CN1403554A - Rolling oil composition for cold rolling steel sheet - Google Patents
Rolling oil composition for cold rolling steel sheet Download PDFInfo
- Publication number
- CN1403554A CN1403554A CN 01130780 CN01130780A CN1403554A CN 1403554 A CN1403554 A CN 1403554A CN 01130780 CN01130780 CN 01130780 CN 01130780 A CN01130780 A CN 01130780A CN 1403554 A CN1403554 A CN 1403554A
- Authority
- CN
- China
- Prior art keywords
- add
- rolling
- oil
- acid
- steel sheet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The present invention is one kind of water soluble rolling composition for cold rolling of carbon steel sheet. The rolling oil composition includes at least one kind of lubricant base oil; at least one kind of surfactant; two or more kinds of antioxidant; one kind of antiwear agent; one kind of fatty acid; one kindof amine antirust agent; one kind of antiseptic anticorrosive agent; and at least two kinds of oily agent. The rolling oil composite is suitable for cold rolling of common carbon steel sheet, stainless steel sheet and tin-plating steel sheet in large control rolling machine and double-roller or multiple-roller reversible rolling machine.
Description
The present invention relates to a kind of rolling oil composition for cold rolling steel sheet, especially a kind of rolling oil composition that is used for high speed tandem rolling unit.The invention belongs to the metal working oil in the lubricating oil field.
(thickness is 0.3～3.5mm) to have good toughness and machining property to Cold Rolled Sheet Steel, is the important materials of producing body of a motor car, therefore is also referred to as autobody sheet.A kind of water-soluble rolling emulsion of rolling needs plays cooling and lubrication, because of the main ingredient of emulsion is water (more than 90%), has favorable cooling effect; A spot of oil ingredient can play good lubrication again and isolate the roller plate.The larger multimachine frame tandem rolling mode of the many employings of the production of Cold Rolled Sheet Steel at present has at a high speed and the characteristics of high yield, and is also more and more higher to the technical feature requirement of rolling mill compound.The using method of ROLLING OIL (emulsion mother liquor) is that its emulsion that is mixed with soluble in water is recycled, and requires emulsion to have: (1) satisfactory stability, and in use not stratified, do not precipitate; (2) lubricity is guaranteed to isolate effectively roll and is avoided roll banding with rolling plate, also will avoid simultaneously skidding between the roller plate; (3) rustless property can breaker roll, roll plate and other equipment unit causes corrosion; (4) anti-bubble performance requires non-foaming foam in recycling process; (5) antibiotic antiseptic property can life-time service and never degenerate smelly; (6) toxicological harmless effect is especially to the skin nonirritant; (7) annealing cleanness rolls plate and do not stay spot after anneal.Product provided by the invention can satisfy these performance requriementss.
The working concentration of emulsion is generally 1～10%, the different applying units and the oil in the different places of production, and concentration is also inequality; Concentration at the different used emulsions of rolling workshop section is also inequality, and in rolling workshop section, pressure is bigger, and required concentration is higher, and the pressure of smooth workshop section is less, and desired concn is also lower.Rolling oil composition for cold rolling steel sheet involved in the present invention, the concentration that is used for rolling workshop section is recommended as 3～5%, and the concentration that is used for smooth workshop section is recommended as 1～3%.
It is main raw material that animal-plant oil is adopted in the preparation of this ROLLING OIL in the past more, and the characteristics of animal-plant oil are to be easy to emulsification, and lubricity is good, but putrid and deteriorated easily, and annealing cleanness is relatively poor.In order to enlarge the source of raw material, the main now mineral oil that adopts, the antibiotic antiseptic property of mineral oil and annealing cleanness can be better, and cheap and easy to get.
More active both at home and abroad to the research of this product, through look into new China's patent have 3 pieces relevant declare as follows: 1, water based lubricating and antirust liquid for cold-rolling
Publication number is CN 1042375A, and water based lubricating and antirust liquid for cold-rolling mainly is to be applied to the steel rolling industry, also can be applicable to the rig bed, grinding machine and the high industry of other cooling and lubricating performance requriements.Technical process is simple, feasible, operation can be finished whole chemical reactions in 8～10 hours, the key problem in technology of water based lubricating and antirust liquid for cold-rolling easily, be to satisfy under the condition of same technical indicator, improve life cycle, economize on the use of funds, increase the final product yield, with water for oil, replace oily fustiness, short, the high deficiency of cost of usage period, one ton of water based lubricating and antirust liquid for cold-rolling can replace 10～15 tons of ROLLING OIL.2, cold-rolled lubricating oil for steel plate
Publication number is CN87102895, the lubricating oil of the rolled sheet material that constitutes by synthesising ester compound, can be by the ternary or the polyvalent alcohol of band tertiary N atom, ethylene oxide adduct and lipid acid as tricarbimide derivative or ethylene diamine make, and it not only has high-caliber rolling lubrication but also have high-caliber milling train clanability.The application people is The Nisshin Oil Mills, Ltd and Nippon Steel Manufacturing Corp 3, the lubricating oil that is used for steel plate water-dispersion cold-rolled lubricating oil and the method for cold-rolled steel sheet
Publication number is CN 1188793A, and the lubricating oil that is used for the water-dispersion cold-rolled lubricating oil of steel plate contains (a) mineral oil and/or by the aliphatic carboxylic acid that contains 12-22 carbon atom with contain the monoesters that the fatty alcohol of 1-12 carbon atom prepares; (b) fat and oily; (c) contain the complex ester of following ester, this ester is by dipolymer acid and/or the polymeric acid and the polyvalent alcohol preparation of the higher aliphatic unsaturated acid that contains 16-20 carbon atom, and wherein remaining carboxyl or hydroxyl are with the monohydroxy-alcohol or the unit price fatty acid esterification that contain 12-22 carbon atom.This lubricating oil also contains (d) phosphorus base stage presses additive or sulfenyl extreme-pressure additive.The application people is a Kao Corp.
