CN1454472A - Process of preparing antibacterial material for microperfusion irrigator - Google Patents
Process of preparing antibacterial material for microperfusion irrigator Download PDFInfo
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- CN1454472A CN1454472A CN 03108048 CN03108048A CN1454472A CN 1454472 A CN1454472 A CN 1454472A CN 03108048 CN03108048 CN 03108048 CN 03108048 A CN03108048 A CN 03108048A CN 1454472 A CN1454472 A CN 1454472A
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Abstract
THe invention is a method to prepare micro-irrigating watering device's antibacterial material, using antibacterial material to infiltrate in the low-voltage, high-density polyethylene plastic, adding with dispersant, coupling agent and assistant, and molding in the product line. It is an organic-inorganic system compound antibacterial material, main components including pyridine salt, chlorophenol, tetravalent-ammonium salt, biguanidine compound, ethanol, hyamine and silver organic complex ion reducing the cost, it can continuously supplement the antibacterial components to the material surface by transferring, and to damage the microbe's cell membrane and respiratory system and make denaturalization, -SH acidification and blocked metabolizing on the protein and cell wall denature is the main mechanism.
Description
One, technical field
The invention belongs to the new high-tech material field, particularly a kind of preparation technology who is used for the micro-irrigation emitter anti-biotic material of agricultural water-saving irrigation.
Two, background technology
The various conduit components and the micro-irrigation emitter that are used for the agricultural water conservation slight irrigation all are made of plastic, irrigator as the slight irrigation end, be distributed with the slow water flow passage of very fine complexity on it, the effect of landing low water flow rate and impurity screening, after the higher current of pressure enter irrigator, through the irrigator energy dissipating, splash into soil with the stabilized uniform low discharge, reach the purpose of water-saving irrigation.Obviously improved irrigation quality although it is so, improved the availability of irrigation water, but because frosting is easily by microbial contamination, all exist a large amount of microorganisms in the water source, except very common iron bacteria, also have microorganisms such as algae, sulphur bacteria, sulfate reducing bacteria, fungi and zoogloea can both in aqueduct, form ooze.To form ooze in water for industrial use known already because of it for common blue algae in the algae, green algae, diatoms.These algae volumes are little, and breeding is fast, therefore are difficult to leach and control.And the not enough 1mm of irrigator flow diameter, minimum only have a 0.2mm, and flow channel length is longer relatively, fluidised form is near laminar flow, because temperature, humidity are suitable, these microorganisms are easy to grow in the runner of irrigator, and water dropper, drip irrigation pipe, irrigate band and the mini sprinkler of irrigator are stopped up.Blockage problem is the biggest obstacle of slight irrigation development always, and it is the obstruction of irrigator that outstanding behaviours is stopped up in slight irrigation, and the quality that blockage problem solves is directly determining the service life and the application benefit of engineering.In various slight irrigations are stopped up, grow the irrigator obstruction that causes by microorganism and accounted for significant proportion.The way that solves mainly is to add a certain amount of chlorine or chlorine liquid in the irrigation water of drip irrigation, adopt ozone sterilization and increase the circulation flushing operation at present, but makes the cost of slight irrigation significantly rise like this.So, use high-new anti-biotic material and make antibiotic micro-irrigation emitter, in time kill the microorganism in the water that enters irrigator, can fundamentally solve the microorganism blockage problem of micro-irrigation emitter.
Three, summary of the invention
The object of the present invention is to provide and a kind ofly can suppress various mushrooms, algae growing in irrigator, improve the preparation technology of the micro-irrigation emitter anti-biotic material of the anti-stifled ability of irrigator.
