CN118318788A - Composite enzyme charcoal bag and manufacturing method and application thereof - Google Patents

Composite enzyme charcoal bag and manufacturing method and application thereof Download PDF

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Publication number
CN118318788A
CN118318788A CN202410508923.1A CN202410508923A CN118318788A CN 118318788 A CN118318788 A CN 118318788A CN 202410508923 A CN202410508923 A CN 202410508923A CN 118318788 A CN118318788 A CN 118318788A
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enzyme
complex enzyme
charcoal
complex
composite enzyme
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黄辉
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Wuhan Aowei Tianshun Biotechnology Co ltd
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Wuhan Aowei Tianshun Biotechnology Co ltd
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Abstract

The invention discloses a marine organism composite enzyme charcoal bag and a manufacturing method and application thereof, and belongs to the technical field of cultivation. The marine organism composite enzyme carbon package comprises active carbon and marine organism composite enzyme (hereinafter referred to as composite enzyme), wherein the composite enzyme is attached to the active carbon. The invention also provides a method for manufacturing the composite enzyme charcoal bag, which comprises the following steps: soaking the carbon bag in the complex enzyme, drying, and then continuously soaking in the complex enzyme, and repeating the steps for a plurality of times to obtain the complex enzyme carbon bag. The invention also provides the application of the composite enzyme charcoal package or the composite enzyme charcoal package prepared by the preparation method of the composite enzyme charcoal package in the aspect of raising livestock. The complex enzyme charcoal bag can facilitate digestion and absorption of livestock and fowl, promote discharge of toxin residue in vivo, and reduce disease chance.

Description

Composite enzyme charcoal bag and manufacturing method and application thereof
Technical Field
The invention relates to the technical field of cultivation, in particular to a composite enzyme charcoal bag and a manufacturing method and application thereof.
Background
The enzyme is a biotechnological navigator and has revolutionary, subversion and introductory. The enzyme exists in all living animals and plants, is a substance with special biological activity and consists of amino acids, and has strong catalytic action on a plurality of organic chemical reactions and complex reactions carried out in organisms. Enzymes are the core of a new technological and industrial revolution in biotechnology.
In the existing breeding technology, more medicines are needed to be added to reduce or prevent the illness condition of livestock; how to reduce or prevent livestock diseases by utilizing enzymes is a problem to be solved in the prior art.
Disclosure of Invention
The invention aims to overcome the technical defects, and provides a composite enzyme charcoal bag, a manufacturing method and application thereof, which solve the technical problem of how to reduce or prevent diseases of livestock by utilizing enzymes in the prior art.
In order to achieve the technical aim, the technical scheme of the invention provides a composite enzyme charcoal package which comprises activated carbon and composite enzyme, wherein the composite enzyme is attached to the activated carbon.
Further, the porosity of the activated carbon is more than 96%, the volume load is 15-16kgBOD 5/m3.d, and the specific surface area is 21-24m 2/g.
Further, the complex enzyme is a marine organism complex enzyme.
Further, the marine organism complex enzyme comprises two or more of amylase, alkaline phosphatase, aminopeptidase, amyloglucosidase, bromelain, ficin, deoxyribonuclease, matriase, telomerase and soybean protease.
In addition, the invention also provides a manufacturing method of the composite enzyme charcoal bag, which comprises the following steps: soaking the carbon bag in the complex enzyme, drying, and then continuously soaking in the complex enzyme, and repeating the steps for a plurality of times to obtain the complex enzyme carbon bag.
Further, the drying temperature is-20 to-30 ℃.
In addition, the invention also provides the application of the composite enzyme charcoal package or the composite enzyme charcoal package prepared by the preparation method of the composite enzyme charcoal package in the aspect of raising livestock.
Further, the composite enzyme charcoal bag is arranged in a drinking water pipe through a slow release device, and is further added into drinking water.
Further, the complex enzyme charcoal bag is placed in a pre-filter of drinking water, the pre-filter is communicated with a drinking water pipe of a farm, and biological membranes formed by complex enzymes and complex enzymes enter drinking water of livestock from the pre-filter, so that the biological membranes enter intestinal tracts of the livestock to take effect.
Further, the temperature of the drinking water is 15-45 ℃.