External Japanese Patent is more, and representative has following several pieces, and division is as follows: 1, the patent No.: JP11061167
A kind of cold-rolled lubricating oil composition comprises: (a) at least a base oil can be animal-plant oil, mineral oil and ester class oil; (b) a kind of N, the cats product that N-dialkylamine and alhpa olefin-copolymer-maleic anhydride forms; (c) a kind of non-ionic polymers comprises polyvinyl alcohol, polyester and polyalphaolefin; (d) a kind of high fatty alcohol.2, the patent No.: JP10121085
Be used for the cold-rolled lubricating oil composition of steel, comprise: (a) base oil is mineral oil or synthetic oil; (b) fatty acid ester and sulfonate.3, the patent No.: JP08337791
The cold-rolled lubricating oil for steel plate that uses under cold condition comprises base oil and tensio-active agent.Base oil comprises at least 30% refining fat and oily, and wherein containing at least 40% linear chain structure and iodine number is the lipid acid of 50-90.4, the patent No.: JP08325588
A kind of cold-rolled steel sheet lubricating oil contains: (a) one or more fat, fatty oil, mineral oil and Synthetic Oil; (b) 0.2～5% (with respect to nonionogenic tenside a), molecular weight be 2000～15,000 and the HLB value be 5～9; (c) 0.2～5% carboxylate salt.5, the patent No.: JP2608472 JP03026794
Oil additive is used in a kind of novel metal processing, contains: (A) one or more fat and fatty oil, fatty acid ester and mineral oil; (B) a kind of alkenyl succinic anhydride or alkenyl succinic acid ester; (C) a kind of phosphoric acid ester.6, the patent No.: KR9614939 EP399377 JP02305894 US5122288 DE69004487
A kind of stable cold-rolled lubricating oil for steel plate, base oil are animal oil, vegetables oil, mineral oil and synthetic grease, contain: (A) 0.2～5% nonionogenic tenside, and molecular weight 2,000～15,000, the HLB value is 5-9; (B) 0.2～5% another kind of nonionogenic tenside, the HLB value is 12-16; (C) a kind of alkynol nonionogenic tenside.7, the patent No.: JP3096289 JP2000001691
A kind of water-soluble cold-rolled lubricating oil for steel plate, viscosity is at least 60mm
2/ s (40 ℃), pour point is lower than 10 ℃, and contains the mixed ester that the 20-90% weight-average molecular weight is 750-20000, and unnecessary carboxyl wherein and hydroxyl are by the unit alcohol of 12-22C or the esterification of unit lipid acid institute.This product is by one or more monoesters of 5-40%, the Fatty Alcohol(C12-C14 and C12-C18) of mineral oil and 12-22C lipid acid and 1-12C, the fat of 5-70% and oil, and the dimerization of one or more 16-20C higher unsaturated fatty acids or polymer, polyol and water soluble dispersing agent are formed.Water soluble dispersing agent is a kind of homopolymer or multipolymer of vinyl monomer, contains a kind of alkalescence or positive nitrogen-atoms or quaternary ammonium salt at least, water-soluble positive macromolecular compound and soluble amphoteric macromolecular compound.This rolling oil surface tension is at least 40mN/m (25 ℃).8, the patent No.: JP2957026 JP05017788
Cold-rolling of steel plate lubricating oil contains a kind of tallow fatty acid glyceryl ester of modification as base oil component.Three ester groups in the tallow fatty acid glyceryl ester have one or two kind of saturated fatty acidic group by 8-12C substitute.The ester surrogate prepares by transesterification reaction, and the existing lipid acid that is used for transesterify comprises capric acid, n-nonanoic acid, sad, undeeanoic acid and laurostearic acid.Ester exchange offspring can reduce zero pour below 10 ℃, can improve lubricity and thermostability simultaneously.Common base oil component also can mix, and comprises synthetic grease, natural fats and oils and mineral oil.Common additive also needs to add, and comprises extreme pressure anti-wear additives, oxidation inhibitor, rust-preventive agent and emulsifying agent.9、JP10121083
Cold-rolled steel rolling oil composition, base oil are selected from mineral oil, synthetic oil and fatty acid ester etc., and additive has C
12-18Sorbitol polyoxyethylene ether, high-grade aliphatic ester and sulfonate etc.10、JP10231494
The aqueous dispersion type cold-rolled lubricating oil for steel plate contains (a) mineral oil and monoesters class, as C
12-22Lipid acid and C
1-12The formed ester of Fatty Alcohol(C12-C14 and C12-C18); (b) lipid and (c) synthesizing ester.Also contain (d) sulphur phosphorus type extreme pressure anti-wear additives in the lubricating oil.
