CN1318591A - Method for making handiwork of yuhua pebbles and polyester resin - Google Patents
Method for making handiwork of yuhua pebbles and polyester resin Download PDFInfo
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- CN1318591A CN1318591A CN 01113591 CN01113591A CN1318591A CN 1318591 A CN1318591 A CN 1318591A CN 01113591 CN01113591 CN 01113591 CN 01113591 A CN01113591 A CN 01113591A CN 1318591 A CN1318591 A CN 1318591A
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- polyester resin
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Abstract
Yuhua pebbles are surface treated; unsaturated polyester resin, curing agent and promoter are mixed through stirring to prepare unsaturated resin liquor; some resin liquor is injected into mold to form base layer; more resin liquor is then injected over the base layer and treated Yuhua pebbles are planted in the liquor to display optimal picture before resin liquor is injected for the third time; and after solidification and demolding and through heat treatment and curing in water, polishing, assembling with base seat and packing, the handiwork is made.
Description
The present invention relates to a kind of making method of artwork, the making method of particularly a kind of unsaturated polyester resin (polyester resin) artwork.
Yuhua stone is described as " national treasure of being bestowed by heaven ", and " China one is exhausted " originates in Nanjing and surrounding area, is the distinctive tourist resources in Nanjing; Yuhua stone also is that four of China views and admires one of stone greatly, is described as queen in the stone; Yuhua stone is a kind of natural gemstone of not being familiar with by most of people, general jewel does not almost have natural image, all need processing treatment, i.e. so-called " as man needs training and discipline also ", and Yuhua stone integrates: matter U.S., look U.S., shape U.S., line U.S., ingenious U.S., artistic conception U.S. are that other jewel is impayable.But Yuhua stone is as natural tourist resources and view and admire stone its insufficient aspect is arranged again: at first be that body is little, do not resemble other and view and admire stone and can be placed directly in antique-and-curio shelves or case and view and admire on several; Secondly the tradition of Yuhua stone is viewed and admired method, must be placed in the water, or view and admire among being placed on brocade box after the polishing, the method of viewing and admiring that these are traditional is extremely inconvenient, had a strong impact on the comprehensive displaying of Yuhua stone six U.S.s, influence the development and use of this characteristic tourism resource of Yuhua stone, made this preciousness of Yuhua stone view and admire the stone kind, be faced with the dangerous condition that enters into " blind alley ".Because Yuhua stone generally all is that the chi width of cloth is below 10 centimetres, the ovoid grain agate that ornamental value is arranged, and generally all to be placed in the water and could show its look, matter, line, beautiful pattern such as artistic conception, it is viewed and admired and plays all inconveniences, the people of especially amateur collection Yuhua stone, it is more inconvenient to appreciate Yuhua stone, even be difficult for being accepted by some people, Yuhua stone is never broken through and is placed on the destiny of viewing and admiring in the water for a long time, so that making this precious resource hide " lady's chamber " people difficulty deeply sees, Yuhua stone collector and some departments of Nanjing government, even sighing for the destiny of Yuhua stone and DEVELOPMENT PROSPECT sorrow.
On the other hand, unsaturated polyester resin (being commonly called as polyester resin), present having is used for craft articles, and its product mainly contains: the first kind is that Fang Ru Kun worm, plantlet are made ambroid in unsaturated polyester resin; Second class is to put into card to make souvenir in unsaturated polyester resin; The 3rd class is to add liquid or put the artwork that some little plastics are made in the unsaturated polyester resin of hollow.These three classes unsaturated polyester resin goods all have a common feature, and the thing weight of promptly putting into is all low weight, manufacture relatively easily, and the magnitude of value is also relatively cheap; Do not resemble Yuhua stone one piece in thousands of at most units of dozens of yuan at least, require the success ratio height of manufacturing.And Yuhua stone weight is big, and the direction position takes place easily to be offset and is difficult to control during implantation, as long as the position that Yuhua stone is implanted has difference slightly, just may make Yuhua stone be difficult to the scenery of showing that it is best; And most critical is that traditional Yuhua stone method of viewing and admiring must be placed in the water, and promptly it need closely contact with water, could show U.S. of Yuhua stone by the refraction of water.Unsaturated polyester resin can be played and water with effect and effect, the difficult problem that this cann't be solved during with the unsaturated polyester resin craft articles before being.