Compared with the prior art, the invention has the beneficial effects that: the complex enzyme charcoal package comprises active carbon and complex enzyme, wherein the complex enzyme is attached to the active carbon, active carbon carrier is provided with amino, carboxyl, epoxy and other active groups to form ionic bond or covalent bond with the amino acid residue of the microbial peptide chain, so that the complex enzyme is fixed on the carrier, when the complex enzyme charcoal package is used for raising livestock, the complex enzyme charcoal package is added into drinking water, biological bacterial film can be generated in the active carbon, when water flows, water, air and biological film can be fully mixed, contacted and exchanged, the biological film can be greatly implanted in the microbial carrier, good activity and void variability are kept, and in the running process, gas is mutually collided under the drive of three-dimensional flowing water and is continuously cut into smaller bubbles by the microbial carrier in peristaltic state, so that the oxygen utilization rate is increased, the complex enzyme can polymerize beneficial microorganism flora, cultivate the formation of self-cleaning ecological mechanism of water body, can actively and rapidly perform chemical reactions such as polymerization, substitution, replacement, decomposition and the like with toxic and peculiar smell molecules in water, change the original toxic and peculiar smell molecular structure into nontoxic and odorless molecules, can automatically decompose organic matters, degrade inorganic matters and remove harmful matters, has obvious effects of purifying and improving water quality, simultaneously the biological bacterial film in the activated carbon can be largely replicated and enter intestines and stomach of livestock, further be largely replicated, and can take away a small amount of complex enzyme when water flows each time, more beneficial bacterial flora is activated and kept stable in the livestock, thereby realizing that the conversion efficiency of the feed is effectively increased by cultivating healthy bacterial flora, the livestock body is easier to digest and absorb and quicken toxin residues in the body, reducing the chance of illness.
Drawings
FIG. 1 is a picture of chickens raised in example 1 of the present invention.
FIG. 2 is a picture of a hen bred in example 1 of the present invention.
Detailed Description
The specific embodiment provides a composite enzyme charcoal package, which comprises active carbon and composite enzyme, wherein the composite enzyme is attached to the active carbon; the porosity of the activated carbon is above 96%, the volume load is 15-16kg BOD 5/m3 & d, and the specific surface area is 21-24m 2/g; the complex enzyme is marine organism complex enzyme; the marine organism complex enzyme comprises more than two of amylase, alkaline phosphatase, aminopeptidase, amyloglucosidase, bromelain, ficin, deoxyribonuclease, matriase, telomerase and soybean proteinase.
The specific embodiment also provides a manufacturing method of the composite enzyme charcoal bag, which comprises the following steps: soaking the carbon bag in the complex enzyme, drying at-20 to-30 ℃, then continuously soaking in the complex enzyme, and repeating the steps for a plurality of times to obtain the complex enzyme carbon bag. The enzyme is water agent, the enzyme is adhered on the activated carbon, the activated carbon is dried, the activated carbon is repeatedly soaked in high-concentration complex enzyme, and the complex enzyme can enter the deep part of the activated carbon, so that the subsequent sustained release is facilitated.
The specific embodiment also provides the application of the composite enzyme charcoal package or the composite enzyme charcoal package prepared by the preparation method of the composite enzyme charcoal package in the aspect of raising livestock, the composite enzyme charcoal package is added into drinking water, further, the composite enzyme charcoal package is placed in a pre-filter of the drinking water, the pre-filter is communicated with a drinking water pipe of a farm, a biological bacterial film formed by the composite enzyme and the composite enzyme enters the drinking water of the livestock from the pre-filter, so that the biological bacterial film enters the intestinal tracts of the livestock to play a role, and the temperature of the drinking water is preferably 15-45 ℃.
The invention introduces a space cantilever for reducing space obstacle formed by metabolism proliferation of fixed microorganisms on activated carbon, provides a living space for metabolism proliferation for the space, and relates to the actions of 4 factors of activated carbon particles, microorganisms, pollutants in water and dissolved oxygen in water, wherein the interaction between the activated carbon and the pollutants belongs to simple activated carbon adsorption, the action of the microorganisms and the dissolved oxygen is that the microorganisms are propagated by using the dissolved oxygen in the water, the process of degrading the pollutants in the water by the microorganisms is that the microorganisms acquire energy and nutrition, and the rapid propagation of the microorganisms on the activated carbon can be promoted due to the adsorption action of the activated carbon and the synergistic action of the activated carbon and the microorganisms.
