CN118373474B - Wastewater treatment equipment for restoring agricultural contaminated soil and application method - Google Patents
Wastewater treatment equipment for restoring agricultural contaminated soil and application method Download PDFInfo
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- CN118373474B CN118373474B CN202410817382.0A CN202410817382A CN118373474B CN 118373474 B CN118373474 B CN 118373474B CN 202410817382 A CN202410817382 A CN 202410817382A CN 118373474 B CN118373474 B CN 118373474B
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- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/105—Phosphorus compounds
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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- C02F2201/002—Construction details of the apparatus
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Abstract
本发明提供了一种农业污染土壤修复用废水处理设备及使用方法,属于废水处理技术领域,包括含环形中空的外壳体,所述外壳体上设置有进液口和出液口;所述外壳体内转动有一导液环,所述导液环外壁上径向开设有多个分液槽,所述分液槽内滑动有一滑环,所述滑环内设置有固体除磷剂的存储结构。本发明通过外壳体和导液环的设置,将待处理的废水分散至各个分液槽内,流入分液槽内的含磷废水,在进入后和排出的过程中,实现含磷废水穿过固体除磷剂存放腔四次,从而实现分液槽内的含磷废水与固体除磷剂充分接触,从而有效去除废水中的磷。
The present invention provides a wastewater treatment device and a method of use for agricultural contaminated soil remediation, which belongs to the field of wastewater treatment technology, and includes an outer shell body with an annular hollow, the outer shell body is provided with a liquid inlet and a liquid outlet; a liquid guide ring rotates in the outer shell body, a plurality of liquid separation grooves are radially opened on the outer wall of the liquid guide ring, a slip ring slides in the liquid separation groove, and a storage structure of a solid phosphorus removal agent is provided in the slip ring. The present invention disperses the wastewater to be treated into each liquid separation groove through the arrangement of the outer shell body and the liquid guide ring, and the phosphorus-containing wastewater flowing into the liquid separation groove passes through the solid phosphorus removal agent storage chamber four times after entering and in the process of discharge, so that the phosphorus-containing wastewater in the liquid separation groove is fully in contact with the solid phosphorus removal agent, thereby effectively removing phosphorus in the wastewater.
Description
技术领域Technical Field
本发明涉及废水处理领域,具体而言,涉及一种农业污染土壤修复用废水处理设备及使用方法。The present invention relates to the field of wastewater treatment, and in particular to a wastewater treatment device for agricultural contaminated soil remediation and a use method thereof.
背景技术Background Art
现有技术中,对农业废水的处理至关重要,农业废水中含有农药,导致废水中含有高浓度的磷,而不控制废水的排放,导致废水中的磷大量流向土壤,进一步的导致土壤理化性质恶化,即过磷酸钙含有大量的游离酸,连续大量施用,会造成土壤酸化。钙镁磷肥含有石灰,大量施用会使土壤碱性加重和理化性质恶化。为此,治理土壤修复的建设中,控制农业废水排放的磷是重要一环,通过实验研究表明,固体除磷剂对治理农业废水的磷具有显著效果,其中固体除磷剂为现有技术,其由钛石膏、粉煤灰、城市污泥、硼砂混合均匀制得,然后成球、干燥、烧结,得到该固体除磷剂。但是现有技术缺少应用该固体除磷剂的设备,而直接将其泼洒到排放的废水中,导致两者不能充分反应,进一步的导致去除农业废水的磷的效果不明显。In the prior art, the treatment of agricultural wastewater is crucial. Agricultural wastewater contains pesticides, which leads to high concentrations of phosphorus in the wastewater. If the discharge of wastewater is not controlled, a large amount of phosphorus in the wastewater will flow to the soil, further leading to the deterioration of soil physical and chemical properties. That is, superphosphate contains a large amount of free acid. Continuous and large-scale application will cause soil acidification. Calcium magnesium phosphate fertilizer contains lime, and large-scale application will increase soil alkalinity and deteriorate physical and chemical properties. For this reason, in the construction of soil remediation, controlling the phosphorus discharged from agricultural wastewater is an important link. Experimental studies have shown that solid phosphorus removal agents have a significant effect on the treatment of phosphorus in agricultural wastewater. Among them, solid phosphorus removal agents are prior art, which are prepared by mixing titanium gypsum, fly ash, urban sludge, and borax, and then balling, drying, and sintering to obtain the solid phosphorus removal agent. However, the prior art lacks equipment for applying the solid phosphorus removal agent, and directly sprinkles it on the discharged wastewater, resulting in the inability of the two to fully react, further resulting in the effect of removing phosphorus from agricultural wastewater is not obvious.
为此,我们设计了一种农业污染土壤修复用废水处理设备及使用方法。To this end, we designed a wastewater treatment equipment and usage method for agricultural contaminated soil remediation.
发明内容Summary of the invention
为了弥补以上不足,本发明提供了一种农业污染土壤修复用废水处理设备及使用方法,旨在改善直接将固体除磷剂泼洒到排放的废水中,导致废水与固体除磷剂不能充分反应的问题。In order to make up for the above shortcomings, the present invention provides a wastewater treatment equipment and a method of use for agricultural contaminated soil remediation, aiming to improve the problem of directly sprinkling solid phosphorus removal agent into the discharged wastewater, resulting in insufficient reaction between the wastewater and the solid phosphorus removal agent.
本发明是这样实现的:The present invention is achieved in that:
本发明提供一种农业污染土壤修复用废水处理设备,包括含环形中空的外壳体,所述外壳体上设置有进液口和出液口;The present invention provides a wastewater treatment device for agricultural contaminated soil remediation, comprising an outer shell body with an annular hollow portion, wherein the outer shell body is provided with a liquid inlet and a liquid outlet;
所述外壳体内转动有一导液环,所述导液环外壁上径向开设有多个分液槽,所述分液槽内滑动有一滑环,所述滑环内设置有固体除磷剂的存储结构。A liquid guide ring is rotated in the outer shell, a plurality of liquid separation grooves are radially opened on the outer wall of the liquid guide ring, a slip ring slides in the liquid separation groove, and a storage structure of a solid dephosphorization agent is arranged in the slip ring.
优选的,所述进液口位于所述出液口的上方。Preferably, the liquid inlet is located above the liquid outlet.
