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Underwater antidispersion concrete admixture for building

Abstract

The present invention belongs to the technical field of construction materials, particularly to an underwater antidispersion concrete admixture for construction. The present invention is composed of methylcellulose, polyacrylamide, sodium dodecyl benzene sulfonate, a naphthalene series high-effective water reducing agent, octadecanoic acid and zeolite powder. The present invention has the performance of no dispersion and no separation in underwater direct casting construction and can automatically fill templates under water and carry out self-compaction. The present invention can increase the structure performance after concrete underwater pouring, simplify underwater coating processes, save labor and avoid environmental pollution to neighborhood water area, and the present invention is important to an engineering field.

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CN1326796C

China

Other languages
Chinese
Inventor
孙振平
蒋正武
Current Assignee
Tongji University

Worldwide applications
2003 CN

Application CNB031169163A events
2007-07-18
Application granted
Anticipated expiration
Expired - Fee Related

Description

The anti-under water concrete admixture that disperses for building
Technical field
The invention belongs to building material technical field, be specifically related to a kind of anti-concrete admixture that disperses for building under water.
Background technology
Adopt normal concrete directly to be cast under water, owing to be subjected to the effect of current scour, cement slurry seriously separates with gathering materials in the concrete mix, grout can be broken up loss by current, not only cement slurry is few in the pour mass, and water/glue ratio increase greatly, concrete structure homogeneity extreme difference, intensity and weather resistance seriously descend.Adopt normal concrete to carry out pollution that underwater pouring causes near water environment and the destruction of organism in water is difficult to the imagination.
For many years, in order to improve quality with normal concrete cast underwater structures, engineering unit also adopted multiple special construction method, constructed as adopting cofferdam drainage, folded bag method, pre-packed method or service tools such as employing conduit, bottom opening container, but facts have proved, adopt these traditional constructional methods, the shortcoming that exists is still a lot, and not only quantities is big, and careless slightly, accident resulting from poor quality of projects is difficult to avoid, and the example of failure is also more.
Since former West Germany in 1974 carried out the anti-concrete development research of dispersion first under water and is applied to actual engineering, many countries all actively dropped into the research of this respect, have obtained successful effect.But, take a broad view of over and resist the research and the application achievements of disperseing the concrete aspect under water, because the anti-dispersant that adopts and the anti-under water limitation of disperseing concrete performance of preparing, the anti-under water concrete strength grade generally lower (C30 is following) that disperses of pouring into a mould disperses concrete erosion resistance, frost resistance, anti-Cl to resisting under water -The research of weather resistance aspects such as perviousness is also less, and more and more incompatible actual engineering is to the anti-new demand that disperses concrete at aspects such as mechanical property and weather resistance under water.In addition, traditional anti-dispersant volume is big, and the cost height has also limited the use of actual engineering.
In relevant patent, also have by plain class of simple adding of fiber or the concrete report of the anti-under water dispersion of polypropylene-base tackifier (water-holding agent) material preparation, but the concrete land and water strength ratio of being prepared has only 65%-70% (7 days) and 70%-75% (28 days), and concrete slump-loss is bigger, is not suitable for remote transportation and pumping construction.
Summary of the invention
The objective of the invention is to propose for building anti-concrete admixture that disperses of good endurance such as good, anti-dispersed strong, the mobile loss of a kind of application property is little, anticorrosive, frost resistance, resistance of chloride ion penetration under water.
The for building anti-under water concrete admixture that disperses that the present invention proposes is made up of methylcellulose gum, polyacrylamide, Sodium dodecylbenzene sulfonate, naphthalene series high-efficiency water-reducing agent, stearic acid, zeolite powder, and the weight ratio of each component is:
Methylcellulose gum 100
Polyacrylamide 85-220
Sodium dodecylbenzene sulfonate 1.3-8
Naphthalene series high-efficiency water-reducing agent 260-720
Stearic acid 1.3-6.5
Zeolite powder 60-245
The weight ratio that each component is preferable:
Methylcellulose gum 100
Polyacrylamide 122-142
Sodium dodecylbenzene sulfonate 3-6
Naphthalene series high-efficiency water-reducing agent 460-520
Stearic acid 2-5
Zeolite powder 85-100
Preparation method of the present invention is: by aforementioned each each component of part by weight weighing, six kinds of raw materials are mixed by physical mechanical, stir, promptly obtain this product.
Among the present invention, methylcellulose gum and polyacrylamide can be used for food and medicine industry as anti-dispersant, to human body and other biological no damaging effect, give good cohesiveness of concrete and anti-water erosion; Sodium dodecylbenzene sulfonate gives concrete good bleed as air entrapment agent, regulates concrete air content, improves concrete workability and freeze-thaw-cyclicity; Naphthalene series high-efficiency water-reducing agent has adaptability preferably with the flocculation composition, can reduce water consumption significantly, improves concrete workability, improves concrete strength and weather resistance; Stearic acid can be adsorbed in the internal surface of bubble in the concrete as the hydrophobic composition, improves bubble inwall hydrophobic nature; Zeolite powder can be used as the stopping composition of this product on the one hand, makes its protection against the tide, prevents caking, can play enhancement on the other hand.
Among the present invention, naphthalene series high-efficiency water-reducing agent is naphthalene sulfonic acidformaldehyde condensation product (wherein sodium sulphate content is less than 3%).
The present invention is the tawny powder mass.Admixture accounts for the anti-concrete admixture that disperses that the gelling material gross weight is 0.5%-3.5% under water in concrete, can make the anti-concrete that disperses of the good high-performance of application property good (slump is greater than 22cm, and the degree of expansion that collapses is greater than 55cm), ultimate compression strength height (C30-C50), weather resistance under water.Test shows, the concrete anti-dispersiveness of this product of admixture is 70%-80% (7 days) and 85%-90% (28 days) when characterizing with the land and water strength ratio.
Among the present invention, anti-under water dispersion concrete is an important branch of high performance concrete, it has direct under water casting and constructing and does not disperse, do not emanate, can be under water from the performance of filling template and self-compacting, be the important materials that improves structure performance, simplification underwater pouring technology, the saving labour after concrete is poured into a mould under water and avoid near waters is caused environmental pollution, enjoy the attention of engineering circle.
Embodiment
Embodiment 1, anti-under water dispersion concrete admixture for building are pressed methylcellulose gum 12% (weight percent, down with), polyacrylamide 18%, Sodium dodecylbenzene sulfonate 0.5%, naphthalene sulfonic acidformaldehyde condensation product 59%, stearic acid 0.5%, zeolite powder 10% be formulated, this anti-dispersant of admixture (anti-dispersant volume be cement weight 1.2%), can make concrete land and water strength ratio reach 80% (7 days) and 86% (28 days), and under volume reaches 1.5% situation, can make concrete land and water strength ratio reach 87% and 90%.
Embodiment 2, for building anti-under water to disperse concrete admixture to press methylcellulose gum 9%, polyacrylamide 13%, Sodium dodecylbenzene sulfonate 0.4%, naphthalene sulfonic acidformaldehyde condensation product 59%, stearic acid 0.6%, zeolite powder 18% formulated, can be at binder total amount 580kg/m 3, anti-dispersant volume 1.2%B under the sand coarse aggregate ratio 44%-50% situation, makes slump 24cm, the degree of expansion 58cm that collapses, and slump-loss was not more than 4cm in 1 hour, and 28 days ultimate compression strength reach the concrete of C50.

