CN1304913A - Process for synthesizing hydrocarbon from syntehtic gas - Google Patents
Process for synthesizing hydrocarbon from syntehtic gas Download PDFInfo
- Publication number
- CN1304913A CN1304913A CN 00121013 CN00121013A CN1304913A CN 1304913 A CN1304913 A CN 1304913A CN 00121013 CN00121013 CN 00121013 CN 00121013 A CN00121013 A CN 00121013A CN 1304913 A CN1304913 A CN 1304913A
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- Prior art keywords
- gas
- hydrocarbon
- synthetic
- synthetic gas
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- 239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 99
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 93
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 93
- 238000000034 method Methods 0.000 title description 18
- 230000008569 process Effects 0.000 title description 14
- 230000002194 synthesizing effect Effects 0.000 title 1
- 239000007789 gas Substances 0.000 claims abstract description 174
- 238000006243 chemical reaction Methods 0.000 claims abstract description 50
- 239000003054 catalyst Substances 0.000 claims abstract description 32
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 20
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 claims abstract description 12
- 239000001301 oxygen Substances 0.000 claims abstract description 12
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 12
- 239000003570 air Substances 0.000 claims abstract description 10
- 238000000926 separation method Methods 0.000 claims abstract 2
- 238000003786 synthesis reaction Methods 0.000 claims description 57
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 48
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 48
- 229910052739 hydrogen Inorganic materials 0.000 claims description 30
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 28
- 230000015572 biosynthetic process Effects 0.000 claims description 25
- 239000001257 hydrogen Substances 0.000 claims description 24
- 229910052757 nitrogen Inorganic materials 0.000 claims description 24
- 238000010790 dilution Methods 0.000 claims description 23
- 239000012895 dilution Substances 0.000 claims description 23
- 238000002360 preparation method Methods 0.000 claims description 23
- 239000007788 liquid Substances 0.000 claims description 20
- 238000001816 cooling Methods 0.000 claims description 19
- 238000004821 distillation Methods 0.000 claims description 19
- 239000008246 gaseous mixture Substances 0.000 claims description 15
- 229910052799 carbon Inorganic materials 0.000 claims description 14
- 239000003345 natural gas Substances 0.000 claims description 14
- 238000010521 absorption reaction Methods 0.000 claims description 13
- 239000002283 diesel fuel Substances 0.000 claims description 13
- 239000000571 coke Substances 0.000 claims description 12
- 239000007787 solid Substances 0.000 claims description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 11
- 230000009466 transformation Effects 0.000 claims description 11
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 10
- 239000003245 coal Substances 0.000 claims description 9
- 239000003350 kerosene Substances 0.000 claims description 9
- 239000003208 petroleum Substances 0.000 claims description 9
- 229910017052 cobalt Inorganic materials 0.000 claims description 8
- 239000010941 cobalt Substances 0.000 claims description 8
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 8
- 235000009508 confectionery Nutrition 0.000 claims description 8
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 7
- 239000002199 base oil Substances 0.000 claims description 7
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 7
- 230000000694 effects Effects 0.000 claims description 7
- 235000013305 food Nutrition 0.000 claims description 7
- 238000002309 gasification Methods 0.000 claims description 7
- 239000000314 lubricant Substances 0.000 claims description 7
- 150000002815 nickel Chemical class 0.000 claims description 7
- 230000003647 oxidation Effects 0.000 claims description 7
- 238000007254 oxidation reaction Methods 0.000 claims description 7
- 235000011089 carbon dioxide Nutrition 0.000 claims description 6
- 239000002808 molecular sieve Substances 0.000 claims description 6
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 6
- 150000002431 hydrogen Chemical class 0.000 claims description 5
- 238000012545 processing Methods 0.000 claims description 5
- 239000002594 sorbent Substances 0.000 claims description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- 230000009471 action Effects 0.000 claims description 3
- 238000007701 flash-distillation Methods 0.000 claims description 2
- 239000000203 mixture Substances 0.000 abstract description 11
- 238000001179 sorption measurement Methods 0.000 abstract description 10
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract description 7
