CN1363537A - Compound B-Mg fertilizer and its preparing process - Google Patents

Compound B-Mg fertilizer and its preparing process Download PDF

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Publication number
CN1363537A
CN1363537A CN 01106052 CN01106052A CN1363537A CN 1363537 A CN1363537 A CN 1363537A CN 01106052 CN01106052 CN 01106052 CN 01106052 A CN01106052 A CN 01106052A CN 1363537 A CN1363537 A CN 1363537A
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China
Prior art keywords
feed liquid
crystallizer
magnesium fertilizer
boron magnesium
mother liquor
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Pending
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CN 01106052
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Chinese (zh)
Inventor
柳忠奇
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Individual
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Individual
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Publication date
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Priority to CN 01106052 priority Critical patent/CN1363537A/en
Publication of CN1363537A publication Critical patent/CN1363537A/en
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Abstract

A compound B-Mg fertilizer is prepared from the waste liquid generated in preparing boric acid by sulfuric acid, and features that it contains MgSO4.7H2O (higher than 90 wt.%), Fe (higher than 0.5), Na2B4O7.10H2O (higher than 3) and chloride (lower than 0.14).

Description

Composite boron magnesium fertilizer and preparation technology thereof
The invention belongs to the boronation worker and administer the extension manufacture field of pollution and comprehensive utilization of resources, particularly utilize the waste liquid of Production By Sulfuric Acid Process boric acid to produce composite boron magnesium fertilizer and production technique.
In the past, China's boronation worker leading product were borax, boric acid.And boric acid is produced today, and still major part adopts the vitriol oil and the one-step technology manufacturing of giving birth to boron powder (higher-grade) reaction always.Adopt this manufactured boric acid, the rate of recovery of general producer boron only reaches a new level about 60%, and the major part of recoverable boric acid and a large amount of sal epsom do not emit with waste liquid (mother liquor), both serious pollution environment, wasted resource again greatly.
For solving the recovery problem of boron, more domestic scientific research departments and production unit, once utilized " salt acid system ", the two step method of saltouing, produce the test of boric acid, magnesium chloride or magnesium sulfate monohydrate, but all be not applied in the actual production, domestic also have tame unit test to add the gas washing in SA production boric magnesium fertilizer with giving birth to boron ore powder.
The object of the present invention is to provide a kind of compliance with environmental protection requirements, effect of increasing production ideal composite boron magnesium fertilizer and preparation technology thereof.
Technical solution of the present invention can realize according to following mode:
Composite boron magnesium fertilizer is characterized in: (percentage composition by weight) contains:
MgSO 4.7H 2O≥90%,
Fe≥0.5%,
Na 2B 4O 7.10H 2O≥3%,
Muriate≤0.14%
The preparation technology of above-mentioned composite boron magnesium fertilizer is characterized in: the waste liquid of Production By Sulfuric Acid Process boric acid as mother liquor, is finished the following step successively:
(1) mother liquor is directly deposited in material-stored pool or the material-storage jar;
(2) utilize submerged pump that feed liquid is added in the vaporizer, utilize steam heating, carry out evaporation concentration, 4~8 hours, the feed liquid of evaporation is carried out the degree Beaume test, when reaching 38~42Be °, in time squeeze into feed liquid in the crystallizer while hot;
(3) after crystallizer is made, open water coolant, cool off, start agitator simultaneously, stir, make it uniform particles, do not form druse;
(4) when from outward appearance to inner essence 100 ℃ when reducing to below 35 ℃ of the feed liquids in the crystallizer, will arrive the feed liquid of temperature and put into the heavy naturally filter of heavy filter pocket, the material adding whizzer with dryer and comfortableer carries out centrifuge dehydration;