优选的,所述导液环一端内壁固定有齿环,所述外壳体外壁固定有电机,所述电机的输出端贯穿外壳体并固定连接有驱动齿轮,所述驱动齿轮与所述齿环啮合。Preferably, a gear ring is fixed to the inner wall of one end of the liquid guide ring, a motor is fixed to the outer wall of the outer shell, an output end of the motor passes through the outer shell and is fixedly connected to a driving gear, and the driving gear is meshed with the gear ring.
优选的,所述固体除磷剂的存储结构包括:Preferably, the storage structure of the solid dephosphorization agent comprises:
下滤板,所述下滤板呈盘型设置于滑环的内壁;A lower filter plate, the lower filter plate is in a disc shape and is arranged on the inner wall of the slip ring;
上滤板,所述上滤板位于所述滑环的内壁,且位于所述下滤板的上方;An upper filter plate, the upper filter plate being located on the inner wall of the slip ring and above the lower filter plate;
所述下滤板和所述上滤板之间留有间隙,形成固体除磷剂存放腔。A gap is left between the lower filter plate and the upper filter plate to form a solid dephosphorization agent storage chamber.
优选的,所述上滤板包括等距设置有进料口的上盘体,所述进料口的下方设置有可转动的滤挡板,随所述滤挡板的转动控制所述进料口开启或闭合。Preferably, the upper filter plate comprises an upper disk body with feed ports equidistantly arranged, and a rotatable filter baffle is arranged below the feed ports, and the feed ports are controlled to be opened or closed as the filter baffle rotates.
优选的,所述滑环内设置有外延伸杆,所述外壳体内中心设置有中心柱,所述中心柱的外壁设置有外凸起A,且所述外延伸杆的内端抵触在所述中心柱外壁。Preferably, an outer extension rod is arranged inside the slip ring, a central column is arranged at the center of the outer shell, an outer protrusion A is arranged on the outer wall of the central column, and the inner end of the outer extension rod abuts against the outer wall of the central column.
优选的,所述外延伸杆外壁固定有连接座,所述连接座和所述导液环内壁之间通过复位弹簧连接。Preferably, a connecting seat is fixed to the outer wall of the outer extension rod, and the connecting seat and the inner wall of the liquid guide ring are connected via a return spring.
优选的,所述分液槽内壁径向转动有搅拌叶套筒,所述搅拌叶套筒套设于所述外延伸杆外壁,所述搅拌叶套筒外壁设置有多个搅拌叶;Preferably, a stirring blade sleeve is radially rotated on the inner wall of the liquid separation tank, the stirring blade sleeve is sleeved on the outer wall of the outer extension rod, and a plurality of stirring blades are arranged on the outer wall of the stirring blade sleeve;
所述外延伸杆外壁设置有外凸起,所述搅拌叶套筒内壁设置有呈螺旋状的内驱动滑槽;The outer wall of the outer extension rod is provided with an outer protrusion, and the inner wall of the stirring blade sleeve is provided with a spiral inner driving groove;
所述中心柱的外壁还设置有外凸起B。An outer protrusion B is also provided on the outer wall of the central column.
优选的,所述外延伸杆通过连接结构与所述滤挡板连接,所述连接结构包括与所述外延伸杆固定的下连接环,所述下连接环通过多根连接筋连接有上连接环,所述滤挡板外壁固定于所述上连接环内壁;Preferably, the outer extension rod is connected to the filter baffle plate via a connecting structure, the connecting structure comprises a lower connecting ring fixed to the outer extension rod, the lower connecting ring is connected to an upper connecting ring via a plurality of connecting ribs, and the outer wall of the filter baffle plate is fixed to the inner wall of the upper connecting ring;
所述外壳体内壁还固定有环状凸台,所述外延伸杆外壁固定有圆弧齿轮,所述环状凸台外壁设置有与所述圆弧齿轮啮合的啮合凸起;The inner wall of the outer shell is also fixed with an annular boss, the outer wall of the outer extension rod is fixed with an arc gear, and the outer wall of the annular boss is provided with an engaging protrusion that engages with the arc gear;
所述外壳体上还设置有固体除磷剂进料口。The outer shell is also provided with a solid dephosphorization agent feed port.
本发明还公开了一种农业污染土壤修复用废水处理设备的使用方法,其特征在于,包括以下步骤:The present invention also discloses a method for using a wastewater treatment device for agricultural contaminated soil remediation, which is characterized by comprising the following steps:
S1、含磷废水流入分液槽:含磷废水通过进液口流向分液槽内;S1. Phosphorus-containing wastewater flows into the liquid separation tank: Phosphorus-containing wastewater flows into the liquid separation tank through the liquid inlet;
S2、导液环转动:电机启动,通过驱动齿轮和齿环配合致使导液环转动,当分液槽脱离进液口后,致使分液槽与外壳体内壁形成闭合空间,致使含磷废水充分与固体除磷剂充分接触反应;该过程中,含磷废水穿过固体除磷剂存放腔,致使含磷废水与固体除磷剂第一次接触,从而去除含磷废水中的磷。S2. Liquid guide ring rotates: the motor starts, and the liquid guide ring rotates through the cooperation of the driving gear and the gear ring. When the liquid separation tank is separated from the liquid inlet, a closed space is formed between the liquid separation tank and the inner wall of the shell, so that the phosphorus-containing wastewater is fully contacted and reacted with the solid phosphorus removal agent. In this process, the phosphorus-containing wastewater passes through the solid phosphorus removal agent storage chamber, so that the phosphorus-containing wastewater is in contact with the solid phosphorus removal agent for the first time, thereby removing phosphorus in the phosphorus-containing wastewater.
S3、滑环内含磷废水流动:外延伸杆随导液环转动后,当外延伸杆抵触外凸起B后,实现外延伸杆相对导液环径向移动,在转动驱动凸起和内驱动滑槽的配合下,致使搅拌叶套筒转动,从而致使搅拌叶转动,进一步的制动滑环内溶解有固体除磷剂的含磷废水流动,使得固体除磷剂与含磷废水中的磷充分接触反应。S3. Flow of phosphorus-containing wastewater in the slip ring: After the outer extension rod rotates with the liquid guide ring, when the outer extension rod hits the outer protrusion B, the outer extension rod moves radially relative to the liquid guide ring, and with the cooperation of the rotating drive protrusion and the inner drive groove, the stirring blade sleeve rotates, thereby causing the stirring blade to rotate, further braking the flow of phosphorus-containing wastewater dissolved with solid phosphorus removal agent in the slip ring, so that the solid phosphorus removal agent fully contacts and reacts with the phosphorus in the phosphorus-containing wastewater.