Purpose of the present invention is exactly in order to address the above problem, and proposes a kind of making method of handiwork of yuhua pebbles and polyester resin of U.S. that can fully show Yuhua stone.
Technical solution of the present invention:
1, selected Yuhua stone is soaked with the rare strong acid of 8-26% (hydrochloric acid or sulfuric acid), remove surperficial rusty stain and dirty, to some profiles not just or have the natural Yuhua stone of obvious flaw to cut, polish, make the profile of Yuhua stone and picture reach best effect; Soak with clear water then, and change water at least and once (preferably change water more than three times), make the Yuhua stone appearance reach complete cleaning, it is standby to dry Yuhua stone.
2, get mixed stirring of unsaturated polyester resin, solidifying agent, promotor gradation and make unsaturated polyester resin solution, the weight permillage of its each composition is:
Vibrin 980-999 ‰
Solidifying agent 0.5-9 ‰
Promotor 0.8-9 ‰
Because chemical reaction very easily takes place in solidifying agent, promotor, and the time can't grasp, when then making, can only earlier unsaturated polyester resin and solidifying agent (or promotor) be made solution, add promotor (or solidifying agent) when pouring into a mould again.And during cast, should carry out several times, be generally 2-4 time.
3,, adopt soft plastics or silicon rubber or other conveniently stripped non-leakage again material to make mould according to the configuration design requirement.
4, get a certain amount of evenly stirring of solidifying agent (or promotor) that promotor (or solidifying agent) unsaturated polyester resin solution adds doses again of having added, inject among the mould, solidify the bottom that back (degree of solidifying is preferably 80-90%) promptly forms artwork of the present invention; On this bottom, reinject can submergence Yuhua stone 1/2-4/5, prepare the unsaturated polyester resin solution of promotor and solidifying agent, in this solution, implant the aforementioned Yuhua stone of having handled well rapidly and make it to show best picture, when the degree of solidifying of the unsaturated polyester resin solution of this submergence Yuhua stone reaches 50-80%, the unsaturated polyester resin solution that reinjects and prepare promotor and solidifying agent, injection rate is advisable to surpass the above 0.5-4 of Yuhua stone highest face temperature centimetre.
5, solidify after the demoulding immediately, put into water temperature 50-100 ℃ water thermal treatment, make it completely solidified.
6, promptly get artwork of the present invention after polishing, polish, join base, trade mark packing.
Among the present invention, solidifying agent can be selected methylethyl ketone peroxide for use.Promotor can be selected cobalt octoate or naphthoic acid cobalt (these several industrial chemicals all have sale on market) for use.The inventive method can satisfy the needs of production to temperature and humidity under physical environment.But the dosage of different solidifying agent that add of envrionment temperature and promotor is different.Of the present invention manufacturing should be carried out under the non-dusting environment of cleaning, when single products weight restrains more than or equal to 150, for avoiding bubble, increases transparency, and preferably adopts the dustless production environment of vacuum.Evenly mix and stir if bottom adds the chemical color of doses in the unsaturated polyester resin solution when needing color, and can after putting into literal or ornament earlier on this bottom, reinject approximately can submergence Yuhua stone 1/2-4/5, prepare the unsaturated polyester resin solution of promotor and solidifying agent.