The present invention will be described in further detail with reference to the drawings and examples, in order to make the objects, technical solutions and advantages of the present invention more apparent. It should be understood that the specific embodiments described herein are for purposes of illustration only and are not intended to limit the scope of the invention.
The biological enzyme technology is a liquid preparation which extracts the information of high-activity, high-concentration and high-combination microbial flora and can be stored for a long time at normal temperature and normal pressure.
When in use, the biological enzyme preparation is put into water to be activated, and the microbial flora is rapidly and largely replicated after the biological enzyme preparation is activated, and the biological enzyme preparation is survived in a biochemical reaction tank (ammonia remover) by means of a special technology (self-immobilization technology of microorganisms, enzymes and carriers), so that a large amount of microbial flora with rich and high activity is always stored in the biochemical reaction tank and a drinking water pipeline of pigs, thereby ensuring the existence of a high content of beneficial microbial flora in drinking water of pigs. And the addition amount of the microorganisms can be timely adjusted according to the actual conditions and total amount changes in the water body.
The quantity of bacteria in the water body is extremely high, the propagation speed is extremely high, only a small quantity of strains are needed to be supplemented during normal operation, and the consumption of high-efficiency biological enzymes can be saved.
The material has good stability and physical and chemical properties in water, the void ratio is over 96 percent, the density of the carrier after microorganism fixation is close to that of water, the microorganism loading capacity is large and is as high as 18-40g/L, the volume loading capacity can be as high as 16kgBOD 5/m3.d, and the specific surface area is 23.3m 2/g.
The carrier can fully mix water, air and biological film for contact exchange due to the structural characteristics, the biological film can be greatly seated in the microbial carrier, good activity and void variability are maintained, and in the running process, the gases are driven by the three-dimensional flowing water to collide with each other and are continuously cut into smaller bubbles by the microbial carrier in a peristaltic state, so that the oxygen utilization rate is increased.
The self-immobilized technology of microorganism, enzyme and carrier is characterized in that ionic bond bonding or covalent bond bonding is formed by virtue of the action of active groups such as amino, carboxyl, epoxy groups and the like on a high-density active carbon carrier and amino acid residues of a microorganism peptide chain, so that the microorganism and the enzyme are immobilized on the carrier.
At the same time, a 'space cantilever' which aims at reducing space obstacle formed by the carrier background to the metabolic proliferation of the immobilized microorganism is introduced on the carrier, so that the living space of the metabolic proliferation is provided for the carrier.
The water fermented by the probiotics is drunk for a long time, the same effect as that produced by adding the probiotics into the feed can be produced, the digestion and absorption rate of pigs can be effectively improved, the gastrointestinal health is protected, and the immunity of the pigs is further improved. The probiotics in the intestinal tract can continue to work and propagate along with the discharge of the excrement, and can also greatly reduce the release of harmful gases in the pig house, relieve a series of problems caused by ammonia, odor and the like in the farm, and bring remarkable benefit improvement. (reducing the influence of ammonia gas emission on pigs, and self-checking data is already disclosed as belonging to the prior art).
Due to the advanced enzyme preparation technology, no new microbial flora is brought from other environments, and the problem of microbial contamination is avoided.
The enzyme preparation technology can cultivate a large amount of indigenous flora, is more suitable for local environment, obviously improves working efficiency, prolongs service life, reduces manual intervention, and greatly reduces use cost.
The ammonia remover developed by the pig house can start working as long as the ammonia remover is connected into a drinking water system of a farm, the change of an ammonia value is monitored through an ammonia sensor arranged in the pig house, and consumable materials are replaced after the ammonia value is restarted to rise.
The ammonia remover can be suitable for most areas of the whole country, and can work at a temperature of between 20 ℃ below zero and 65 ℃ above zero.
The electric power is not needed at normal temperature, and the heat preservation device can be added in the cold winter, so that the power consumption is about 100w.
The consumable can be used for about 3 months when replaced once.
Example 1
The embodiment provides a composite enzyme charcoal package, which comprises active carbon and composite enzyme, wherein the composite enzyme is attached to the active carbon; the porosity of the activated carbon is more than 96%, the volume load is 16kg BOD 5/m3 & d, and the specific surface area is 23.3m 2/g; the complex enzyme is marine organism complex enzyme; the marine organism complex enzyme comprises amylase, alkaline phosphatase, aminopeptidase, amyloglucosidase and bromelain, wherein the amylase accounts for 15% by mass, the alkaline phosphatase accounts for 20% by mass, the aminopeptidase accounts for 20% by mass, the amyloglucosidase accounts for 25% by mass, and the bromelain accounts for 20% by mass.