For achieving the above object, the preparation technology that the present invention adopts is: be 2 of 0.003M with concentration at first, 2 '-bipyridyl or 1, the complex ion aqueous solution of 10 phenanthroline silver and purity greater than 95% carrier with layer structure by solid: liquid 1: 25-1: 30 volume ratio reaction bonded, make a layer structure antibacterial agent material that carries silver; Secondly, utilize the interlayer insertion with percent by volume to be: 0.2%～1.1% pyridiniujm, 0.3%～1% chlorophenol, 0.2%～0.8% tetravalence ammonium salt, 0.5%～0.9% biguanide compound, 0.4%～1.3% ethanol, 0.3%～1.5% quaternary ammonium salt organic anti-bacterial component are incorporated in the layer structure antibacterial agent material that carries silver, and making organic and inorganic is composite antibacterial material; At last, with percent by volume be: 0.5%～1.8% organic and inorganic is that composite antibacterial material infiltrates in the low-pressure high-density polyethylene plastics, gets final product with the dispersant of 0.5%～2% low-molecular polyethylene wax as anti-biotic material.
The carrier of the layer structure of indication of the present invention is bentonite, montmorillonite, saponite class clay, salt of phosphoric acid or holds in the palm vigorous mullite; The tetravalence ammonium salt is tetraacetyl ethylene diamine, hexamethylenetetramine; Biguanide compound is lipophilic poly-hexamethyl guanidine stearate, poly-hexamethyl two guanidine stearate; Quaternary ammonium salt is polyquaternium, poly-bi-quaternary ammonium salt.
The present invention also can add volume ratio in vinyon be 0.2%～1% calcium chloride or calcium carbonate, gets final product through mixing and stirring.
Because it is composite antibacterial material that the present invention adopts organic and inorganic, can reduce the consumption of silver, greatly reduce cost like this; And the organic and inorganic antibacterial components, Ag
+Can discharge together at leisure with various organic anti-bacterial compositions,, make the antibiotic irrigator surface of making have stable antimicrobial component content, make anti-microbial property effective lastingly by the antimicrobial component of the continuous supplementary material surface losses of migration.
Four, embodiment
Embodiment 1, be 2 of 0.003M at first with concentration, the complex ion aqueous solution of 2 '-bipyridyl and purity greater than 95% bentonite with layer structure by solid: 1: 25 volume ratio reaction bonded of liquid, make antibiotic lasting, layer structure antibacterial agent material that heat-resistant stable carries silver; Secondly, utilize the interlayer insertion with percent by volume to be: 1.1% pyridiniujm, 0.3% chlorophenol, 0.5% tetraacetyl ethylene diamine, 0.5% lipophilic poly-hexamethyl guanidine stearate, 1.3% ethanol, 0.3% polyquaternium organic anti-bacterial component are incorporated in the layer structure antibacterial agent material that carries silver, and making organic and inorganic is composite antibacterial material; At last, with percent by volume be: 1.8% organic and inorganic is that composite antibacterial material infiltrates in the low-pressure high-density polyethylene plastics, and the low-molecular polyethylene wax with 0.5% is as the dispersant of anti-biotic material; For preventing polyethylene jaundice variable color, the present invention also can add percent by volume and be in vinyon: 0.2% calcium chloride gets final product through mixing to stir.The antibiotic micro-irrigation emitter that adopts the made anti-biotic material of preparation technology of the present invention to produce can effectively suppress various mushrooms, algae growing in irrigator, improves the anti-stifled ability of irrigator.This organic and inorganic is a composite antibacterial material, combines the advantage of organic antibacterial agent and inorganic antiseptic, and the prompt effect of existing organic antibacterial agent and continuation have the safety and the discoloration-resistant of inorganic antiseptic again.Therefore it has broad-spectrum antiseptic, in time efficient sterilizing, nontoxic, lasting, cheap characteristics, does not contain heavy metal in the active ingredient, and has overcome shortcomings such as organic material poor heat resistance, facile hydrolysis, and extremely strong stability is arranged, can variable color, fade.