The present invention optimizes technology, operation and adjustment proportioning by under different temperature condition, has solved this difficult problem that can not show U.S. of Yuhua stone when the unsaturated polyester resin is made rain flower pebble handicraft.View and admire inconvenient by the present invention except having overcome Yuhua stone, carry the shortcoming of primary such as inconvenience, low level, the appreciation effect that makes Yuhua stone near or surpassed traditional being placed on outside the effect of viewing and admiring in the water, more increased the multi-level sight of Yuhua stone, developed the practical value of Yuhua stone, the artistic appeal of Yuhua stone has greatly distilled, thereby can promote the commercial value of Yuhua stone to be achieved early, make Yuhua stone as the further exploitation of the characteristic tourism resource in Nanjing, utilize, develop into possibility.Nanjing is called " Stone City ", Yuhua stone is as the jewellery in Nanjing, has infinite charm, enjoy people to praise highly over the past thousands of years, Neolithic period, northern negative and positive people from battalion found Yuhua stone, and with as jewelry, the collection of sacrificing one's life for (existing) in Nanjing Museum, the reward stone in Song Yuan period, opinion stone are enjoyed great reputation Yuhua stone, and the upsurge of Yuhua stone and the culture of research Yuhua stone has appearred collecting for the first time in history in the Ming Dynasty.The Qing Dynasty Dream of the Red Mansion (stone note), " The Scholars ", " peach blossom fan " etc. have occurred and has had the highly Yuhua stone culture of art achievements, after the foundation, especially after the reform and opening-up, upsurge one wave of collection Yuhua stone exceeds a wave, and especially Yuhua stone is subjected to many people's love as the combination of a kind of natural culture and history culture.And this invention of Yuhua stone being implanted unsaturated polyester resin (polyester resin), solve Yuhua stone and be difficult to the further puzzlement of exploitation development, solve the puzzlement Yuhua stone and viewed and admired an inconvenient difficult problem over thousands of years, solve Yuhua stone and can only play a difficult problem that does not have practical value, this invention will make this rarity of Yuhua stone view and admire, field such as practicality, tourism, art yields unusually brilliant results, and will start the unprecedented new situation of Yuhua stone.
Embodiment 1:
1, envrionment temperature-21 ℃, physical environment humidity, a normal atmosphere.
(1) get one piece or many pieces of Yuhua stone and soaked four hours with 10% dilute hydrochloric acid, it is dirty to remove the surface rust.
(2) profile being omited polishing is trimmed to: color, picture, profile optimum regime (when need referring to).
(3) soaked 24 hours with clear water, changed water once in per 12 hours.
(4) it is standby to dry Yuhua stone.
2, unsaturated polyester resin solution is prepared
Get 300 gram unsaturated polyester resin solution and add 2.7 gram cobalt octoate promotor.
3, envrionment conditions and mould are prepared
Under no dust atmosphere, artwork profile, make mould with plastics or silicon rubber according to design, lie on the worktable standby.
4, cast (1) is got unsaturated polyester resin solution that 60 grams have added promotor and is added white chemical color and evenly stir.(2) after adding 0.52 gram methylethyl ketone peroxide solidifying agent evenly stirs, inject among the off-the-shelf mould.(3) solidify fully after, put into ornaments such as stone name, get unsaturated polyester resin solution 20 gram that has added promotor again, add 0.17 gram solidifying agent and evenly stir the back and inject.(4) standby Yuhua stone is implanted, requirement can be showed best picture.(5) solidify when reaching 8-9 and becoming, get the unsaturated polyester resin solution that 200 grams have prepared promotor again, add 1.6 gram solidifying agent and evenly stir to inject and reach Yuhua stone more than the highest 1.2 centimetres.(6) solidify after the demoulding immediately.(7) put into 80 ℃ water thermal treatment 2 hours.(8) polishing.(9) polishing.(10) join the base trade mark, packing gets product.
Embodiment 2:
1, envrionment temperature is 36 ℃, the humidity under the physical environment, 0.8 normal atmosphere.
(1) get one piece or many pieces of Yuhua stone and soaked three hours with 16% dilute sulphuric acid, it is dirty to remove the surface rust.
(2) profile being omited polishing is trimmed to: color, picture, profile optimum regime (when need referring to).
(3) soaked 48 hours with clear water, changed water one time, changed water once in back 24 hours per 12 hours in preceding 24 hours per 8 hours.
(4) it is standby to dry Yuhua stone.
2, unsaturated polyester resin solution is prepared
Get 500 gram unsaturated polyester resin solution, add 0.45 gram naphthoic acid brill promotor and evenly stir standby.
3, envrionment conditions and mould are prepared (with embodiment 1)
4, cast
(1) gets the unsaturated polyester resin solution that 60 grams prepare, add 0.03 gram methylethyl ketone peroxide solidifying agent and evenly stir, inject among the mould.