In addition, many in addition through looking into the foreign patent that newly arrives, especially Japanese Patent introduction, majority all contains animal-plant oil.
Formulation composition of the present invention all is different from above introduction.Base oil component has particularly adopted hydrocracking mineral oil component based on mineral oil, yet there are no the patent report.The present invention's used main additive of filling a prescription all is different from other patent introduction.
Purpose of the present invention is exactly to prepare a kind of oil-in-water type rolling oil composition modern large-scale continuous mill needs and excellent performance that is adapted to.
To achieve these goals, at first external more advanced product performance are investigated, and formulated corresponding quality index according to the characteristic that product uses.It is base oil that the present invention adopts the exquisite mineral oil of modest viscosity and hydrogenated oil, for guaranteeing that product can reach performance requriements, has carried out selected to various additives and other fine chemical products.Be easy to emulsification and lubricity for what guarantee product, and consider and be difficult for forming chemical reaction film, guarantee to roll the annealing cleanness of plate, should select active lower nonionogenic tenside and oiliness improver for use in the metallic surface; Because rolling emulsion recycles at the scene for a long time, need possess good oxidative stability and antibiotic preservative property, rely on adding antioxidant addn and sanitas to solve; Add rust-preventive agent and improve rustless property, the macromole nitrogenous compound improves anti-bubble performance.
Rolling oil composition for cold rolling steel sheet of the present invention contains (a) at least a lubricant base; (b) at least a tensio-active agent; (c) two or more oxidation inhibitor; (d) a kind of anti-wear agent; (e) a kind of organic acid; (f) a kind of amine rust-preventive agent; (g) a kind of antibiotic antiseptic; (h) at least two kinds of oiliness improvers.Wherein said (a) be the refined mineral oil component (MVI150, MVI300,100SN, 200SN) or hydrocracking mineral oil component (125N, 200N), or they are with certain proportion blended mixture, 40 ℃ of kinematic viscosity are 20～60mm
2/ s, add-on is 45～70%; (b) be Nonyl pheno (10) ether (o π-10), add-on is 5～15%; (c) be 2,6-ditertbutylparacresol (T501), add-on is 0.2～1.0% and 124 Triazole stearylamine salt (T551), add-on is 0.01～0.10%; (d) be iso-octyl acid phosphoric acid ester stearylamine salt (T308) or iso-octyl acid phosphoric acid ester (RY86), add-on is 1.0～2.0%; (e) be lipid acid, add-on is 1.0～5.0%; (f) be diethanolamine or trolamine or their mixture, add-on is 0.5～2.0%; (g) be s-triazine (YN-215) or isothiazolinone anticorrosion and bactericidal agent (YN-187) or their mixture, add-on is 0.5～2.0%; Surplus is oiliness improver (h), (h) is in the following compound at least two kinds: oleic acid glycol ester, oleic acid epoxy ester, benzotriazole lipid acid amine salt, sorbitan monooleate.The preparation method is identical substantially with plain oil, in (a) that meets the demands, add component (b), (c), (d), (e), (f) and (g), in stirring more than the 2h under 70～80 ℃ the temperature, add component (h) then, continue to stir 1h down in 60～70 ℃ and get final product.It is ineffective in order to prevent this component and other component from reacting that component (h) adds at last, transfers oil temperature unsuitable too high, in case some component decomposes.
For the experiment product is in time evaluated, the present invention has adopted the analyzing evaluation method shown in the table 1:
Corresponding physico-chemical analysis method of other of table 1 ROLLING OIL and assessment method
* visual method is after oil is in harmonious proportion, to place 24h under room temperature, observes the state of oil product outward appearance, as transparent, translucent, muddy and have or not precipitation.