Embodiment 2, at first are the complex ion aqueous solution of 1,10 phenanthroline silver of 0.003M and purity with concentration greater than 95% the montmorillonite with layer structure by solid: 1: 26 volume ratio reaction bonded of liquid, make a layer structure antibacterial agent material that carries silver; Secondly, utilize the interlayer insertion with percent by volume to be: 0.8% pyridiniujm, 1% chlorophenol, 0.6% hexamethylenetetramine, 0.9% poly-hexamethyl two guanidine stearate, 0.8% ethanol, 1.5% poly-bi-quaternary ammonium salt organic anti-bacterial component are incorporated in the layer structure antibacterial agent material that carries silver, and making organic and inorganic is composite antibacterial material; At last, with percent by volume be: 0.7% organic and inorganic is that composite antibacterial material infiltrates in the low-pressure high-density polyethylene plastics, gets final product with the dispersant of 0.9% low-molecular polyethylene wax as anti-biotic material; For preventing polyethylene jaundice variable color, the present invention also can add percent by volume and be in vinyon: 1% calcium carbonate gets final product through mixing to stir.
Embodiment 3, are 2 of 0.003M with concentration at first, the complex ion aqueous solution of 2 '-bipyridyl and purity greater than 95% saponite class clay with layer structure by solid: 1: 29 volume ratio reaction bonded of liquid, make a layer structure antibacterial agent material that carries silver; Secondly, utilize the interlayer insertion with percent by volume to be: 0.5, the pyridiniujm of %, 0.7% chlorophenol, 0.2% hexamethylenetetramine, 0.8% lipophilic poly-hexamethyl guanidine stearate, 0.4% ethanol, 1.3% polyquaternium organic anti-bacterial component are incorporated in the layer structure antibacterial agent material that carries silver, and making organic and inorganic is composite antibacterial material; At last, with percent by volume be: 0.5% organic and inorganic is that composite antibacterial material infiltrates in the low-pressure high-density polyethylene plastics, gets final product with the dispersant of 1.2% low-molecular polyethylene wax as anti-biotic material; For preventing polyethylene jaundice variable color, the present invention also can add percent by volume and be in vinyon: 0.5% calcium chloride gets final product through mixing to stir.
Embodiment 4, are 2 of 0.003M with concentration at first, the complex ion aqueous solution of 2 '-bipyridyl and purity greater than 95% salt of phosphoric acid with layer structure by solid: 1: 30 volume ratio reaction bonded of liquid, make a layer structure antibacterial agent material that carries silver; Secondly, utilize the interlayer insertion with percent by volume to be: 0.9% pyridiniujm, 0.5% chlorophenol, 0.8% tetraacetyl ethylene diamine, 0.6% poly-hexamethyl two guanidine stearate, 0.5% ethanol, 0.7% poly-bi-quaternary ammonium salt organic anti-bacterial component are incorporated in the layer structure antibacterial agent material that carries silver, and making organic and inorganic is composite antibacterial material; At last, with percent by volume be: 1.6% organic and inorganic is that composite antibacterial material infiltrates in the low-pressure high-density polyethylene plastics, gets final product with the dispersant of 1.8% low-molecular polyethylene wax as anti-biotic material; For preventing polyethylene jaundice variable color, the present invention also can add percent by volume and be in vinyon: 0.8% calcium carbonate gets final product through mixing to stir.
Embodiment 5, at first are the complex ion aqueous solution of 1,10 phenanthroline silver of 0.003M and purity with concentration greater than 95% the vigorous mullite of the holder with layer structure by solid: 1: 28 volume ratio reaction bonded of liquid, make a layer structure antibacterial agent material that carries silver; Secondly, utilize the interlayer insertion with percent by volume to be: 0.4% pyridiniujm, 0.6% chlorophenol, 0.3% tetraacetyl ethylene diamine, 0.7% lipophilic poly-hexamethyl guanidine stearate, 0.9% ethanol, 0.5% polyquaternium organic anti-bacterial component are incorporated in the layer structure antibacterial agent material that carries silver, and making organic and inorganic is composite antibacterial material; At last, with percent by volume be: 1.2% organic and inorganic is that composite antibacterial material infiltrates in the low-pressure high-density polyethylene plastics, gets final product with the dispersant of 1.6% low-molecular polyethylene wax as anti-biotic material; For preventing polyethylene jaundice variable color, the present invention also can add percent by volume and be in vinyon: 0.6% calcium chloride gets final product through mixing to stir.