Claims (4)
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translated from Chinese

1、一种建筑用水下抗分散混凝土外加剂,其特征在于由甲基纤维素、聚丙烯酰胺、十二烷基苯磺酸钠、萘系高效减水剂、硬脂酸、沸石粉组成,各组分的重量比为:1. An underwater anti-dispersion concrete admixture for construction, characterized in that it is composed of methylcellulose, polyacrylamide, sodium dodecylbenzenesulfonate, naphthalene series superplasticizer, stearic acid, and zeolite powder. The weight ratio of each component is: 甲基纤维素          100Methylcellulose 100 聚丙烯酰胺          85-220Polyacrylamide 85-220 十二烷基苯磺酸钠    1.3-8Sodium dodecylbenzenesulfonate 1.3-8 萘系高效减水剂      260-720Naphthalene series superplasticizer 260-720 硬脂酸              1.3-6.5Stearic acid 1.3-6.5 沸石粉              60-245。Zeolite powder 60-245. 2、根据权利要求1所述的建筑用水下抗分散混凝土外加剂,其特征在于各组分的重量比为:2. The underwater anti-dispersion concrete admixture for construction according to claim 1, characterized in that the weight ratio of each component is: 甲基纤维素          100Methylcellulose 100 聚丙烯酰胺          122-142Polyacrylamide 122-142 十二烷基苯磺酸钠    3-6Sodium dodecylbenzenesulfonate 3-6 萘系高效减水剂      460-520Naphthalene superplasticizer 460-520 硬脂酸              2-5Stearic acid 2-5 沸石粉              85-100。Zeolite powder 85-100. 3、根据权利要求1所述的建筑用水下抗分散混凝土外加剂,其特征在于萘系高效减水剂为硫酸钠含量小于3%的萘磺酸甲醛缩合物。3. The underwater anti-dispersion concrete admixture for construction according to claim 1, characterized in that the naphthalene-based high-efficiency water reducer is a naphthalenesulfonic acid formaldehyde condensate with a sodium sulfate content of less than 3%. 4、一种如权利要求1所述混凝土外加剂的使用方法,其特征在于外加剂在混凝土中掺加量为占胶凝材料总重量的0.5%-3.5%。4. A method for using the concrete admixture as claimed in claim 1, characterized in that the amount of the admixture in the concrete is 0.5%-3.5% of the total weight of the cementitious material.