(2) degree of solidifying reaches ornaments such as putting into the stone name behind the 70-80%, gets unsaturated polyester resin solution 20 grams that prepare again, adds 0.01 gram solidifying agent and evenly stirs injection.
(3) standby Yuhua stone is implanted.
(4) solidify to reach and get the unsaturated polyester resin solution that 250 grams prepare when 6-7 becomes, add 0.13 gram solidifying agent and evenly stir to inject and reach Yuhua stone more than the highest 1.5 centimetres.
(5) solidify after the demoulding immediately.
(6) put into 50 ℃ water thermal treatment 30 minutes.
(7) polishing, polishing.
(8) join base, trade mark, packing gets final product.
Embodiment 3:
1, envrionment temperature is 0 ℃, physical environment humidity, 1 normal atmosphere
(1) get one piece or many pieces of Yuhua stone and soaked two hours with 25% dilute hydrochloric acid, it is dirty to remove the surface rust.
(2) profile being omited polishing is trimmed to: color, picture, profile optimum regime (when need referring to).
(3) soaked 48 hours with clear water, changed water one time, changed water once in back 24 hours per 12 hours in preceding 24 hours per 6 hours.
(4) it is standby to dry Yuhua stone.
2, get 500 gram unsaturated polyester resin solution, add 3.8 gram naphthoic acid cobalt promotor and evenly stir standby.
3, envrionment conditions and mould are prepared (with embodiment 1)
4, cast (1) is got 60 grams and has been prepared standby unsaturated polyester resin solution, and the chemical color that adds design color evenly stirs.(2) getting 0.41 gram solidifying agent adding evenly injects among the off-the-shelf mould stirring back.(3) put into ornaments such as stone name after degree of solidifying reaches 90%, get unsaturated polyester resin solution 20 grams of having got ready again, add 0.13 gram solidifying agent and evenly stir the back injection.(4) Yuhua stone of getting ready is implanted.(5) solidify to reach and get the standby unsaturated polyester resin solution that 250 grams have prepared when 6-7 becomes again, add 1.63 gram solidifying agent and evenly stir, inject and reach Yuhua stone more than the highest 1.5 centimetres, put into vacuum chamber and vacuumize and allow its curing under the condition.(6) demoulding (7) thermal treatment: the product after will solidifying is put into 70 ℃ water 50 minutes.(8) polishing.(9) polishing.(10) join base, trade mark, packing.
Embodiment 4:
1, envrionment temperature is 20 ℃, physical environment humidity, 1 normal atmosphere
(1) get one piece or many pieces of Yuhua stone and soaked two hours with 20% dilute hydrochloric acid, it is dirty to remove the surface rust.
(2) profile being omited polishing is trimmed to: color, picture, profile optimum regime (when need referring to).
(3) soaked 48 hours with clear water, changed water one time, changed water once in back 24 hours per 12 hours in preceding 24 hours per 6 hours.
(4) it is standby to dry Yuhua stone.
2, unsaturated polyester resin solution is prepared
Get 500 gram unsaturated polyester resin solution, add 2.65 gram cobalt octoate promotor and evenly stir
The back is standby.
3, envrionment conditions and mould are prepared (with embodiment 1)
4, cast
(1) gets 60 grams and prepare standby unsaturated polyester resin solution, add the chemical industry of design background color
After pigment evenly stirs, add again and annotate after 0.24 gram methylethyl ketone peroxide solidifying agent stirs
Go among the mould.
(2) degree of solidifying is put into ornaments such as stone name after reaching 80-90%, gets the unsaturated polyester for preparing again
Resin solution 20 grams add 0.08 gram solidifying agent and evenly stir back injection mould.
(3) standby Yuhua stone is implanted.
(4) solidify to reach and get the unsaturated polyester resin solution that 250 grams have prepared when 5-6 becomes again, add
Go into 1.00 gram solidifying agent and evenly stir the back and inject, reach Yuhua stone more than the highest 1.2 lis
Putting into vacuum chamber after the rice vacuumizes.
Remaining step is with embodiment 3.
