CN1299889A - Additive material for preparing efficient nanometer negative-oxygen ion health fiber - Google Patents

Additive material for preparing efficient nanometer negative-oxygen ion health fiber Download PDF

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Publication number
CN1299889A
CN1299889A CN 00136520 CN00136520A CN1299889A CN 1299889 A CN1299889 A CN 1299889A CN 00136520 CN00136520 CN 00136520 CN 00136520 A CN00136520 A CN 00136520A CN 1299889 A CN1299889 A CN 1299889A
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China
Prior art keywords
oxygen ion
negative
ion health
health fiber
nanometer negative
Prior art date
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Pending
Application number
CN 00136520
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Chinese (zh)
Inventor
王华平
张玉梅
王彪
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Donghua University
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Donghua University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Donghua University filed Critical Donghua University
Priority to CN 00136520 priority Critical patent/CN1299889A/en
Publication of CN1299889A publication Critical patent/CN1299889A/en
Pending legal-status Critical Current

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Abstract

The present invention discloses an additive material for preparing high-effective nanometer negative oxygen ion health-care fibres, which is characterized by that the nanometer-level inorganic particles can be made into mother particles by means of special slicing process, and said nanometer-level inorganic particles include the following ingredients: tourmaline 10-30, TiO2 10-25%, ZnO 1-11% and rare earth complex 1-12%. The health-care fibres prepared with said additive material can clean air, eliminate indoor obnormal smell and various harmful gases, and possess health-care function.