S4、含磷废水第二次与固体除磷剂存放腔内的固体除磷剂接触:随导液环转动,当导液环转动至其一半以下位置时,含磷废水在重力作用下从滑环流向外壳体内壁,该过程中穿过固体除磷剂存放腔,致使含磷废水与固体除磷剂第二次接触;S4, the phosphorus-containing wastewater contacts the solid phosphorus removal agent in the solid phosphorus removal agent storage chamber for the second time: As the liquid guide ring rotates, when the liquid guide ring rotates to less than half of its position, the phosphorus-containing wastewater flows from the sliding ring to the inner wall of the housing under the action of gravity, and passes through the solid phosphorus removal agent storage chamber in the process, causing the phosphorus-containing wastewater to contact the solid phosphorus removal agent for the second time;
S5、含磷废水第三次与固体除磷剂存放腔内的固体除磷剂接触:随导液环转动,外延伸杆抵触外凸起A,致使滑环沿分液槽径向向外移动,从而致使滑环外端部挤压其外端的废水,被挤压的废水从固体除磷剂存放腔外端流向滑环内,实现含磷废水第三次与固体除磷剂存放腔内的固体除磷剂接触。S5. The phosphorus-containing wastewater contacts the solid phosphorus-removing agent in the solid phosphorus-removing agent storage chamber for the third time: as the liquid guide ring rotates, the outer extension rod contacts the outer protrusion A, causing the slip ring to move radially outward along the liquid separation groove, thereby causing the outer end of the slip ring to squeeze the wastewater at its outer end, and the squeezed wastewater flows from the outer end of the solid phosphorus-removing agent storage chamber to the inside of the slip ring, thereby achieving the third contact between the phosphorus-containing wastewater and the solid phosphorus-removing agent in the solid phosphorus-removing agent storage chamber.
S6、含磷废水第四次与固体除磷剂存放腔内的固体除磷剂接触,并完成下料:随导液环转动,转动至出液口上方时,分液槽内废水从穿过固体除磷剂存放腔后,从出液口流出,即分液槽内废水在完成下料时,也同步完成第四次与固体除磷剂存放腔内的固体除磷剂接触。S6. The phosphorus-containing wastewater contacts the solid phosphorus removal agent in the solid phosphorus removal agent storage chamber for the fourth time and completes the discharge: as the liquid guide ring rotates to above the liquid outlet, the wastewater in the liquid separation tank passes through the solid phosphorus removal agent storage chamber and flows out from the liquid outlet. That is, when the wastewater in the liquid separation tank completes the discharge, it also simultaneously completes the fourth contact with the solid phosphorus removal agent in the solid phosphorus removal agent storage chamber.
S7、固体除磷剂存放腔内的固体除磷剂补料:随导液环转动,转动至固体除磷剂进料口下方时,通过圆弧齿轮与啮合凸起的配合实现进料口打开,此时,方便固体除磷剂依次通过固体除磷剂进料口和进料口流向固体除磷剂存放腔内。S7. Refilling the solid dephosphorus agent in the solid dephosphorus agent storage chamber: When the liquid guide ring rotates to below the solid dephosphorus agent feed port, the feed port is opened by the cooperation of the circular arc gear and the meshing protrusion. At this time, the solid dephosphorus agent can flow into the solid dephosphorus agent storage chamber through the solid dephosphorus agent feed port and the feed port in turn.
本发明的有益效果是:The beneficial effects of the present invention are:
本发明通过外壳体和导液环的设置,将待处理的废水分散至各个分液槽内,流入分液槽内的含磷废水,在进入后和排出的过程中,实现含磷废水穿过固体除磷剂存放腔四次,从而实现分液槽内的含磷废水与固体除磷剂充分接触,从而有效去除废水中的磷。The present invention disperses the wastewater to be treated into each liquid separation tank through the arrangement of the outer shell and the liquid guide ring. The phosphorus-containing wastewater flowing into the liquid separation tank passes through the solid phosphorus removal agent storage chamber four times after entering and during the discharge process, thereby achieving full contact between the phosphorus-containing wastewater in the liquid separation tank and the solid phosphorus removal agent, thereby effectively removing phosphorus in the wastewater.
另外,本发明还通过搅拌叶套筒的转动实现搅拌叶转动,从而致使分液槽内的废水流动,这样增加溶于废水中的固体除磷剂成分与废水中的磷接触,可进一步的有助于实现去除废水中的磷。In addition, the present invention also realizes the rotation of the stirring blade by rotating the stirring blade sleeve, thereby causing the wastewater in the separation tank to flow, thereby increasing the contact between the solid phosphorus removal agent components dissolved in the wastewater and the phosphorus in the wastewater, which can further help to remove the phosphorus in the wastewater.
最后,本发明还通过外延伸杆的转动设置,实现固体除磷剂可补充至固体除磷剂存放腔内,有助于本装置实用时的持续性和连续性。Finally, the present invention also realizes that the solid dephosphorization agent can be added to the solid dephosphorization agent storage chamber through the rotation setting of the outer extension rod, which helps the sustainability and continuity of the device during practical use.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
为了更清楚地说明本发明实施方式的技术方案,下面将对实施方式中所需要使用的附图作简单地介绍,应当理解,以下附图仅示出了本发明的某些实施例,因此不应被看作是对范围的限定,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他相关的附图。In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings required for use in the embodiments will be briefly introduced below. It should be understood that the following drawings only show certain embodiments of the present invention and therefore should not be regarded as limiting the scope. For ordinary technicians in this field, other related drawings can be obtained based on these drawings without paying creative work.