(5) will take off the crystal material of water, take out the packing weighing, i.e. the efficient composite boron magnesium fertilizer of output.
The present invention's energy efficent use of resources, compliance with environmental protection requirements has effect of increasing production to farm crop.
Below in conjunction with accompanying drawing in detail preferred forms of the present invention is described in detail:
Fig. 1 is a process flow sheet of the present invention;
Embodiment 1:
Utilize the production boric acid waste liquid to produce efficient composite boron magnesium fertilizer, its primary condition is: produce the waste liquid (mother liquor) that one ton of boric acid can produce tens cubic metres, boronic acid containing 38~42kg in every cubic metre of waste liquid, sulfur acid magnesium 280~300kg, about 28 ℃ of the temperature of discharging waste liquid, 27Be ° of its degree Beaume.
Composite boron magnesium fertilizer of the present invention, (percentage composition by weight) contains:
MgSO 4.7H 2O 93.39%,
Fe 0.6%,
Na 2B 4O 7.10H 2O?4%,
Muriate 0.01%.
Free-water 2%
This product appearance: white little yellowish green tiny crystalline particle of being with.
Finished product be do not have smell, bitter, soluble in water, be slightly soluble in ethanol, proportion 1.68, easy-weathering in dry air.
Purposes: be mainly used in trace element fertilizer in the agricultural.
The preparation technology of above-mentioned composite boron magnesium fertilizer is characterized in: the waste liquid of Production By Sulfuric Acid Process boric acid as mother liquor, is finished the following step successively:
(1) mother liquor is directly deposited in material-stored pool or the material-storage jar;
(2) utilize submerged pump that feed liquid is added in the vaporizer, utilize steam heating, carried out evaporation concentration 6 hours, the feed liquid of evaporation is carried out the degree Beaume test, when reaching 40Be °, in time squeeze into feed liquid in the crystallizer while hot;
(3) after crystallizer is made, open water coolant, cool off, start agitator simultaneously, stir, make it uniform particles, do not form druse;
(4) when from outward appearance to inner essence 100 ℃ when reducing to below 35 ℃ of the feed liquids in the crystallizer, will arrive the feed liquid of temperature and put into the heavy naturally filter of heavy filter pocket, the material adding whizzer with dryer and comfortableer carries out centrifuge dehydration;
(5) will take off the crystal material of water, take out the packing weighing, i.e. the efficient composite boron magnesium fertilizer of output.
Embodiment 2:
Composite boron magnesium fertilizer of the present invention, (percentage composition by weight) contains:
MgSO 4.7H 2O 91.488%,
Fe 0.5%,
Na 2B 4O 7.10H 2O 5.0%,
Muriate 0.012%.
Free-water 3%
The preparation technology of above-mentioned composite boron magnesium fertilizer is characterized in: the waste liquid of Production By Sulfuric Acid Process boric acid as mother liquor, is finished the following step successively:
(1) mother liquor is directly deposited in material-stored pool or the material-storage jar;
(2) utilize submerged pump that feed liquid is added in the vaporizer, utilize steam heating, carried out evaporation concentration 5.5 hours, during evaporation, should grasp feed concentration at any time, when feed concentration reaches the nearly saturation concentration (90 ℃~100 ℃) of boric acid or sal epsom, the feed liquid of evaporation be carried out the degree Beaume test, when reaching 41Be °, in time squeeze into feed liquid in the crystallizer while hot; What vaporizer adopted is row formula single-effect evaporation, and vapor pressure is controlled at 0.15~0.25Mpa.
(3) after crystallizer is made, open water coolant, cool off, start agitator simultaneously, stir, make it uniform particles, do not form druse;
(4) when from outward appearance to inner essence 100 ℃ when reducing to below 35 ℃ of the feed liquids in the crystallizer, will arrive the feed liquid of temperature and put into the heavy naturally filter of heavy filter pocket, the material adding whizzer with dryer and comfortableer carries out centrifuge dehydration;
(5) will take off the crystal material of water, take out the packing weighing, i.e. the efficient composite boron magnesium fertilizer of output.

Claims (2)