Description

A kind ofly prepare the interpolation material that efficient nanometer negative-oxygen ion health fiber is used
The present invention relates to a kind of interpolation material that efficient nanometer negative-oxygen ion health fiber is used for preparing.
Along with the raising day by day of Human's production activity, particularly industrialization degree, the pollution of air is also more and more serious.People are thirsting for graceful environment, so various environment-friendly materials, functional material arise at the historic moment.The negative-oxygen ion health fiber of Chu Xianing is paid close attention to by common people with its particular performances in recent years.
Mainly there is following problem in Kai Fa negative-ion fiber in the market:
1. negative oxygen ion fiber only just can make air generation ionization under piezo-electric effect or uniform temperature, produces negative oxygen ion.Do not having under the friction situation, the incidence of negative oxygen ion is very low.
2. the concentration of every cubic centimetre negative oxygen ion is low under Frotteurism, generally all less than 2000/cm 3
3. spinning technique is immature, and the row yielding of product is very low.
4. particle active low in the prescription of inorganic particle, bad dispersibility.
The objective of the invention is: a kind of interpolation material that efficient nanometer negative-oxygen ion health fiber is used for preparing is provided, can purifies air, eliminate foreign flavor indoors and various pernicious gas with the negative-oxygen ion health fiber of this material preparation, and with health role.
Technical scheme of the present invention is: a kind ofly prepare the interpolation material that efficient nanometer negative-oxygen ion health fiber is used, comprise the nano grade inorganic particle, the Main Ingredients and Appearance of nano grade inorganic particle is:
Tourmaline 10--30%
TiO 2 10--25%
ZnO 1--11%
Rare-earth complex 1--12%.
The further technical scheme of the present invention is: a kind ofly prepare the interpolation material that efficient nanometer negative-oxygen ion health fiber is used, comprise the nano grade inorganic particle, the Main Ingredients and Appearance of nano grade inorganic particle is:
Tourmaline 10--30%
TiO 2 10--25%
ZnO 1--11%
Rare-earth complex 1--12%
Dispersant 5--20%
Surfactant 2--15%.
The more detailed technical scheme of the present invention is:
Tourmaline 10--30%
TiO 2 10--25%
ZnO 1--11%
Rare-earth complex 1--12%
Dispersant 5--20%
Surfactant 2--15%
The average grain diameter of described nano grade inorganic particle is 15--80nm; The polymer or the polyester slice that add 70--50% in the nano inoganic particle of 30--50% carry out dry mixed, and make master batch; Described surfactant adopts alkylsulfonate; Described dispersant adopts one or more mixing in titanate ester, aluminate, laruate, hard acid ester salt, the silicate; The melt index of described polymer or polyester slice is 28--30.
Advantage of the present invention is:
Utilize the function and the health-care function of the negative-oxygen ion health fiber that the present invention prepares:
1. permanent negative aeroion generation function
The mechanism of gas molecule ionization in the air, main outer boundary ionizer is to the result of gas effect, and ionizer has ultraviolet ray, radioactive ray, photoelectric effect etc.The negative oxygen ion powder has pyroelectricity and piezoelectricity, therefore (even small variation) can cause the electrical potential difference between the anion crystal under the situation that has temperature and pressure to change, this static is up to 1,000,000 electron-volts, thereby make air generation ionization, the electron attachment of being hit is in contiguous water and oxygen molecule and make it be converted into negative aeroion, i.e. negative oxygen ion.
Negative-oxygen ion health fiber can discharge anion unvaryingly, and 1 square of negative ion health cloth is placed in the cubic meter closed container, and the 40--50 that records anion number and be the contrast sample doubly thereby has significance to environmental protection and health.
Suck an amount of anion every day, and health is had the barnyard grass benefit greatly, mainly shows:
(1) make human body full of vitality, allaying tiredness and burnout are increased work efficiency;
(2) improve sleep, eliminate neurasthenia;
(3) reduce disease incidence, preventing cold and breathing problem;
(4) improve the symptom of the heart, cranial vascular disease;
(5) prevention air conditioner disease;
(6) under the anion effect, can make the emerging increase fully of skeletal muscle, help to improve sports achievement;
(7) can reduce central nervous system disease behind the absorption of human body negative aeroion, quicken " thrombocytin " content of human senescence, therefore play anti-aging effects, people are " longevity in the atmosphere is plain " with the anion analogy.
2. stronger far-infrared transmitting function
The used interpolation material of the present invention is with tourmaline, TiO 2ZnO and other compound are the material of feature, because of its pyroelectricity and piezoelectricity, make its polarity ion cause that in the equilbrium position vibration dipole moment changes the electromagnetic radiation that produces the negative oxygen ion wave band, and the negative oxygen ion powder polar molecule of blending by a certain percentage can fully be penetrated in the lattice tissue of organic matter fiber, form uniform island structure with the nonpolar molecule group of fiber, free ion by negative oxygen ion powder self, impurity ion and ionic substance, impurity and two, three phonon sympathetic responses produce radiation, affect ionic bond polarity vibration organic and the inorganic molecule interlinkage, formed stronger radiation broadband, according to the test negative oxygen ion fiber to the emissivity of negative oxygen ion more than 82%.The anionic property of negative-oxygen ion health fiber mainly contains following three aspects to the health-care function of human body:
(1) negative oxygen ion can quicken the hydrone motion, makes light water become active water, and penetrability, extension, dissolving power, the metabolism power of water are strengthened, and produces the water conservation film.
(2) negative oxygen ion can play the expansion capillary for the circulatory system, strengthens blood circulation, enhances metabolism, and strengthens the effect of the circulation of lymph liquid.
(3) negative oxygen ion can make cell activation for cell tissue, makes old dead cell drainage or gives power of regeneration, can strengthen cellular energy, effects such as the function of enhancing cell and vigor.
(4) fabric in the automobile: automobile, especially car, the railway carriage of sealing is easy to become the hotbed that germ grows, and the also very mixed erosion of air in the car not only influences the healthy of people, more impel driver fatigue, traffic accident taking place, make fabric in the automobile with negative-oxygen ion health fiber, can eliminate peculiar smell in the automobile, purify air, regulate the holddown of the neural excitement of driver, improve the cerebral cortex function and keep the good state of mind.
(5) water treatment: the filtering material made from negative-oxygen ion health fiber is used for water dispenser and crosses filter core, can kill bacterium in the water, increase oxygen in water, make the bathroom towel or be used for the bathroom water treatment with strange ice mineral wool, can quicken the hydrone motion, make light water become active water, increase energy, remove human body dirt, allaying tiredness easily.
(6) water of handling with negative-oxygen ion health fiber is used for the training in indoor year of high-grade green plants, can improve the survival rate of plant, and shorten the maturity period, is sprayed onto the blade face of flowers, can make the freshness date of flowers prolong 50--100% doubly.
The invention will be further described below in conjunction with embodiment:
Embodiment: a kind ofly prepare the interpolation material that efficient nanometer negative-oxygen ion health fiber is used, adopting average grain diameter is the nano grade inorganic particle of 40nm, and concrete prescription is:
Tourmaline 28%
TiO 2 20%
ZnO 8%
Rare-earth complex 10%
Dispersant 20%
Surfactant 14%
Described surfactant adopts alkylsulfonate; Described dispersant adopts one or more mixing in titanate ester, aluminate, laruate, hard acid ester salt, the silicate.
With melt index is that the polymer of 28--30 or the nano grade inorganic particle of polyester slice+above-mentioned prescription carry out combination drying, carries out the twin-screw granulation again, is the interpolation material that efficient nanometer negative-oxygen ion health fiber of the present invention is used.
The negative-oxygen ion health fiber that utilizes the present invention to prepare has following purposes:
1. purify air
Aerial the moving of anion in the negative-oxygen ion health fiber is zigzag, and carries negative electrical charge to give bacterium, dust, smoke particles and water droplet etc., and electric charge slightly slightly combines glomeration with this and sinks, thereby reaches the purpose that purifies air.
2. eliminate foreign flavor indoors and various pernicious gas
The acid smell of leftovers meal in irritative gas such as the benzene that the decorative materials that uses in the interior decoration process evaporates, formaldehyde, ketone, ammonia and the daily life, the peculiar smell that cigarette etc. are harmful, make stranding cloth, curtain etc. with negative-oxygen ion health fiber, the negative aeroion of its release can both be eliminated effectively.
3. health-care function
The wallpaper of using through fabric such as clothes, sheet and the upholster of negative-oxygen ion health fiber processing, carpet etc. all have health care and environmental protection dual-use function.