图1是本发明实施方式提供的一种农业污染土壤修复用废水处理设备结构示意图;FIG1 is a schematic structural diagram of a wastewater treatment device for agricultural contaminated soil remediation provided by an embodiment of the present invention;
图2是本发明实施方式提供的一种农业污染土壤修复用废水处理设备中中心柱与外壳体的连接结构示意图;FIG2 is a schematic diagram of the connection structure between a central column and an outer shell in a wastewater treatment device for agricultural contaminated soil remediation provided by an embodiment of the present invention;
图3是本发明实施方式提供的一种农业污染土壤修复用废水处理设备的内部结构示意图;FIG3 is a schematic diagram of the internal structure of a wastewater treatment device for agricultural contaminated soil remediation provided by an embodiment of the present invention;
图4是本发明实施方式提供的一种农业污染土壤修复用废水处理设备中齿环、环状凸台和外延伸杆的连接结构示意图;4 is a schematic diagram of the connection structure of a toothed ring, an annular boss and an outer extension rod in a wastewater treatment device for agricultural contaminated soil remediation provided by an embodiment of the present invention;
图5是图4中A处放大图;FIG5 is an enlarged view of point A in FIG4;
图6是本发明实施方式提供的一种农业污染土壤修复用废水处理设备中外延伸杆与搅拌叶套筒之间的连接结构示意图;6 is a schematic diagram of the connection structure between the outer extension rod and the stirring blade sleeve in a wastewater treatment device for agricultural contaminated soil remediation provided by an embodiment of the present invention;
图7是本发明实施方式提供的一种农业污染土壤修复用废水处理设备中存储结构的结构示意图。FIG. 7 is a schematic diagram of a storage structure in a wastewater treatment device for agricultural contaminated soil remediation provided in an embodiment of the present invention.
图中:In the figure:
1、外壳体;10、进液口;11、出液口;12、环状凸台;120、啮合凸起;13、固体除磷剂进料口;1. outer shell; 10. liquid inlet; 11. liquid outlet; 12. annular boss; 120. meshing protrusion; 13. solid dephosphorization agent feed port;
2、导液环;20、分液槽;200、搅拌叶套筒;201、搅拌叶;202、内驱动滑槽;21、滑环;2. Liquid guide ring; 20. Liquid separation groove; 200. Stirring blade sleeve; 201. Stirring blade; 202. Internal drive slide groove; 21. Slip ring;
3、齿环;3. Gear ring;
4、电机;4. Motor;
5、驱动齿轮;5. Driving gear;
6、存储结构;60、下滤板;61、上滤板;610、进料口;611、上盘体;612、滤挡板;62、固体除磷剂存放腔;6. Storage structure; 60. Lower filter plate; 61. Upper filter plate; 610. Feed inlet; 611. Upper plate; 612. Filter baffle; 62. Solid dephosphorization agent storage chamber;
7、外延伸杆;70、连接座;71、复位弹簧;72、转动驱动凸起;73、圆弧齿轮;7. External extension rod; 70. Connecting seat; 71. Return spring; 72. Rotation drive protrusion; 73. Circular arc gear;
8、中心柱;80、外凸起A;81、外凸起B;8. center column; 80. outer protrusion A; 81. outer protrusion B;
9、连接结构;90、下连接环;91、上连接环。9. Connecting structure; 90. Lower connecting ring; 91. Upper connecting ring.
具体实施方式DETAILED DESCRIPTION
为使本发明实施方式的目的、技术方案和优点更加清楚,下面将结合本发明实施方式中的附图,对本发明实施方式中的技术方案进行清楚、完整地描述,显然,所描述的实施方式是本发明一部分实施方式,而不是全部的实施方式。基于本发明中的实施方式,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施方式,都属于本发明保护的范围。In order to make the purpose, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below in conjunction with the drawings in the embodiments of the present invention. Obviously, the described embodiments are part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention.
实施例Example
参照图1-图7,一种农业污染土壤修复用废水处理设备,包括含环形中空的外壳体1,其中外壳体1的两端闭合,内部的中空腔呈圆柱形结构,方便其内部设置的导液环2转动,转动过程中,导液环2外壁紧贴外壳体1中空腔内壁,为保证转动密封性,在一些实施方式中,导液环2外壁和外壳体1中空内壁之间设置有密封组件,优先的,密封组件由O型圈和密封环组成。Referring to Figures 1 to 7, a wastewater treatment device for remediation of agricultural contaminated soil includes an outer shell body 1 with an annular hollow portion, wherein both ends of the outer shell body 1 are closed, and the inner hollow cavity is in a cylindrical structure, so as to facilitate the rotation of a liquid guide ring 2 arranged therein. During the rotation, the outer wall of the liquid guide ring 2 is in close contact with the inner wall of the hollow cavity of the outer shell body 1. To ensure the rotational sealing, in some embodiments, a sealing assembly is provided between the outer wall of the liquid guide ring 2 and the hollow inner wall of the outer shell body 1. Preferably, the sealing assembly is composed of an O-ring and a sealing ring.
参照图1-图3,外壳体1上设置有进液口10,进液口10用于流入待处理的含磷废水。1 to 3 , a liquid inlet 10 is provided on the outer shell 1 , and the liquid inlet 10 is used for the inflow of phosphorus-containing wastewater to be treated.
参照图2和图3,外壳体1上设置有出液口11,出液口11用于流出处理后的废水。其中需要说明的是:进液口10位于出液口11的上方,则随导液环2的转动,致使处理后的废水在重力作用下有序的从出液口11排出。2 and 3, a liquid outlet 11 is provided on the outer shell 1, and the liquid outlet 11 is used to discharge the treated wastewater. It should be noted that the liquid inlet 10 is located above the liquid outlet 11, and as the liquid guide ring 2 rotates, the treated wastewater is discharged from the liquid outlet 11 in an orderly manner under the action of gravity.
参照图3和图4,本实施例还公开了一种驱动导液环2转动的驱动结构,该结构优选采用齿轮和齿环的传动实现,其中齿环3固定于导液环2内壁;另外,外壳体1外壁固定有电机4,电机4的输出端贯穿外壳体1,而齿轮5固定于电机4的输出端上;再进一步的,驱动齿轮5与齿环3啮合。3 and 4 , the present embodiment further discloses a driving structure for driving the liquid guiding ring 2 to rotate, and the structure is preferably implemented by transmission of gears and toothed rings, wherein the toothed ring 3 is fixed to the inner wall of the liquid guiding ring 2; in addition, a motor 4 is fixed to the outer wall of the outer shell 1, the output end of the motor 4 passes through the outer shell 1, and the gear 5 is fixed to the output end of the motor 4; further, the driving gear 5 is meshed with the toothed ring 3.