| Project | Method | Project | Method |
| The oil base outward appearance | Range estimation * | Pour point | ????GB/T3535 |
| Oil base viscosity | ????GB/T265 | Acid number | ????GB/T264 |
| Viscosity index | ????GB/T2541 | Copper corrosion (100 ℃, 3h) | ????GB/T5096 |
| Open flash point | ????GB/T3536 | ||
| Emulsion stability | ????SH/T0579-94 | The pH value | The SH/T0365-92 appendix A |
| The anti-bubble property of emulsion | SH/T0365-92 appendix E | Emulsion corrodibility, T3 copper sheet, 55 ± 2 ℃, 6h | SH/T0365-92 appendix D |
| The salt allowance | The SH/T0365-92 appendix C | Tetra-ball machine test P B | ????GB/T3142 |
Also has the test of emulsion rust-preventing characteristic in addition, with reference to ZBA29001-90 cast iron powder corrosion test method.Take by weighing the 8g reduced iron powder in the beaker of a 60～100mL, dry up with cold wind again after cleaning twice with acetone.The emulsion 30mL of adding 5% leaves standstill 15min after the stirring, remove emulsion.Get the qualitative filter paper of a diameter 90mm, at square frame of paper center picture (50mm * 50mm), iron powder is layered on equably puts into a culture dish in the square frame, put into a moisture eliminator, under the condition of relative saturation humidity RH 〉=90%, place 4h in room temperature together with culture dish.Wash away the paper iron powder with tap water, measure the corrosion area behind the airing, measuring result is 0～4 grade.
0 grade: non-corroding;
1 grade: micro-corrosion, corrosion area 1～3%, the rust spot diameter is no more than 1mm;
2 grades: slight corrosion, corrosion area 4～10%, the rusty stain look shallow;
3 grades: medium corrosion, corrosion area 11～25%, rusty stain is darker;
4 grades: serious corrosion.Corrosion area＞25%, rusty stain is darker.
Qualified emulsion should be not more than 1 grade.
Following example does not limit the scope of the invention, and any change that does not exceed design of the present invention and scope all within the scope of the present invention.
Embodiment 1:
Refined wax base mineral oil component 200SN with 634.5g, 80.0g Nonyl pheno (10) ether (o π-10), 100.0g oleic acid glycol ester (T403), 100.0g oleic acid epoxy ester, 20.0g sorbitan monooleate (span-80), 10.0g iso-octyl acid phosphoric acid ester stearylamine salt (T308), 20.0g benzotriazole lipid acid amine salt (T406), 5.0g 2,6-ditertbutylparacresol (T501), 0.5g 124 Triazole stearylamine salt (T551), 10.0g oleic acid, the trolamine of 10.0g joins in the beaker, in stirring under 70～80 ℃ the temperature more than the 2h, to dissolving evenly, add the s-triazine anticorrosion and bactericidal agent (YN-215) of 10.0g then, under 60～70 ℃ temperature, stir 1h.Relevant analyzing evaluation the results are shown in Table 2.The measured result of the quality standard of table 2 product and embodiment 1 product
Embodiment 2: with the refining intermediate base mineral oil component MVI300 of 694.5g, 50.0g Nonyl pheno (10) ether (o π-10), 150.0g oleic acid glycol ester (T403), 10.0g iso-octyl acid phosphoric acid ester stearylamine salt (T308), 20.0g benzotriazole lipid acid amine salt (T406), 5.0g 2,6-ditertbutylparacresol (T501), 0.5g 124 Triazole stearylamine salt (T551), 50.0g oleic acid, 10.0g trolamine, join in the beaker, in stirring under 70～80 ℃ the temperature more than the 2h, to dissolving evenly, add the s-triazine anticorrosion and bactericidal agent (YN-215) of 10.0g then, under 60～70 ℃ temperature, stir 1h.Relevant analyzing evaluation the results are shown in Table 3.The measured result of the quality standard of table 3 product and embodiment 2 products
Embodiment 3:
| Analysis project | Quality index | Measured result | Analytical procedure | |
| 40 ℃ of kinematic viscosity, mm 2/s | Be not more than 60 | ????52.12 | ??GB/T265 | |
| Viscosity index | Report | ????90 | ??GB/T2541 | |
| Flash-point (opening), ℃ | Be not less than 180 | ????204 | ??GB/T3536 | |
| Pour point, ℃ | Be not higher than-5 | ????-9 | ??GB/T3535 | |
| Tetra-ball machine test P BValue, N | Be not less than 588.0 | ????686.0 | ??GB/T3142 | |
| 5% emulsion | Emulsion appearance | Oyster white | Oyster white | ??SH/T0579 |
| The saponification layer, mL | Be not more than 5.0 | ????＜1.0 | ||