Claims (7)

1. one kind prepares the interpolation material that efficient nanometer negative-oxygen ion health fiber is used, and comprises the nano grade inorganic particle, and the Main Ingredients and Appearance of nano grade inorganic particle is:
Tourmaline 10--30%
TiO 2 10--25%
ZnO 1--11%
Rare-earth complex 1--12%.
2. the interpolation material that preparation efficient nanometer negative-oxygen ion health fiber according to claim 1 is used is characterized in that: described nano grade inorganic particle also comprises:
Dispersant 5--20%
Surfactant 2--15%.
3. the interpolation material that preparation efficient nanometer negative-oxygen ion health fiber according to claim 1 and 2 is used is characterized in that: the average grain diameter of described nano grade inorganic particle is 15--80nm.
4. the interpolation material that preparation efficient nanometer negative-oxygen ion health fiber according to claim 1 and 2 is used is characterized in that: the polymer or the polyester slice that add 70--50% in the nano inoganic particle of 30--50% carry out dry mixed, and make master batch.
5. the interpolation material that preparation efficient nanometer negative-oxygen ion health fiber according to claim 2 is used is characterized in that: described surfactant adopts alkylsulfonate.
6. the interpolation material that preparation efficient nanometer negative-oxygen ion health fiber according to claim 2 is used is characterized in that: described dispersant adopts one or more mixing in titanate ester, aluminate, laruate, hard acid ester salt, the silicate.
7. the interpolation material that preparation efficient nanometer negative-oxygen ion health fiber according to claim 4 is used is characterized in that: the melt index of described polymer or polyester slice is 28--30.
CN 00136520 2000-12-27 2000-12-27 Additive material for preparing efficient nanometer negative-oxygen ion health fiber Pending CN1299889A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 00136520 CN1299889A (en) 2000-12-27 2000-12-27 Additive material for preparing efficient nanometer negative-oxygen ion health fiber

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 00136520 CN1299889A (en) 2000-12-27 2000-12-27 Additive material for preparing efficient nanometer negative-oxygen ion health fiber

Publications (1)

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CN1299889A true CN1299889A (en) 2001-06-20