需要说明的是:电机4采用的是伺服电机,电机4致动驱动齿轮5后,进一步的致动齿环3,从而驱动导液环2,本实施例中采用的是驱动齿轮5致动齿环3的方式,该方式中,采用的是小齿轮传动大齿环,则随着驱动齿轮5的转动,缓慢的致动齿环3,从而缓慢的驱动导液环2,这样为之后充分处理含磷废水提供时间。It should be noted that: the motor 4 is a servo motor. After the motor 4 actuates the driving gear 5, it further actuates the gear ring 3, thereby driving the liquid guiding ring 2. In this embodiment, the driving gear 5 actuates the gear ring 3. In this method, a small gear drives a large gear ring. As the driving gear 5 rotates, the gear ring 3 is slowly actuated, thereby slowly driving the liquid guiding ring 2, thereby providing time for fully treating the phosphorus-containing wastewater.
参照图3,导液环2外壁上径向开设有多个分液槽20,分液槽20的设置,将流动的含磷废水形成“静态”,即待处理的含磷废水分散流向独立的空腔内,在该独立的空腔内实现对含磷废水的净化处理,从而为实现充分净化废水提供空间设置的基础;另外,采用分液槽20的结构设置,还将含磷的废水通过“化整为零”的方式被充分净化。3 , a plurality of liquid separation grooves 20 are radially opened on the outer wall of the liquid guide ring 2. The arrangement of the liquid separation grooves 20 makes the flowing phosphorus-containing wastewater "static", that is, the phosphorus-containing wastewater to be treated is dispersed and flows into an independent cavity, and the phosphorus-containing wastewater is purified in the independent cavity, thereby providing a spatial setting basis for fully purifying the wastewater; in addition, the structural arrangement of the liquid separation grooves 20 can also fully purify the phosphorus-containing wastewater by a "breaking the whole into parts" approach.
参照图3,基于分液槽20的设置,分液槽20内滑动有一滑环21,滑环21内设置有固体除磷剂的存储结构6,其中滑环21的设置为存储结构6提供安装基础,该存储结构6用于存放固体除磷剂,则流入分液槽20内的废水,与滑环21内设置的固体除磷剂充分接触,从而通过固体除磷剂充分净化含磷废水。Referring to Figure 3, based on the setting of the liquid separation tank 20, a slip ring 21 slides in the liquid separation tank 20, and a storage structure 6 for a solid dephosphorus removal agent is arranged in the slip ring 21, wherein the setting of the slip ring 21 provides an installation basis for the storage structure 6, and the storage structure 6 is used to store the solid dephosphorus removal agent. The wastewater flowing into the liquid separation tank 20 is in full contact with the solid dephosphorus removal agent arranged in the slip ring 21, so that the phosphorus-containing wastewater is fully purified by the solid dephosphorus removal agent.
在一些实施方式中,固体除磷剂的存储结构6包括下滤板60和上滤板61,其中下滤板60和上滤板61之间留有间隙,形成固体除磷剂存放腔62,致使固体除磷剂设置有特定的存放空间,不会使得固体除磷剂以流动,从而保证固体除磷剂与含磷废水充分接触。In some embodiments, the storage structure 6 of the solid dephosphorus removal agent includes a lower filter plate 60 and an upper filter plate 61, wherein a gap is left between the lower filter plate 60 and the upper filter plate 61 to form a solid dephosphorus removal agent storage chamber 62, so that the solid dephosphorus removal agent is provided with a specific storage space, and the solid dephosphorus removal agent will not flow, thereby ensuring that the solid dephosphorus removal agent is in full contact with the phosphorus-containing wastewater.
参照图5和图7,下滤板60呈盘型设置于滑环21的内壁,其中下滤板60上设置有滤孔,该滤孔用于含磷废水穿过固体除磷剂的存储结构6,从而与存储结构6内的固体除磷剂充分接触。5 and 7 , the lower filter plate 60 is disc-shaped and arranged on the inner wall of the slip ring 21 , wherein the lower filter plate 60 is provided with filter holes, which are used for the phosphorus-containing wastewater to pass through the storage structure 6 of the solid phosphorus removal agent, so as to fully contact with the solid phosphorus removal agent in the storage structure 6 .
参照图5和图7,上滤板61位于滑环21的内壁,且位于下滤板60的上方,为固体除磷剂存放腔62的形成提供结构基础。5 and 7 , the upper filter plate 61 is located on the inner wall of the slide ring 21 and above the lower filter plate 60 , providing a structural basis for the formation of the solid dephosphorization agent storage chamber 62 .
需要说明的是:上滤板61包括等距设置有进料口610的上盘体611,进料口610的下方设置有可转动的滤挡板612,随滤挡板612的转动控制进料口610开启或闭合。其中滤挡板612上也设置有滤孔,保证了含磷废水穿过固体除磷剂的存储结构6,从而与存储结构6内的固体除磷剂充分接触。It should be noted that the upper filter plate 61 includes an upper plate body 611 with feed ports 610 arranged at equal intervals, and a rotatable filter baffle plate 612 is arranged below the feed port 610, and the feed port 610 is opened or closed with the rotation of the filter baffle plate 612. The filter baffle plate 612 is also provided with filter holes, which ensures that the phosphorus-containing wastewater passes through the storage structure 6 of the solid phosphorus removal agent, so as to fully contact with the solid phosphorus removal agent in the storage structure 6.