| PH value | ????7～8 | ????7～8 | ||
| Corrosion, level | Be not more than 1 | ????0 | Self-built | |
| 2% emulsion | Foam, mL | Be not more than 2 | ????0 | SH/T0365 appendix A～E |
| Copper corrosion | Qualified | Qualified | ||
| Saturated aqueous common salt | Qualified | Qualified | ||
| The oil base outward appearance | Pale brown look is to light brown | Brown | Range estimation | |
| Analysis project | Quality index | Measured result | Analytical procedure | |
| 40 ℃ of kinematic viscosity, mm 2/s | Be not more than 60 | ????54.04 | ??GB/T265 | |
| Viscosity index | Report | ????78 | ??GB/T2541 | |
| Flash-point (opening), ℃ | Be not less than 180 | ????196 | ??GB/T3536 | |
| Pour point, ℃ | Be not higher than-5 | ????-9 | ??GB/T3535 | |
| Tetra-ball machine test P BValue, N | Be not less than 588.0 | ????656.6 | ??GB/T3142 | |
| 5% emulsion | Emulsion appearance | Oyster white | Oyster white | ??SH/T0579 |
| The saponification layer, mL | Be not more than 5.0 | ????4.0 | ||
| PH value | ????7～8 | ????7～8 | ||
| Corrosion, level | Be not more than 1 | ????＜1 | Self-built | |
| 2% emulsion | Foam, mL | Be not more than 2 | ????2.0 | SH/T0365 appendix A～E |
| Copper corrosion | Qualified | Qualified | ||
| Saturated aqueous common salt | Qualified | Qualified | ||
| The oil base outward appearance | Pale brown look is to light brown | Brown | Range estimation | |
Hydrocracking oil ingredient 125N with 674.5g, 60.0g Nonyl pheno (10) ether (o π-10), 100.0g oleic acid glycol ester (T403), 100.0g sorbitan monooleate (span-80), 20.0g iso-octyl acid phosphoric acid ester (RY86), 20.0g benzotriazole lipid acid amine salt (T406), 5.0g 2,6-ditertbutylparacresol (T501), 0.5g 124 Triazole stearylamine salt (T551), 10.0g oleic acid, the trolamine of 10.0g joins in the beaker, in stirring under 70～80 ℃ the temperature more than the 2h, even to dissolving.Add the s-triazine anticorrosion and bactericidal agent (YN-215) of 10.0g then, under 60～70 ℃ temperature, stir 1h.Relevant analyzing evaluation the results are shown in Table 4.
The measured result of the quality standard of table 4 product and embodiment 3 products
| Analysis project | Quality index | Measured result | Analytical procedure | |
| 40 ℃ of kinematic viscosity, mm 2/s | Be not more than 60 | ????40.83 | ??GB/T265 | |
| Viscosity index | Report | ????110 | ??GB/T2541 | |
| Flash-point (opening), ℃ | Be not less than 180 | ????200 | ??GB/T3536 | |
| Pour point, ℃ | Be not higher than-5 | ????-14 | ??GB/T3535 | |
| Tetra-ball machine test P BValue, N | Be not less than 588.0 | ????931.0 | ??GB/T3142 | |
| 5% emulsion | Emulsion appearance | Oyster white | Oyster white | ??SH/T0579 |
| The saponification layer, mL | Be not more than 5.0 | ????3.5 | ||
| PH value | ????7～8 | ????7～8 | ||
| Corrosion, level | Be not more than 1 | ????0 | Self-built | |
| 2% emulsion | Foam, mL | Be not more than 2 | ????＜1 | SH/T0365 appendix A～E |
| Copper corrosion | Qualified | Qualified | ||
| Saturated aqueous common salt | Qualified | Qualified | ||
| The oil base outward appearance | Pale brown look is to light brown | Brown | Range estimation | |
From the analyzing evaluation result of table 2～table 4 as can be seen, this rolling oil composition example can satisfy the requirement of quality index.
Claims (1)
1, a kind of rolling oil composition for cold rolling steel sheet is characterized in that containing (a) at least a lubricant base; (b) at least a tensio-active agent; (c) two or more oxidation inhibitor; (d) a kind of anti-wear agent; (e) a kind of organic acid; (f) a kind of amine rust-preventive agent; (g) a kind of antibiotic antiseptic; (h) at least two kinds of oiliness improvers, contained component (a) is the refined mineral oil component, or hydrocracking mineral oil component, or their mixture, its performance should satisfy: 40 ℃ of kinematic viscosity are 20～60mm