1, composite boron magnesium fertilizer is characterized in that: (percentage composition by weight) contains:
MgSO 4.7H 2O≥90%,
Fe≥0.5%,
Na 2B 4O 7.10H 2O≥3%,
Muriate≤0.14%.
2, the preparation technology of composite boron magnesium fertilizer according to claim 1 is characterized in that: the waste liquid of Production By Sulfuric Acid Process boric acid as mother liquor, is finished the following step successively:
(1) mother liquor is directly deposited in material-stored pool or the material-storage jar;
(2) utilize submerged pump that feed liquid is added in the vaporizer, utilize steam heating, carried out evaporation concentration 4~8 hours, the feed liquid of evaporation is carried out the degree Beaume test, when reaching 38~42Be °, in time squeeze into feed liquid in the crystallizer while hot;
(3) after crystallizer is made, open water coolant, cool off, start agitator simultaneously, stir, make it uniform particles, do not form druse;
(4) when from outward appearance to inner essence 100 ℃ when reducing to below 35 ℃ of the feed liquids in the crystallizer, will arrive the feed liquid of temperature and put into the heavy naturally filter of heavy filter pocket, the material adding whizzer with dryer and comfortableer carries out centrifuge dehydration;
(5) will take off the crystal material of water, take out the packing weighing, i.e. the efficient composite boron magnesium fertilizer of output.
CN 01106052 2001-01-08 2001-01-08 Compound B-Mg fertilizer and its preparing process Pending CN1363537A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 01106052 CN1363537A (en) 2001-01-08 2001-01-08 Compound B-Mg fertilizer and its preparing process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 01106052 CN1363537A (en) 2001-01-08 2001-01-08 Compound B-Mg fertilizer and its preparing process

Publications (1)

Publication Number Publication Date
CN1363537A true CN1363537A (en) 2002-08-14

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN 01106052 Pending CN1363537A (en) 2001-01-08 2001-01-08 Compound B-Mg fertilizer and its preparing process

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CN (1) CN1363537A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009052701A1 (en) 2007-10-16 2009-04-30 Sinopec Yangzi Petrochemical Company Ltd. Non-metallocene catalyst supported on magnesium compound and its preparation method
WO2011050565A1 (en) 2009-10-26 2011-05-05 中国石油化工股份有限公司 Supported non-metallocene catalyst, manufacturing method and application thereof
WO2011050566A1 (en) 2009-10-26 2011-05-05 中国石油化工股份有限公司 Supported non-metallocene catalyst, preparation method and uses thereof
WO2011057468A1 (en) 2009-11-13 2011-05-19 中国石油化工股份有限公司 Supported non-metallocene catalyst, preparation method and application thereof
WO2011057469A1 (en) 2009-11-13 2011-05-19 中国石油化工股份有限公司 Supported non-metallocene catalyst and preparation method and uses thereof
US8193288B2 (en) 2007-10-16 2012-06-05 Sinopec Yangzi Petro-Chemical Ltd. Supported nonmetallocene catalyst and preparation thereof

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009052701A1 (en) 2007-10-16 2009-04-30 Sinopec Yangzi Petrochemical Company Ltd. Non-metallocene catalyst supported on magnesium compound and its preparation method
US8193288B2 (en) 2007-10-16 2012-06-05 Sinopec Yangzi Petro-Chemical Ltd. Supported nonmetallocene catalyst and preparation thereof
US8716416B2 (en) 2007-10-16 2014-05-06 Sinopec Yangzi Petrochemical Company Ltd. Magnesium-compound supported nonmetallocene catalyst and preparation thereof
WO2011050565A1 (en) 2009-10-26 2011-05-05 中国石油化工股份有限公司 Supported non-metallocene catalyst, manufacturing method and application thereof
WO2011050566A1 (en) 2009-10-26 2011-05-05 中国石油化工股份有限公司 Supported non-metallocene catalyst, preparation method and uses thereof
US8952112B2 (en) 2009-10-26 2015-02-10 China Petroleum & Chemical Corp. Supported nonmetallocene catalyst, preparation and use thereof
US8981023B2 (en) 2009-10-26 2015-03-17 China Petroleum & Chemical Corp. Supported nonmetallocene catalyst, preparation and use thereof
WO2011057468A1 (en) 2009-11-13 2011-05-19 中国石油化工股份有限公司 Supported non-metallocene catalyst, preparation method and application thereof
WO2011057469A1 (en) 2009-11-13 2011-05-19 中国石油化工股份有限公司 Supported non-metallocene catalyst and preparation method and uses thereof
US8952113B2 (en) 2009-11-13 2015-02-10 China Petroleum & Chemical Corp. Supported nonmetallocene catalyst, preparation and use thereof
US8957169B2 (en) 2009-11-13 2015-02-17 China Petroleum & Chemical Corp. Supported nonmetallocene catalyst, preparation and use thereof

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