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1299577C (en) * 2004-03-03 2007-02-14 中国科学院理化技术研究所 Microporous silicon dioxide-cladding tourmaline and titanium dioxide particle composition, its preparation and application
CN1299576C (en) * 2004-03-03 2007-02-14 中国科学院理化技术研究所 Slicon dioxide-cladding tourmaline and titanium dioxide particle composite antibacterial material, its preparation and application
CN1317041C (en) * 2004-10-26 2007-05-23 深圳市金士吉康复用品科技有限公司 Ultra-fine highly effective anion powder material and its preparation method
CN100351438C (en) * 2005-03-09 2007-11-28 丁宏广 Monofilament capable of emitting negative ion, its preparing method and use
CN100497767C (en) * 2005-05-18 2009-06-10 上海海欣集团股份有限公司 Process for preparing negative ion far infrared acrylic yarn
CN101922060A (en) * 2010-09-01 2010-12-22 青岛大学 Method for preparing rare earth fluorescence micro/nano fibers
CN102168367A (en) * 2011-02-23 2011-08-31 北京健热宝科技开发有限公司 Textile product with weight losing function and preparation method thereof
CN102560724A (en) * 2010-12-31 2012-07-11 上海德福伦化纤有限公司 Production method of inorganic nanometer light response type self-cleaning polyester fiber
CN105080220A (en) * 2015-09-09 2015-11-25 江苏创云环保科技有限公司 Air filter material as well as preparation method and application of air filter material
CN105951207A (en) * 2016-07-12 2016-09-21 苏州宇希新材料科技有限公司 Preparation method of far-infrared negative ion nanometer slurry
CN105951208A (en) * 2016-07-12 2016-09-21 苏州宇希新材料科技有限公司 Modified polyester fiber and preparation method thereof
CN106192059A (en) * 2016-07-12 2016-12-07 苏州宇希新材料科技有限公司 A kind of containing far infrared negative ion nano function slurry
CN106245127A (en) * 2016-08-03 2016-12-21 三德亿顺商贸(深圳)有限公司 A kind of natural nano-mineral stone powder functional fibre and a kind of functional heat energy cotton
CN111205488A (en) * 2020-03-12 2020-05-29 广东世童智能科技有限公司 Anion flame-retardant high-temperature-resistant nano-silicon modified antibacterial engineering plastic master batch

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1299576C (en) * 2004-03-03 2007-02-14 中国科学院理化技术研究所 Slicon dioxide-cladding tourmaline and titanium dioxide particle composite antibacterial material, its preparation and application
CN1299577C (en) * 2004-03-03 2007-02-14 中国科学院理化技术研究所 Microporous silicon dioxide-cladding tourmaline and titanium dioxide particle composition, its preparation and application
CN1317041C (en) * 2004-10-26 2007-05-23 深圳市金士吉康复用品科技有限公司 Ultra-fine highly effective anion powder material and its preparation method
CN100351438C (en) * 2005-03-09 2007-11-28 丁宏广 Monofilament capable of emitting negative ion, its preparing method and use
CN100497767C (en) * 2005-05-18 2009-06-10 上海海欣集团股份有限公司 Process for preparing negative ion far infrared acrylic yarn
CN101922060A (en) * 2010-09-01 2010-12-22 青岛大学 Method for preparing rare earth fluorescence micro/nano fibers
CN102560724A (en) * 2010-12-31 2012-07-11 上海德福伦化纤有限公司 Production method of inorganic nanometer light response type self-cleaning polyester fiber
CN102168367A (en) * 2011-02-23 2011-08-31 北京健热宝科技开发有限公司 Textile product with weight losing function and preparation method thereof
CN105080220A (en) * 2015-09-09 2015-11-25 江苏创云环保科技有限公司 Air filter material as well as preparation method and application of air filter material
CN105951207A (en) * 2016-07-12 2016-09-21 苏州宇希新材料科技有限公司 Preparation method of far-infrared negative ion nanometer slurry
CN105951208A (en) * 2016-07-12 2016-09-21 苏州宇希新材料科技有限公司 Modified polyester fiber and preparation method thereof
CN106192059A (en) * 2016-07-12 2016-12-07 苏州宇希新材料科技有限公司 A kind of containing far infrared negative ion nano function slurry
CN106245127A (en) * 2016-08-03 2016-12-21 三德亿顺商贸(深圳)有限公司 A kind of natural nano-mineral stone powder functional fibre and a kind of functional heat energy cotton
CN111205488A (en) * 2020-03-12 2020-05-29 广东世童智能科技有限公司 Anion flame-retardant high-temperature-resistant nano-silicon modified antibacterial engineering plastic master batch

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