2/ s, add-on is 45～70%; Contained component (b) is Nonyl pheno (a 10) ether, and add-on is 5～15%; (c) be 2, the 6-ditertbutylparacresol, add-on is 0.2～1.0% and 124 Triazole stearylamine salt, add-on is 0.01～0.10%; (d) be iso-octyl acid phosphoric acid ester stearylamine salt or iso-octyl acid phosphoric acid ester, add-on is 1.0～2.0%; (e) be lipid acid, add-on is 1.0～5.0%; (f) be diethanolamine or trolamine or their mixture, add-on is 0.5～2.0%; (g) be s-triazine or isothiazolinone anticorrosion and bactericidal agent or their mixture, add-on is 0.5～2.0%; Surplus is oiliness improver (h), (h) is in the following compound at least two kinds: oleic acid glycol ester, oleic acid epoxy ester, benzotriazole lipid acid amine salt, sorbitan monooleate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011307803A CN1173021C (en) | 2001-08-24 | 2001-08-24 | Rolling oil composition for cold rolling steel sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011307803A CN1173021C (en) | 2001-08-24 | 2001-08-24 | Rolling oil composition for cold rolling steel sheet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1403554A true CN1403554A (en) | 2003-03-19 |
| CN1173021C CN1173021C (en) | 2004-10-27 |
Family
ID=4670139
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB011307803A Expired - Lifetime CN1173021C (en) | 2001-08-24 | 2001-08-24 | Rolling oil composition for cold rolling steel sheet |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1173021C (en) |
Cited By (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1309812C (en) * | 2004-07-06 | 2007-04-11 | 中国石油化工集团公司 | Lubricating oil composition and use thereof |
| WO2007085130A1 (en) * | 2006-01-25 | 2007-08-02 | Zhengzhao Li | A lubricating oil composition for diesel oil vehicle |
| CN1332006C (en) * | 2006-02-14 | 2007-08-15 | 中国石油化工股份有限公司 | Lubricant composition for computer flat-knitting machine |
| CN100425677C (en) * | 2006-08-31 | 2008-10-15 | 无锡惠源高级润滑油有限公司 | Processing method of softening oil (paraffin base) |
| CN101255374B (en) * | 2008-04-22 | 2012-04-11 | 大连三达奥克化学股份有限公司 | Water-based lubricating oil and production method |
| CN101624547B (en) * | 2009-07-31 | 2012-08-08 | 常州曙光化工厂 | Anti-rust oil for automobile leaf-spring |
| CN101084074B (en) * | 2004-11-22 | 2012-08-29 | 新日本制铁株式会社 | Method for supplying lubricant in cold rolling |
| CN101434886B (en) * | 2008-12-17 | 2012-08-29 | 武汉同盛精细化工技术开发有限责任公司 | Rolling oil composition for 12-roller reversing mill |
| CN102776052A (en) * | 2012-05-14 | 2012-11-14 | 清华大学 | Water-soluble metal antirusting agent and preparation method thereof |
| CN101717687B (en) * | 2009-11-20 | 2013-01-09 | 江门市日盈不锈钢材料厂有限公司 | Novel milling liquid for four-roll mill and preparation method thereof |
| CN101724502B (en) * | 2009-12-09 | 2013-01-09 | 彭美东 | Water-soluble rolling oil |
| CN103013618A (en) * | 2013-01-05 | 2013-04-03 | 北京科技大学 | Method for producing rolling liquid of cold-rolled sheet strip steel by utilizing swill-cooked dirty oil |
| CN103031189A (en) * | 2011-10-10 | 2013-04-10 | 洛科斯润滑油（上海）有限公司 | Metal drawing oil |
| CN103450994A (en) * | 2013-09-12 | 2013-12-18 | 广西大学 | Cold rolling lubricating agent for tin and tin alloy foils |
| CN103450989A (en) * | 2013-09-12 | 2013-12-18 | 广西大学 | Cold rolling lubricating agent for tungsten and tungsten alloy plates and strips |
| CN103450988A (en) * | 2013-09-12 | 2013-12-18 | 广西大学 | Cold rolling lubricating agent for tantalum and tantalum alloy foils |
| CN103627487A (en) * | 2013-11-04 | 2014-03-12 | 广西大学 | Lubricant for cold rolling of chromium and alloy foils of chromium |
| CN103627480A (en) * | 2013-11-04 | 2014-03-12 | 广西大学 | Cold-rolling lubricant for cadmium and alloy foil materials thereof |
| CN103627473A (en) * | 2013-11-04 | 2014-03-12 | 广西大学 | Lubricant for cold rolling of celtium and alloy plate strips of celtium |
| CN103627479A (en) * | 2013-11-04 | 2014-03-12 | 广西大学 | Cold-rolling lubricant for hafnium and alloy foil materials thereof |
| CN103627472A (en) * | 2013-11-04 | 2014-03-12 | 广西大学 | Lubricant for cold rolling of cobalt and alloy plate strip products of cobalt |
| CN103666673A (en) * | 2013-11-19 | 2014-03-26 | 广西大学 | Cold-rolling lubricant for silver and alloy plate strip |
| CN103666676A (en) * | 2013-11-19 | 2014-03-26 | 广西大学 | Middle cold rolling lubricant for nickel and nickel alloy plate strip |
| CN103666671A (en) * | 2013-11-19 | 2014-03-26 | 广西大学 | Cold rolling lubricant for zinc and zinc alloy foil |
| CN103666672A (en) * | 2013-11-19 | 2014-03-26 | 广西大学 | Cold-rolling lubricant for indium and indium alloy plate strip |