Claims (8)
1, a kind of making method of handiwork of yuhua pebbles and polyester resin is characterized in that:
A. selected Yuhua stone is soaked with the rare strong acid of 8-26%, remove surperficial rusty stain and dirty, to some profiles not just or have the natural Yuhua stone of obvious flaw to cut, polish, make the profile of Yuhua stone and picture reach best effect; Soak with clear water then, and change water at least once, make the Yuhua stone appearance reach complete cleaning, it is standby to dry Yuhua stone;
B, get mixed stirring of unsaturated polyester resin, solidifying agent, promotor gradation and make unsaturated polyester resin solution, the weight permillage of its each composition is:
Vibrin 980-999 ‰
Solidifying agent 0.5-9 ‰
Promotor 0.8-9 ‰
During making, earlier unsaturated polyester resin and solidifying agent (or promotor) are made solution, add promotor (or solidifying agent) during to cast again; And cast should be carried out several times.
C, according to the configuration design requirement, adopt soft plastics or silicon rubber or other conveniently stripped non-leakage again material to make mould;
D, get and a certain amount ofly added the solidifying agent (or promotor) that promotor (or solidifying agent) unsaturated polyester resin solution adds doses more and evenly stir, inject among the mould, promptly form the bottom of artwork of the present invention after solidifying; On this bottom, reinject can submergence Yuhua stone 1/2-4/5, prepare the unsaturated polyester resin solution of promotor and solidifying agent, in this solution, implant the aforementioned Yuhua stone of having handled well rapidly and make it to show best picture, when the degree of solidifying of the unsaturated polyester resin solution of this submergence Yuhua stone reaches 50-80%, the unsaturated polyester resin solution that reinjects and prepare promotor and solidifying agent, injection rate is advisable to surpass the above 0.5-4 of Yuhua stone highest face temperature centimetre;
E, solidify after the demoulding immediately, put into water temperature 50-100 ℃ water thermal treatment, make it completely solidified;
F, polishing, promptly get artwork of the present invention after polishing, join base, trade mark packing.
2,, it is characterized in that described solidifying agent selects methylethyl ketone peroxide for use, described promotor or select cobalt octoate for use or naphthoic acid cobalt by the making method of the described a kind of handiwork of yuhua pebbles and polyester resin of claim 1.
3, press the making method of the described a kind of handiwork of yuhua pebbles and polyester resin of claim 1, it is characterized in that manufacturing and under the non-dusting environment of cleaning, to carry out, when single products weight restrains more than or equal to 150, adopt the dustless production environment of vacuum.
4, press the making method of the described a kind of handiwork of yuhua pebbles and polyester resin of claim 1, it is characterized in that if bottom is when needing color, the chemical color of doses added in the unsaturated polyester resin solution evenly mixes and stirs, and after putting into literal or ornament earlier on this bottom, reinject approximately can submergence Yuhua stone 1/2-4/5, prepare the unsaturated polyester resin solution of promotor and solidifying agent.
5,, it is characterized in that soaking selected rare strong acid in a step adopts dilute hydrochloric acid or dilute sulphuric acid by the making method of the described a kind of handiwork of yuhua pebbles and polyester resin of claim 1.
6, by the making method of the described a kind of handiwork of yuhua pebbles and polyester resin of claim 1, it is characterized in that the water that changes in a step should be more than three times.
7, press the making method of the described a kind of handiwork of yuhua pebbles and polyester resin of claim 1, it is characterized in that in the d step, get a certain amount of evenly stirring of solidifying agent (or promotor) that promotor (or solidifying agent) unsaturated polyester resin solution adds doses again of having added, inject among the mould, solidify then, its degree of solidifying is 80-90%.
