公司 | Environment-friendly adhesive |
CN104293287A (en) * | 2014-11-12 | 2015-01-21 | 广西南宁绿园北林木业有限公司 | Lignin damp-proof fiberboard adhesive and producing method thereof |
CN104293288A (en) * | 2014-11-12 | 2015-01-21 | 广西南宁绿园北林木业有限公司 | Lignin thermostable fiberboard adhesive and producing method thereof |
CN105419653A (en) * | 2015-11-18 | 2016-03-23 | 广德县常丰竹木业制品有限公司 | Flame-retardant adhesive for bamboo wood and preparation method thereof |
CN108501478A (en) * | 2018-05-25 | 2018-09-07 | 南京林业大学 | A kind of compound laminated veneer lumber of high intensity eucalyptus poplar and its manufacturing method |
CN111793454A (en) * | 2020-08-17 | 2020-10-20 | 广西龙酉商贸有限公司 | Green non-formaldehyde wood adhesive and preparation method thereof |
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C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
WD01 | Invention patent application deemed withdrawn after publication |