| CN103666670A (en) * | 2013-11-19 | 2014-03-26 | 广西大学 | Cold rolling lubricant for copper and copper alloy foil |
| CN103666675A (en) * | 2013-11-19 | 2014-03-26 | 广西大学 | Cold-rolling lubricant for indium and indium alloy foil |
| CN104293427A (en) * | 2014-09-25 | 2015-01-21 | 北京科技大学 | Oxidation-resistant corrosion-resistant copper rolling oil and preparation method thereof |
| CN105062646A (en) * | 2015-08-24 | 2015-11-18 | 沧州华润化工有限公司 | Rolling oil for rolling thin plate |
| CN105154180A (en) * | 2015-08-24 | 2015-12-16 | 沧州华润化工有限公司 | Preparation method of rolling oil for cold rolling of sheets |
| CN105613589A (en) * | 2015-01-30 | 2016-06-01 | 深圳百乐宝生物农业科技有限公司 | Herbicide as well as preparation method and use method thereof |
| CN106520292A (en) * | 2016-11-04 | 2017-03-22 | 广西大学 | An environment friendly stainless steel pipe cold rolling lubricant composition |
-
2001
- 2001-08-24 CN CNB011307803A patent/CN1173021C/en not_active Expired - Lifetime
Cited By (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1309812C (en) * | 2004-07-06 | 2007-04-11 | 中国石油化工集团公司 | Lubricating oil composition and use thereof |
| CN101084074B (en) * | 2004-11-22 | 2012-08-29 | 新日本制铁株式会社 | Method for supplying lubricant in cold rolling |
| WO2007085130A1 (en) * | 2006-01-25 | 2007-08-02 | Zhengzhao Li | A lubricating oil composition for diesel oil vehicle |
| US8138131B2 (en) | 2006-01-25 | 2012-03-20 | Beijing Hookeyvery Lubrication Technology Co., Ltd. | Lubricating oil composition for diesel oil vehicle |
| CN1332006C (en) * | 2006-02-14 | 2007-08-15 | 中国石油化工股份有限公司 | Lubricant composition for computer flat-knitting machine |
| CN100425677C (en) * | 2006-08-31 | 2008-10-15 | 无锡惠源高级润滑油有限公司 | Processing method of softening oil (paraffin base) |
| CN101255374B (en) * | 2008-04-22 | 2012-04-11 | 大连三达奥克化学股份有限公司 | Water-based lubricating oil and production method |
| CN101434886B (en) * | 2008-12-17 | 2012-08-29 | 武汉同盛精细化工技术开发有限责任公司 | Rolling oil composition for 12-roller reversing mill |
| CN101624547B (en) * | 2009-07-31 | 2012-08-08 | 常州曙光化工厂 | Anti-rust oil for automobile leaf-spring |
| CN101717687B (en) * | 2009-11-20 | 2013-01-09 | 江门市日盈不锈钢材料厂有限公司 | Novel milling liquid for four-roll mill and preparation method thereof |
| CN101724502B (en) * | 2009-12-09 | 2013-01-09 | 彭美东 | Water-soluble rolling oil |
| CN103031189A (en) * | 2011-10-10 | 2013-04-10 | 洛科斯润滑油（上海）有限公司 | Metal drawing oil |
| CN102776052A (en) * | 2012-05-14 | 2012-11-14 | 清华大学 | Water-soluble metal antirusting agent and preparation method thereof |
| CN102776052B (en) * | 2012-05-14 | 2014-12-24 | 清华大学 | Water-soluble metal antirusting agent and preparation method thereof |
| CN103013618A (en) * | 2013-01-05 | 2013-04-03 | 北京科技大学 | Method for producing rolling liquid of cold-rolled sheet strip steel by utilizing swill-cooked dirty oil |
| CN103450988B (en) * | 2013-09-12 | 2015-03-11 | 广西大学 | Cold rolling lubricating agent for tantalum and tantalum alloy foils |
| CN103450989A (en) * | 2013-09-12 | 2013-12-18 | 广西大学 | Cold rolling lubricating agent for tungsten and tungsten alloy plates and strips |
| CN103450989B (en) * | 2013-09-12 | 2015-10-07 | 广西大学 | Tungsten and alloy plate strip cold-rolling lubricant thereof |
| CN103450988A (en) * | 2013-09-12 | 2013-12-18 | 广西大学 | Cold rolling lubricating agent for tantalum and tantalum alloy foils |
| CN103450994B (en) * | 2013-09-12 | 2015-03-11 | 广西大学 | Cold rolling lubricating agent for tin and tin alloy foils |
| CN103450994A (en) * | 2013-09-12 | 2013-12-18 | 广西大学 | Cold rolling lubricating agent for tin and tin alloy foils |
| CN103627472B (en) * | 2013-11-04 | 2015-06-03 | 广西大学 | Lubricant for cold rolling of cobalt and alloy plate strip products of cobalt |
| CN103627479A (en) * | 2013-11-04 | 2014-03-12 | 广西大学 | Cold-rolling lubricant for hafnium and alloy foil materials thereof |
| CN103627487A (en) * | 2013-11-04 | 2014-03-12 | 广西大学 | Lubricant for cold rolling of chromium and alloy foils of chromium |
| CN103627487B (en) * | 2013-11-04 | 2015-06-03 | 广西大学 | Lubricant for cold rolling of chromium and alloy foils of chromium |
| CN103627480A (en) * | 2013-11-04 | 2014-03-12 | 广西大学 | Cold-rolling lubricant for cadmium and alloy foil materials thereof |
| CN103627480B (en) * | 2013-11-04 | 2015-04-29 | 广西大学 | Cold-rolling lubricant for cadmium and alloy foil materials thereof |