The embodiment also provides a manufacturing method of the composite enzyme charcoal bag, which comprises the following steps: soaking the carbon bag in the complex enzyme, drying at-20 ℃, then continuously soaking in the complex enzyme, and repeating the steps for 5 times to obtain the complex enzyme carbon bag.
The preparation materials before manufacturing are as follows:
1. preparing a bucket with about 50 liters, namely a plastic bucket;
2. preparing a gas-packing pump and a gas-explosion pipe;
3. about 25 kg of molasses is prepared, so that the molasses is not available for buying again, and the Taobao is sold.
The basic principle of the complex enzyme is as follows:
The stock solution of the product is prepared from active plant enzymes, can polymerize beneficial microorganism flora, cultivate the formation of a self-cleaning ecological mechanism of a water body, can actively and rapidly perform chemical reactions such as polymerization, substitution, replacement, decomposition and the like with toxic and odorous molecules in the water, changes the original toxic and odorous molecular structure, changes the toxic and odorous molecular structure into nontoxic and odorless molecules, can automatically decompose organic matters, degrade inorganic matters and remove harmful matters, and has obvious purification and deodorization effects.
The stock solution is colorless, odorless, nontoxic, non-irritating, and non-corrosive.
Can remove and decompose toxic and harmful substances (such as COD, BOD, ammonia nitrogen, phosphorus, heavy metals, etc.) in water.
The odor of the odor and the like in the water can be rapidly removed, and bacteria and viruses in the water can be killed.
Has the characteristics of rapid self-propagation, low cost and lasting action effect.
Is an edible all-natural environment-friendly product, and has no adverse effect on the health of human bodies and animals.
The natural plant is extracted, does not contain any chemical substances, and does not cause secondary pollution.
The beneficial effects are that:
1. the method is similar to 'ferment', but the effect is far better than that of ferment, because the complex enzyme in the embodiment is utilized to allocate a large amount of dominant bacteria in the local water source, and the energy supplement (molasses) is carried out on the local bacteria, so the bacteria are very suitable for local use, the rejection and inadaptation are not generated, the working efficiency is extremely high, and the method is not comparable with that of common ferment.
2. When preparing the water source daily, it is preferable to use local water sources such as local tap water and well water, reuse water, and outsourced barreled water.
3. At temperatures below 25 degrees, each time water needs to be warmed, 35-45 degrees being the temperature at which the best microorganisms reproduce.
4. The method is suitable for: highly and moderately contaminated aquaculture industries such as "bullfrog, eel, turtle, tortoise, etc. are also suitable for use in the general aquaculture industry, for example: four big domestic fish, weever, etc.
5. There is no practical case of mariculture, but it is theoretically possible.
6. Taking bullfrog as an example: in the process of breeding bullfrog by using the product, the breeding tail water can be degraded to a safe level within 3-5 days, so that the death rate is greatly reduced, the growth speed is obviously improved, and compared with the bullfrog without using the product, the single weight difference is between 50% and 100%.
7. The method is used for culturing freshwater fishes, so that the effect of hanging water can be obtained in a pond, and the effects of no earthy smell, no fishy smell and the like can be mostly realized.
8. The death rate of the crayfish cultured by the method is far lower than that of the crayfish cultured by the common culture method (dead crayfish is not found by naked eyes), the crayfish individual is obviously improved, and the yield is optimally about 20% -50%.
9. When the freshwater south white shrimps are cultured, the quality is obviously improved.
Example 2
The embodiment also provides an application of the composite enzyme charcoal package prepared based on the composite enzyme charcoal package or the preparation method of the composite enzyme charcoal package in the aspect of raising livestock.
The specific application method and the key points are as follows:
1. About 50 liters of water (depending on the amount of food and feed) is prepared every day, about 4 jin of molasses is added, a 400g of carbon bag is added into the barrel together, the air pump is started to blow out the air, and the air pump is stopped after about 2-3 hours of blowing out the air (the air pump does not have the condition of blowing out the air, and the air pump can not blow out the air, so that the effect is slightly poor). Preferably, the mixture is allowed to stand for more than 8 hours.