Embodiment 6, at first are the complex ion aqueous solution of 1,10 phenanthroline silver of 0.003M and purity with concentration greater than 95% the bentonite with layer structure by solid: 1: 27 volume ratio reaction bonded of liquid, make a layer structure antibacterial agent material that carries silver; Secondly, utilize the interlayer insertion with percent by volume to be: 0.2% pyridiniujm, 0.9% chlorophenol, 0.7% hexamethylenetetramine, 0.9% poly-hexamethyl two guanidine stearate, 1.0% ethanol, 1.0% poly-bi-quaternary ammonium salt organic anti-bacterial component are incorporated in the layer structure antibacterial agent material that carries silver, and making organic and inorganic is composite antibacterial material; At last, with percent by volume be: 0.9% organic and inorganic is that composite antibacterial material infiltrates in the low-pressure high-density polyethylene plastics, gets final product with the dispersant of 2% low-molecular polyethylene wax as anti-biotic material; For preventing polyethylene jaundice variable color, the present invention also can add percent by volume and be in vinyon: 0.3% calcium carbonate gets final product through mixing to stir.
Because anti-biotic material of the present invention is that organic and inorganic is a composite antibacterial material, its main antibacterial components is the stable silver-colored organic complex ion of pyridiniujm, chlorophenol, tetravalence ammonium salt, biguanide compound, ethanol, quaternary ammonium salt and physico chemical property etc., with the activity of destroy microorganisms cell membrane, respiratory system or cellular plasm organized enzyme, make protein and cell wall sex change ,-SH acidifying, metabolism be obstructed and be main sterilization mechanism.
Claims (8)
1, a kind of preparation technology of micro-irrigation emitter anti-biotic material, it is characterized in that: be 2 of 0.003M at first concentration, 2 '-bipyridyl or 1, the complex ion aqueous solution of 10 phenanthroline silver and purity greater than 95% carrier with layer structure by solid: liquid 1: 25-1: 30 volume ratio reaction bonded, make a layer structure antibacterial agent material that carries silver;
Secondly, utilize the interlayer insertion with percent by volume to be: 0.2%～1.1% pyridiniujm, 0.3%～1% chlorophenol, 0.2%～0.8% tetravalence ammonium salt, 0.5%～0.9% biguanide compound, 0.4%～1.3% ethanol, 0.3%～1.5% quaternary ammonium salt organic anti-bacterial component are incorporated in the layer structure antibacterial agent material that carries silver, and making organic and inorganic is composite antibacterial material;
At last, with percent by volume be: 0.5%～1.8% organic and inorganic is that composite antibacterial material infiltrates in the low-pressure high-density polyethylene plastics, gets final product with the dispersant of 0.5%～2% low-molecular polyethylene wax as anti-biotic material.
2, the preparation technology of micro-irrigation emitter anti-biotic material according to claim 1 is characterized in that: the carrier of said layer structure is bentonite, montmorillonite, saponite class clay, salt of phosphoric acid or holds in the palm vigorous mullite.
3, the preparation technology of micro-irrigation emitter anti-biotic material according to claim 1 is characterized in that: said tetravalence ammonium salt is tetraacetyl ethylene diamine, hexamethylenetetramine.
4, the preparation technology of micro-irrigation emitter anti-biotic material according to claim 1 is characterized in that: said biguanide compound is lipophilic poly-hexamethyl guanidine stearate, poly-hexamethyl two guanidine stearate.
5, the preparation technology of micro-irrigation emitter anti-biotic material according to claim 1 is characterized in that: said quaternary ammonium salt is polyquaternium, poly-bi-quaternary ammonium salt.