| CN103627473B (en) * | 2013-11-04 | 2015-04-29 | 广西大学 | Lubricant for cold rolling of celtium and alloy plate strips of celtium |
| CN103627472A (en) * | 2013-11-04 | 2014-03-12 | 广西大学 | Lubricant for cold rolling of cobalt and alloy plate strip products of cobalt |
| CN103627473A (en) * | 2013-11-04 | 2014-03-12 | 广西大学 | Lubricant for cold rolling of celtium and alloy plate strips of celtium |
| CN103666675A (en) * | 2013-11-19 | 2014-03-26 | 广西大学 | Cold-rolling lubricant for indium and indium alloy foil |
| CN103666673A (en) * | 2013-11-19 | 2014-03-26 | 广西大学 | Cold-rolling lubricant for silver and alloy plate strip |
| CN103666670A (en) * | 2013-11-19 | 2014-03-26 | 广西大学 | Cold rolling lubricant for copper and copper alloy foil |
| CN103666672A (en) * | 2013-11-19 | 2014-03-26 | 广西大学 | Cold-rolling lubricant for indium and indium alloy plate strip |
| CN103666671A (en) * | 2013-11-19 | 2014-03-26 | 广西大学 | Cold rolling lubricant for zinc and zinc alloy foil |
| CN103666676A (en) * | 2013-11-19 | 2014-03-26 | 广西大学 | Middle cold rolling lubricant for nickel and nickel alloy plate strip |
| CN104293427A (en) * | 2014-09-25 | 2015-01-21 | 北京科技大学 | Oxidation-resistant corrosion-resistant copper rolling oil and preparation method thereof |
| CN104293427B (en) * | 2014-09-25 | 2016-08-24 | 北京科技大学 | A kind of copper ROLLING OIL of oxidation and corrosion and preparation method thereof |
| CN105613589A (en) * | 2015-01-30 | 2016-06-01 | 深圳百乐宝生物农业科技有限公司 | Herbicide as well as preparation method and use method thereof |
| CN105062646A (en) * | 2015-08-24 | 2015-11-18 | 沧州华润化工有限公司 | Rolling oil for rolling thin plate |
| CN105154180A (en) * | 2015-08-24 | 2015-12-16 | 沧州华润化工有限公司 | Preparation method of rolling oil for cold rolling of sheets |
| CN106520292A (en) * | 2016-11-04 | 2017-03-22 | 广西大学 | An environment friendly stainless steel pipe cold rolling lubricant composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1173021C (en) | 2004-10-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1173021C (en) | Rolling oil composition for cold rolling steel sheet | |
| CN100523154C (en) | Composition of cold rolling sheet rolling oil | |
| CN102746924B (en) | Aluminium hot-rolling oil | |
| CN102002418B (en) | Cold rolled silicon steel rolled oil composition | |
| CN102260580B (en) | Cold rolling extreme thin plate rolling oil composition | |
| CN103589491A (en) | Lubricating material for cold rolling and its preparation method and use | |
| EP3372660B1 (en) | High temperature lubricants | |
| CN108570341A (en) | A kind of belt steel rolling oil and its production method | |
| CN105154180A (en) | Preparation method of rolling oil for cold rolling of sheets | |
| CN102399616B (en) | Synthetic circulating emulsified oil for rolling | |
| CN1332001C (en) | Cold-rolled lubricating oil for steel plate | |
| CN105062646A (en) | Rolling oil for rolling thin plate | |
| CN114381319B (en) | Emulsified oil for copper and copper alloy wire drawing and preparation method thereof | |
| JP2007077216A (en) | Cold rolling oil for steel plate | |
| DE112010005707B4 (en) | Lubricant composition and its use | |
| CN106590843A (en) | Precision stainless steel band cold-rolling rolling oil | |
| DE112013000604B4 (en) | Lubricating composition and its use for bearings | |
| CN108865365A (en) | Stable emulsifying type straight carbon steel cold rolling oil and application thereof | |
| CN113201391A (en) | Water-based automobile plate stamping oil and preparation method and use method thereof | |
| CH617717A5 (en) | Process for producing a lithium soap lubricating grease of high dripping point | |
| CN105087122A (en) | Rolling oil composition for cold-rolled stainless steel sheet and preparation method thereof | |
| JPH01301793A (en) | Lubricating oil | |
| KR950010600B1 (en) | Cold roll oil of steel foil | |
| CN110923046A (en) | Stamping lubricating anti-rust oil and preparation method thereof | |
| CN1435472A (en) | Lubricating oil composition for wide steel strip hot continuous mill rolling process |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CX01 | Expiry of patent term |
Granted publication date: 20041027 |
|
| CX01 | Expiry of patent term |