2. When the frog is fed, the water in the bucket is firstly used for wetting the feed, and the feed is uniformly scattered in the frog pond, and the problem that not all the feed needs to be mixed with water of complex enzyme can be solved, small parts and small particle materials can be firstly used for uniformly feeding after being wetted, so that all the frog can eat the feed, and then the normal particle feed is fed according to the feed intake. The purpose of the small particles is to give all the frogs the opportunity to eat the complex enzyme, and the large particles are to be full.
3. The superfluous water can be directly and evenly sprayed into the frog pond. Or which frog pond is more polluted, and multiple points can be emphasized.
4. The complex enzyme carbon bag after the explosion needs to be taken out, and can be prevented from being wetted in a clean water container, so that the complex enzyme carbon bag has no special preservation requirement and does not need special cleaning.
5. Each carbon package can handle more than 50 tons of water, and 400g of carbon package has a selling price of 4000 yuan.
Related application test 1
The complex enzyme charcoal pack in this example was used for raising chickens: the composite enzyme charcoal bag is placed in a pre-filter of drinking water, the pre-filter is communicated with a drinking water pipe of a farm, and the temperature of the drinking water is above 15 ℃. Calculation of charcoal pack usage the weight of charcoal pack was calculated according to the weight of water flow rate-cultivated plants as a factor, and in this test 500g of activated charcoal (calculated according to the synthesized weight) was used per 1 ten thousand chickens.
Location: fengshun county, plum, guangdong province, city, pan Tianzhen; quantity: 10000.
The cultivation mode is as follows: rail type cultivation, feed and medicine provided by company
Chickens Miao Di enter the fence five days, and begin to add complex enzymes into the drinking water until the chickens go out of the fence. The staff in the farm feed back that the smell is not basically smelled by the farm, even the smell of chicken manure is not smelled, and as a layer of padding is paved on the ground, the smell similar to the vinasse of which the padding is fermented can only be smelled, the chicken is not obvious, and after 2 months, the fermentation smell is obvious. When the chicks enter the field, the chicks die in batches, after the chicks adapt to the environment, the number of dead chicks is obviously reduced, and when the chicks go out of the field, the number of the chicks is reduced by half compared with the number of the chicks in the upper batch, the death amount of the chicks in the culture batch without adding the complex enzyme is about 500, and the death amount in the test is about 250.
The chicken raising method helps the company to raise chickens, the company distributes various 8000 yuan medicines according to experience when the chickens enter the chickens, but the chicken has better mental condition and no medicine requirement, people only need to afraid of the chicken cold when weather changes, a little medicine is used for preventing the cold, statistics is carried out until the chickens come out at last, the total medicine consumption is about 2400 yuan, and the medicine consumption is saved by 70%.
According to the feedback of the staff of the farm, the chickens are obviously well raised, have sufficient vitality, do not have the condition of dead chickens every day, and can be seen to be more clean and tidy than the chicken feather without feeding the complex enzyme and have vivid cockscomb color by combining with the figure 1.
After the chicken comes out of the fence, the chicken has clear layers, darker chicken skin color and clear viscera, no obvious fishy smell after the chicken is boiled in the white porridge, smooth chicken skin, elastic meat, easy separation of meat and bones, and no obvious peculiar smell even if no scallion and ginger are added.
The development team also found that:
1) The complex enzyme of example 1 can also increase the health level and resistance of hens by adding to the drinking system. As healthy flora is established in the intestinal canal, the escherichia coli is greatly reduced, even a small amount of escherichia coli is discharged, the escherichia coli can be rapidly decomposed, the egg laying efficiency is obviously improved, the egg laying period is prolonged, the egg quality is greatly improved, the egg laying period is prolonged by more than 100 days, the lecithin content in the egg is increased, the cholesterol is reduced by 10%, the egg liquid concentration is increased, the fishy smell is reduced, and the taste is better.
Related application test II
Test time:
2022, 4, 30-2022, 5, 16;
Test site:
chenzhou market horse-trace mountain of Hunan province;
The test content is as follows:
I.e. 400 pigs in the fence, each pig has a weight of about 220-230 jin and about 250 jin when in the fence.
The complex enzyme charcoal pack in this example was used for raising pigs: the composite enzyme charcoal bag is added into drinking water, the temperature of the drinking water is 25-35 ℃, and in order to ensure the accuracy of data, the sanitation of the pig shed is cleaned until the ammonia value of the pig shed is lower than 0.5PPM.