基于滑环21的设置,本实施例还公开了可驱动滑环21在分液槽20内移动的结构,基于该结构,可进一步的实现存储结构6内的固体除磷剂与含磷废水再一次的接触,从而保证固体除磷剂与含磷废水的充分反应,保证净化的充分性。该结构设置如下:Based on the setting of the slip ring 21, this embodiment also discloses a structure that can drive the slip ring 21 to move in the liquid separation tank 20. Based on this structure, the solid dephosphorization agent in the storage structure 6 can be further contacted with the phosphorus-containing wastewater again, thereby ensuring the full reaction of the solid dephosphorization agent with the phosphorus-containing wastewater and ensuring the adequacy of purification. The structure is set as follows:
参照图3-图7,滑环21内设置有外延伸杆7,优选的,外延伸杆7与滑环21同轴设置,外壳体内中心设置有中心柱8,中心柱8的外壁设置有外凸起A80,且外延伸杆7的内端抵触在中心柱8外壁。外延伸杆7随导液环2同步转动,当外延伸杆7端部与外凸起A80抵触后,外延伸杆7径向向导液环2外部移动,从而与分液槽20内流向下方的待净化含磷废水再次充分接触。3 to 7, an outer extension rod 7 is provided in the slip ring 21. Preferably, the outer extension rod 7 is coaxially arranged with the slip ring 21, a central column 8 is arranged in the center of the outer shell, an outer protrusion A80 is arranged on the outer wall of the central column 8, and the inner end of the outer extension rod 7 abuts against the outer wall of the central column 8. The outer extension rod 7 rotates synchronously with the liquid guide ring 2. When the end of the outer extension rod 7 abuts against the outer protrusion A80, the outer extension rod 7 moves radially to the outside of the liquid guide ring 2, so as to fully contact with the phosphorus-containing wastewater to be purified flowing downward in the liquid separation tank 20 again.
需要补充的是:在一些实施方式中,为了保证滑环21位置的稳定,本实施例还设置了复位弹簧71,具体设置如下:外延伸杆7外壁固定有连接座70,其中连接座70为套设在外延伸杆7外壁的凸起结构,复位弹簧71的两端分别连接在连接座70和导液环2内壁之间,在初始状态下,滑环21位于分液槽20槽底,当外延伸杆7抵触外凸起A80后,致使复位弹簧71被压缩,外延伸杆7脱离外凸起A80后,在复位弹簧71弹簧力驱动下,致使外延伸杆7复位至初始状态。It should be added that: in some embodiments, in order to ensure the stability of the position of the slip ring 21, a reset spring 71 is also provided in this embodiment, and the specific configuration is as follows: a connecting seat 70 is fixed to the outer wall of the outer extension rod 7, wherein the connecting seat 70 is a protruding structure sleeved on the outer wall of the outer extension rod 7, and the two ends of the reset spring 71 are respectively connected between the connecting seat 70 and the inner wall of the liquid guide ring 2. In the initial state, the slip ring 21 is located at the bottom of the liquid separation groove 20. When the outer extension rod 7 contacts the outer protrusion A80, the reset spring 71 is compressed. After the outer extension rod 7 is separated from the outer protrusion A80, the outer extension rod 7 is reset to the initial state under the drive of the spring force of the reset spring 71.
基于外延伸杆7的设置,本实施例还进一步的公开了一种可驱动滑环21内待处理的废水流动结构,从而致使待处理的废水与溶解与其内的固体除磷剂充分反应,优选的,该结构包括搅拌叶套筒200和搅拌叶201。Based on the setting of the outer extension rod 7, this embodiment further discloses a structure that can drive the flow of wastewater to be treated in the slip ring 21, so that the wastewater to be treated and the solid dephosphorization agent dissolved therein fully react. Preferably, the structure includes a stirring blade sleeve 200 and a stirring blade 201.
参照图5-图7,搅拌叶套筒200转动于分液槽20内壁,且搅拌叶套筒8套设于外延伸杆7外壁,搅拌叶201设置于搅拌叶套筒200外壁。搅拌叶套筒200的转动致使搅拌叶201转动,从而制动位于滑环21内溶解有固体除磷剂的含磷废水流动,进一步的增加固体除磷剂与含磷废水中的磷充分接触。5-7, the stirring blade sleeve 200 rotates on the inner wall of the liquid separation tank 20, and the stirring blade sleeve 8 is sleeved on the outer wall of the outer extension rod 7, and the stirring blade 201 is arranged on the outer wall of the stirring blade sleeve 200. The rotation of the stirring blade sleeve 200 causes the stirring blade 201 to rotate, thereby braking the flow of the phosphorus-containing wastewater dissolved with the solid phosphorus removal agent in the slip ring 21, and further increasing the solid phosphorus removal agent and the phosphorus in the phosphorus-containing wastewater.
本实施例还公开了一种外延伸杆7驱动搅拌叶套筒8转动的结构,参照图6,外延伸杆7外壁设置有转动驱动凸起72,优选的,该转动驱动凸起72为半球形结构;相对的,搅拌叶套筒200内壁设置有呈螺旋状的内驱动滑槽202,转动驱动凸起72滑动于内驱动滑槽202内,随着外延伸杆7的线性运动,通过转动驱动凸起72抵触内驱动滑槽202内壁后,致动搅拌叶套筒8转动,进一步的致动搅拌叶201转动,从而制动滑环21内溶解有固体除磷剂的含磷废水流动,使得固体除磷剂与含磷废水中的磷充分接触反应。The present embodiment also discloses a structure in which an outer extension rod 7 drives the stirring blade sleeve 8 to rotate. Referring to Figure 6, a rotation driving protrusion 72 is provided on the outer wall of the outer extension rod 7. Preferably, the rotation driving protrusion 72 is a hemispherical structure. Conversely, a spiral inner driving groove 202 is provided on the inner wall of the stirring blade sleeve 200. The rotation driving protrusion 72 slides in the inner driving groove 202. With the linear movement of the outer extension rod 7, the rotation driving protrusion 72 contacts the inner wall of the inner driving groove 202, thereby actuating the stirring blade sleeve 8 to rotate, and further actuating the stirring blade 201 to rotate, thereby braking the flow of phosphorus-containing wastewater dissolved with solid dephosphorus removal agent in the slip ring 21, so that the solid dephosphorus removal agent is fully contacted and reacted with phosphorus in the phosphorus-containing wastewater.
需要补充的是,为了进一步的增加外延伸杆7相对导液环2径向移动的次数,则本实施中,在中心柱8的外壁还设置有外凸起B81,从而增加滑环21内溶解有固体除磷剂的含磷废水流动次数。It should be added that in order to further increase the number of radial movements of the outer extension rod 7 relative to the liquid guide ring 2, in this embodiment, an outer protrusion B81 is also provided on the outer wall of the central column 8, thereby increasing the number of flows of phosphorus-containing wastewater containing solid dephosphorization agent dissolved in the slip ring 21.