8, by the making method of the described a kind of handiwork of yuhua pebbles and polyester resin of claim 1, it is characterized in that in the b step repeatedly Jiao Zhu number of times is 2-4 time.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011135913A CN1166739C (en) | 2001-04-30 | 2001-04-30 | Method for making handiwork of yuhua pebbles and polyester resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011135913A CN1166739C (en) | 2001-04-30 | 2001-04-30 | Method for making handiwork of yuhua pebbles and polyester resin |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1318591A true CN1318591A (en) | 2001-10-24 |
| CN1166739C CN1166739C (en) | 2004-09-15 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB011135913A Expired - Fee Related CN1166739C (en) | 2001-04-30 | 2001-04-30 | Method for making handiwork of yuhua pebbles and polyester resin |
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| Country | Link |
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| CN (1) | CN1166739C (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101973098A (en) * | 2010-09-16 | 2011-02-16 | 上海华特汽车配件有限公司 | Casting method for polyurethane product |
| CN103072416A (en) * | 2013-01-05 | 2013-05-01 | 重庆市九重山食品开发有限公司 | Artware and preparation method thereof |
| CN103070548A (en) * | 2013-01-05 | 2013-05-01 | 重庆市九重山食品开发有限公司 | Table and manufacture method thereof |
| CN103070563A (en) * | 2013-01-05 | 2013-05-01 | 重庆市九重山食品开发有限公司 | Chair and manufacture method thereof |
| CN103640398A (en) * | 2013-11-22 | 2014-03-19 | 陆军 | Transparent resin stereoscopic painting, special mould and manufacturing method |
| CN106957516A (en) * | 2016-01-10 | 2017-07-18 | 天津金衫易德塑料包装有限责任公司 | A kind of unsaturated polyester resin ornament art and craft making method |
| CN109017106A (en) * | 2018-09-29 | 2018-12-18 | 南昌航空大学 | A kind of stereolithography resin relief painting and preparation method thereof |
| CN110525105A (en) * | 2019-09-16 | 2019-12-03 | 韩东 | A kind of funeral and interment handicraft and preparation method |
| CN113942171A (en) * | 2021-10-15 | 2022-01-18 | 德化县齐禛陶瓷工艺有限公司 | Preparation method of high-cycle recycled resin artware |
-
2001
- 2001-04-30 CN CNB011135913A patent/CN1166739C/en not_active Expired - Fee Related
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101973098A (en) * | 2010-09-16 | 2011-02-16 | 上海华特汽车配件有限公司 | Casting method for polyurethane product |
| CN103070563B (en) * | 2013-01-05 | 2015-07-22 | 重庆市九重山食品开发有限公司 | Chair and manufacture method thereof |
| CN103070548A (en) * | 2013-01-05 | 2013-05-01 | 重庆市九重山食品开发有限公司 | Table and manufacture method thereof |
| CN103070563A (en) * | 2013-01-05 | 2013-05-01 | 重庆市九重山食品开发有限公司 | Chair and manufacture method thereof |
| CN103070548B (en) * | 2013-01-05 | 2015-06-17 | 重庆市九重山食品开发有限公司 | Table and manufacture method thereof |
| CN103072416A (en) * | 2013-01-05 | 2013-05-01 | 重庆市九重山食品开发有限公司 | Artware and preparation method thereof |
| CN103072416B (en) * | 2013-01-05 | 2015-08-19 | 重庆市九重山食品开发有限公司 | A kind of handicraft and preparation method thereof |
| CN103640398A (en) * | 2013-11-22 | 2014-03-19 | 陆军 | Transparent resin stereoscopic painting, special mould and manufacturing method |
| CN103640398B (en) * | 2013-11-22 | 2016-03-30 | 陆军 | Transparent resin relief painting, particular manufacturing craft and manufacture method |
| CN106957516A (en) * | 2016-01-10 | 2017-07-18 | 天津金衫易德塑料包装有限责任公司 | A kind of unsaturated polyester resin ornament art and craft making method |
| CN109017106A (en) * | 2018-09-29 | 2018-12-18 | 南昌航空大学 | A kind of stereolithography resin relief painting and preparation method thereof |
| CN110525105A (en) * | 2019-09-16 | 2019-12-03 | 韩东 | A kind of funeral and interment handicraft and preparation method |
| CN113942171A (en) * | 2021-10-15 | 2022-01-18 | 德化县齐禛陶瓷工艺有限公司 | Preparation method of high-cycle recycled resin artware |
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|---|---|
| CN1166739C (en) | 2004-09-15 |
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