The ammonia gas values were measured daily and the results are shown in table 1.
TABLE 1 variation of Ammonia gas
Time of Ammonia (PPM)
Day 1 9.1
Day 2 8.6
Day 3 7.4
Day 4 5.6
Day 5 3.7
Day 6 2.4
Day 7 1.2
As can be seen from Table 1, the ammonia value was reduced to 1.2PPM on day 7, and the addition of the complex enzyme charcoal bag significantly reduced the ammonia emission value from pigs.
The invention has other beneficial effects:
1) The water quality control device is simple to use and easy to control, has strong adaptability to water quality, water temperature change, and has extremely strong stability, and years of practice shows that the water quality control device can effectively reduce cost and prolong ageing.
2) Different from the common microbial inoculum added with probiotics, the product does not contain any living bacteria in the enzyme state, and ensures that no external flora invades. The development of harmful bacteria is inhibited by culturing a great amount of autologous copies of beneficial bacteria of livestock, so that a long-term stable effect is obtained; a large number of livestock experiments show that after the activated carbon bag is fixed in a container (slow release device) with calculated volume through a livestock water feeding system, drinking water can be purified and harmful substances can be removed in advance, and the water quality is improved; each time water flows, a small amount of complex enzyme is carried away, so that more beneficial bacteria are activated and kept stable in the livestock body.
3) Through culturing healthy flora, the conversion efficiency of the feed can be effectively increased, so that the animal body is easier to digest and absorb, toxin residues in the body are accelerated to be discharged, and the chance of illness is reduced. The increase of the intestinal health level can change the components of the excrement discharged by animals, so that various detection indexes are greatly different, the probability of gastrointestinal problems is reduced, and the intestinal flatulence phenomenon caused by unhealthy flora is obviously reduced.
4) The animal can reduce diseases caused by excessive ammonia absorption, increase energy consumption, and obviously improve hair color and meat quality.
The above-described embodiments of the present invention do not limit the scope of the present invention. Any other corresponding changes and modifications made in accordance with the technical idea of the present invention shall be included in the scope of the claims of the present invention.

Claims (10)

1. A complex enzyme charcoal pack comprising activated carbon and a complex enzyme, wherein the complex enzyme is attached to the activated carbon.
2. The composite enzyme charcoal package according to claim 1, wherein the active carbon has a void ratio of 96% or more, a volume load of 15-16kg BOD 5/m3 ·d, and a specific surface area of 21-24m 2/g.
3. The complex enzyme charcoal package of claim 1, wherein the complex enzyme is a marine organism complex enzyme.
4. The complex enzyme charcoal package according to claim 3, wherein the marine organism complex enzyme comprises two or more of amylase, alkaline phosphatase, aminopeptidase, amyloglucosidase, bromelain, ficin, deoxyribonuclease, matriase, telomerase, and soybean protease.
5. The preparation method of the composite enzyme charcoal bag is characterized by comprising the following steps: soaking the carbon bag in the complex enzyme, then rapidly drying under the condition of freezing, then recovering normal temperature, continuously soaking in the complex enzyme, and repeating the steps for a plurality of times to obtain the complex enzyme carbon bag.
6. The method for producing a composite enzyme charcoal pack according to claim 4, wherein the drying temperature is-20 to-30 ℃.
7. Use of a complex enzyme charcoal package according to any one of claims 1-3 or a complex enzyme charcoal package manufactured by a method of manufacturing a complex enzyme charcoal package according to any one of claims 4-6 in feeding livestock.
8. The use according to claim 7, wherein the complex enzyme charcoal package is added to drinking water.
9. The use according to claim 8, wherein the complex enzyme charcoal package is placed in a prefilter of drinking water, the prefilter is communicated with a drinking water pipe of a farm, and a biological membrane formed by complex enzymes and complex enzymes enters the drinking water of livestock from the prefilter, thereby entering intestinal tracts of the livestock to play a role.
10. The use according to claim 8, wherein the temperature of the drinking water is 15-45 ℃.
CN202410508923.1A 2024-04-24 2024-04-24 Composite enzyme charcoal bag and manufacturing method and application thereof Pending CN118318788A (en)

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Application Number Priority Date Filing Date Title
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Publication Number Publication Date
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