最后,本实施例还基于外延伸杆7和滤挡板612的结构设置,还公开了一种可随外延伸杆7转动而打开进料口610的结构,该结构设置如下:外延伸杆7通过连接结构9与滤挡板612连接,连接结构9包括与外延伸杆7固定的下连接环90,该连接方式可通过多根连接筋串联外延伸杆7外端部和下连接环90内壁,其中下连接环90的内径大于下滤板60的外径,且滑环21内壁设置有与下连接环90对应的下环形滑槽;另外,下连接环90通过多根连接筋连接有上连接环91,相对的,滑环21内壁设置有与上连接环91上连接环91对应的上环形滑槽,滤挡板612外壁固定于上连接环91内壁,随着下连接环90转动致动上连接环91转动,从而控制进料口610开启或闭合。当进料口610开启时,有助于固体除磷剂进入至固体除磷剂存放腔62内;当进料口610闭合时,固体除磷剂稳定的存放于固体除磷剂存放腔62内。Finally, based on the structural arrangement of the outer extension rod 7 and the filter baffle plate 612, this embodiment also discloses a structure that can open the feed port 610 as the outer extension rod 7 rotates. The structure is arranged as follows: the outer extension rod 7 is connected to the filter baffle plate 612 through a connecting structure 9, and the connecting structure 9 includes a lower connecting ring 90 fixed to the outer extension rod 7. This connection method can connect the outer end of the outer extension rod 7 and the inner wall of the lower connecting ring 90 in series through a plurality of connecting ribs, wherein the inner diameter of the lower connecting ring 90 is larger than the outer diameter of the lower filter plate 60, and the inner wall of the slip ring 21 is provided with a lower annular groove corresponding to the lower connecting ring 90; in addition, the lower connecting ring 90 is connected to the upper connecting ring 91 through a plurality of connecting ribs, and correspondingly, the inner wall of the slip ring 21 is provided with an upper annular groove corresponding to the upper connecting ring 91, and the outer wall of the filter baffle plate 612 is fixed to the inner wall of the upper connecting ring 91, and the upper connecting ring 91 is actuated to rotate as the lower connecting ring 90 rotates, thereby controlling the feed port 610 to be opened or closed. When the feed port 610 is opened, it helps the solid dephosphorus agent to enter the solid dephosphorus agent storage chamber 62 ; when the feed port 610 is closed, the solid dephosphorus agent is stably stored in the solid dephosphorus agent storage chamber 62 .
进一步的,本实施例还公开了一种驱动外延伸杆7转动的结构,该结构由圆弧齿轮73和啮合凸起120组成,其中外壳体1内壁还固定有环状凸台12,圆弧齿轮73固定于外延伸杆7外端壁,啮合凸起120设置于环状凸台12外壁处,且啮合凸起120与圆弧齿轮73啮合,外延伸杆7随导液环2转动后,当啮合凸起120与圆弧齿轮73啮合后,致使外延伸杆7转动,从而实现进料口610开启,用于固体除磷剂放料至固体除磷剂存放腔62内;当啮合凸起120与圆弧齿轮73脱离啮合后,在复位弹簧71的作用下,致使滤挡板612反向转动,从而关闭进料口610,保证固体除磷剂存放腔62内的固体除磷剂放置的稳定性。Furthermore, the present embodiment also discloses a structure for driving the outer extension rod 7 to rotate, the structure is composed of a circular arc gear 73 and an engaging protrusion 120, wherein an annular boss 12 is also fixed to the inner wall of the outer shell 1, the circular arc gear 73 is fixed to the outer end wall of the outer extension rod 7, the engaging protrusion 120 is arranged at the outer wall of the annular boss 12, and the engaging protrusion 120 is engaged with the circular arc gear 73. After the outer extension rod 7 rotates with the liquid guide ring 2, when the engaging protrusion 120 is engaged with the circular arc gear 73, the outer extension rod 7 is caused to rotate, thereby realizing the opening of the feed port 610 for discharging the solid dephosphorization agent into the solid dephosphorization agent storage chamber 62; when the engaging protrusion 120 is disengaged from the circular arc gear 73, under the action of the reset spring 71, the filter baffle 612 is caused to rotate in the opposite direction, thereby closing the feed port 610, and ensuring the stability of the solid dephosphorization agent placed in the solid dephosphorization agent storage chamber 62.
另外,本实施例中,在外壳体1上还设置有固体除磷剂进料口13,这样当进料口610打开后,固体除磷剂依次穿过固体除磷剂进料口13和进料口610放置于固体除磷剂存放腔62内。In addition, in this embodiment, a solid dephosphorus agent feed port 13 is also provided on the outer shell 1, so that when the feed port 610 is opened, the solid dephosphorus agent passes through the solid dephosphorus agent feed port 13 and the feed port 610 in sequence and is placed in the solid dephosphorus agent storage chamber 62.
基于一种农业污染土壤修复用废水处理设备的设置,本实施例还公开了其使用方法,该使用方法包括以下步骤:Based on the setting of a wastewater treatment device for agricultural contaminated soil remediation, this embodiment also discloses a method for using the device, which includes the following steps:
S1、含磷废水流入分液槽20:含磷废水通过进液口10流向分液槽20内。S1. Phosphorus-containing wastewater flows into the liquid separation tank 20: the phosphorus-containing wastewater flows into the liquid separation tank 20 through the liquid inlet 10.
S2、导液环2转动:电机4启动,通过驱动齿轮5和齿环3配合致使导液环2转动,当分液槽20脱离进液口10后,致使分液槽20与外壳体1内壁形成闭合空间,致使含磷废水充分与固体除磷剂充分接触反应;该过程中,含磷废水穿过固体除磷剂存放腔62,致使含磷废水与固体除磷剂第一次接触,从而去除含磷废水中的磷。S2, the liquid guide ring 2 rotates: the motor 4 is started, and the liquid guide ring 2 rotates by driving the gear 5 and the gear ring 3. When the liquid separation groove 20 is separated from the liquid inlet 10, the liquid separation groove 20 and the inner wall of the outer shell 1 form a closed space, so that the phosphorus-containing wastewater is fully contacted and reacted with the solid phosphorus removal agent; in this process, the phosphorus-containing wastewater passes through the solid phosphorus removal agent storage chamber 62, so that the phosphorus-containing wastewater is in contact with the solid phosphorus removal agent for the first time, thereby removing phosphorus in the phosphorus-containing wastewater.