6, the preparation technology of micro-irrigation emitter anti-biotic material according to claim 1, it is characterized in that: be 1 of 0.003M at first concentration, the complex ion aqueous solution of 10 phenanthroline silver and purity greater than 95% montmorillonite with layer structure by solid: 1: 26 volume ratio reaction bonded of liquid, make a layer structure antibacterial agent material that carries silver; Secondly, utilize the interlayer insertion with percent by volume to be: 0.8% pyridiniujm, 1% chlorophenol, 0.6% hexamethylenetetramine, 0.9% poly-hexamethyl two guanidine stearate, 0.8% ethanol, 1.5% poly-bi-quaternary ammonium salt organic anti-bacterial component are incorporated in the layer structure antibacterial agent material that carries silver, and making organic and inorganic is composite antibacterial material; At last, with percent by volume be: 0.7% organic and inorganic is that composite antibacterial material infiltrates in the low-pressure high-density polyethylene plastics, gets final product with the dispersant of 0.9% low-molecular polyethylene wax as anti-biotic material.
7, the preparation technology of micro-irrigation emitter anti-biotic material according to claim 1, it is characterized in that: be 2 of 0.003M at first concentration, the complex ion aqueous solution of 2 '-bipyridyl and purity greater than 95% saponite class clay with layer structure by solid: 1: 29 volume ratio reaction bonded of liquid, make a layer structure antibacterial agent material that carries silver; Secondly, utilize the interlayer insertion with percent by volume to be: 0.5, the pyridiniujm of %, 0.7% chlorophenol, 0.2% hexamethylenetetramine, 0.8% lipophilic poly-hexamethyl guanidine stearate, 0.4% ethanol, 1.3% polyquaternium organic anti-bacterial component are incorporated in the layer structure antibacterial agent material that carries silver, and making organic and inorganic is composite antibacterial material; At last, with percent by volume be: 0.5% organic and inorganic is that composite antibacterial material infiltrates in the low-pressure high-density polyethylene plastics, gets final product with the dispersant of 1.2% low-molecular polyethylene wax as anti-biotic material.
8, the preparation technology of micro-irrigation emitter anti-biotic material according to claim 1 is characterized in that: the said volume ratio that also can add in vinyon is 0.2%～1% calcium chloride or calcium carbonate, gets final product through mixing and stirring.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03108048 CN1231122C (en) | 2003-05-20 | 2003-05-20 | Process of preparing antibacterial material for microperfusion irrigator |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03108048 CN1231122C (en) | 2003-05-20 | 2003-05-20 | Process of preparing antibacterial material for microperfusion irrigator |
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| CN1454472A true CN1454472A (en) | 2003-11-12 |
| CN1231122C CN1231122C (en) | 2005-12-14 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101724284B (en) * | 2008-10-31 | 2012-06-27 | 中国石油化工股份有限公司 | Anti-bacterial thermoplastic composite and preparation method thereof |
| CN105218964A (en) * | 2014-06-25 | 2016-01-06 | 北京化工大学 | Antibacterial polyvinyl chloride material and its preparation method and application |
| CN105792639A (en) * | 2013-11-27 | 2016-07-20 | 恩普乐股份有限公司 | Emitter and drip irrigation tube |
-
2003
- 2003-05-20 CN CN 03108048 patent/CN1231122C/en not_active Expired - Fee Related
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101724284B (en) * | 2008-10-31 | 2012-06-27 | 中国石油化工股份有限公司 | Anti-bacterial thermoplastic composite and preparation method thereof |
| CN105792639A (en) * | 2013-11-27 | 2016-07-20 | 恩普乐股份有限公司 | Emitter and drip irrigation tube |
| US10034439B2 (en) | 2013-11-27 | 2018-07-31 | Enplas Corporation | Emitter and drip irrigation tube |
| CN105792639B (en) * | 2013-11-27 | 2019-11-19 | 恩普乐股份有限公司 | Transmitter and trickle irrigation delivery pipe |
| CN105218964A (en) * | 2014-06-25 | 2016-01-06 | 北京化工大学 | Antibacterial polyvinyl chloride material and its preparation method and application |
| CN105218964B (en) * | 2014-06-25 | 2017-06-16 | 北京化工大学 | Antibacterial polyvinyl chloride material and its preparation method and application |
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| Publication number | Publication date |
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| CN1231122C (en) | 2005-12-14 |
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Granted publication date: 20051214 Termination date: 20110520 |