- 238000005292 vacuum distillation Methods 0.000 description 11
- 238000005516 engineering process Methods 0.000 description 10
- 238000009835 boiling Methods 0.000 description 9
- 229910004298 SiO 2 Inorganic materials 0.000 description 8
- 239000000376 reactant Substances 0.000 description 8
- 239000004964 aerogel Substances 0.000 description 7
- 238000005194 fractionation Methods 0.000 description 6
- 230000008676 import Effects 0.000 description 5
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 239000003599 detergent Substances 0.000 description 4
- 239000000446 fuel Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000000746 purification Methods 0.000 description 4
- 238000011160 research Methods 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000002453 autothermal reforming Methods 0.000 description 2
- FFBHFFJDDLITSX-UHFFFAOYSA-N benzyl N-[2-hydroxy-4-(3-oxomorpholin-4-yl)phenyl]carbamate Chemical compound OC1=C(NC(=O)OCC2=CC=CC=C2)C=CC(=C1)N1CCOCC1=O FFBHFFJDDLITSX-UHFFFAOYSA-N 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 230000006837 decompression Effects 0.000 description 2
- 238000006477 desulfuration reaction Methods 0.000 description 2
- 230000023556 desulfurization Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000004005 microsphere Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 238000007084 catalytic combustion reaction Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000004517 catalytic hydrocracking Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000003009 desulfurizing effect Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 210000000952 spleen Anatomy 0.000 description 1
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Abstract
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Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB001210130A CN1167650C (en) | 2000-07-17 | 2000-07-17 | Process for synthesizing hydrocarbon from syntehtic gas |
Applications Claiming Priority (1)
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CNB001210130A CN1167650C (en) | 2000-07-17 | 2000-07-17 | Process for synthesizing hydrocarbon from syntehtic gas |
Publications (2)
Publication Number | Publication Date |
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CN1304913A true CN1304913A (en) | 2001-07-25 |
CN1167650C CN1167650C (en) | 2004-09-22 |
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CNB001210130A Expired - Lifetime CN1167650C (en) | 2000-07-17 | 2000-07-17 | Process for synthesizing hydrocarbon from syntehtic gas |
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Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1948438B (en) * | 2006-10-08 | 2010-06-30 | 神华集团有限责任公司 | Two stage Fischer-Tropsch synthesis method |
CN101979468A (en) * | 2010-11-11 | 2011-02-23 | 中国科学院山西煤炭化学研究所 | Low-carbon emission Fischer-Tropsch synthesis reaction process |
CN101559320B (en) * | 2009-04-15 | 2011-09-28 | 惠生工程(中国)有限公司 | Separation method of Fischer-Tropsch synthesis gas by combining rectification and solvent absorption |
CN102325859A (en) * | 2009-02-27 | 2012-01-18 | 日本石油天然气·金属矿物资源机构 | Method for purifying hydrocarbon compound and apparatus for separating hydrocarbon compound by distillation |
CN101372626B (en) * | 2008-09-28 | 2012-06-13 | 陕西金巢能源化工技术有限公司 | Method for producing clean fuel oil and high-purity chemical products from coal bed gas |
CN101186550B (en) * | 2006-11-16 | 2012-09-12 | 中国石油化工股份有限公司 | Fischer-Tropsch synthesis method for increasing liquid hydrocarbon selectivity |
CN102703107A (en) * | 2012-06-26 | 2012-10-03 | 武汉凯迪工程技术研究总院有限公司 | Method for manufacturing liquid hydrocarbon product with synthetic gas produced by biomass |
CN101538205B (en) * | 2008-03-17 | 2012-10-17 | 株洲珊林科技有限公司 | Process system and method for continuously preparing long chain alkyl dimethyl tertiary amine |
CN102858919A (en) * | 2010-03-30 | 2013-01-02 | 日本石油天然气·金属矿物资源机构 | Process for producing hydrocarbons |
CN101970344B (en) * | 2008-03-14 | 2013-01-23 | 独立行政法人石油天然气·金属矿物资源机构 | Process for producing liquid hydrocarbons from natural gas |
CN101735872B (en) * | 2008-11-12 | 2013-01-30 | 中科合成油技术有限公司 | Non-steady state reactor and method for producing synthesis gas |
WO2014000502A1 (en) * | 2012-06-26 | 2014-01-03 | 武汉凯迪工程技术研究总院有限公司 | Method for fischer-tropsch synthesis and for utilizing exhaust |
WO2014012458A1 (en) | 2012-07-17 | 2014-01-23 | 武汉凯迪工程技术研究总院有限公司 | Process for comprehensively utilizing low carbon emission fischer-tropsch synthesis tail gas |
CN105542832A (en) * | 2015-12-15 | 2016-05-04 | 七台河宝泰隆煤化工股份有限公司 | Method for making light hydrocarbons from coke |
CN110368983A (en) * | 2018-04-13 | 2019-10-25 | 株式会社模范 | A kind of preparation method of synthesis gas synthesis aviation kerosine catalyst and thus obtained catalyst and its application |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1297523C (en) * | 2005-04-01 | 2007-01-31 | 上海兖矿能源科技研发有限公司 | Method for treating water reacted from Fischer-Tropsch synthesis |