S3、滑环21内含磷废水流动:参照图3,外延伸杆7随导液环2转动后,当外延伸杆7抵触外凸起B81后,实现外延伸杆7相对导液环2径向移动,在转动驱动凸起72和内驱动滑槽202的配合下,致使搅拌叶套筒200转动,从而致使搅拌叶201转动,进一步的制动滑环21内溶解有固体除磷剂的含磷废水流动,使得固体除磷剂与含磷废水中的磷充分接触反应。S3. Flow of phosphorus-containing wastewater in the slip ring 21: Referring to FIG. 3 , after the outer extension rod 7 rotates with the liquid guide ring 2, when the outer extension rod 7 hits the outer protrusion B81, the outer extension rod 7 moves radially relative to the liquid guide ring 2, and with the cooperation of the rotating drive protrusion 72 and the inner drive groove 202, the stirring blade sleeve 200 rotates, thereby causing the stirring blade 201 to rotate, and further braking the flow of phosphorus-containing wastewater dissolved with solid phosphorus removal agent in the slip ring 21, so that the solid phosphorus removal agent fully contacts and reacts with phosphorus in the phosphorus-containing wastewater.
S4、含磷废水第二次与固体除磷剂存放腔62内的固体除磷剂接触:随导液环2转动,当导液环2转动至其一半以下位置时,含磷废水在重力作用下从滑环21流向外壳体1内壁,该过程中穿过固体除磷剂存放腔62,致使含磷废水与固体除磷剂第二次接触。S4. The phosphorus-containing wastewater contacts the solid phosphorus-removing agent in the solid phosphorus-removing agent storage chamber 62 for the second time: As the liquid guide ring 2 rotates, when the liquid guide ring 2 rotates to a position below half of its original position, the phosphorus-containing wastewater flows from the slip ring 21 to the inner wall of the outer shell 1 under the action of gravity, and passes through the solid phosphorus-removing agent storage chamber 62 in the process, causing the phosphorus-containing wastewater to contact the solid phosphorus-removing agent for the second time.
S5、含磷废水第三次与固体除磷剂存放腔62内的固体除磷剂接触:随导液环2转动,外延伸杆7抵触外凸起A80,致使滑环21沿分液槽20径向向外移动,从而致使滑环21外端部挤压其外端的废水,被挤压的废水从固体除磷剂存放腔62外端流向滑环21内,实现含磷废水第三次与固体除磷剂存放腔62内的固体除磷剂接触。S5. The phosphorus-containing wastewater contacts the solid phosphorus-removing agent in the solid phosphorus-removing agent storage chamber 62 for the third time: As the liquid guide ring 2 rotates, the outer extension rod 7 contacts the outer protrusion A80, causing the slip ring 21 to move radially outward along the liquid separation groove 20, thereby causing the outer end of the slip ring 21 to squeeze the wastewater at its outer end, and the squeezed wastewater flows from the outer end of the solid phosphorus-removing agent storage chamber 62 to the inside of the slip ring 21, thereby achieving the third contact between the phosphorus-containing wastewater and the solid phosphorus-removing agent in the solid phosphorus-removing agent storage chamber 62.
S6、含磷废水第四次与固体除磷剂存放腔62内的固体除磷剂接触,并完成下料:随导液环2转动,转动至出液口11上方时,分液槽20内废水从穿过固体除磷剂存放腔62后,从出液口11流出,即分液槽20内废水在完成下料时,也同步完成第四次与固体除磷剂存放腔62内的固体除磷剂接触。S6. The phosphorus-containing wastewater contacts the solid phosphorus removal agent in the solid phosphorus removal agent storage chamber 62 for the fourth time and completes the discharge: as the liquid guide ring 2 rotates, when it rotates above the liquid outlet 11, the wastewater in the liquid separation tank 20 passes through the solid phosphorus removal agent storage chamber 62 and flows out from the liquid outlet 11. That is, when the wastewater in the liquid separation tank 20 completes the discharge, it also synchronously completes the fourth contact with the solid phosphorus removal agent in the solid phosphorus removal agent storage chamber 62.
S7、固体除磷剂存放腔62内的固体除磷剂补料:随导液环2转动,转动至固体除磷剂进料口13下方时,通过圆弧齿轮73与啮合凸起120的配合实现进料口610打开,此时,方便固体除磷剂依次通过固体除磷剂进料口13和进料口610流向固体除磷剂存放腔62内。S7. Refilling the solid dephosphorus agent in the solid dephosphorus agent storage chamber 62: When the liquid guide ring 2 rotates to below the solid dephosphorus agent feed port 13, the feed port 610 is opened through the cooperation of the circular arc gear 73 and the meshing protrusion 120. At this time, the solid dephosphorus agent can flow into the solid dephosphorus agent storage chamber 62 through the solid dephosphorus agent feed port 13 and the feed port 610 in turn.
需要说明的是,电机具体的型号规格需根据该装置的实际规格等进行选型确定,具体选型计算方法采用本领域现有技术,故不再详细赘述。It should be noted that the specific model and specifications of the motor need to be selected and determined based on the actual specifications of the device, and the specific selection calculation method adopts the existing technology in this field, so it will not be described in detail.
以上所述仅为本发明的优选实施方式而已,并不用于限制本发明,对于本领域的技术人员来说,本发明可以有各种更改和变化。凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The above description is only a preferred embodiment of the present invention and is not intended to limit the present invention. For those skilled in the art, the present invention may have various modifications and variations. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention shall be included in the protection scope of the present invention.
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| CN112978977A (en) * | 2021-01-28 | 2021-06-18 | 生态环境部南京环境科学研究所 | Elution wastewater treatment device after organo-chlorine pesticide contaminated soil synergism elution restoration |
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| CN112978977A (en) * | 2021-01-28 | 2021-06-18 | 生态环境部南京环境科学研究所 | Elution wastewater treatment device after organo-chlorine pesticide contaminated soil synergism elution restoration |
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