-
2000
- 2000-07-17 CN CNB001210130A patent/CN1167650C/en not_active Expired - Lifetime
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1948438B (en) * | 2006-10-08 | 2010-06-30 | 神华集团有限责任公司 | Two stage Fischer-Tropsch synthesis method |
CN101186550B (en) * | 2006-11-16 | 2012-09-12 | 中国石油化工股份有限公司 | Fischer-Tropsch synthesis method for increasing liquid hydrocarbon selectivity |
CN101970344B (en) * | 2008-03-14 | 2013-01-23 | 独立行政法人石油天然气·金属矿物资源机构 | Process for producing liquid hydrocarbons from natural gas |
CN101538205B (en) * | 2008-03-17 | 2012-10-17 | 株洲珊林科技有限公司 | Process system and method for continuously preparing long chain alkyl dimethyl tertiary amine |
CN101372626B (en) * | 2008-09-28 | 2012-06-13 | 陕西金巢能源化工技术有限公司 | Method for producing clean fuel oil and high-purity chemical products from coal bed gas |
CN101735872B (en) * | 2008-11-12 | 2013-01-30 | 中科合成油技术有限公司 | Non-steady state reactor and method for producing synthesis gas |
CN102325859A (en) * | 2009-02-27 | 2012-01-18 | 日本石油天然气·金属矿物资源机构 | Method for purifying hydrocarbon compound and apparatus for separating hydrocarbon compound by distillation |
CN101559320B (en) * | 2009-04-15 | 2011-09-28 | 惠生工程(中国)有限公司 | Separation method of Fischer-Tropsch synthesis gas by combining rectification and solvent absorption |
US8722748B2 (en) | 2010-03-30 | 2014-05-13 | Japan Oil, Gas And Metals National Corporation | Process for producing hydrocarbons |
CN102858919A (en) * | 2010-03-30 | 2013-01-02 | 日本石油天然气·金属矿物资源机构 | Process for producing hydrocarbons |
CN102858919B (en) * | 2010-03-30 | 2015-01-28 | 日本石油天然气·金属矿物资源机构 | Process for producing hydrocarbons |
CN101979468A (en) * | 2010-11-11 | 2011-02-23 | 中国科学院山西煤炭化学研究所 | Low-carbon emission Fischer-Tropsch synthesis reaction process |
US20150099813A1 (en) * | 2012-06-26 | 2015-04-09 | Wuhan Kaidi Engineering Technology Research Institute Co., Ltd. | Method for improving fischer-tropsch synthesis and recycling exhaust gases therefrom |
WO2014000502A1 (en) * | 2012-06-26 | 2014-01-03 | 武汉凯迪工程技术研究总院有限公司 | Method for fischer-tropsch synthesis and for utilizing exhaust |
CN102703107A (en) * | 2012-06-26 | 2012-10-03 | 武汉凯迪工程技术研究总院有限公司 | Method for manufacturing liquid hydrocarbon product with synthetic gas produced by biomass |
US9255226B2 (en) * | 2012-06-26 | 2016-02-09 | Wuhan Kaidi Engineering Technology Research Institute Co., Ltd. | Method for improving Fischer-Tropsch synthesis and recycling exhaust gases therefrom |
RU2594723C2 (en) * | 2012-06-26 | 2016-08-20 | Ухань Кайди Инджиниринг Текнолоджи Рисерч Инститьют Ко., Лтд. | Method of fischer-tropsch synthesis and application of exhaust gases |
WO2014012458A1 (en) | 2012-07-17 | 2014-01-23 | 武汉凯迪工程技术研究总院有限公司 | Process for comprehensively utilizing low carbon emission fischer-tropsch synthesis tail gas |
CN105542832A (en) * | 2015-12-15 | 2016-05-04 | 七台河宝泰隆煤化工股份有限公司 | Method for making light hydrocarbons from coke |
CN105542832B (en) * | 2015-12-15 | 2017-08-11 | 七台河宝泰隆煤化工股份有限公司 | A kind of method of coke lighter hydrocarbons |
CN110368983A (en) * | 2018-04-13 | 2019-10-25 | 株式会社模范 | A kind of preparation method of synthesis gas synthesis aviation kerosine catalyst and thus obtained catalyst and its application |
Also Published As
Publication number | Publication date |
---|---|
CN1167650C (en) | 2004-09-22 |
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Legal Events
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Owner name: ZHONGKE SYNTHETIC OIL TECHNOLOGY CO., LTD., DISTR Free format text: FORMER OWNER: SHANXI INST. OF COAL CHEMISTRY, CHINESE ACADEMY OF SCIENCES Effective date: 20070119 |
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Effective date of registration: 20070119 Address after: 030006, Taiyuan hi tech Zone, Shanxi, South Central Cyberport, port 4, 2, A and B Patentee after: Zhongke Synthetic Oil Technology Co., Ltd. Address before: 165 mailbox 030001, Shanxi City, Taiyuan Province Patentee before: Shanxi Institute of Coal Chemistry, Chinese Academy of Sciences |
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C56 | Change in the name or address of the patentee | ||
CP02 | Change in the address of a patent holder |
Address after: 101407 Beijing city Huairou District Yanqi Economic Development Zone C District No. 1 south two Street Park Patentee after: Zhongke Synthetic Oil Technology Co., Ltd. Address before: 030006, Taiyuan hi tech Zone, Shanxi, South Central Cyberport, port 4, 2, A and B Patentee before: Zhongke Synthetic Oil Technology Co., Ltd. |
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CX01 | Expiry of patent term |
Granted publication date: 20040922 |
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CX01 | Expiry of patent term |